CN109365118A - The gangue seprating assistant method of pyrometallurgy - Google Patents

The gangue seprating assistant method of pyrometallurgy Download PDF

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CN109365118A
CN109365118A CN201811259780.6A CN201811259780A CN109365118A CN 109365118 A CN109365118 A CN 109365118A CN 201811259780 A CN201811259780 A CN 201811259780A CN 109365118 A CN109365118 A CN 109365118A
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gangue
scheelite
pyrometallurgy
mineral
ore
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不公告发明人
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B7/00Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets

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Abstract

The invention discloses the gangue seprating assistant methods of pyrometallurgy, belong to gangue separation field, the gangue seprating assistant method of pyrometallurgy, including coarse crushing, washup, differential separation, waste recovery, ore grinding, fluorescence sorting and flotation, the step of passing through waste recovery by part the W content rejected in differential separation it is higher but do not meet the gangue mineral of production requirement carry out it is finely divided, briquetting after enrichment, re-starting coarse crushing, washup and differential separation, carry out postsearch screening, it is not easy to result in waste of resources, the utilization rate of wolfram element in increase scheelite may be implemented, it is not easy to generate the higher tailing of more W content in generating process, although a little higher than current more extensive production method of meeting in terms of production cost of the present invention, but meet the recyclable production of current country and the fundamental state policy of built environment friendly society, It is also an important directions of the following mining industry cycle development.

Description

The gangue seprating assistant method of pyrometallurgy
Technical field
The present invention relates to gangue separation fields, more specifically to the gangue seprating assistant method of pyrometallurgy.
Background technique
Pyrometallurgy is exactly that ore or concentrate are subjected to a series of physicochemical change process under the high temperature conditions, makes it In metal separated with gangue or other impurities, and obtain the metallurgical method of metal, including roasting (or baking with agglomeration), melting, The processes such as blowing, distillation and smart gold-plating, pyro-refining, molten-salt electrolysis.
For economic angle, the raw material of pyrometallurgy is mostly the higher gangue mineral of purity, and in nature The gangue mineral ingredient of formation is not quite similar, and particularly, the unearthed gangue mineral in a pit is also likely to be present biggish gap, Therefore need to carry out ore dressing to gangue money object before metallurgy, select the higher gangue mineral of purity to carry out metallurgy, and purity is lower Gangue mineral can only do waste processing.
But metalliferous mineral belongs to non-renewable resources, and how much consumption is exactly to lose how many, for by tungsten ore, China As tungsten ore big country in the world, the rich reserves of tungsten ore, and tungsten ore is in nature mainly with wolframite and two kinds of scheelite Form exists, and wherein wolframite is easily purified and smelts and first utilized by people, the wolframite reserves in China also compared with horn of plenty, But the initial stage exploited and utilized in wolframite, due to the technical restriction of gangue separation and pyrometallurgy, along with more extensive Production method, cause the waste of a large amount of tungsten ore resource, partial metallurgical factory is even direct by tailing in order to save production cost It is discharged into nature, it is without any processing, serious influence also is caused on environment while wasting vast resources, and in length Up to after the more extensive wolframite metallurgical production of over half a century, also there is resource in the wolframite for being considered rich reserves originally Deficient situation, people have to sight turning the scheelite for being difficult to purify and smelt.
Summary of the invention
1. technical problems to be solved
Aiming at the problems existing in the prior art, the purpose of the present invention is to provide the gangue seprating assistant sides of pyrometallurgy Method, it may be implemented to increase the utilization rate of wolfram element in scheelite, during gangue mineral separation, for part W content Gangue mineral that is higher but not meeting production requirement carries out postsearch screening, is not easy to result in waste of resources, is the current mining industry in China An important ring in circular economy meets the recyclable production of current country and the fundamental state policy of built environment friendly society, though So a little higher than current more extensive production method of meeting in terms of production cost of the present invention, but be also the following mining industry cycle development An important directions.
2. technical solution
To solve the above problems, the present invention adopts the following technical scheme that.
The gangue seprating assistant method of pyrometallurgy, including the following steps are included:
Scheelite is crushed to the size of suitable differential separation by S1, coarse crushing, staff with mineral breaker.
S2, washup, staff clean the scheelite Jing Guo coarse crushing, the impurity for scheelite surface attachment of going out.
