CN109504515A - A kind of energy saving and environment friendly agricultural machinery oil and preparation method thereof - Google Patents

A kind of energy saving and environment friendly agricultural machinery oil and preparation method thereof Download PDF

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Publication number
CN109504515A
CN109504515A CN201910034557.XA CN201910034557A CN109504515A CN 109504515 A CN109504515 A CN 109504515A CN 201910034557 A CN201910034557 A CN 201910034557A CN 109504515 A CN109504515 A CN 109504515A
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China
Prior art keywords
additive
base oil
oil
agricultural machinery
energy saving
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CN201910034557.XA
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Chinese (zh)
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CN109504515B (en
Inventor
孙风成
孙亚楠
王路阳
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YANTAI HENGBANG CHEMICAL CO Ltd
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YANTAI HENGBANG CHEMICAL CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40Low content or no content compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64Environmental friendly compositions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention provides a kind of energy saving and environment friendly agricultural machinery oil, including following components in percentage by weight: base oil and additive, including following components in percentage by weight: base oil and additive, the 7.151%~16.102% of oily weight based on additive, the additive includes six kinds of components: oleic acid ethylene glycol rouge 0.5%~2%, RC9300 is ashless wear-resistant antioxygen corrosion inhibitor 0.45%~0.6%, polymethacrylates viscosity index improver 3%~10%, composite anti-foam agent 0.001~0.002%, organic molybdenum nitride 0.2%~1%, boronation polyisobutylene succinamide 1.5%~4%.The present invention uses environment-friendly type IV and V class base oil, is aided with excellent additive, has an excellent anti-friction performance, splendid cryogenic property, excellent antioxygenic property, and splendid rustless property does not contain harmful substance, energy conservation and environmental protection, long service life in oil product.

