CN109487591A - A kind of fade-proof and crack resistence printed material and caloric transfer printing technology - Google Patents
A kind of fade-proof and crack resistence printed material and caloric transfer printing technology Download PDFInfo
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- CN109487591A CN109487591A CN201811143333.4A CN201811143333A CN109487591A CN 109487591 A CN109487591 A CN 109487591A CN 201811143333 A CN201811143333 A CN 201811143333A CN 109487591 A CN109487591 A CN 109487591A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65112—Compounds containing aldehyde or ketone groups
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
Abstract
The invention discloses a kind of fade-proof and crack resistence printed materials, belong to printing technique field；The bright-coloured of color can not be guaranteed well by solving existing printed material, crack resistence performance is bad simultaneously, it is easy to damage because surface is corroded so as to cause printing product people, the problem of wasting a large amount of resource, technical characteristic are: including below according to the raw material of parts by weight: gold printing starches 50-150 parts, 100-120 parts of sodium alginate, 15-30 parts of rosin lactic acid, 5-10 parts of colloid silicon microparticle, 50-80 parts of color fixing agent, 20-40 parts of moisturizer, 5-10 parts of preservative, 30-60 parts of coarse sand；It is strong using printing product three-dimensional sense produced by the present invention, also enhance the appearance of printing product.
Description
Technical field
The present invention relates to printing technique field, specifically a kind of fade-proof and crack resistence printed material and thermal transfer work
Skill.
Background technique
Printed material has excellent covering power, we are usually in linen-cotton and the blended exterior surface print of all kinds of staple fibres
Flower is not only able in this way so that its appearance is beautiful, while it is also possible that linen-cotton and all kinds of staple fibre blend have one
The service life of excellent performance, linen-cotton and all kinds of staple fibre blend also extends, and has saved our living cost, with
The innovation of printing technology, people it is also higher and higher to the design requirement of stamp, need using the different town pattern He Zhuan technique
The eyeball of buyer is won, in order to preferably guarantee that stamp of different shapes can be blended with linen-cotton and all kinds of staple fibres
Object combines, and caloric transfer printing technology is currently used printing technology.
But existing printed material can not guarantee the bright-coloured of color well, while crack resistence performance is bad, thus
Cause printing product people to be easy to damage because surface is corroded, wastes a large amount of resource.
Summary of the invention
The purpose of the present invention is to provide a kind of fade-proof and crack resistence printed materials, to solve existing stamp material
Material can not guarantee the bright-coloured of color well, while crack resistence performance is bad, so as to cause printing product people be easy because surface by
The problem of damaging to corrosion, waste a large amount of resource.
To achieve the above object, the invention provides the following technical scheme:
A kind of fade-proof and crack resistence printed material, including below according to the raw material of parts by weight: 50-150 parts of gold printing slurry,
100-120 parts of sodium alginate, 15-30 parts of rosin lactic acid, 5-10 parts of colloid silicon microparticle, 50-80 parts of color fixing agent, moisturizer 20-
40 parts, 5-10 parts of preservative, 30-60 parts of coarse sand.
As a further solution of the present invention: including below according to the raw material of parts by weight: gold printing starches 60-120 parts, sea
105-110 parts of mosanom, 20-25 parts of rosin lactic acid, 7-9 parts of colloid silicon microparticle, 60-70 parts of color fixing agent, moisturizer 25-35
Part, 6-9 parts of preservative, 40-55 parts of coarse sand.
As further scheme of the invention: including below according to the raw material of parts by weight: gold printing starches 100 parts, sea
107 parts of mosanom, 22 parts of rosin lactic acid, 8 parts of colloid silicon microparticle, 65 parts of color fixing agent, 30 parts of moisturizer, 8 parts of preservative, coarse sand
50 parts.
As further scheme of the invention: the color fixing agent is Diacetone Acrylamide, epoxychloropropane and peroxide
Change one of methyl ethyl ketone or a variety of mixtures；The moisturizer is the mixture of glycerol and diethylene glycol (DEG), and glycerol and diethylene glycol (DEG)
Mass ratio be 1-5:0.2-3.