S3, differential separation, cleaned scheelite and clear water are added in mineral centrifuge staff together, carry out from Heart separation, obtains the gangue mineral and waste tailing of the white tungsten stone of target.
S4, waste recovery after tailing is carried out waste recovery processing by staff, repeat S1-S3, carry out to tailing secondary Separation.
S5, ore grinding, staff cut after being dried from the gangue mineral for the white tungsten stone that the separation of S3 differential obtains It cuts or shaping, the shape and size of the gangue mineral of white tungsten stone is made to reach compound back production requirement.
S6, fluorescence sorting, staff utilizes ultraviolet lamp, fluorescence detection device and automatic discharging device, right Scheelite gangue mineral carries out primary election, testing by taking 80-120 millimeters of partial size scheelites as an example as a result, charging grade is 0.60% WO3, barren rock grade 0.10%WO3, WO in barren rock3Distributive law be 7.0%, barren rock mine amount percentage is about 55%.
S7, flotation, the flotation of scheelite are carried out in alkaline medium, with sodium carbonate by pH to the 9-10.5 of ore pulp, are added Enter waterglass as inhibitor, adds oxidized paraffin wax soap as capturing agent, the ore pulp formed by one ton of raw ore needs to be added in terms of coming The inhibitor waterglass and 200-400 grams of capturing agent oxidized paraffin wax soap that 500-2000 grams of modulus is 2.2-3.
The utilization rate that wolfram element in increase scheelite may be implemented, during gangue mineral separation, for part tungsten Content is higher but does not meet the progress postsearch screening of the gangue mineral of production requirement, is not easy to result in waste of resources, is that China is current An important ring in Mining Recycling Economy meets the recyclable production of current country and the basic state of built environment friendly society Plan is also that the following mining industry follows although a little higher than current more extensive production method of meeting in terms of production cost of the present invention One important directions of ring development.
Further, the S4 waste recovery includes finely divided, enrichment and briquetting, the finely divided and adjustable waste of enrichment The distribution of tungsten in tungsten ore is made the higher part enrichment of W content in waste tailing in the way of differential centrifugation, allows to waste It is easier to separate by S3 differential after mining tailing, and briquetting is then the work in order to preferably repeat S1-S3.
Further, the briquetting process in the S4 waste recovery need to add few during briquetting when necessary The adhesive of amount, such as glue improve the intensity of dough made of waste mine tailing, facilitate the work of S1-S3.
Further, mineral centrifuge described in the S3 differential centrifugation includes vertical centrifugal ore selector bracket, described Rotary drum and motor are connected on vertical centrifugal ore selector bracket, the motor is located at the side of rotary drum, the rotary drum and electricity It is connected with driving belt between motivation, waste outlet is connected on the rotary drum, is connected on the vertical centrifugal ore selector bracket There is fixing axle, and fixing axle runs through rotary drum, and the both ends of fixing axle are fixedly connected with vertical centrifugal ore selector bracket, it is described solid Disintegrating knife is connected on dead axle, and Disintegrating knife is located in rotary drum, and multiple sealings are connected between the rotary drum and fixing axle Bearing, and multiple sealing bearings are fixedly connected with rotary drum, during gangue mineral centrifuge separation, utilize high-speed rotation Higher relative velocity between rotary drum and static Disintegrating knife is finely divided to the progress of waste tailing, has saved S waste recovery In it is finely divided consumed by the energy and working hour, save the cost.
Further, when the scheelite gangue mineral that briquetting obtains in the S4 waste recovery carries out differential separation again, Influence of the adhesive added in briquetting to scheelite gangue mineral density need to be considered, to the dependency number of mineral centrifuge work It is set according to being calculated and being changed, improves the precision of secondary heart separation.
Further, the partial size of scheelite gangue mineral obtained is about 50-150mm in the S5 ore grinding, improves S6's Sharpness of separation reduces the work difficulty of fluorescence sorting machine.
Further, it needs to be ready work before the S7 Scheelite Flotation mine, since white tungsten bed mine generally entails sulphide ore, Wherein molybdenite is especially common, therefore general elder generation's Flotation of Sulfide Ores, rear fubai tungsten ore improve S7 in the beneficiation method in scheelite Flotation precision reduces the difficulty of S7 flotation.