Description

A kind of energy saving and environment friendly agricultural machinery oil and preparation method thereof
Technical field
The invention belongs to chemical field, a kind of energy saving and environment friendly agricultural machinery oil and preparation method thereof is related in particular to.
Background technique
Ministry of Industry and Information, the Ministry of Agriculture and National Development and Reform Committee combine print and distribute " Agricultural Machinery Equipment developing activity scheme (2016-2025) " when Middle proposition the year two thousand twenty, the key components and parts degree of self-sufficiency reach 50% or so, tractor, and the emphasis agricultural machinery product such as combine harvester is reliable Property compared with " 12th Five-Year Plan " promote 50% or more, national crop cultivation receives comprehensive mechanical rate and reaches 70% or more, it can be seen that, agricultural machinery Market development space is huge, but major part currently on the market is mineral oil origin product, and credit rating is low, the pollution to environment Greatly, as environmental requirement is more and more tighter, energy conservation and environmental protection is main trend from now on, and the present invention uses IV and V class synthetic base oil, It is aided with energy saving and environment friendly additive, production is a can a degree of biodegrade, energy-saving and environment-friendly multifunctional farm implements oil.
Summary of the invention
The present invention provides a kind of energy saving and environment friendly agricultural machinery oil and preparation method thereof, solve mineral oil product bring The problem of environmental pollution and low quality.
The technical scheme of the present invention is realized as follows: a kind of energy saving and environment friendly agricultural machinery oil, including following weight percent The component of ratio: base oil and additive, the 7.151%~16.102% of oily weight based on additive, the additive includes six Kind of component: oleic acid ethylene glycol rouge 0.5%~2%, RC9300 is ashless wear-resistant antioxygen corrosion inhibitor 0.45%~0.6%, polymethyl Acid esters viscosity index improver 3%~10%, composite anti-foam agent 0.001~0.002%, organic molybdenum nitride 0.2%~1%, boronation is gathered different Cyclobutenyl succimide 1.5%~4%;
Preferably, including following components in percentage by weight: base oil and additive, oily weight based on additive 12.0215%, the additive includes six kinds of components: oleic acid ethylene glycol rouge 1.2%, RC9300 is ashless wear-resistant antioxygen corrosion inhibitor 0.52%, polymethacrylates viscosity index improver 7%, composite anti-foam agent 0.0015%, organic molybdenum nitride 0.6%, boronation is poly- Isobutenyl succimide 2.7%;
Preferably, the base oil be polyalphaolefin, alkylnaphthalene, polyester, base oil polyalphaolefin 75%~85%, alkylnaphthalene 10%~ 15%, polyester 5~10%;
A kind of method for preparing energy environment-friendly type agricultural machinery oil, comprising the following steps:
(1), base oil, polymethacrylates viscosity index improver, composite anti-foam agent are put into reaction kettle, are warming up to 60 It~70 DEG C, stirs 8~10 minutes;
(2), oleic acid ethylene glycol rouge, RC9300 is ashless wear-resistant antioxygen corrosion inhibitor, organic molybdenum nitride, the poly- isobutyl of boronation are successively put into Alkenyl succimide, stirs 30 minutes, becomes finished product after 15 μm of sock filtrations by 60 DEG C~70 DEG C of constant temperature.
Polyalphaolefin belongs to IV class base oil by hydrogenated olefins quasi-oligomer and passes through the polymerization reaction system of linear alpha olefins At, have regular no wax, isoparaffin structure, have good low-temperature characteristics, high viscosity index (HVI), low volatility and preferably Thermal stability, particularly suitable for needing the lubricating oil application of good stability under extreme operating conditions.
Alkylnaphthalene belongs to V class base oil, by how being prepared with the alkylations of linear alpha olefins, just have well heat it is steady Qualitative, oxidation stability and hydrolytic stability, it has good dissolubility, can be improved base oil and produces to additive and oxidation The dissolubility of object, making product just has splendid detergency.
Polyester belongs to V class base oil, belongs to ester copolymer, has outstanding lubricating ability, high Viscosity Index and shearing Stability, high oxidation stability and film strength, cleaning evaporation and low volatility, first-class seal compatibility.
Oleic acid ethylene glycol rouge, yellow or brown liquid have splendid oiliness, inoxidizability, resistance to emulsion and rust-preventing characteristic.
RC9300 is ashless wear-resistant antioxygen corrosion inhibitor has splendid oxidation stability, high bearing capacity, good anti-cream Change ability, good filterability.
Polymethacrylates viscosity index improver has excellent anti-shear ability and cryogenic property, can be improved Fuel economy.
Organic boron nitride, have it is good wear-resistant, antifriction, antioxygenic property is non-corrosive, can reduce rubbing for movement parts Coefficient is wiped, there is energy conservation, cooling, the performance of noise reduction.
Composite anti-foam agent: non-silicon oil type anti-foaming agent can reduce product frothing capacity.
Boronation polyisobutylene succinamide, belongs to boronation ashless dispersant, has excellent detergent-dispersant performance, splendid anti- Oxidation susceptibility and high wear resistence.
The beneficial effects of the present invention are: the present invention has excellent anti-friction performance, splendid cryogenic property, excellent antioxygen Change performance, splendid rustless property does not contain harmful substance, energy conservation and environmental protection, long service life in oil product.
Specific embodiment
For a better understanding and implementation, the following detailed description of a kind of energy saving and environment friendly agricultural machinery oil and preparation method thereof:
Example 1: a kind of energy saving and environment friendly agricultural machinery oil prepares base oil polyalphaolefin (PAO6) 820kg, alkylnaphthalene (synesstic5) 120kg, polyester (KL135) 60kg, the additive ashless wear-resistant antioxygen of oleic acid ethylene glycol rouge 10kg, RC9300 are anti- Corrosive agent 5kg, polymethacrylates viscosity index improver 45kg, composite anti-foam agent 0.01kg, organic molybdenum nitride 7kg, boron Change polyisobutylene succinamide 20kg.
Production method: into reaction kettle put into polyalphaolefin (PAO6), alkylnaphthalene (synesstic5), polyester (KL135), Polymethacrylates viscosity index improver, composite anti-foam agent are warming up to 65 DEG C, stir 10 minutes, then successively investment is oily Sour ethylene glycol rouge, RC9300 is ashless wear-resistant antioxygen corrosion inhibitor, organic molybdenum nitride, boronation polyisobutylene succinamide, perseverance 65 DEG C of temperature stirs 30 minutes, becomes finished product after 15 μm of sock filtrations.
Quality index
Example 2: a kind of energy saving and environment friendly agricultural machinery oil prepares base oil polyalphaolefin (PAO4) 400kg, polyalphaolefin (PAO6) 400kg, alkylnaphthalene (synesstic12) 100kg, polyester (KL135) 100kg, it is anti-that oleic acid ethylene glycol rouge 10kg, RC9300 is ashless Grind antioxygen corrosion inhibitor 5.5kg, polymethacrylates viscosity index improver 47kg, composite anti-foam agent 0.01kg, organic nitrogen Change molybdenum 6kg, boronation polyisobutylene succinamide 25kg.
Production method: polyalphaolefin (PAO4), polyalphaolefin (PAO6), alkylnaphthalene are put into reaction kettle (synesstic12), polyester (KL135), polymethacrylates viscosity index improver, composite anti-foam agent, are warming up to 65 DEG C, Then stirring 10 minutes successively puts into oleic acid ethylene glycol rouge, RC9300 is ashless wear-resistant antioxygen corrosion inhibitor, organic molybdenum nitride, boron Change polyisobutylene succinamide, 65 DEG C of constant temperature, stirs 30 minutes, become finished product after 15 μm of sock filtrations.
Quality index
The present invention uses peace and quiet type synthetic base oil, and additive selects energy saving and environment friendly additive, has excellent anti-friction performance, Splendid cryogenic property, excellent antioxygenic property, splendid rustless property do not contain harmful substance in oil product, energy conservation and environmental protection, Long service life.