The preparation method of a kind of fade-proof and crack resistence printed material, steps are as follows:
1) it takes gold printing slurry and rosin lactic acid to be mixed, then stirs evenly obtained mixture A, it is spare；2) alginic acid is taken
Sodium and color fixing agent after mixing, are ground to 100-150 mesh, obtain mixture B, spare；3) by twice of second of mixture A
Alcoholic solution dissolution, then obtains mixed solution A, mixture B is uniformly added into mixed solution A, obtain mixed solution C, then
Mixed solution is heated, uniform stirring, mixing time 30min are kept in heating process；4) it takes colloid silicon microparticle, protect
Humectant, preservative and coarse sand obtain mixture D after mixing, and mixture D is added in mixed solution C, then to mixed
It closes and adds acetic acid in solution, adjust PH to 4-4.5, mashing processing is homogenized to mixed solution, carries out decatize after mashing
Processing, then mixture is dried, obtain printed material.
As a further solution of the present invention: heating temperature is 80 DEG C in step 3), mixing speed 200-300r/min.
As further scheme of the invention: in step 4), steam temperature is 150 DEG C, steaming time 3h.
A kind of caloric transfer printing technology of fade-proof and crack resistence printed material, comprising the following steps:
1) cleaning treatment is carried out to printing product outer surface；2) printing product is heated by heating device, heating temperature
It is 80 DEG C；3) printed material is taken, printed material is dissolved in acetone soln, is heated with printed material solution, heating temperature
Degree is 30 DEG C, is then coated uniformly on printing product outer surface；4) then hot pressing is carried out to printing product and printed material to scald at molding
Reason, is placed in oven and dried processing for printing product after the completion of compacting, then takes out, obtain into.
As a further solution of the present invention: hot pressing temperature is 150-170 DEG C in step 4), time 1min.
Compared with prior art, the beneficial effects of the present invention are: it is strong using printing product three-dimensional sense produced by the present invention, also increase
The strong appearance of printing product；And by addition coarse sand, so that printed material has very strong crack resistence performance, while passing through addition
The case where color fixing agent makes printed material be able to maintain the appearance of printing product, and the group of avoiding fades.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1
A kind of fade-proof and crack resistence printed material, including below according to the raw material of parts by weight: gold printing starches 50 parts, seaweed
100 parts of sour sodium, 15 parts of rosin lactic acid, 5 parts of colloid silicon microparticle, 50 parts of color fixing agent, 20 parts of moisturizer, 5 parts of preservative, coarse sand 30
Part.
The color fixing agent is the mixture of Diacetone Acrylamide, epoxychloropropane；And acrylamide, epoxychloropropane
Mass ratio is 1:1；The moisturizer is the mixture of glycerol and diethylene glycol (DEG), and the mass ratio of glycerol and diethylene glycol (DEG) is 1:1.3.
In the present embodiment, a kind of fade-proof and crack resistence printed material preparation method, steps are as follows:
1) it takes gold printing slurry and rosin lactic acid to be mixed, then stirs evenly obtained mixture A, it is spare；2) alginic acid is taken
Sodium and color fixing agent after mixing, are ground to 150 mesh, obtain mixture B, spare；3) mixture A is molten with twice of ethyl alcohol
Liquid dissolution, then obtains mixed solution A, mixture B is uniformly added into mixed solution A, obtain mixed solution C, then to mixed
It closes solution to be heated, uniform stirring, mixing time 30min is kept in heating process；4) colloid silicon microparticle, moisturizing are taken
Agent, preservative and coarse sand obtain mixture D after mixing, and mixture D is added in mixed solution C, then to mixing
Acetic acid is added in solution, adjusts PH to 4, and mashing processing is homogenized to mixed solution, carries out individual composition after mashing, so
Mixture is dried afterwards, obtains printed material.
Heating temperature is 80 DEG C in step 3), mixing speed 200r/min；In step 4), steam temperature is 150 DEG C,
Steaming time is 3h.