Further, in the S7 floatation process, need to carry out carrying out again after 1 primary election 2-3 times scan with it is selected, obtain White tungsten rough concentrate and tailing improve S7 flotation precision.
Further, in the S7 flotation, a small amount of ferrous sulfate can be mixed in inhibitor waterglass, can improve S7 Selectivity in flotation improves the flotation effect of scheelite.
Further, zinc sulfate and sodium carbonate can be selected during the S7 Flotation of Sulfide Ores as inhibitor, avoid It selects cyanide as inhibitor, reduces and polluted caused by cyanide.
3. beneficial effect
Compared with the prior art, the present invention has the advantages that
(1) this programme may be implemented to increase the utilization rate of wolfram element in scheelite, meet the recyclable production of current country It but is also an important directions of the following mining industry cycle development with the fundamental state policy of built environment friendly society.
(2) S4 waste recovery includes finely divided, enrichment and briquetting, tungsten in the finely divided and adjustable waste tungsten ore of enrichment Distribution makes the higher part enrichment of W content in waste tailing, after allowing to waste mining tailing in the way of differential centrifugation It is easier to separate by S3 differential, and briquetting is then the work in order to preferably repeat S1-S3.
(3) the briquetting process in S4 waste recovery need to add a small amount of bonding during briquetting when necessary Agent, such as glue improve the intensity of dough made of waste mine tailing, facilitate the work of S1-S3.
(4) the mineral centrifuge in S3 differential centrifugation includes vertical centrifugal ore selector bracket, vertical centrifugal ore selector bracket On be connected with rotary drum and motor, motor is located at the side of rotary drum, driving belt, rotary drum is connected between rotary drum and motor On be connected with waste outlet, be connected with fixing axle on vertical centrifugal ore selector bracket, and fixing axle runs through rotary drum, and fixing axle Both ends are fixedly connected with vertical centrifugal ore selector bracket, Disintegrating knife are connected in fixing axle, and Disintegrating knife is located at rotary drum It is interior, multiple sealing bearings are connected between rotary drum and fixing axle, and multiple sealing bearings are fixedly connected with rotary drum, in gangue mine During object is centrifugated, using the higher relative velocity between the rotary drum and static Disintegrating knife of high-speed rotation to useless The progress of object tailing is finely divided, has saved the finely divided consumed energy and working hour, save the cost in S waste recovery.
It (5), need to be in view of system when the scheelite gangue mineral that briquetting obtains in S4 waste recovery carries out differential separation again Influence of the adhesive added in group to scheelite gangue mineral density calculates the related data of mineral centrifuge work It is set with changing, improves the precision of secondary heart separation.
(6) partial size of scheelite gangue mineral obtained is about 50-150mm in S5 ore grinding, improves the sharpness of separation of S6, is dropped The work difficulty of low Poison sorting machine.
(7) it needs to be ready work before S7 Scheelite Flotation mine, since white tungsten bed mine generally entails sulphide ore, wherein molybdenite It is especially common, therefore general elder generation's Flotation of Sulfide Ores, rear fubai tungsten ore improve S7 flotation precision in the beneficiation method in scheelite, Reduce the difficulty of S7 flotation.
(8) in S7 floatation process, need to carry out carrying out again after 1 primary election 2-3 times scan with it is selected, obtain white tungsten rough concentrate S7 flotation precision is improved with tailing.
(9) in S7 flotation, a small amount of ferrous sulfate can be mixed in inhibitor waterglass, can be improved in S7 flotation Selectivity, improves the flotation effect of scheelite.
(10) zinc sulfate and sodium carbonate can be selected during S7 Flotation of Sulfide Ores as inhibitor, avoid selecting cyanide As inhibitor, reduces and polluted caused by cyanide.
Detailed description of the invention
Fig. 1 is the concrete technology flow process figure that gangue of the invention separates;
Fig. 2 is the structural schematic diagram of centrifugal ore separator of the invention;
Fig. 3 is the structural schematic diagram in Fig. 2 at A.
