CN109574322A - A kind of waste water treatment process - Google Patents

A kind of waste water treatment process Download PDF

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Publication number
CN109574322A
CN109574322A CN201910044594.9A CN201910044594A CN109574322A CN 109574322 A CN109574322 A CN 109574322A CN 201910044594 A CN201910044594 A CN 201910044594A CN 109574322 A CN109574322 A CN 109574322A
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CN
China
Prior art keywords
waste water
treatment process
water treatment
pond
filtering ponds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910044594.9A
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Chinese (zh)
Inventor
黄凤翔
石飞
袁波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Hung Peng New Materials Co Ltd
Original Assignee
Sichuan Hung Peng New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Hung Peng New Materials Co Ltd filed Critical Sichuan Hung Peng New Materials Co Ltd
Priority to CN201910044594.9A priority Critical patent/CN109574322A/en
Publication of CN109574322A publication Critical patent/CN109574322A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment

Abstract

The present invention provides a kind of waste water treatment process, belongs to technical field of waste water processing.A kind of waste water treatment process successively adjusts sour neutralization pond by sedimentation basin, the first filtering ponds, first, the second filtering ponds, coagulative precipitation tank, third filtering ponds, the sour neutralization pond of the second tune, adsorption tank, pH is adjusted to discharge pond.The waste water treatment process simply, in treatment process does not use sulfide, reduces the pollution to environment, good waste water treatment effect.

