CN109605891A - A kind of food packaging antifog film - Google Patents

A kind of food packaging antifog film Download PDF

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Publication number
CN109605891A
CN109605891A CN201811637476.0A CN201811637476A CN109605891A CN 109605891 A CN109605891 A CN 109605891A CN 201811637476 A CN201811637476 A CN 201811637476A CN 109605891 A CN109605891 A CN 109605891A
Authority
CN
China
Prior art keywords
layer
antifog
polyethylene
nylon
food packaging
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811637476.0A
Other languages
Chinese (zh)
Inventor
华永芬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Pacific New Material Co Ltd
Original Assignee
Wuxi Pacific New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Pacific New Material Co Ltd filed Critical Wuxi Pacific New Material Co Ltd
Priority to CN201811637476.0A priority Critical patent/CN109605891A/en
Publication of CN109605891A publication Critical patent/CN109605891A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/40Applications of laminates for particular packaging purposes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2553/00Packaging equipment or accessories not otherwise provided for

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Wrappers (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of food packaging antifog film, the antifog film is divided into outer layer, middle layer and internal layer from outside to inside, and the outer layer is made of the stacking of 2-6 layer film, and the middle layer is barrier layer, and the internal layer is made of the stacking of 2-6 layer film.The present invention is by using multilayered structure, good antifogging effect and stabilization, it can be cold and hot antifog, using transparent polyethylene (PE) layer, binder resin (Tie), nylon (PA) layer and ethylene-vinyl alcohol copolymer (EVOH) layer, so that the transparency of antifog film of the invention is high, with good antipollution effect, long shelf-life is used.

