CN109626956A - Buddha's warrior attendant anion glaze Dali stone ceramic tile and preparation method thereof - Google Patents

Buddha's warrior attendant anion glaze Dali stone ceramic tile and preparation method thereof Download PDF

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Publication number
CN109626956A
CN109626956A CN201910088046.6A CN201910088046A CN109626956A CN 109626956 A CN109626956 A CN 109626956A CN 201910088046 A CN201910088046 A CN 201910088046A CN 109626956 A CN109626956 A CN 109626956A
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parts
buddha
ceramic tile
glaze
warrior attendant
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王文进
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Red Bold And Unconstrained Ceramic Co Ltd In Jinjiang City Fujian Province
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Red Bold And Unconstrained Ceramic Co Ltd In Jinjiang City Fujian Province
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Publication of CN109626956A publication Critical patent/CN109626956A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/24Manufacture of porcelain or white ware
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite

Abstract

Present invention relates particularly to a kind of Buddha's warrior attendant anion glaze Dali stone ceramic tiles and preparation method thereof, belong to technical field of tile production.Buddha's warrior attendant anion glaze Dali stone ceramic tile includes green body, overglaze and throws glaze, and the green body includes the following component according to mass fraction meter: washing 10-20 parts of soil, 2-9 parts of kaolin, black earth 1-5 parts of ZhangZhou, clay 5-10 parts of Zhangpu, 1-5 parts of bentonite, carclazyte 2-10 parts of Guangdong, carclazyte 2-9 parts of ZhangZhou, 1-7 parts of bauxite, 20-25 parts of potassium feldspar, 15-25 parts of albite.Buddha's warrior attendant anion glaze Dali stone ceramic tile produced by the present invention have preferable wear-resisting property, the pattern of ceramic tile obtained is more three-dimensional, marble dare it is true to nature, have good decorative effect.

Description

Buddha's warrior attendant anion glaze Dali stone ceramic tile and preparation method thereof
Technical field
The invention belongs to technical field of tile production, and in particular to a kind of Buddha's warrior attendant anion glaze Dali stone ceramic tile and its preparation Method.
Background technique
Dali stone ceramic tile is gained the name because being exactly like marble in appearance, is widely used in room due to preferable decorative effect In inside and outside metope, ground decoration.Buddha's warrior attendant glaze Dali stone ceramic tile imparts the hard physical property of Dali stone ceramic tile diamond-like, because This Buddha's warrior attendant glaze Dali stone ceramic tile has excellent wearability, impact strength and lower water absorption rate.
Though Buddha's warrior attendant glaze Dali stone ceramic tile has preferable performance and preferably decorative effect, anti-fouling effect and antibacterial effect Fruit is still barely satisfactory, while because Buddha's warrior attendant glaze Dali stone ceramic tile is stringenter to formula and manufacture craft requirement, if formula ingredient and work Skill setting is improper to be easy to cause glaze to generate defect or cause Buddha's warrior attendant glaze performance not up to standard, therefore to Buddha's warrior attendant anion glaze marble The research of ceramic tile is just particularly important.
Therefore recycling and reusing research is carried out to monazite tailings, it has also become technical problem instantly urgently to be resolved.
Summary of the invention
There is provided the purpose of the present invention is overcome the deficiencies in the prior art a kind of Buddha's warrior attendant anion glaze Dali stone ceramic tile and its Preparation method, which has excellent wear-resisting scratch resistance, and has stronger crystalistic sense, Dali Stone sense is true to nature.