In the present embodiment, the caloric transfer printing technology of a kind of fade-proof and crack resistence printed material, comprising the following steps:
1) cleaning treatment is carried out to printing product outer surface；2) printing product is heated by heating device, heating temperature
It is 80 DEG C；3) printed material is taken, printed material is dissolved in acetone soln, is heated with printed material solution, heating temperature
Degree is 30 DEG C, is then coated uniformly on printing product outer surface；4) then hot pressing is carried out to printing product and printed material to scald at molding
Reason, is placed in oven and dried processing for printing product after the completion of compacting, then takes out, obtain into.
Hot pressing temperature is 150 DEG C in step 4), time 1min.
Embodiment 2
A kind of fade-proof and crack resistence printed material, including below according to the raw material of parts by weight: gold printing starches 150 parts, sea
It is 120 parts of mosanom, 30 parts of rosin lactic acid, 10 parts of colloid silicon microparticle, 80 parts of color fixing agent, 40 parts of moisturizer, 10 parts of preservative, thick
60 parts of sand.
The color fixing agent is the mixture of Diacetone Acrylamide, epoxychloropropane and methyl ethyl ketone peroxide, and diacetone
The mass ratio of acrylamide, epoxychloropropane and methyl ethyl ketone peroxide is 1:1.5:3；The moisturizer is glycerol and diethylene glycol (DEG)
Mixture, and the mass ratio of glycerol and diethylene glycol (DEG) is 2:0.7.
In the present embodiment, a kind of fade-proof and crack resistence printed material preparation method, steps are as follows:
1) it takes gold printing slurry and rosin lactic acid to be mixed, then stirs evenly obtained mixture A, it is spare；2) alginic acid is taken
Sodium and color fixing agent after mixing, are ground to 110 mesh, obtain mixture B, spare；3) mixture A is molten with twice of ethyl alcohol
Liquid dissolution, then obtains mixed solution A, mixture B is uniformly added into mixed solution A, obtain mixed solution C, then to mixed
It closes solution to be heated, uniform stirring, mixing time 30min is kept in heating process；4) colloid silicon microparticle, moisturizing are taken
Agent, preservative and coarse sand obtain mixture D after mixing, and mixture D is added in mixed solution C, then to mixing
Acetic acid is added in solution, adjusts PH to 4, and mashing processing is homogenized to mixed solution, carries out individual composition after mashing, so
Mixture is dried afterwards, obtains printed material.
Heating temperature is 80 DEG C in step 3), mixing speed 220r/min；In step 4), steam temperature is 150 DEG C,
Steaming time is 3h.
In the present embodiment, the caloric transfer printing technology of a kind of fade-proof and crack resistence printed material, comprising the following steps:
1) cleaning treatment is carried out to printing product outer surface；2) printing product is heated by heating device, heating temperature
It is 80 DEG C；3) printed material is taken, printed material is dissolved in acetone soln, is heated with printed material solution, heating temperature
Degree is 30 DEG C, is then coated uniformly on printing product outer surface；4) then hot pressing is carried out to printing product and printed material to scald at molding
Reason, is placed in oven and dried processing for printing product after the completion of compacting, then takes out, obtain into.
Hot pressing temperature is 153 DEG C in step 4), time 1min.
Embodiment 3
A kind of fade-proof and crack resistence printed material, including below according to the raw material of parts by weight: gold printing starches 60 parts, seaweed
105 parts of sour sodium, 20 parts of rosin lactic acid, 7 parts of colloid silicon microparticle, 60 parts of color fixing agent, 25 parts of moisturizer, 6 parts of preservative, coarse sand 40
Part.
The color fixing agent is the mixture of Diacetone Acrylamide, epoxychloropropane and methyl ethyl ketone peroxide, and diacetone
The mass ratio of acrylamide, epoxychloropropane and methyl ethyl ketone peroxide is 2:1:3；The moisturizer is the mixed of glycerol and diethylene glycol (DEG)
Object is closed, and the mass ratio of glycerol and diethylene glycol (DEG) is 5:3.