Description

A kind of waste water treatment process
Technical field
The invention belongs to technical field of waste water processing, specifically, being related to a kind of waste water treatment process.
Background technique
Industrial wastewater includes production waste water, production waste and cooling water, refer to the waste water generated in industrial processes and Waste liquid, wherein containing the pollution generated in industrial production materials, intermediate product, byproduct and the production process outflowed with water Object, since, often containing there are many noxious material, pollution environment has very big harm to human health, needs to take corresponding in industrial wastewater Control techniques be disposed after, can just discharge.
Acid compared with strong, heavy metal ion is more in industrial wastewater, especially lead, zinc, cadmium plasma severely exceed.Existing skill In art, commonly used treatment process is to be handled using neutralisation, and waste residue usually contains a large amount of element sulphurs after processing, simultaneously The less effective of wastewater treatment.
Therefore, inventing a kind of waste water treatment process for being able to solve the above problem becomes current urgent problem to be solved.
Summary of the invention
The purpose of the present invention is to provide a kind of waste water treatment process, vulcanization is not used in simple process, treatment process Object reduces the pollution to environment, good waste water treatment effect.
In order to achieve the above object, the solution that the present invention uses is:
A kind of waste water treatment process, successively by sedimentation basin, the first filtering ponds, first adjust sour neutralization pond, the second filtering ponds, Coagulative precipitation tank, third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond.
Further, in preferred embodiments of the present invention, pH is 10-13 in the sour neutralization pond of the first tune.
Further, in preferred embodiments of the present invention, pH is 8-10 in coagulative precipitation tank.
Further, in preferred embodiments of the present invention, pH is 10-13 in the sour neutralization pond of the second tune.
Further, in preferred embodiments of the present invention, adjusting pH in pH discharge pond is 6-9.
Further, in preferred embodiments of the present invention, first adjusts sour neutralization pond, second adjust sour neutralization pond, adjust pH discharge The adjusting that caustic soda carries out pH is added in pond.
Further, coagulant is added in preferred embodiments of the present invention, in coagulative precipitation tank and carries out coagulating sedimentation.
Further, in preferred embodiments of the present invention, coagulant includes magnesium carbonate or ferric trichloride.
Further, in preferred embodiments of the present invention, the adsorbent in adsorption tank is absorption resin.
The beneficial effect of waste water treatment process provided by the invention is first passed around in natural sedimentation and filtering removal waste water Slag and precipitating, avoid influencing subsequent neutralization efficiency, then adjust sour neutralization pond, coagulative precipitation tank, second to adjust by first Sour neutralization pond and adsorption tank carry out 4 purified treatments, and the effect of wastewater treatment is greatly improved under the conditions of suitable pH, During entire waste water treatment process, be added without sulfide and precipitated, reduce the pollution to environment.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention Technical solution be clearly and completely described.The person that is not specified actual conditions in embodiment, according to normal conditions or manufacturer builds The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase Product.
A kind of waste water treatment process of the embodiment of the present invention is specifically described below.
A kind of waste water treatment process provided in an embodiment of the present invention successively adjusts acid by sedimentation basin, the first filtering ponds, first Neutralization pond, the second filtering ponds, coagulative precipitation tank, third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond.
Wherein, the purpose for first passing through sedimentation basin is to avoid slag etc. from entering for the slag etc. of band in natural sedimentation waste water The efficiency neutralized is influenced in neutralization pond, is then passed through the first filtering ponds, is filtered out the slag precipitated in sedimentation basin.
It is adjusted first and carries out adjusting acid and neutralization precipitation in sour neutralization pond, pH is 10-13 in the sour neutralization pond of the first tune, it is therefore an objective to In order to precipitate some metals that tapping etc. is easy to generate precipitating in conjunction with hydroxyl, in the process, caustic soda is added and carries out Neutralization precipitation, wherein caustic soda is a kind of highly basic with strong corrosive, generally sheet or block-shape morphology, soluble easily in water, valence The cheap source of lattice is wide.
By the precipitating in sour neutralization pond with after will be adjusted to filter removal first, due to zinc, cadmium etc. in the second filtering ponds Metal ion is difficult to generate precipitating in conjunction with hydroxyl, therefore, can not remove the gold such as zinc, cadmium after first adjusts sour neutralization pond Belong to ion, therefore, the waste water after the second filtering ponds have passed through coagulative precipitation tank and carry out coagulating sedimentation.
Wherein, pH is that coagulant is added into waste water at the pH by 8-10 in coagulative precipitation tank, in the weak of pH=8-10 Under alkaline condition, hydroxide floccule body is formed, has flocculation to metal ions such as zinc, cadmiums, and is co-precipitated and is precipitated.The present invention In embodiment, coagulant includes magnesium carbonate or ferric trichloride, and the coagulant of sulfide is not added, and avoids occurring in slag a large amount of Sulfide influences environment.
Waste water is filtered after coagulating sedimentation by third filtering ponds, because joined excess carbon in coagulating sedimentation Sour magnesium or ferric trichloride are as coagulant, it is therefore desirable to which neutralization precipitation falls magnesium or iron ion again, therefore, filters by third The filtered waste water in pond is adjusting sour neutralization pond to carry out neutralization reaction by second, and pH is 10-13, purpose in the sour neutralization pond of the second tune It is in the process, causticity to be added to be settled out some metals that magnesium or iron etc. are easy to generate precipitating in conjunction with hydroxyl Sodium carries out neutralization precipitation.
Waste water after second adjusts sour neutralization pond is carrying out adsorption cleaning by adsorption tank, further increases processing effect Fruit, wherein the adsorbent in adsorption tank is absorption resin, and it is useless that absorption resin refers to that a kind of high molecular polymer can be used for removing Organic matter in water, Sugarcane juice decolorization, separation and purification of natural products and biochemistry product etc..
Pond finally is discharged through toning pH, waste water is made to reach the standard of discharge, adjusting pH in pH discharge pond is 6-9, adjusts pH discharge The adjusting that caustic soda carries out pH is added in pond
Embodiment 1
A kind of waste water treatment process, successively by sedimentation basin, the first filtering ponds, first adjust sour neutralization pond, the second filtering ponds, Coagulative precipitation tank, third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond, wherein first adjusts in sour neutralization pond Caustic soda is added to be adjusted, pH 10, pH is 8 in coagulative precipitation tank, and magnesium carbonate is added and carries out coagulating sedimentation, second adjusts in acid It is adjusted with caustic soda is added in pond, pH 10, adjusts addition caustic soda in pH discharge pond to be adjusted, pH 6.
Embodiment 2
A kind of waste water treatment process, successively by sedimentation basin, the first filtering ponds, first adjust sour neutralization pond, the second filtering ponds, Coagulative precipitation tank, third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond, wherein first adjusts in sour neutralization pond Caustic soda is added to be adjusted, pH 11, pH is 9 in coagulative precipitation tank, and magnesium carbonate is added and carries out coagulating sedimentation, second adjusts in acid It is adjusted with caustic soda is added in pond, pH 11, adjusts addition caustic soda in pH discharge pond to be adjusted, pH 7.
Embodiment 3
A kind of waste water treatment process, successively by sedimentation basin, the first filtering ponds, first adjust sour neutralization pond, the second filtering ponds, Coagulative precipitation tank, third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond, wherein first adjusts in sour neutralization pond Caustic soda is added to be adjusted, pH 12, pH is 10 in coagulative precipitation tank, and magnesium carbonate is added and carries out coagulating sedimentation, second adjusts acid Caustic soda is added in neutralization pond to be adjusted, pH 12, adjusts addition caustic soda in pH discharge pond to be adjusted, pH 8.
Embodiment 4
A kind of waste water treatment process, successively by sedimentation basin, the first filtering ponds, first adjust sour neutralization pond, the second filtering ponds, Coagulative precipitation tank, third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond, wherein first adjusts in sour neutralization pond Caustic soda is added to be adjusted, pH 13, pH is 11 in coagulative precipitation tank, and magnesium carbonate is added and carries out coagulating sedimentation, second adjusts acid Caustic soda is added in neutralization pond to be adjusted, pH 11, adjusts addition caustic soda in pH discharge pond to be adjusted, pH 9.
Embodiment 5
A kind of waste water treatment process, successively by sedimentation basin, the first filtering ponds, first adjust sour neutralization pond, the second filtering ponds, Coagulative precipitation tank, third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond, wherein first adjusts in sour neutralization pond Caustic soda is added to be adjusted, pH 11.5, pH is 9.5 in coagulative precipitation tank, and magnesium carbonate is added and carries out coagulating sedimentation, second adjusts Caustic soda is added in sour neutralization pond to be adjusted, pH 9,5, adjusts addition caustic soda in pH discharge pond to be adjusted, pH 7.5.
Embodiment 6
A kind of waste water treatment process, successively by sedimentation basin, the first filtering ponds, first adjust sour neutralization pond, the second filtering ponds, Coagulative precipitation tank, third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond, wherein first adjusts in sour neutralization pond Caustic soda being added to be adjusted, pH 12.5, pH is 10.5 in coagulative precipitation tank, addition magnesium carbonate progress coagulating sedimentation, second Caustic soda is added in the sour neutralization pond of tune to be adjusted, pH 10.5, adjusts addition caustic soda in pH discharge pond to be adjusted, pH 8.
Comparative example 1
A kind of waste water treatment process, successively by sedimentation basin, the first filtering ponds, first adjust sour neutralization pond, the second filtering ponds, Third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond, wherein first adjust be added in sour neutralization pond caustic soda into Row is adjusted, pH 10, and second adjusts addition caustic soda in sour neutralization pond to be adjusted, and pH 10 is adjusted in pH discharge pond and causticity is added Sodium is adjusted, pH 6.
Comparative example 2
A kind of waste water treatment process, successively by sedimentation basin, the first filtering ponds, first adjust sour neutralization pond, the second filtering ponds, Coagulative precipitation tank, adjusts pH to discharge pond at third filtering ponds, wherein first adjusts addition caustic soda in sour neutralization pond to be adjusted, and pH is 10, pH is 8 in coagulative precipitation tank, and magnesium carbonate is added and carries out coagulating sedimentation, and second adjusts and caustic soda is added in sour neutralization pond is adjusted Section, pH 10 adjust addition caustic soda in pH discharge pond to be adjusted, pH 6.
Comparative example 3
A kind of waste water treatment process, successively by sedimentation basin, the first filtering ponds, first adjust sour neutralization pond, the second filtering ponds, Coagulative precipitation tank, third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond, wherein first adjusts in sour neutralization pond Caustic soda is added to be adjusted, pH 9, pH is 6 in coagulative precipitation tank, and magnesium carbonate is added and carries out coagulating sedimentation, second adjusts in acid It is adjusted with caustic soda is added in pond, pH 9, adjusts addition caustic soda in pH discharge pond to be adjusted, pH 6.
Experimental example
By embodiment 1-6 and comparative example 1-3 through treatment process treated waste water, detected respectively, testing result is such as Shown in table 1.
Table 1
As shown in Table 1,1-6 of the embodiment of the present invention treated waste water, zinc, cadmium, suspended matter concentration significantly reduce, comparison The step of example 1 lacks coagulating sedimentation, zinc, cadmium concentration do not change significantly, comparative example 2 lacked second tune acid neutralize and absorption The step of, suspension content is higher, and not within the protection scope of the present invention, it is useless that treated for the pH value in each stage of comparative example 3 Water, zinc, cadmium, the concentration variation of suspended matter are smaller.
In conclusion the waste water treatment process that the present invention improves, first passes around in natural sedimentation and filtering removal waste water Slag and precipitating avoid influencing subsequent neutralization efficiency, then adjust sour neutralization pond, coagulative precipitation tank, second to adjust acid by first Neutralization pond and adsorption tank carry out 4 purified treatments, the effect of wastewater treatment are greatly improved, wherein in entire wastewater treatment work It during skill, is added without sulfide and is precipitated, reduce the pollution to environment.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (9)