The present invention adopts the following technical scheme:
Buddha's warrior attendant anion glaze Dali stone ceramic tile, including green body, overglaze and throwing glaze, the green body includes according to mass fraction meter Following component: washing 10-20 parts of soil, 2-9 parts of kaolin, black earth 1-5 parts of ZhangZhou, clay 5-10 parts of Zhangpu, bentonite 1-5 Part, carclazyte 2-10 parts of Guangdong, carclazyte 2-9 parts of ZhangZhou, 1-7 parts of bauxite, 20-25 parts of potassium feldspar, 15-25 parts of albite;
The overglaze includes the following component according to mass fraction meter: 15-25 parts of potassium feldspar, 15-25 parts of albite, quartz 15-20 parts, washing 5-10 parts of soil, 10-20 parts of nepheline, 15-25 parts of aluminium oxide, 3-5 parts of tourmaline powder;
The glaze of throwing includes the following component according to mass fraction meter: 15-25 parts of potassium feldspar, 15-25 parts of albite, washing 5-10 parts native, 3-8 parts of zinc oxide, 10-15 parts of talcum, 4-8 parts of corundum, 10-15 parts of barium carbonate, 5-15 parts of dolomite, quartz 2-8 Part.
The present invention also provides the production methods of the Buddha's warrior attendant anion glaze Dali stone ceramic tile, and steps are as follows:
Step 1: by the green body each component, mixing and water adding carries out ball milling, discharging according to the proportion;
Step 2: the slurry after discharging is crossed into 60-80 mesh, and after except iron, is stored spare;
Step 3: slurry is sieved, and dry to water content 7.5-8.0%, obtains powder, powder is delivered to through magnetic separator de-ironing The middle roll-over of mixing system, mixing system match colorant according to required color pattern;
Step 4: each colorant is arranged into marble pattern with material distributing machine after the completion of ingredient, compression moulding is dried, drying After remove surface dust, obtain first product;
Step 5: overglaze and throwing glaze are adjusted respectively according to the proportion of the overglaze and throwing glaze, and according to actual needs Match, after the completion of allotment, sprays water on first product surface, then drench overglaze, and printed through printing of inkjet printer pattern, then drying, roller Glaze is thrown in flower, leaching, is burnt into get Buddha's warrior attendant anion glaze Dali stone ceramic tile.
Further, Ball-milling Time described in step 1 is 12-14h, and the water that when ball milling is added is the 34% of blank, It was milled to the material accounting 1.0%-1.5% of 250 meshes.
Further, the slurry specific gravity after discharging described in step 1 is 1.68-1.74g/cm3, water content 32.5- 36%.
Further, sieving described in step 3 was 80 meshes.
Further, the grain composition of powder described in step 3 are as follows: 20 mesh < 1.5%, 40 mesh: 36%-48%, 60 Mesh: 30%-40%, 80 mesh: 6%-12%, 100 mesh: 4%-8%, fine powder < 3.0%.
Further, firing temperature described in step 5 is 1180 DEG C, and time when firing is 60min.
Compared with the prior art, the present invention has the following beneficial effects:
Buddha's warrior attendant anion glaze Dali stone ceramic tile produced by the present invention has excellent wear-resisting property and lower water absorbing properties, Also has the effect of environment purification simultaneously, the pattern of ceramic tile made from the method according to the invention is more three-dimensional, and marbling effect is more It is true to nature, there is good decorative effect.
Specific embodiment
Below by specific embodiment, invention is further described in detail, but those skilled in the art will manage Solution, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.
Embodiment 1
Buddha's warrior attendant anion glaze Dali stone ceramic tile, including green body, overglaze and throwing glaze, the green body includes according to mass fraction meter Following component: wash native 15 parts, 5 parts of kaolin, 3 parts of ZhangZhou black earth, 7 parts of Zhangpu clay, 3 parts of bentonite, Guangdong carclazyte 6 Part, 5 parts of ZhangZhou carclazyte, 4 parts of bauxite, 22 parts of potassium feldspar, 20 parts of albite;
The overglaze includes the following component according to mass fraction meter: 20 parts of potassium feldspar, 20 parts of albite, quartz 17 parts, Wash native 7 parts, 15 parts of nepheline, 20 parts of aluminium oxide, 4 parts of tourmaline powder;
The glaze of throwing includes following component according to mass fraction meter: 20 parts of potassium feldspar, 20 parts of albite, 7 parts of washing soil, 5 parts of zinc oxide, 12 parts of talcum, 6 parts of corundum, 12 parts of barium carbonate, 10 parts of dolomite, 6 parts of quartz.