In the present embodiment, a kind of fade-proof and crack resistence printed material preparation method, steps are as follows:
1) it takes gold printing slurry and rosin lactic acid to be mixed, then stirs evenly obtained mixture A, it is spare；2) alginic acid is taken
Sodium and color fixing agent after mixing, are ground to 130 mesh, obtain mixture B, spare；3) mixture A is molten with twice of ethyl alcohol
Liquid dissolution, then obtains mixed solution A, mixture B is uniformly added into mixed solution A, obtain mixed solution C, then to mixed
It closes solution to be heated, uniform stirring, mixing time 30min is kept in heating process；4) colloid silicon microparticle, moisturizing are taken
Agent, preservative and coarse sand obtain mixture D after mixing, and mixture D is added in mixed solution C, then to mixing
Acetic acid is added in solution, adjusts PH to 4.3, and mashing processing is homogenized to mixed solution, carries out individual composition after mashing,
Then mixture is dried, obtains printed material.
Heating temperature is 80 DEG C in step 3), mixing speed 240r/min；In step 4), steam temperature is 150 DEG C,
Steaming time is 3h.
In the present embodiment, the caloric transfer printing technology of a kind of fade-proof and crack resistence printed material, comprising the following steps:
1) cleaning treatment is carried out to printing product outer surface；2) printing product is heated by heating device, heating temperature
It is 80 DEG C；3) printed material is taken, printed material is dissolved in acetone soln, is heated with printed material solution, heating temperature
Degree is 30 DEG C, is then coated uniformly on printing product outer surface；4) then hot pressing is carried out to printing product and printed material to scald at molding
Reason, is placed in oven and dried processing for printing product after the completion of compacting, then takes out, obtain into.
Hot pressing temperature is 170 DEG C in step 4), time 1min.
Embodiment 4
A kind of fade-proof and crack resistence printed material, including below according to the raw material of parts by weight: gold printing starches 120 parts, sea
110 parts of mosanom, 25 parts of rosin lactic acid, 9 parts of colloid silicon microparticle, 70 parts of color fixing agent, 35 parts of moisturizer, 9 parts of preservative, coarse sand
55 parts.
The color fixing agent is the mixture of epoxychloropropane and methyl ethyl ketone peroxide；And epoxychloropropane and peroxidating first and second
The mass ratio of ketone is 1:1.5, and the moisturizer is the mixture of glycerol and diethylene glycol (DEG), and the mass ratio of glycerol and diethylene glycol (DEG) is
3:2.
In the present embodiment, a kind of fade-proof and crack resistence printed material preparation method, steps are as follows:
1) it takes gold printing slurry and rosin lactic acid to be mixed, then stirs evenly obtained mixture A, it is spare；2) alginic acid is taken
Sodium and color fixing agent after mixing, are ground to 145 mesh, obtain mixture B, spare；3) mixture A is molten with twice of ethyl alcohol
Liquid dissolution, then obtains mixed solution A, mixture B is uniformly added into mixed solution A, obtain mixed solution C, then to mixed
It closes solution to be heated, uniform stirring, mixing time 30min is kept in heating process；4) colloid silicon microparticle, moisturizing are taken
Agent, preservative and coarse sand obtain mixture D after mixing, and mixture D is added in mixed solution C, then to mixing
Acetic acid is added in solution, adjusts PH to 4.3, and mashing processing is homogenized to mixed solution, carries out individual composition after mashing,
Then mixture is dried, obtains printed material.
Heating temperature is 80 DEG C in step 3), mixing speed 245r/min；In step 4), steam temperature is 150 DEG C,
Steaming time is 3h.
In the present embodiment, the caloric transfer printing technology of a kind of fade-proof and crack resistence printed material, comprising the following steps:
1) cleaning treatment is carried out to printing product outer surface；2) printing product is heated by heating device, heating temperature
It is 80 DEG C；3) printed material is taken, printed material is dissolved in acetone soln, is heated with printed material solution, heating temperature
Degree is 30 DEG C, is then coated uniformly on printing product outer surface；4) then hot pressing is carried out to printing product and printed material to scald at molding
Reason, is placed in oven and dried processing for printing product after the completion of compacting, then takes out, obtain into.