Claims (4)

1. a kind of energy saving and environment friendly agricultural machinery oil, it is characterised in that including following components in percentage by weight: base oil and addition Agent, the 7.151%~16.102% of oily weight based on additive, the additive includes six kinds of components: oleic acid ethylene glycol rouge 0.5%~2%, RC9300 are ashless wear-resistant antioxygen corrosion inhibitor 0.45%~0.6%, polymethacrylates viscosity index improver 3% ~10%, composite anti-foam agent 0.001~0.002%, organic molybdenum nitride 0.2%~1%, boronation polyisobutylene succinamide 1.5% ~4%.
2. a kind of energy saving and environment friendly agricultural machinery oil as described in claim 1, it is characterised in that including following weight percent Component: base oil and additive, the 12.0215% of oily weight based on additive, the additive includes six kinds of components: oleic acid Ethylene glycol rouge 1.2%, RC9300 is ashless wear-resistant antioxygen corrosion inhibitor 0.52%, polymethacrylates viscosity index improver 7%, Composite anti-foam agent 0.0015%, organic molybdenum nitride 0.6%, boronation polyisobutylene succinamide 2.7%.
3. a kind of energy saving and environment friendly agricultural machinery oil as claimed in claim 1 or 2, it is characterised in that the base oil is poly- α alkene Hydrocarbon, alkylnaphthalene, polyester, base oil polyalphaolefin 75%~85%, alkylnaphthalene 10%~15%, polyester 5~10%.
4. the method for preparing a kind of energy environment-friendly type agricultural machinery oil as described in claims 1 to 3 is any, comprising the following steps:
(1), base oil, polymethacrylates viscosity index improver, composite anti-foam agent are put into reaction kettle, are warming up to 60 It~70 DEG C, stirs 8~10 minutes;
(2), oleic acid ethylene glycol rouge, RC9300 is ashless wear-resistant antioxygen corrosion inhibitor, organic molybdenum nitride, the poly- isobutyl of boronation are successively put into Alkenyl succimide, stirs 30 minutes, becomes finished product after 15 μm of sock filtrations by 60 DEG C~70 DEG C of constant temperature.
CN201910034557.XA 2019-01-15 2019-01-15 Energy-saving environment-friendly agricultural machine oil and preparation method thereof Active CN109504515B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109880680A (en) * 2019-04-16 2019-06-14 江苏现代节能科技发展有限公司 A kind of no phosphorous gasoline engine lubricant oil and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102453589A (en) * 2010-10-18 2012-05-16 王严绪 Sulfur-phosphor-free oil-soluble organic molybdenum additive
CN103642563A (en) * 2013-11-15 2014-03-19 沈阳中科石化有限公司 Energy-saving type total synthetic automatic transmission transmission fluid, and synthetic method thereof
CN104471101A (en) * 2012-03-12 2015-03-25 欧瑞康贸易股份公司(特吕巴赫) Coating with enhanced sliding properties
CN106520327A (en) * 2016-11-04 2017-03-22 万德 Special engine oil for improving engine oil combustion phenomenon of turbocharged engine and preparation method thereof
CN106609172A (en) * 2015-10-21 2017-05-03 中国石油化工股份有限公司 Ashless hydraulic oil composition and preparation method and application thereof
CN107828480A (en) * 2017-10-30 2018-03-23 江苏龙蟠科技股份有限公司 A kind of high-performance synthesis type power-assisted steering fluid composition and preparation method thereof
CN108504420A (en) * 2017-02-24 2018-09-07 淄博大创自动化科技有限公司 A kind of farm machinery special lube

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102453589A (en) * 2010-10-18 2012-05-16 王严绪 Sulfur-phosphor-free oil-soluble organic molybdenum additive
CN104471101A (en) * 2012-03-12 2015-03-25 欧瑞康贸易股份公司(特吕巴赫) Coating with enhanced sliding properties
CN103642563A (en) * 2013-11-15 2014-03-19 沈阳中科石化有限公司 Energy-saving type total synthetic automatic transmission transmission fluid, and synthetic method thereof
CN106609172A (en) * 2015-10-21 2017-05-03 中国石油化工股份有限公司 Ashless hydraulic oil composition and preparation method and application thereof
CN106520327A (en) * 2016-11-04 2017-03-22 万德 Special engine oil for improving engine oil combustion phenomenon of turbocharged engine and preparation method thereof
CN108504420A (en) * 2017-02-24 2018-09-07 淄博大创自动化科技有限公司 A kind of farm machinery special lube
CN107828480A (en) * 2017-10-30 2018-03-23 江苏龙蟠科技股份有限公司 A kind of high-performance synthesis type power-assisted steering fluid composition and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109880680A (en) * 2019-04-16 2019-06-14 江苏现代节能科技发展有限公司 A kind of no phosphorous gasoline engine lubricant oil and preparation method thereof

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