The present invention also provides the production methods of the Buddha's warrior attendant anion glaze Dali stone ceramic tile, and steps are as follows:
Step 1: the green body each component is sent into ball milling workshop according to the proportion, ball milling workshop is accurately matched according to formula is single Material, it is desirable that every kind of raw material error is ± 20kg, and the water for ball milling 12-14h of blank total amount 34% is added, was milled to 250 meshes Material accounting 1.0%-1.5%, discharging, slurry specific gravity are 1.70g/cm3, water content 35%;
Step 2: crossing 70 meshes for the qualified slurry after discharging, and after except iron, is evacuated in 600 tons of bucket (every 600 tons are a batch, in order to steady production materials) storage is spare, storage is logical fill after, through detecting, after qualified, enter Flouring technology;
Step 3: crossing 80 meshes for qualified slurry, and send to drying tower (drying tower yield be 37 tons of hourly output) into Row drying, it is dry to water content 7.8%, obtain powder, the grain composition of the powder are as follows: 20 mesh < 1.5%, 40 mesh: 36%- 48%, 60 mesh: 30%-40%, 80 mesh: 6%-12%, 100 mesh: 4%-8%, fine powder < 3.0%.Powder is stored to powder (there are 65 tons of storehouses and 90 tons of storehouses in storehouse), by powder through rolling muscle and magnetic separator de-ironing is delivered to the middle roll-over of mixing system, mixing system according to Required color pattern matches colorant, such as: yellow entire body marble, the storehouse A: pale yellow colorant, the storehouse B: white material, the storehouse C: white material, the storehouse D: deep Lines material;
The pale yellow colorant distribution in the storehouse A: adding the orange colorant of 0.4wt% with white material, and shrink has colorant to be both needed to claim through flow Accurate feed proportioning, each 1000kg are stirred through roller positive and negative rotation, continuously send the small feed bin to press;
B, the white material in the storehouse C: the white material in basis directly claims through flow, and roller positive and negative rotation stirring is sent to small feed bin;
The storehouse D depth lines material: add the orange colorant of 1.0wt%, 0.7wt% coral colorant with white material, accurate feed proportioning is sent to small Feed bin.
Step 4: use after the completion of ingredient multitube material distributing machine according to the white material of No. 1 24wt%, No. 2 bucket 10wt% depth lines material, No. 3 white material of bucket 24wt%, No. 4 pale yellow colorants of bucket 18wt%, No. 5 white material of bucket 24wt%, cloth are pressed at parian pattern Type dries kiln drying into multilayer, removes surface dust through mill blank machine after drying, obtain first product;
Step 5: overglaze and throwing glaze are adjusted respectively according to the proportion of the overglaze and throwing glaze, and according to actual needs Match, after the completion of allotment, sprays water on first product surface, then drench overglaze, and printed through printing of inkjet printer pattern, then drying, roller Glaze is thrown in flower, leaching, is burnt into 60min at 1180 DEG C to get Buddha's warrior attendant anion glaze Dali stone ceramic tile.
Embodiment 2
Buddha's warrior attendant anion glaze Dali stone ceramic tile, including green body, overglaze and throwing glaze, the green body includes according to mass fraction meter Following component: wash native 10 parts, 2 parts of kaolin, 1 part of ZhangZhou black earth, 5 parts of Zhangpu clay, 1 part of bentonite, Guangdong carclazyte 2 Part, 2 parts of ZhangZhou carclazyte, 1 part of bauxite, 20 parts of potassium feldspar, 15 parts of albite;
The overglaze includes the following component according to mass fraction meter: 15 parts of potassium feldspar, 15 parts of albite, quartz 15 parts, Wash native 5 parts, 10 parts of nepheline, 15 parts of aluminium oxide, 3 parts of tourmaline powder;
The glaze of throwing includes following component according to mass fraction meter: 15 parts of potassium feldspar, 15 parts of albite, 5 parts of washing soil, 3 parts of zinc oxide, 10 parts of talcum, 4 parts of corundum, 10 parts of barium carbonate, 5 parts of dolomite, 2 parts of quartz.