Hot pressing temperature is 168 DEG C in step 4), time 1min.
Embodiment 5
A kind of fade-proof and crack resistence printed material, including below according to the raw material of parts by weight: gold printing starches 100 parts, sea
107 parts of mosanom, 22 parts of rosin lactic acid, 8 parts of colloid silicon microparticle, 65 parts of color fixing agent, 30 parts of moisturizer, 8 parts of preservative, coarse sand
50 parts.
The color fixing agent is one of Diacetone Acrylamide, epoxychloropropane and methyl ethyl ketone peroxide or a variety of mixing
Object；And the mass ratio of Diacetone Acrylamide, epoxychloropropane and methyl ethyl ketone peroxide is 3:2:1；The moisturizer is glycerol
With the mixture of diethylene glycol (DEG), and the mass ratio of glycerol and diethylene glycol (DEG) be 3:2.5.
In the present embodiment, a kind of fade-proof and crack resistence printed material preparation method, steps are as follows:
1) it takes gold printing slurry and rosin lactic acid to be mixed, then stirs evenly obtained mixture A, it is spare；2) alginic acid is taken
Sodium and color fixing agent after mixing, are ground to 137 mesh, obtain mixture B, spare；3) mixture A is molten with twice of ethyl alcohol
Liquid dissolution, then obtains mixed solution A, mixture B is uniformly added into mixed solution A, obtain mixed solution C, then to mixed
It closes solution to be heated, uniform stirring, mixing time 30min is kept in heating process；4) colloid silicon microparticle, moisturizing are taken
Agent, preservative and coarse sand obtain mixture D after mixing, and mixture D is added in mixed solution C, then to mixing
Acetic acid is added in solution, is adjusted PH to 4.5 pairs of mixed solution and is homogenized mashing processing, carries out individual composition after mashing,
Then mixture is dried, obtains printed material.
Heating temperature is 80 DEG C in step 3), mixing speed 290r/min；In step 4), steam temperature is 150 DEG C,
Steaming time is 3h.
In the present embodiment, the caloric transfer printing technology of a kind of fade-proof and crack resistence printed material, comprising the following steps:
1) cleaning treatment is carried out to printing product outer surface；2) printing product is heated by heating device, heating temperature
It is 80 DEG C；3) printed material is taken, printed material is dissolved in acetone soln, is heated with printed material solution, heating temperature
Degree is 30 DEG C, is then coated uniformly on printing product outer surface；4) then hot pressing is carried out to printing product and printed material to scald at molding
Reason, is placed in oven and dried processing for printing product after the completion of compacting, then takes out, obtain into.
Hot pressing temperature is 170 DEG C in step 4), time 1min.
Comparative example 1
In the present embodiment, coarse sand is not contained in raw material, other are same as Example 5.
Comparative example 2
In the present embodiment, color fixing agent is not contained in raw material, other are same as Example 5.
Comparative example 3
In the present embodiment, coarse sand and color fixing agent are not contained in raw material, other are same as Example 5.
Embodiment 1-5 in the present invention, comparative example 1-3 and commercial product are taken, then it is tested for the property, by above-mentioned print
Floral material will spray water for 24 hours with water according to the weight ratio of 200:50 first, and then carrying out surface water spray moisturizing, (20 times/day, continue 3
It, relative to the printed material of 100g, each amount of water sprayed is 50-60g), it is finally placed at 20 DEG C and dries in the shade 10 days, finally count
The face checking rate concrete outcome of steel seal material is shown in Table 1 test result is as follows table；
1 performance test table of table
| Group | Cracking rate W(%) |
| Embodiment 1 | 0.9 |
| Embodiment 2 | 0.85 |
| Embodiment 3 | 0.86 |
| Embodiment 4 | 0.85 |
| Embodiment 5 | 0.8 |
| Comparative example 1 | 2.5 |
| Comparative example 2 | 1.2 |
| Comparative example 3 | 2.7 |
| Commercial product | 1.5 |
It is strong using printing product three-dimensional sense produced by the present invention, also enhance the appearance of printing product；And by addition coarse sand, so that print
Floral material has very strong crack resistence performance, while making printed material be able to maintain the outer of printing product by adding color fixing agent
The case where sight, the group of avoiding fades.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (10)
1. a kind of fade-proof and crack resistence printed material, which is characterized in that including below according to the raw material of parts by weight: bronze print
Flower slurry 50-150 parts, 100-120 parts of sodium alginate, 15-30 parts of rosin lactic acid, 5-10 parts of colloid silicon microparticle, color fixing agent 50-80
Part, 20-40 parts of moisturizer, 5-10 parts of preservative, 30-60 parts of coarse sand.