1. a kind of waste water treatment process, it is characterised in that: successively adjust sour neutralization pond, the by sedimentation basin, the first filtering ponds, first Two filtering ponds, coagulative precipitation tank, third filtering ponds, second adjust sour neutralization pond, adsorption tank, pH are adjusted to discharge pond.
2. waste water treatment process according to claim 1, it is characterised in that: pH is 10- in the sour neutralization pond of the first tune 13。
3. waste water treatment process according to claim 1, it is characterised in that: pH is 8-10 in the coagulative precipitation tank.
4. waste water treatment process according to claim 1, it is characterised in that: pH is 10- in the sour neutralization pond of the second tune 13。
5. waste water treatment process according to claim 1, it is characterised in that: pH is 6-9 in tune pH discharge pond.
6. waste water treatment process according to claim 1, it is characterised in that: described first adjusts sour neutralization pond, described second Adjust sour neutralization pond, described adjust in pH discharge pond that the adjusting that caustic soda carries out pH is added.
7. waste water treatment process according to claim 1, it is characterised in that: coagulant is added in coagulative precipitation tank and is mixed Retrogradation is formed sediment.
8. waste water treatment process according to claim 7, it is characterised in that: the coagulant includes magnesium carbonate or tri-chlorination Iron.
9. waste water treatment process according to claim 1, it is characterised in that: the adsorbent in the adsorption tank is absorption tree Rouge.
CN201910044594.9A 2019-01-17 2019-01-17 A kind of waste water treatment process Pending CN109574322A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112321092A (en) * 2020-11-10 2021-02-05 菏泽华意化工有限公司 Processing system of waste water containing cyanuric acid

