CN109306126A - Substitute materials for wood and mold - Google Patents

Substitute materials for wood and mold Download PDF

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Publication number
CN109306126A
CN109306126A CN201811171022.9A CN201811171022A CN109306126A CN 109306126 A CN109306126 A CN 109306126A CN 201811171022 A CN201811171022 A CN 201811171022A CN 109306126 A CN109306126 A CN 109306126A
Authority
CN
China
Prior art keywords
wood
substitute materials
weight
mold
thermoplastic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811171022.9A
Other languages
Chinese (zh)
Inventor
李�瑞
周晓东
满洪洋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Apko Mould Materials (shanghai) Co Ltd
Original Assignee
Apko Mould Materials (shanghai) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Apko Mould Materials (shanghai) Co Ltd filed Critical Apko Mould Materials (shanghai) Co Ltd
Priority to CN201811171022.9A priority Critical patent/CN109306126A/en
Publication of CN109306126A publication Critical patent/CN109306126A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to substitute materials for wood domain variabilities to disclose a kind of substitute materials for wood and a kind of mold, the filler of the thermoplastic resin containing 10-80 weight % and 20-90 weight % in the substitute materials for wood.The mold is formed by substitute materials for wood according to the present invention by extrusion process.Substitute materials for wood of the invention has the advantages that can to recycle and environmental protection.

Description

Substitute materials for wood and mold
Technical field
The present invention relates to substitute materials for wood fields, and in particular, to a kind of substitute materials for wood and a kind of mold.
Background technique
In model and mold manufacture field, early stage timber is chosen for the material of modeling and mold, because timber is just It is preferably easy to get and is easily worked, so being once widely used.There is also obvious disadvantages for timber: being easy to absorb moisture, intensity not Enough high, easily-deformable, homogeneity are poor etc..In today's technologically advanced, very high to requirements such as the precision and stabilities of mold, it passes The timber of system has been unable to meet such requirement.
Since hardness is high, thermal expansion coefficient is low and good stability of the dimension, metal material are also widely used for die industry. But the intermetallic composite coating period is long and feature at high cost equally also limits it in the application of certain die industries, such as metal material It is unsuitable for manufacturing large-scale model mold, the mould for needing quickly to deliver etc..
With the development of modern high molecular material, macromolecule generation wood is synthesized in fast-developing trend, which overcome tradition The shortcomings that timber and Metal mould material, a kind of substitute materials for wood for the modeling mold being commonly used are heat cured generations Wood material (such as epoxy generation wood, Polyurethane wood substitution, polyester generation is wooden and phenolic resin is for wood etc.), these substitute materials for wood are at present not It can be efficiently recovered utilization, discarded rear thermosetting material therein is difficult to degrade, and causes very big pollution to environment.
Summary of the invention
The object of the present invention is to provide one kind can recycle and environmental protection substitute materials for wood.
To achieve the goals above, the present invention provides a kind of substitute materials for wood, contains 10-80 weight in the substitute materials for wood Measure the thermoplastic resin of % and the filler of 20-90 weight %.
Further, the thermoplastic resin is selected from polypropylene, ABS plastic, polyethylene terephthalate and Buddhist nun One or more of dragon.
Further, the ABS modeling of the polypropylene containing 30-50 weight % in the thermoplastic resin, 10-20 weight % The nylon of material, the polyethylene terephthalate of 10-20 weight % and 10-20 weight %.
Further, the filler is selected from glass microsphere powder, the one or more of talcum powder and pearl powder.
Further, plasticizer, catalyst and defoaming agent are also contained in the substitute materials for wood.
Further, the catalyst in organic bismuth catalyst, organozinc catalyst or zirconium class catalyst one Kind is a variety of.
Further, the plasticizer is one or both of DOTP or DOP.
Further, the defoaming agent is fluorine richness organic silicon defoamer.
In addition, the mold passes through extrusion by substitute materials for wood above-mentioned according to the present invention the present invention also provides a kind of mold Technique is formed.
Substitute materials for wood of the invention due to the thermoplastic resin containing 10-80 weight % and 20-90 weight % filler, because This can make substitute materials for wood melt to reuse after manufacturing mold by heating mould, it is seen that substitute materials for wood of the invention Have the advantages that can to recycle and environmental protection.
Mold of the invention equally has substitute materials for wood of the invention due to being made of substitute materials for wood of the invention Above-mentioned advantage.
Other features and advantages of the present invention will the following detailed description will be given in the detailed implementation section.
Specific embodiment
Detailed description of the preferred embodiments below.It should be understood that described herein specific Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
The present invention provides a kind of substitute materials for wood, specifically, the thermoplastic resin containing 10-80 weight % in the substitute materials for wood The filler of rouge and 20-90 weight %.
Substitute materials for wood of the invention due to the thermoplastic resin containing 10-80 weight % and 20-90 weight % filler, because This can make substitute materials for wood melt to reuse after manufacturing mold by heating mould, it is seen that substitute materials for wood of the invention Have the advantages that can to recycle and environmental protection.In addition, substitute materials for wood of the invention also has, hardness is higher, be easy to machine, The high advantage of accurate to dimension.
In substitute materials for wood of the invention, specifically, the thermoplastic resin is selected from polypropylene, ABS plastics, poly- pair One or more of ethylene terephthalate and nylon.In above-mentioned substitute materials for wood, it is preferred that the thermoplastic resin In the polypropylene containing 30-50 weight %, the ABS plastics of 10-20 weight %, 10-20 weight % poly terephthalic acid second two The nylon of alcohol ester and 10-20 weight %.In above-mentioned substitute materials for wood, more specifically, containing 50 weights in the thermoplastic resin Measure the polypropylene of %, the ABS plastic of 15 weight %, the polyethylene terephthalate of 15 weight % and the Buddhist nun of 20 weight % Dragon.
In substitute materials for wood of the invention, specifically, the filler is selected from glass microsphere powder, talcum powder and pearl powder It is one or more kinds of.
In substitute materials for wood of the invention, it is preferred that also contain plasticizer, catalyst and defoaming in the substitute materials for wood Agent.Specifically, the catalyst is selected from one of organic bismuth catalyst, organozinc catalyst or zirconium class catalyst or more Kind, the plasticizer is one or both of DOTP or DOP, and the defoaming agent is fluorine richness organic silicon defoamer.
In addition, the mold passes through extrusion by substitute materials for wood according to the present invention the present invention also provides a kind of mold Technique is formed.
Mold of the invention equally has substitute materials for wood of the invention due to being made of substitute materials for wood of the invention Above-mentioned advantage.
It is the specific embodiment of substitute materials for wood according to the present invention below.
First embodiment
The filler of thermoplastic resin, 20.7 weight % containing 69.1 weight % in the substitute materials for wood of first embodiment, 7.6 The defoaming agent of the plasticizer of weight %, the catalyst of 0.4 weight % and 2.2 weight %.
Second embodiment
The filler of thermoplastic resin, 36.5 weight % containing 55.6 weight % in the substitute materials for wood of second embodiment, 5.5 The defoaming agent of the plasticizer of weight %, the catalyst of 0.3 weight % and 2.1 weight %.
3rd embodiment
The filler of thermoplastic resin, 48.6 weight % containing 45.6 weight % in the substitute materials for wood of second embodiment, 4.1 The defoaming agent of the plasticizer of weight %, the catalyst of 0.2 weight % and 1.5 weight %.
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above Detail within the scope of the technical concept of the present invention can be with various simple variants of the technical solution of the present invention are made, this A little simple variants all belong to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance In the case where shield, can be combined in any appropriate way, in order to avoid unnecessary repetition, the present invention to it is various can No further explanation will be given for the combination of energy.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally The thought of invention, it should also be regarded as the disclosure of the present invention.