The present invention also provides the production methods of the Buddha's warrior attendant anion glaze Dali stone ceramic tile, and steps are as follows:
Step 1: the green body each component is sent into ball milling workshop according to the proportion, ball milling workshop is accurately matched according to formula is single Material, it is desirable that every kind of raw material error is ± 20kg, and the water for ball milling 12-14h of blank total amount 34% is added, was milled to 250 meshes Material accounting 1.0%-1.5%, discharging, slurry specific gravity are 1.68g/cm3, water content 32.5%;
Step 2: crossing 60 meshes for the qualified slurry after discharging, and after except iron, is evacuated in 600 tons of bucket (every 600 tons are a batch, in order to steady production materials) storage is spare, storage is logical fill after, through detecting, after qualified, enter Flouring technology;
Step 3: crossing 80 meshes for qualified slurry, and send to drying tower (drying tower yield be 37 tons of hourly output) into Row drying, it is dry to water content 7.5%, obtain powder, the grain composition of the powder are as follows: 20 mesh < 1.5%, 40 mesh: 36%- 48%, 60 mesh: 30%-40%, 80 mesh: 6%-12%, 100 mesh: 4%-8%, fine powder < 3.0%.Powder is stored to powder (there are 65 tons of storehouses and 90 tons of storehouses in storehouse), by powder through rolling muscle and magnetic separator de-ironing is delivered to the middle roll-over of mixing system, mixing system according to Required color pattern matches colorant, such as: yellow entire body marble, the storehouse A: pale yellow colorant, the storehouse B: white material, the storehouse C: white material, the storehouse D: deep Lines material;
The pale yellow colorant distribution in the storehouse A: adding the orange colorant of 0.4wt% with white material, and shrink has colorant to be both needed to claim through flow Accurate feed proportioning, each 1000kg are stirred through roller positive and negative rotation, continuously send the small feed bin to press;
B, the white material in the storehouse C: the white material in basis directly claims through flow, and roller positive and negative rotation stirring is sent to small feed bin;
The storehouse D depth lines material: add the orange colorant of 1.0wt%, 0.7wt% coral colorant with white material, accurate feed proportioning is sent to small Feed bin.
Step 4: use after the completion of ingredient multitube material distributing machine according to the white material of No. 1 24wt%, No. 2 bucket 10wt% depth lines material, No. 3 white material of bucket 24wt%, No. 4 pale yellow colorants of bucket 18wt%, No. 5 white material of bucket 24wt%, cloth are pressed at parian pattern Type dries kiln drying into multilayer, removes surface dust through mill blank machine after drying, obtain first product;
Step 5: overglaze and throwing glaze are adjusted respectively according to the proportion of the overglaze and throwing glaze, and according to actual needs Match, after the completion of allotment, sprays water on first product surface, then drench overglaze, and printed through printing of inkjet printer pattern, then drying, roller Glaze is thrown in flower, leaching, is burnt into 60min at 1180 DEG C to get Buddha's warrior attendant anion glaze Dali stone ceramic tile.
Embodiment 3
Buddha's warrior attendant anion glaze Dali stone ceramic tile, including green body, overglaze and throwing glaze, the green body includes according to mass fraction meter Following component: wash native 20 parts, 9 parts of kaolin, 5 parts of ZhangZhou black earth, 10 parts of Zhangpu clay, 5 parts of bentonite, Guangdong carclazyte 10 Part, 9 parts of ZhangZhou carclazyte, 7 parts of bauxite, 25 parts of potassium feldspar, 25 parts of albite;
The overglaze includes the following component according to mass fraction meter: 25 parts of potassium feldspar, 25 parts of albite, quartz 20 parts, Wash native 10 parts, 20 parts of nepheline, 25 parts of aluminium oxide, 5 parts of tourmaline powder;
The glaze of throwing includes the following component according to mass fraction meter: 25 parts of potassium feldspar, 25 parts of albite, washing soil 10 Part, 8 parts of zinc oxide, 15 parts of talcum, 8 parts of corundum, 15 parts of barium carbonate, 15 parts of dolomite, 8 parts of quartz.