Figure label explanation:
1 vertical centrifugal ore selector bracket, 2 rotary drums, 3 fixing axles, 4 motor, 5 driving belts, 6 Disintegrating knifes, 7 waste materials go out Mouth, 8 sealing bearings.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention;Technical solution in the embodiment of the present invention carries out clear, complete Site preparation description;Obviously;Described embodiments are only a part of the embodiments of the present invention;Instead of all the embodiments, it is based on Embodiment in the present invention;It is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment;It shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that the instruction such as term " on ", "lower", "inner", "outside", " top/bottom end " Orientation or positional relationship be based on the orientation or positional relationship shown in the drawings, be merely for convenience of description the present invention and simplification retouch It states, rather than the device or element of indication or suggestion meaning must have a particular orientation, be constructed and operated in a specific orientation, Therefore it is not considered as limiting the invention.In addition, term " first ", " second " are used for description purposes only, and cannot understand For indication or suggestion relative importance.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " installation " " is set Be equipped with ", " be arranged/connect ", " connection " etc., shall be understood in a broad sense, such as " connection ", may be a fixed connection, be also possible to removable Connection is unloaded, or is integrally connected;It can be mechanical connection, be also possible to be electrically connected;It can be directly connected, it can also be in Between medium be indirectly connected, can be the connection inside two elements.It for the ordinary skill in the art, can be specific Situation understands the concrete meaning of above-mentioned term in the present invention.
Embodiment 1:
Fig. 1-3 is please referred to, the gangue seprating assistant method of pyrometallurgy includes the next steps:
Scheelite is crushed to the size of suitable differential separation by S1, coarse crushing, staff with mineral breaker.
S2, washup, staff clean the scheelite Jing Guo S1 coarse crushing, the impurity for scheelite surface attachment of going out.
S3, differential separation, cleaned scheelite and clear water are added in mineral centrifuge staff together, carry out from Heart separation, obtains the gangue mineral and waste tailing of the white tungsten stone of target, particularly, obtains for briquetting in S4 waste recovery It, need to be close to scheelite gangue mineral in view of the adhesive added in briquetting when scheelite gangue mineral carries out differential separation again The influence of degree is calculated and is changed and set to the related data of mineral centrifuge work, and the precision of secondary heart separation is improved.
S4, waste recovery after tailing is carried out waste recovery processing by staff, repeat S1-S3, carry out to tailing secondary Separation, wherein S4 waste recovery includes finely divided, enrichment and briquetting, point that be finely divided and being enriched with tungsten in adjustable waste tungsten ore Cloth makes in waste tailing the higher part enrichment of W content in the way of differential centrifugation, allows to after waste mining tailing more Easily separated by S3 differential, and briquetting is then the work in order to preferably repeat S1-S3, the briquetting process in S4 waste recovery exists A small amount of adhesive, such as glue need to be added when necessary during briquetting, improves bulk made of waste mine tailing The intensity of object facilitates the work of S1-S3.
S5, ore grinding, staff cut after being dried from the gangue mineral for the white tungsten stone that the separation of S3 differential obtains It cuts or shaping, the shape and size of the gangue mineral of white tungsten stone is made to reach compound back production requirement, it is obtained white in S5 ore grinding The partial size of tungsten ore gangue mineral is about 50-150mm, improves the sharpness of separation of S6 fluorescence sorting, reduces the work of fluorescence sorting machine Difficulty.
S6, fluorescence sorting, staff utilizes ultraviolet lamp, fluorescence detection device and automatic discharging device, right Scheelite gangue mineral carries out primary election, testing by taking 80-120 millimeters of partial size scheelites as an example as a result, charging grade is 0.60% WO3, barren rock grade 0.10%WO3, WO in barren rock3Distributive law be 7.0%, barren rock mine amount percentage is about 55%.
S7, flotation, the flotation of scheelite are carried out in alkaline medium, with sodium carbonate by pH to the 9-10.5 of ore pulp, are added Enter waterglass as inhibitor, adds oxidized paraffin wax soap as capturing agent, the ore pulp formed by one ton of raw ore needs to be added in terms of coming 500-2000 grams of modulus is the inhibitor waterglass of 2.2-3, can mix a small amount of ferrous sulfate in waterglass, and it is floating can to improve S7 The selectivity chosen improves the flotation effect of scheelite and 200-400 grams of capturing agent oxidized paraffin wax soap, is carrying out 1 time Carried out again after primary election 2-3 times scan with it is selected, obtain white tungsten rough concentrate and tailing, improve the flotation precision of S7 flotation, S7 is floating Need to be ready work before selecting scheelite, since white tungsten bed mine generally entails sulphide ore, wherein molybdenite is especially common, therefore General elder generation's Flotation of Sulfide Ores, rear fubai tungsten ore improve S7 flotation precision, reduce the difficulty of S7 flotation in the beneficiation method of scheelite It spends, zinc sulfate and sodium carbonate can be selected as inhibitor during Flotation of Sulfide Ores in S7 flotation, avoid that cyanide is selected to make For inhibitor, reduces and polluted caused by cyanide.
