CN109370048A - The preparation method of wear-resisting landscape sprinkler - Google Patents

The preparation method of wear-resisting landscape sprinkler Download PDF

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Publication number
CN109370048A
CN109370048A CN201811196455.XA CN201811196455A CN109370048A CN 109370048 A CN109370048 A CN 109370048A CN 201811196455 A CN201811196455 A CN 201811196455A CN 109370048 A CN109370048 A CN 109370048A
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China
Prior art keywords
parts
plastics
sprinkler
weight
preparation
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Pending
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CN201811196455.XA
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Chinese (zh)
Inventor
潘建龙
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Cixi Bojie Metal Products Co Ltd
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Cixi Bojie Metal Products Co Ltd
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Priority to CN201811196455.XA priority Critical patent/CN109370048A/en
Publication of CN109370048A publication Critical patent/CN109370048A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of preparation methods of wear-resisting landscape sprinkler, the landscape sprinkler includes plastics sprinkler head, and the plastics sprinkler head includes 30-40 parts PP, 20-30 parts ABS, 10-20 parts HDPE, 10-20 parts equal styrene, 1-2 parts of antioxidants, 1-5 parts of abrasion resistant particles, 2-3 parts of toughener, 2-3 parts of pigment and 5-10 parts of glass fibres by weight.The preparation method for the wear-resisting landscape sprinkler that the present invention obtains, it uses polystyrene and ABS to be mixed as flocculating agent with PP and HDPE, it is set to improve the flexibility of plastics in coacervation process, make plastics that there is certain crushing resistance, in addition antioxidant and abrasion resistant particles are added, so that plastics sprinkler head can be satisfied with the feature of environmental protection, safety and wearability simultaneously.