The present invention also provides the production methods of the Buddha's warrior attendant anion glaze Dali stone ceramic tile, and steps are as follows:
Step 1: the green body each component is sent into ball milling workshop according to the proportion, ball milling workshop is accurately matched according to formula is single Material, it is desirable that every kind of raw material error is ± 20kg, and the water for ball milling 12-14h of blank total amount 34% is added, was milled to 250 meshes Material accounting 1.0%-1.5%, discharging, slurry specific gravity are 1.74g/cm3, water content 36%;
Step 2: crossing 80 meshes for the qualified slurry after discharging, and after except iron, is evacuated in 600 tons of bucket (every 600 tons are a batch, in order to steady production materials) storage is spare, storage is logical fill after, through detecting, after qualified, enter Flouring technology;
Step 3: crossing 80 meshes for qualified slurry, and send to drying tower (drying tower yield be 37 tons of hourly output) into Row drying, it is dry to water content 8.0%, obtain powder, the grain composition of the powder are as follows: 20 mesh < 1.5%, 40 mesh: 36%- 48%, 60 mesh: 30%-40%, 80 mesh: 6%-12%, 100 mesh: 4%-8%, fine powder < 3.0%.Powder is stored to powder (there are 65 tons of storehouses and 90 tons of storehouses in storehouse), by powder through rolling muscle and magnetic separator de-ironing is delivered to the middle roll-over of mixing system, mixing system according to Required color pattern matches colorant, such as: yellow entire body marble, the storehouse A: pale yellow colorant, the storehouse B: white material, the storehouse C: white material, the storehouse D: deep Lines material;
The pale yellow colorant distribution in the storehouse A: adding the orange colorant of 0.4wt% with white material, and shrink has colorant to be both needed to claim through flow Accurate feed proportioning, each 1000kg are stirred through roller positive and negative rotation, continuously send the small feed bin to press;
B, the white material in the storehouse C: the white material in basis directly claims through flow, and roller positive and negative rotation stirring is sent to small feed bin;
The storehouse D depth lines material: add the orange colorant of 1.0wt%, 0.7wt% coral colorant with white material, accurate feed proportioning is sent to small Feed bin.
Step 4: use after the completion of ingredient multitube material distributing machine according to the white material of No. 1 24wt%, No. 2 bucket 10wt% depth lines material, No. 3 white material of bucket 24wt%, No. 4 pale yellow colorants of bucket 18wt%, No. 5 white material of bucket 24wt%, cloth are pressed at parian pattern Type dries kiln drying into multilayer, removes surface dust through mill blank machine after drying, obtain first product;
Step 5: overglaze and throwing glaze are adjusted respectively according to the proportion of the overglaze and throwing glaze, and according to actual needs Match, after the completion of allotment, sprays water on first product surface, then drench overglaze, and printed through printing of inkjet printer pattern, then drying, roller Glaze is thrown in flower, leaching, is burnt into 60min at 1180 DEG C to get Buddha's warrior attendant anion glaze Dali stone ceramic tile.
The test of formaldehyde removal rate, sample specification are carried out to Buddha's warrior attendant anion glaze Dali stone ceramic tile made from embodiment 1 800mm multiplies 800mm, thickness 10.8mm.Wherein, formaldehyde removal rate is detected according to JC/T 1074-2008, as a result such as the following table 1 It is shown;
1 formaldehyde removal rate test result of table
Wearability and water absorption rate test, table are carried out respectively to Buddha's warrior attendant anion glaze Dali stone ceramic tile made from embodiment 1 to 3 Face Mohs' hardness (evaluation wearability) is tested according to JC/T 665-1997 appendix A, and water absorption rate is according to GB/T3810.1- 2006 are tested, as a result as shown in table 2 below:
2 wearability test result of table
Test item Embodiment 1 Embodiment 2 Embodiment 3
Water absorption rate, % 0.01 0.02 0.01
Surface Mohs' hardness, grade 8 8 8
The basic principles and main features and advantages of the present invention of the invention have been shown and described above, the industry For technical staff it should be appreciated that the present invention is not limited to the above embodiments, what is described in the above embodiment and the description is only say Bright the principle of the present invention, under the premise of not departing from the inventive spirit of the present invention and range, the present invention also has various change and changes Into these changes and improvements all fall within the protetion scope of the claimed invention, and the claimed scope of the invention is by appended right Claim and its equivalent thereof.