Description

A kind of food packaging antifog film
Technical field
The present invention relates to co-extrusion technical field of membrane, in particular to a kind of food packaging antifog film.
Background technique
With the development of world economy, people's lives tempo increase, shopping-time is short, will generally carry out one weekly and arrive Big buying twice, and due to time and the division of labor in society are meticulous typically purchases veterinary antibiotics, sushi, cold in supermarket Fresh meat etc., these food are then refrigerated and are sold into supermarket first by fresh clean, processing, packaging by food provider.By In fresh commodity such as veterinary antibiotics, cold fresh meat classes during transport, refrigeration and sale, temperature inside and outside packaging bag and The temperature difference changes repeatedly, and these fresh commodity contained humidities are larger, if do not use antifog film, easily in bag generate mist and Steam.Water mist can be generated first, so that consumer is can't see the fresh commodity in bag, then these water mists produce biggish water again Drop, and these water droplets can make these fresh commodity rotten quickly after contacting the fresh commodity such as veterinary antibiotics or cold fresh meat class Lose, this objectively require packaging transparency to get well, it is anti-fog properties to get well, illustrative will be got well, the shelf-life to grow and safety It is better.Now in the market, many antifog films can not meet these requirements simultaneously.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of food packaging antifog films that can be used for food packaging.
In order to solve the above-mentioned technical problem, the technical solution of the present invention is as follows:
A kind of food packaging antifog film, the antifog film are divided into outer layer, middle layer and internal layer from outside to inside, the outer layer by 2-6 layer film stacking composition, the middle layer are barrier layer, and the internal layer is made of the stacking of 2-6 layer film.
Preferably, the outer layer is formed by nylon (PA) layer or polyethylene (PE) layer stackup, nylon (PA) layer or poly- Ethylene (PE) layer passes through binder resin (Tie) between layers and is attached.
Preferably, the middle layer is at least one of nylon (PA) or ethylene-vinyl alcohol copolymer (EVOH).
Preferably, the internal layer is formed by polyethylene (PE) layer stackup.
Preferably, nylon (PA) layer is the mixture of homopolymerization nylon and amorphous nylons copolymer, wherein the nothing Sizing nylon copolymer accounts for the 5-30% of the mixture;Polyethylene (PE) layer is low density polyethylene (LDPE) and linea low density The mixture of polyethylene, wherein the weight of low density polyethylene (LDPE) and linear low density polyethylene is 1:1-1:2.
Preferably, nylon (PA) layer is homopolymerization nylon;Polyethylene (PE) layer is for low density polyethylene (LDPE) and linearly The weight of the mixture of low density polyethylene (LDPE), the low density polyethylene (LDPE) and linear low density polyethylene is 1:1-1:2.
Preferably, polyethylene (PE) layer of innermost layer is the first antifog modified poly ethylene in the stepped construction of the internal layer (PE) layer, first antifog modified poly ethylene (PE) layer contain modified antifog polyvinyl resin and POP resin.
Preferably, polyethylene (PE) layer of secondary internal layer is the second antifog modified poly ethylene in the stepped construction of the internal layer (PE) layer contains modified antifog polyvinyl resin in second antifog modified poly ethylene (PE) layer.
Preferably, the structure composition of the antifog film is from outside to inside successively are as follows: nylon (PA) layer/binder resin (Tie)/poly- Ethylene (PE) layer/binder resin (Tie)/nylon (PA) layer/ethylene-vinyl alcohol copolymer (EVOH)/nylon (PA) layer/bonding tree Nine layers of structure of rouge (Tie)/first antifog modified poly ethylene (PE) layer, the antifog film is with a thickness of 50-150 μm.
Preferably, the structure composition of the antifog film is from outside to inside successively are as follows: and polyethylene (PE) layer/binder resin (Tie)/ Nylon (PA) layer/ethylene-vinyl alcohol copolymer (the EVOH)/poly- second of nylon (PA) layer/binder resin (Tie)/second antifog modification Nine layers of structure of alkene (PE) layer/binder resin (Tie)/first antifog modified poly ethylene (PE) layer, the antifog film is with a thickness of 50- 150μm。
By adopting the above technical scheme, can be cold and hot antifog by using multilayered structure, good antifogging effect and stabilization, it uses Transparent polyethylene (PE) layer, binder resin (Tie), nylon (PA) layer and ethylene-vinyl alcohol copolymer (EVOH) layer, so that this The transparency of the antifog film of invention is high, has good antipollution effect, uses long shelf-life.
Detailed description of the invention
Fig. 1 is a kind of schematic diagram of structure of the invention;
Fig. 2 is the schematic diagram of another structure of the invention.
In figure, 1- outer layer, the middle layer 2-, 3- internal layer.
Specific embodiment
Specific embodiments of the present invention will be further explained with reference to the accompanying drawing.It should be noted that for The explanation of these embodiments is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, disclosed below The each embodiment of the present invention involved in technical characteristic can be combined with each other as long as they do not conflict with each other.
Embodiment 1
As shown in Figure 1, a kind of food packaging antifog film, including outer layer 1, middle layer 2 and internal layer 3;The outer layer 1 is by nylon (PA) layer or polyethylene (PE) layer stackup form, and nylon (PA) layer is the mixing of homopolymerization nylon and amorphous nylons copolymer Object, wherein the amorphous nylons copolymer accounts for the 5-30% of the mixture,;Polyethylene (PE) layer is low density polyethylene The mixture of alkene and linear low density polyethylene, wherein the weight of low density polyethylene (LDPE) and linear low density polyethylene For 1:1-1:2;Nylon (PA) layer or polyethylene (PE) layer pass through binder resin (Tie) between layers and are attached;
The middle layer 2 is at least one of nylon (PA) or ethylene-vinyl alcohol copolymer (EVOH);
The internal layer 3 is formed by polyethylene (PE) layer stackup, wherein polyethylene (PE) layer of innermost layer is first antifog to change Property polyethylene (PE) layer, first antifog modified poly ethylene (PE) layer contains modified antifog polyvinyl resin and POP resin;This The specific structure of the antifog film of invention forms from outside to inside successively are as follows: nylon (PA) layer/binder resin (Tie)/polyethylene (PE) Layer/binder resin (Tie)/nylon (PA) layer/ethylene-vinyl alcohol copolymer (EVOH)/nylon (PA) layer/binder resin (Tie)/ Nine layers of structure of the first antifog modified poly ethylene (PE) layer, the antifog film is with a thickness of 50-150 μm.
Embodiment 2
As shown in Fig. 2, a kind of food packaging antifog film, including outer layer 1, middle layer 2 and internal layer 3;
The outer layer 1 is formed by nylon (PA) layer stackup, and nylon (PA) layer is homopolymerization nylon;The polyethylene (PE) Layer is the mixture of low density polyethylene (LDPE) and linear low density polyethylene, the low density polyethylene (LDPE) and linear low density polyethylene Weight be 1:1-1:2;Nylon (PA) layer or polyethylene (PE) layer pass through binder resin (Tie) between layers It is attached;
The middle layer 2 is at least one of nylon (PA) or ethylene-vinyl alcohol copolymer (EVOH);
The internal layer 3 is formed by polyethylene (PE) layer stackup, wherein polyethylene (PE) layer of innermost layer is first antifog to change Property polyethylene (PE) layer, first antifog modified poly ethylene (PE) layer contains modified antifog polyvinyl resin and POP resin, secondary Polyethylene (PE) layer of internal layer is the second antifog modified poly ethylene (PE) layer, is contained in second antifog modified poly ethylene (PE) layer There is modified antifog polyvinyl resin;The specific structure of antifog film of the invention forms from outside to inside successively are as follows: and polyethylene (PE) layer/ Binder resin (Tie)/nylon (PA) layer/ethylene-vinyl alcohol copolymer (EVOH)/nylon (PA) layer/binder resin (Tie)/the Nine layers of structure of two antifog modified poly ethylene (PE) layer/binder resin (Tie)/first antifog modified poly ethylene (PE) layers, it is described Antifog film is with a thickness of 50-150 μm.
Using the above structure, it is tested at 135 DEG C, the heat seal strength of the antifog film is 30N/15mm, and oxygen is saturating Excessive (OTR)≤5cc*24h.Antifog film of the invention uses multilayered structure, good antifogging effect and stabilization, can be cold and hot antifog, Using transparent polyethylene (PE) layer, binder resin (Tie) nylon (PA) layer and ethylene-vinyl alcohol copolymer (EVOH)
Layer has good antipollution effect, uses long shelf-life so that the transparency of antifog film of the invention is high.
In conjunction with attached drawing, the embodiments of the present invention are described in detail above, but the present invention is not limited to described implementations Mode.For a person skilled in the art, in the case where not departing from the principle of the invention and spirit, to these embodiments A variety of change, modification, replacement and modification are carried out, are still fallen in protection scope of the present invention.