Further, the mineral centrifuge in S3 differential centrifugation includes vertical centrifugal ore selector bracket 1, vertical centrifugal ore dressing Rotary drum 2 and motor 4 are connected on machine support 1, motor 4 is located at the side of rotary drum 2, is connected between rotary drum 2 and motor 4 Driving belt 5 is connected with waste outlet 7 on rotary drum 2, fixing axle 3, and fixing axle 3 is connected on vertical centrifugal ore selector bracket 1 Through rotary drum 2, and the both ends of fixing axle 3 are fixedly connected with vertical centrifugal ore selector bracket 1, and crushing is connected in fixing axle 3 Blade 6, and Disintegrating knife 6 is located in rotary drum 2, and multiple sealing bearings 8, and multiple sealings are connected between rotary drum 2 and fixing axle 3 Bearing 8 is fixedly connected with rotary drum 2, during gangue mineral centrifuge separation, utilizes the rotary drum 2 of high-speed rotation and static Higher relative velocity between Disintegrating knife 6 is finely divided to the progress of waste tailing, has saved finely divided institute in S4 waste recovery The energy of consumption and working hour, save the cost.
In the work of mineral centrifuge, motor 4 drives 2 high-speed rotation of rotary drum by driving belt 5, at this time rotary drum 2 The clear water and gangue mineral of interior placement can also be rotated with rotary drum 2, since the density of scheelite is higher than gangue density, therefore tungstenic amount The density of higher gangue mineral is high, while rotating with rotary drum 2, can tightly be attached on the inner wall of rotary drum 2, and tungstenic The lower part of rotary drum 2 can be fallen on by measuring lower unqualified gangue mineral then, since gangue mineral can turn with 2 one superhigh speed of rotary drum It is dynamic, thus referring now to the static Disintegrating knife 6 being ignorant of, the relative velocity of gangue mineral is larger, when striking Disintegrating knife 6, meeting It is crashed, is achieved the purpose that finely divided.
Compared to existing more extensive production method, the present invention may be implemented to increase the utilization of wolfram element in scheelite Rate, during gangue mineral separation, gangue mineral that is higher for part W content but not meeting production requirement is carried out Postsearch screening is not easy to result in waste of resources, and is an important ring in the current Mining Recycling Economy in China, meets following for current country Ring production and built environment friendly society fundamental state policy, although in terms of production cost of the present invention can it is a little higher than currently more Extensive production method, but be also an important directions of the following mining industry cycle development.
It is described above;It is merely preferred embodiments of the present invention;But scope of protection of the present invention is not limited thereto; Anyone skilled in the art is in the technical scope disclosed by the present invention;According to the technique and scheme of the present invention and its It improves design and is subject to equivalent substitution or change;It should be covered by the scope of protection of the present invention.

Claims (10)

1. the gangue seprating assistant method of pyrometallurgy, it is characterised in that: the following steps are included:
Scheelite is crushed to the size of suitable differential separation by S1, coarse crushing, staff with mineral breaker.
S2, washup, staff clean the scheelite Jing Guo S1 coarse crushing, the impurity for scheelite surface attachment of going out.
Cleaned scheelite and clear water are added together in mineral centrifuge by S3, differential separation, staff, carry out centrifugation point From obtaining the gangue mineral and waste tailing of the white tungsten stone of target.
S4, waste recovery after tailing is carried out waste recovery processing by staff, repeat S1-S3, carry out secondary point to tailing From.
S5, ore grinding, staff will be separated from S3 differential cut after the gangue mineral of white tungsten stone obtained is dried or Shaping makes the shape and size of the gangue mineral of white tungsten stone reach compound back production requirement.