Description

The preparation method of wear-resisting landscape sprinkler
Technical field
The present invention relates to a kind of preparation method of hydraulic giant, the preparation method of especially wear-resisting landscape sprinkler.
Background technique
Landscape sprinkler is that people usually require that different types of garden instrument is used alternatingly in horticulture-working.The garden Woods sprinkler includes plastics sprinkler head, and plastics sprinkler head needs to guarantee the feature of environmental protection of its material, safety and resistance to when in use Mill property, however existing plastics sprinkler head is tended not to due to the unicity of material so that being satisfied with the feature of environmental protection, peace simultaneously at present Full property and wearability, this also causes its service life shorter, and product replacement rate is high.
Summary of the invention
The wear-resisting landscape sprinkler of one kind is provided the purpose of the present invention is to solve above-mentioned the deficiencies in the prior art Preparation method.
To achieve the goals above, the preparation method of a kind of wear-resisting landscape sprinkler designed by the present invention, the garden Woods sprinkler includes plastics sprinkler head, and the plastics sprinkler head includes 30-40 parts PP, 20-30 parts ABS, 10-20 parts by weight HDPE, 10-20 parts of equal styrene, 1-2 parts of antioxidants, 1-5 parts of abrasion resistant particles, 2-3 parts of toughener, 2-3 parts of pigment and 5- 10 parts of glass fibres,
The antioxidant includes 30-40 parts of sodium tripolyphosphates, 10-15 parts of hexamethylenetetramines, 20-30 parts of tertiary fourths by weight Base hydroquinone, 5-10 part polybutadiene polyurethane, 5-10 parts of potassium fluoborates and 2-5 parts of benzotriazole,
The abrasion resistant particles include 50-60 parts of aluminium oxide, 5-15 parts of silicon carbide, 8-15 parts of quartz sands, 5-10 part four by weight Silicon fluoride and 1-5 parts of graphenes,
The toughener include by weight 70-80 parts of ethylene octane copolymers, 10-15 parts of polyether sulfones, 3-5 parts of maleic anhydrides with And 3-5 parts of hexamethylene diamines,
The pigment includes titanium dioxide, iron oxide red, iron oxide yellow, iron oxide black, carbon black, cadmium red, cadmium yellow, lead chromate yellow, oxidation One or more of chrome green, barba hispanica, zinc oxide, zinc yellow, cobalt blue.
The preparation method of the plastics sprinkler head the following steps are included:
Step 1: antioxidant is prepared, by weight by 30-40 parts of sodium tripolyphosphates, 10-15 parts of hexamethylenetetramines, 20-30 Part tert-butyl hydroquinone, 5-10 parts of polybutadiene polyurethanes, 5-10 parts of potassium fluoborates and 2-5 parts of benzotriazole are uniformly mixed, It is melted, is then pulverized after cooling up to antioxidant in high temperature furnace;
Step 2: preparation abrasion resistant particles, by weight by 50-60 parts of aluminium oxide, 5-15 parts of silicon carbide, 8-15 parts of quartz sands, 5- 10 parts of ocratations and 1-5 parts of graphenes after mixing, are dissolved in ethanol solution, and then ball grinds are up to abrasion resistant particles,
Step 3: plastics sprinkler head is prepared, by weight by 30-40 parts PP, 20-30 parts ABS, 10-20 parts HDPE, 10-20 parts Equal styrene, 1-2 parts of antioxidants, 1-5 parts of abrasion resistant particles, 2-3 parts of toughener, 2-3 parts of pigment and 5-10 parts of glass fibres Mixing, melt blending is then carried out by way of heating, is finally injected in injection molding machine and is molded, after cooling To the plastics sprinkler head, wherein injection pressure is 60Mpa, and dwell pressure 50Mpa, the dwell time is 3-4 seconds, cooling Time is 10 seconds, and mold temperature is maintained between 40-50 DEG C.
The preparation method for the wear-resisting landscape sprinkler that the present invention obtains, uses polystyrene and ABS as flocculating agent It is mixed with PP and HDPE, it is made to improve the flexibility of plastics in coacervation process, make plastics that there is certain crushing resistance, separately Outer addition antioxidant and abrasion resistant particles, so that plastics sprinkler head can be satisfied with the feature of environmental protection, safety and resistance to simultaneously Mill property.
Specific embodiment
Below with reference to embodiment, the present invention is further described.
Embodiment 1:
The preparation method of the wear-resisting landscape sprinkler of one kind provided in this embodiment, the landscape sprinkler include plastics sprinkling Head, the plastics sprinkler head include by weight 30 parts of PP, 20 parts of ABS, 10 parts of HDPE, 10 parts of equal styrene, 1 part it is anti-oxidant Agent, 1 part of abrasion resistant particles, 2 parts of toughener, 2 parts of pigment and 5 parts of glass fibres,
The antioxidant includes 30 parts of sodium tripolyphosphates, 10 parts of hexamethylenetetramines, 20 parts of tert-butyls to benzene two by weight Phenol, 5 parts of polybutadiene polyurethanes, 5 parts of potassium fluoborates and 2 parts of benzotriazole,
The abrasion resistant particles include 50 parts of aluminium oxide, 5 parts of silicon carbide, 8 parts of quartz sands, 5 parts of ocratations and 1 part by weight Graphene,
The toughener include by weight 70 parts of ethylene octane copolymers, 10 parts of polyether sulfones, 3 parts of maleic anhydrides and 3 parts oneself Diamines,
The pigment includes titanium dioxide, iron oxide red, iron oxide yellow, iron oxide black, carbon black, cadmium red, cadmium yellow, lead chromate yellow, oxidation One or more of chrome green, barba hispanica, zinc oxide, zinc yellow, cobalt blue.
The preparation method of the plastics sprinkler head the following steps are included:
Step 1: antioxidant is prepared, by weight by 30 parts of sodium tripolyphosphates, 10 parts of hexamethylenetetramines, 20 parts of tert-butyls Hydroquinone, 5 parts of polybutadiene polyurethanes, 5 parts of potassium fluoborates and 2 parts of benzotriazole are uniformly mixed, and are melted in high temperature furnace Melt, then pulverizes after cooling up to antioxidant;
Step 2: preparation abrasion resistant particles, by weight by 50 parts of aluminium oxide, 5 parts of silicon carbide, 8 parts of quartz sands, 5 parts of ocratations And 1 part of graphene is after mixing, is dissolved in ethanol solution, then ball grinds are up to abrasion resistant particles,
Step 3: plastics sprinkler head is prepared, by weight by 30 parts of PP, 20 parts of ABS, 10 parts of HDPE, 10 parts of equal styrene, 1 part Antioxidant, 1 part of abrasion resistant particles, 2 parts of toughener, 2 parts of pigment and 5 parts of glass fibre mixing, then by way of heating Melt blending is carried out, is finally injected in injection molding machine and is molded, obtains the plastics sprinkler head after cooling, wherein Injection pressure is 60Mpa, and dwell pressure 50Mpa, the dwell time is 3-4 seconds, and cooling time is 10 seconds, and mold temperature is protected It holds between 40-50 DEG C.
Embodiment 2:
The preparation method of the wear-resisting landscape sprinkler of one kind provided in this embodiment, substantially production method and embodiment 1 are consistent, Its difference is that the plastics sprinkler head includes 40 parts of PP, 30 parts of ABS, 20 parts of HDPE, 20 parts of equal styrene, 2 parts by weight Antioxidant, 5 parts of abrasion resistant particles, 3 parts of toughener, 3 parts of pigment and 10 parts of glass fibres.
Embodiment 3:
The preparation method of the wear-resisting landscape sprinkler of one kind provided in this embodiment, substantially production method and embodiment 1 are consistent, It includes 40 parts of sodium tripolyphosphates, 15 parts of hexamethylenetetramines, 30 parts of tert-butyls that its difference, which is the antioxidant by weight, Hydroquinone, 10 parts of polybutadiene polyurethanes, 10 parts of potassium fluoborates and 5 parts of benzotriazole.
Embodiment 4:
The preparation method of the wear-resisting landscape sprinkler of one kind provided in this embodiment, substantially production method and embodiment 1 are consistent, It includes 60 parts of aluminium oxide, 15 parts of silicon carbide, 15 parts of quartz sands, 10 parts of tetrafluorides that its difference, which is the abrasion resistant particles by weight, Silicon and 5 parts of graphenes.
Embodiment 5:
The preparation method of the wear-resisting landscape sprinkler of one kind provided in this embodiment, substantially production method and embodiment 1 are consistent, Its distinguish be the toughener by weight and include 80 parts of ethylene octane copolymers, 15 parts of polyether sulfones, 5 parts of maleic anhydrides and 5 parts of hexamethylene diamines.