Claims (10)

1. a kind of food packaging antifog film, it is characterised in that: the antifog film be divided into from outside to inside outer layer (1), middle layer (2) and Internal layer (3), the outer layer (1) are made of the stacking of 2-6 layer film, and the middle layer (2) is barrier layer, and the internal layer (3) is by 2-6 layers Film layer is stacked.
2. food packaging antifog film according to claim 1, it is characterised in that: the outer layer (1) is by nylon (PA) layer Or polyethylene (PE) layer stackup forms, nylon (PA) layer or polyethylene (PE) layer pass through binder resin between layers (Tie) it is attached.
3. food packaging antifog film according to claim 1, it is characterised in that: the middle layer (2) be nylon (PA) or At least one of ethylene-vinyl alcohol copolymer (EVOH).
4. food packaging antifog film according to claim 1, it is characterised in that: the internal layer (3) is by polyethylene (PE) Layer stackup forms.
5. food packaging antifog film according to claim 2, it is characterised in that: nylon (PA) layer is homopolymerization nylon With the mixture of amorphous nylons copolymer, wherein the amorphous nylons copolymer accounts for the 5-30% of the mixture;It is described Polyethylene (PE) layer is the mixture of low density polyethylene (LDPE) and linear low density polyethylene, wherein low density polyethylene (LDPE) and linear The weight of low density polyethylene (LDPE) is 1:1-1:2.
6. food packaging antifog film according to claim 2, it is characterised in that: nylon (PA) layer is homopolymerization Buddhist nun Dragon;Polyethylene (PE) layer is the mixture of low density polyethylene (LDPE) and linear low density polyethylene, the low density polyethylene (LDPE) Weight with linear low density polyethylene is 1:1-1:2.
7. food packaging antifog film according to claim 4, it is characterised in that: in the stepped construction of the internal layer (3) Polyethylene (PE) layer of innermost layer is the first antifog modified poly ethylene (PE) layer, and first antifog modified poly ethylene (PE) layer contains There are modified antifog polyvinyl resin and POP resin.
8. food packaging antifog film according to claim 4, it is characterised in that: in the stepped construction of the internal layer (3) Polyethylene (PE) layer of secondary internal layer is the second antifog modified poly ethylene (PE) layer, in second antifog modified poly ethylene (PE) layer Contain the antifog polyvinyl resin of modification.
9. food packaging antifog film according to claim 1, it is characterised in that: the structure composition of the antifog film is from outer To it is interior successively are as follows: nylon (PA) layer/binder resin (Tie)/polyethylene (PE) layer/binder resin (Tie)/nylon (PA) layer/second Nine layers of alkene-ethenol copolymer (EVOH)/nylon (PA) layer/binder resin (Tie)/first antifog modified poly ethylene (PE) layer Structure, the antifog film is with a thickness of 50-150 μm.
10. food packaging antifog film according to claim 1, it is characterised in that: the structure composition of the antifog film from Outside successively in are as follows: polyethylene (PE) layer/binder resin (Tie)/nylon (PA) layer/ethylene-vinyl alcohol copolymer (EVOH)/Buddhist nun Imperial (PA) layer/binder resin (Tie)/second antifog modified poly ethylene (PE) layer/binder resin (Tie)/first antifog modification is poly- Nine layers of structure of ethylene (PE) layer, the antifog film is with a thickness of 50-150 μm.
CN201811637476.0A 2018-12-29 2018-12-29 A kind of food packaging antifog film Pending CN109605891A (en)