Claims (7)

1. Buddha's warrior attendant anion glaze Dali stone ceramic tile, including green body, overglaze and throw glaze, which is characterized in that the green body include according to The following component of mass fraction meter: washing 10-20 parts of soil, 2-9 parts of kaolin, black earth 1-5 parts of ZhangZhou, clay 5-10 parts of Zhangpu, 1-5 parts of bentonite, carclazyte 2-10 parts of Guangdong, carclazyte 2-9 parts of ZhangZhou, 1-7 parts of bauxite, 20-25 parts of potassium feldspar, albite 15- 25 parts;
The overglaze includes the following component according to mass fraction meter: 15-25 parts of potassium feldspar, 15-25 parts of albite, quartz 15- 20 parts, washing 5-10 parts of soil, 10-20 parts of nepheline, 15-25 parts of aluminium oxide, 3-5 parts of tourmaline powder;
The glaze of throwing includes the following component according to mass fraction meter: 15-25 parts of potassium feldspar, 15-25 parts of albite, washing soil 5- 10 parts, 3-8 parts of zinc oxide, 10-15 parts of talcum, 4-8 parts of corundum, 10-15 parts of barium carbonate, 5-15 parts of dolomite, 2-8 parts of quartz.
2. the production method of Buddha's warrior attendant anion glaze Dali described in claim 1 stone ceramic tile, which is characterized in that steps are as follows:
Step 1: by the green body each component, mixing and water adding carries out ball milling, discharging according to the proportion;
Step 2: the slurry after discharging is crossed into 60-80 mesh, and after except iron, is stored spare;
Step 3: slurry is sieved, and dry to water content 7.5-8.0%, obtains powder, powder is delivered to spice through magnetic separator de-ironing The middle roll-over of system, mixing system match colorant according to required color pattern;
Step 4: each colorant is arranged into marble pattern, compression moulding with material distributing machine after the completion of ingredient, drying removes after drying Surface dust is removed, first product is obtained;
Step 5: overglaze and throwing glaze are deployed respectively according to the proportion of the overglaze and throwing glaze, and according to actual needs, adjusted It with after the completion, sprays water on first product surface, then drench overglaze, and through print pattern, then drying, roller printing, leaching throwing glaze, through burning At to get Buddha's warrior attendant anion glaze Dali stone ceramic tile.
3. the production method of Buddha's warrior attendant anion glaze Dali according to claim 2 stone ceramic tile, which is characterized in that in step 1 The Ball-milling Time is 12-14h, and the water that when ball milling is added is the 34% of blank, is milled to the material accounting of 250 meshes 1.0%-1.5%。
4. the production method of Buddha's warrior attendant anion glaze Dali according to claim 2 stone ceramic tile, which is characterized in that in step 1 Slurry specific gravity after the discharging is 1.68-1.74g/cm3, water content 32.5-36%.
5. the production method of Buddha's warrior attendant anion glaze Dali according to claim 2 stone ceramic tile, which is characterized in that in step 3 The sieving was 80 meshes.
6. the production method of Buddha's warrior attendant anion glaze Dali according to claim 2 stone ceramic tile, which is characterized in that in step 3 The grain composition of the powder are as follows: 20 mesh < 1.5%, 40 mesh: 36%-48%, 60 mesh: 30%-40%, 80 mesh: 6%-12%, 100 mesh: 4%-8%, fine powder < 3.0%.
7. the production method of Buddha's warrior attendant anion glaze Dali according to claim 2 stone ceramic tile, which is characterized in that in step 5 The firing temperature is 1180 DEG C, and time when firing is 60min.
CN201910088046.6A 2019-01-29 2019-01-29 Buddha's warrior attendant anion glaze Dali stone ceramic tile and preparation method thereof Pending CN109626956A (en)

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