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102826684A (en) * 2012-09-14 2012-12-19 上海问鼎水处理工程有限公司 Method for removing lead ions in sewage
CN106587438A (en) * 2016-12-28 2017-04-26 安徽华塑股份有限公司 Treatment method for waste water containing mercury in PVC production through calcium carbide process
CN106673255A (en) * 2016-12-22 2017-05-17 北京恩菲环保技术有限公司 Wastewater treatment method and wastewater treatment device
CN109019972A (en) * 2018-08-24 2018-12-18 江苏开放大学(江苏城市职业学院) A kind of bath sewage processing unit and method
CN109264939A (en) * 2018-12-06 2019-01-25 湖南大辰环保科技有限公司 The processing method and system of Lithium Battery Industry production waste water

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102826684A (en) * 2012-09-14 2012-12-19 上海问鼎水处理工程有限公司 Method for removing lead ions in sewage
CN106673255A (en) * 2016-12-22 2017-05-17 北京恩菲环保技术有限公司 Wastewater treatment method and wastewater treatment device
CN106587438A (en) * 2016-12-28 2017-04-26 安徽华塑股份有限公司 Treatment method for waste water containing mercury in PVC production through calcium carbide process
CN109019972A (en) * 2018-08-24 2018-12-18 江苏开放大学(江苏城市职业学院) A kind of bath sewage processing unit and method
CN109264939A (en) * 2018-12-06 2019-01-25 湖南大辰环保科技有限公司 The processing method and system of Lithium Battery Industry production waste water

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112321092A (en) * 2020-11-10 2021-02-05 菏泽华意化工有限公司 Processing system of waste water containing cyanuric acid

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Application publication date: 20190405