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Application Number Priority Date Filing Date Title
CN201811637476.0A CN109605891A (en) 2018-12-29 2018-12-29 A kind of food packaging antifog film

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Application Number Priority Date Filing Date Title
CN201811637476.0A CN109605891A (en) 2018-12-29 2018-12-29 A kind of food packaging antifog film

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110982158A (en) * 2019-10-23 2020-04-10 江阴市德惠热收缩包装材料有限公司 Membrane and method of making the same
US20230347630A1 (en) * 2020-04-07 2023-11-02 Sofresh, Inc. Laminated film materials and processes for manufacturing thereof and uses thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202283804U (en) * 2011-10-24 2012-06-27 上海唐科新型包装材料有限公司 Anti-fog barrier film
CN104476753A (en) * 2014-11-25 2015-04-01 朝阳佛瑞达科技有限公司 Multilayer co-extrusion high-barrier film and preparation method thereof
CN107856375A (en) * 2017-10-25 2018-03-30 无锡市太平洋新材料股份有限公司 A kind of boiling film for packaging for foodstuff
CN107891643A (en) * 2017-10-25 2018-04-10 无锡市太平洋新材料股份有限公司 A kind of easily tore film for packaging for foodstuff
CN207345171U (en) * 2017-10-19 2018-05-11 江阴升辉包装材料有限公司 A kind of heat shrink films suitable for the automatic fast package of production line
CN108248164A (en) * 2018-01-12 2018-07-06 朝阳佛瑞达科技有限公司 A kind of drinking water Multilayer co-extrusion packaging bag film and its production method
CN108263062A (en) * 2018-03-15 2018-07-10 南通环球塑料工程有限公司 A kind of multilayer shrinks antifog epiphragma and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202283804U (en) * 2011-10-24 2012-06-27 上海唐科新型包装材料有限公司 Anti-fog barrier film
CN104476753A (en) * 2014-11-25 2015-04-01 朝阳佛瑞达科技有限公司 Multilayer co-extrusion high-barrier film and preparation method thereof
CN207345171U (en) * 2017-10-19 2018-05-11 江阴升辉包装材料有限公司 A kind of heat shrink films suitable for the automatic fast package of production line
CN107856375A (en) * 2017-10-25 2018-03-30 无锡市太平洋新材料股份有限公司 A kind of boiling film for packaging for foodstuff
CN107891643A (en) * 2017-10-25 2018-04-10 无锡市太平洋新材料股份有限公司 A kind of easily tore film for packaging for foodstuff
CN108248164A (en) * 2018-01-12 2018-07-06 朝阳佛瑞达科技有限公司 A kind of drinking water Multilayer co-extrusion packaging bag film and its production method
CN108263062A (en) * 2018-03-15 2018-07-10 南通环球塑料工程有限公司 A kind of multilayer shrinks antifog epiphragma and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110982158A (en) * 2019-10-23 2020-04-10 江阴市德惠热收缩包装材料有限公司 Membrane and method of making the same
US20230347630A1 (en) * 2020-04-07 2023-11-02 Sofresh, Inc. Laminated film materials and processes for manufacturing thereof and uses thereof

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Application publication date: 20190412