2. according to claim 1 fade-proof and crack resistence printed material, which is characterized in that including below according to weight
The raw material of part: gold printing starches 60-120 parts, 105-110 parts of sodium alginate, 20-25 parts of rosin lactic acid, colloid silicon microparticle 7-9
Part, 60-70 parts of color fixing agent, 25-35 parts of moisturizer, 6-9 parts of preservative, 40-55 parts of coarse sand.
3. according to claim 1 fade-proof and crack resistence printed material, which is characterized in that including below according to weight
The raw material of part: gold printing starches 100 parts, 107 parts of sodium alginate, 22 parts of rosin lactic acid, 8 parts of colloid silicon microparticle, color fixing agent 65
Part, 30 parts of moisturizer, 8 parts of preservative, 50 parts of coarse sand.
4. according to claim 1 fade-proof and crack resistence printed material, which is characterized in that the color fixing agent is double third
One of ketone acrylamide, epoxychloropropane and methyl ethyl ketone peroxide or a variety of mixtures.
5. according to claim 1 fade-proof and crack resistence printed material, which is characterized in that the moisturizer is glycerol
With the mixture of diethylene glycol (DEG), and the mass ratio of glycerol and diethylene glycol (DEG) be 1-5:0.2-3.
6. a kind of preparation method of a method as claimed in any one of claims 1 to 5 fade-proof and crack resistence printed material, feature exist
In steps are as follows:
1) it takes gold printing slurry and rosin lactic acid to be mixed, then stirs evenly obtained mixture A, it is spare；
2) sodium alginate and color fixing agent are taken, after mixing, is ground to 100-150 mesh, mixture B is obtained, it is spare；
3) twice of ethanol solution of mixture A is dissolved, then obtains mixed solution A, uniformly addition is mixed into mixed solution A
Object B is closed, mixed solution C is obtained, then mixed solution is heated, uniform stirring is kept in heating process, mixing time is
30min；
4) it takes colloid silicon microparticle, moisturizer, preservative and coarse sand, after mixing, obtain mixture D, mixture D is added
Into mixed solution C, acetic acid is then added into mixed solution, adjusts PH to 4-4.5, mixed solution is homogenized at mashing
Reason, carries out individual composition after mashing, then dries mixture, obtain printed material.
7. the preparation method of according to claim 6 fade-proof and crack resistence printed material, which is characterized in that step 3)
Middle heating temperature is 80 DEG C, mixing speed 200-300r/min.
8. the preparation method of according to claim 6 fade-proof and crack resistence printed material, which is characterized in that in step
4) in, steam temperature is 150 DEG C, steaming time 3h.
9. a kind of caloric transfer printing technology of fade-proof and crack resistence the printed material as described in any according to claim 1-6, special
Sign is, comprising the following steps:
Cleaning treatment is carried out to printing product outer surface；
Printing product is heated by heating device, heating temperature is 80 DEG C；
Printed material is taken, printed material is dissolved in acetone soln, is heated with printed material solution, heating temperature 30
DEG C, then it is coated uniformly on printing product outer surface；
4) hot pressing then is carried out to printing product and printed material and scalds forming processes, printing product is put into baking oven after the completion of compacting and is done
Dry processing, then takes out, obtains into.
10. the caloric transfer printing technology of according to claim 9 fade-proof and crack resistence printed material, which is characterized in that step
It is rapid 4) in hot pressing temperature be 150-170 DEG C, time 1min.
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