S6, fluorescence sorting, staff utilize ultraviolet lamp, fluorescence detection device and automatic discharging device, dialogue tungsten Mine gangue mineral carries out primary election, testing by taking 80-120 millimeters of partial size scheelites as an example as a result, charging grade is 0.6%WO3, give up Stone grade is 0.1%WO3, WO in barren rock3Distributive law be 7.0%, barren rock mine amount percentage is about 55%.
S7, flotation, the flotation of scheelite are carried out in alkaline medium, and with sodium carbonate by pH to the 9-10.5 of ore pulp, water is added Glass adds oxidized paraffin wax soap as capturing agent, 500- need to be added in terms of coming in the ore pulp formed by one ton of raw ore as inhibitor The inhibitor waterglass and 200-400 grams of capturing agent oxidized paraffin wax soap that 2000 grams of moduluses are 2.2-3.
2. the gangue seprating assistant method of pyrometallurgy according to claim 1, it is characterised in that: the S4 waste recovery Including finely divided, enrichment and briquetting.
3. the gangue seprating assistant method of pyrometallurgy according to claim 1 or 2, it is characterised in that: the S4 waste material Briquetting process in recycling need to add a small amount of adhesive, such as glue during briquetting when necessary.
4. the gangue seprating assistant method of pyrometallurgy according to claim 1, it is characterised in that: the S3 differential separation Described in mineral centrifuge include vertical centrifugal ore selector bracket (1), be connected on the vertical centrifugal ore selector bracket (1) Rotary drum (2) and motor (4), the motor (4) is located at the side of rotary drum (2), between the rotary drum (2) and motor (4) It is connected with driving belt (5), is connected with waste outlet (7) on the rotary drum (2), on the vertical centrifugal ore selector bracket (1) Be connected with fixing axle (3), and fixing axle (3) run through rotary drum (2), and the both ends of fixing axle (3) with vertical centrifugal ore selector branch Frame (1) is fixedly connected, and is connected with Disintegrating knife (6) on the fixing axle (3), and Disintegrating knife (6) is located in rotary drum (2), institute It states and is connected with multiple sealing bearings (8) between rotary drum (2) and fixing axle (3), and multiple sealing bearings (8) are solid with rotary drum (2) Fixed connection.
5. the gangue seprating assistant method of pyrometallurgy according to claim 1,2 or 3, it is characterised in that: the S4 is useless When the scheelite gangue mineral that briquetting obtains in material recycling carries out differential separation again, the adhesive added in briquetting need to be considered Influence to scheelite gangue mineral density is calculated and is changed and set to the related data of mineral centrifuge work.
6. the gangue seprating assistant method of pyrometallurgy according to claim 1, it is characterised in that: made in the S5 ore grinding The partial size of the scheelite gangue mineral obtained is about 50-150mm.
7. the gangue seprating assistant method of pyrometallurgy according to claim 1, it is characterised in that: the S7 Scheelite Flotation It needs to be ready work before mine, since white tungsten bed mine generally entails sulphide ore, wherein molybdenite is especially common, therefore in scheelite Beneficiation method in general first Flotation of Sulfide Ores, rear fubai tungsten ore.
8. the gangue seprating assistant method of pyrometallurgy according to claim 1, it is characterised in that: the S7 floatation process In, need to carry out carrying out again after 1 primary election 2-3 times scan with it is selected, obtain white tungsten rough concentrate and tailing.
9. the gangue seprating assistant method of pyrometallurgy according to claim 1, it is characterised in that: inhibiting in the S7 A small amount of ferrous sulfate can be mixed in agent waterglass.
10. the gangue seprating assistant method of pyrometallurgy according to claim 7, it is characterised in that: flotation in the S7 Zinc sulfate and sodium carbonate can be selected during sulphide ore as inhibitor.
CN201811259780.6A 2018-10-26 2018-10-26 The gangue seprating assistant method of pyrometallurgy Pending CN109365118A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114682392A (en) * 2022-03-29 2022-07-01 洛阳毅流选矿技术服务有限公司 Scheelite flotation process for improving tungsten recovery rate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114682392A (en) * 2022-03-29 2022-07-01 洛阳毅流选矿技术服务有限公司 Scheelite flotation process for improving tungsten recovery rate

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