Claims (10)

1. a kind of substitute materials for wood, which is characterized in that thermoplastic resin and 20- containing 10-80 weight % in the substitute materials for wood The filler of 90 weight %.
2. substitute materials for wood according to claim 1, which is characterized in that the thermoplastic resin is moulded selected from polypropylene, ABS One or more of material, polyethylene terephthalate and nylon.
3. substitute materials for wood according to claim 2, which is characterized in that contain 30-50 weight % in the thermoplastic resin Polypropylene, the ABS plastic of 10-20 weight %, the polyethylene terephthalate of 10-20 weight % and 10-20 weight % Nylon.
4. substitute materials for wood according to claim 3, which is characterized in that poly- containing 50 weight % in the thermoplastic resin Propylene, the ABS plastic of 15 weight %, the polyethylene terephthalate of 15 weight % and 20 weight % nylon.
5. substitute materials for wood according to claim 1, which is characterized in that the filler is selected from glass microsphere powder, talcum powder With the one or more of pearl powder.
6. substitute materials for wood according to claim 1, which is characterized in that also containing plasticizer, catalysis in the substitute materials for wood Agent and defoaming agent.
7. substitute materials for wood according to claim 6, it is characterised in that: the catalyst is selected from organic bismuth catalyst, has One of machine zinc catalyst or zirconium class catalyst are a variety of.
8. substitute materials for wood according to claim 6, it is characterised in that: the plasticizer be one of DOTP or DOP or Two kinds.
9. substitute materials for wood according to claim 6, it is characterised in that: the defoaming agent is fluorine richness organic silicon defoamer.
10. a kind of mold, which is characterized in that the mold is by substitute materials for wood as claimed in any of claims 1 to 9 It is formed by extrusion process.
CN201811171022.9A 2018-10-09 2018-10-09 Substitute materials for wood and mold Pending CN109306126A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811171022.9A CN109306126A (en) 2018-10-09 2018-10-09 Substitute materials for wood and mold

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811171022.9A CN109306126A (en) 2018-10-09 2018-10-09 Substitute materials for wood and mold

Publications (1)

Publication Number Publication Date
CN109306126A true CN109306126A (en) 2019-02-05

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811171022.9A Pending CN109306126A (en) 2018-10-09 2018-10-09 Substitute materials for wood and mold

Country Status (1)

Country Link
CN (1) CN109306126A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1621440A (en) * 2004-10-21 2005-06-01 俞立群 Plastic lignified board and its making method
WO2009036089A1 (en) * 2007-09-10 2009-03-19 Sabic Innovative Plastics Ip B.V. Synthetic resin process and article useful for plating applications
CN105906940A (en) * 2016-05-27 2016-08-31 中山大学惠州研究院 Marble or wood 3D printing plastic and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1621440A (en) * 2004-10-21 2005-06-01 俞立群 Plastic lignified board and its making method
WO2009036089A1 (en) * 2007-09-10 2009-03-19 Sabic Innovative Plastics Ip B.V. Synthetic resin process and article useful for plating applications
CN105906940A (en) * 2016-05-27 2016-08-31 中山大学惠州研究院 Marble or wood 3D printing plastic and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
卢毅: "《新技术革命研读资料摘编》", 31 May 1984 *

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Application publication date: 20190205

RJ01 Rejection of invention patent application after publication