Claims (3)

1. a kind of preparation method of wear-resisting landscape sprinkler, the landscape sprinkler includes plastics sprinkler head, it is characterised in that: The plastics sprinkler head includes 30-40 parts PP, 20-30 parts ABS, 10-20 parts HDPE, 10-20 parts equal styrene, 1- by weight 2 parts of antioxidants, 1-5 parts of abrasion resistant particles, 2-3 parts of toughener, 2-3 parts of pigment and 5-10 parts of glass fibres,
The antioxidant includes 30-40 parts of sodium tripolyphosphates, 10-15 parts of hexamethylenetetramines, 20-30 parts of tertiary fourths by weight Base hydroquinone, 5-10 part polybutadiene polyurethane, 5-10 parts of potassium fluoborates and 2-5 parts of benzotriazole,
The abrasion resistant particles include 50-60 parts of aluminium oxide, 5-15 parts of silicon carbide, 8-15 parts of quartz sands, 5-10 part four by weight Silicon fluoride and 1-5 parts of graphenes,
The preparation method of the plastics sprinkler head the following steps are included:
Step 1: antioxidant is prepared, by weight by 30-40 parts of sodium tripolyphosphates, 10-15 parts of hexamethylenetetramines, 20-30 Part tert-butyl hydroquinone, 5-10 parts of polybutadiene polyurethanes, 5-10 parts of potassium fluoborates and 2-5 parts of benzotriazole are uniformly mixed, It is melted, is then pulverized after cooling up to antioxidant in high temperature furnace;
Step 2: preparation abrasion resistant particles, by weight by 50-60 parts of aluminium oxide, 5-15 parts of silicon carbide, 8-15 parts of quartz sands, 5- 10 parts of ocratations and 1-5 parts of graphenes after mixing, are dissolved in ethanol solution, and then ball grinds are up to abrasion resistant particles,
Step 3: plastics sprinkler head is prepared, by weight by 30-40 parts PP, 20-30 parts ABS, 10-20 parts HDPE, 10-20 parts Equal styrene, 1-2 parts of antioxidants, 1-5 parts of abrasion resistant particles, 2-3 parts of toughener, 2-3 parts of pigment and 5-10 parts of glass fibres Mixing, melt blending is then carried out by way of heating, is finally injected in injection molding machine and is molded, after cooling To the plastics sprinkler head, wherein injection pressure is 60Mpa, and dwell pressure 50Mpa, the dwell time is 3-4 seconds, cooling Time is 10 seconds, and mold temperature is maintained between 40-50 DEG C.
2. the preparation method of wear-resisting landscape sprinkler according to claim 1, it is characterised in that: the toughener is by weight Measuring part includes 70-80 parts of ethylene octane copolymers, 10-15 parts of polyether sulfones, 3-5 parts of maleic anhydrides and 3-5 parts of hexamethylene diamines.
3. the preparation method of wear-resisting landscape sprinkler according to claim 1, it is characterised in that: the pigment includes titanium White powder, iron oxide red, iron oxide yellow, iron oxide black, carbon black, cadmium red, cadmium yellow, lead chromate yellow, chrome oxide green, barba hispanica, zinc oxide, zinc One or more of yellow, cobalt blue.
CN201811196455.XA 2018-10-15 2018-10-15 The preparation method of wear-resisting landscape sprinkler Pending CN109370048A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112480527A (en) * 2020-10-19 2021-03-12 镇江星扬电气管业有限公司 High-temperature-resistant anticorrosive plate and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107629325A (en) * 2017-11-22 2018-01-26 南通展鹏塑料有限公司 A kind of PP ABS composite materials formula
CN108377885A (en) * 2018-04-20 2018-08-10 张剑 A kind of gardens lawn watering device
CN207754272U (en) * 2018-01-03 2018-08-24 天津三花艳蔬菜种植专业合作社 Vegetable cultivation irrigation device

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107629325A (en) * 2017-11-22 2018-01-26 南通展鹏塑料有限公司 A kind of PP ABS composite materials formula
CN207754272U (en) * 2018-01-03 2018-08-24 天津三花艳蔬菜种植专业合作社 Vegetable cultivation irrigation device
CN108377885A (en) * 2018-04-20 2018-08-10 张剑 A kind of gardens lawn watering device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112480527A (en) * 2020-10-19 2021-03-12 镇江星扬电气管业有限公司 High-temperature-resistant anticorrosive plate and preparation method thereof

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Application publication date: 20190222