CN109251467A - A kind of High Strength Wear-Resistance Material - Google Patents
A kind of High Strength Wear-Resistance Material Download PDFInfo
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- CN109251467A CN109251467A CN201811046164.2A CN201811046164A CN109251467A CN 109251467 A CN109251467 A CN 109251467A CN 201811046164 A CN201811046164 A CN 201811046164A CN 109251467 A CN109251467 A CN 109251467A
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- high strength
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
- C08L2205/20—Hollow spheres
Abstract
The invention discloses a kind of High Strength Wear-Resistance Materials, it is mixed by component A and B component according to mass ratio 2:3, component A includes following components according to the mass fraction: 100-200 parts of ABS, 10-13 parts of glass fibre, 50-80 parts of high density polyvinyl-chloride, 6-12 parts of unsaturated polyester (UP), 15-20 parts of graphite microparticles, 6-8 parts of polypropylene grafted maleic anhydride, 4-8 parts of ZnOw, 3-5 parts of coupling agent;B component includes following components according to the mass fraction: 80-100 parts of nylon resin, 30-50 parts of phenol-formaldehyde resin modified, 10-15 parts of carbon fiber, 30-40 parts of reinforcing fiber, 50-70 parts of nano silica, 2-4 parts of metal powder, 4-5 parts of 2,6 di tert butyl 4 methyl phenol, 3-8 parts of methyl ethyl ketone peroxide, polyurethane -10-20 parts of graphene composite light foam stuffing, 6-10 parts of Noryl, 3-5 parts of dispersing agent, 1-3 parts of antistatic agent.
Description
Technical field
The present invention relates to a kind of High Strength Wear-Resistance Materials.
Background technique
Blackboard eraser be it is essential in our daily study as teaching aid, and common blackboard eraser also has it that can not keep away
The drawbacks of exempting from is exactly that can often not small touching fall on the ground in use, causes its damage, it is often necessary to replace, it is therefore desirable to
A kind of High Strength Wear-Resistance Material is hardly damaged it durable.
Summary of the invention
The technical problem to be solved by the present invention is to provide a kind of high intensity for the above disadvantage of the existing technology
Wear-resistant material.
The technical solution that the present invention solves the above technical problem is: a kind of High Strength Wear-Resistance Material, by component A and B component
It is mixed according to mass ratio 2:3, wherein component A includes following components according to the mass fraction: 100-200 parts of ABS, glass fibers
It is 10-13 parts of dimension, 50-80 parts of high density polyvinyl-chloride, 6-12 parts of unsaturated polyester (UP), 15-20 parts of graphite microparticles, polypropylene grafted
6-8 parts of maleic anhydride, 4-8 parts of ZnOw, 3-5 parts of coupling agent;
B component includes following components according to the mass fraction: 80-100 parts of nylon resin, 30-50 parts of phenol-formaldehyde resin modified, carbon fiber
Tie up 10-15 parts, 30-40 parts of reinforcing fiber, 50-70 parts of nano silica, 2-4 parts of metal powder, 2,6- di-t-butyl -4- first
4-5 parts of base phenol, 3-8 parts of methyl ethyl ketone peroxide, polyurethane -10-20 parts of graphene composite light foam stuffing, Noryl
6-10 parts, 3-5 parts of dispersing agent, 1-3 parts of antistatic agent.
The technical solution that the present invention further limits is:
Component A above-mentioned includes following components according to the mass fraction: 100 parts of ABS, 10 parts of glass fibre, high density polyvinyl-chloride
50 parts, 6 parts of unsaturated polyester (UP), 15 parts of graphite microparticles, 6 parts of polypropylene grafted maleic anhydride, 4 parts of ZnOw, coupling agent 3
Part,
B component includes following components according to the mass fraction: 80 parts of nylon resin, 10 parts of carbon fiber, increases 30 parts of phenol-formaldehyde resin modified
Strong 30 parts of fiber, 50 parts of nano silica, 2 parts of metal powder, 4 parts of 2,6- di-t-butyl -4- methylphenol, peroxidating first
3 parts of ethyl ketone, polyurethane -10 parts of graphene composite light foam stuffing, 6 parts of Noryl, 3 parts of dispersing agent, antistatic agent 1
Part.
Component A above-mentioned includes following components according to the mass fraction: 150 parts of ABS, 12 parts of glass fibre, high density are poly-
65 parts of vinyl chloride, 9 parts of unsaturated polyester (UP), 18 parts of graphite microparticles, 7 parts of polypropylene grafted maleic anhydride, 6 parts of ZnOw, idol
4 parts of agent of connection;
B component includes following components according to the mass fraction: 90 parts of nylon resin, 40 parts of phenol-formaldehyde resin modified, 13 parts of carbon fiber,
35 parts of reinforcing fiber, 60 parts of nano silica, 3 parts of metal powder, 4.5 parts of 2,6- di-t-butyl -4- methylphenol, peroxide
Change 5 parts of methyl ethyl ketone, polyurethane -15 parts of graphene composite light foam stuffing, 8 parts of Noryl, 3.5 parts of dispersing agent, resist it is quiet
2 parts of electric agent.
Component A above-mentioned includes following components according to the mass fraction: 180 parts of ABS, 13 parts of glass fibre, high density it is poly-
70 parts of vinyl chloride, 10 parts of unsaturated polyester (UP), 20 parts of graphite microparticles, 8 parts of polypropylene grafted maleic anhydride, 8 parts of ZnOw, idol
5 parts of agent of connection;
B component includes following components according to the mass fraction: 100 parts of nylon resin, 45 parts of phenol-formaldehyde resin modified, carbon fiber 15
Part, 40 parts of reinforcing fiber, 65 parts of nano silica, 4 parts of metal powder, 5 parts of 2,6- di-t-butyl -4- methylphenol, peroxide
Change 7 parts of methyl ethyl ketone, polyurethane -18 parts of graphene composite light foam stuffing, 10 parts of Noryl, 4 parts of dispersing agent, resist it is quiet
3 parts of electric agent.
Coupling agent above-mentioned is silane coupling agent, the silane coupling agent be CG-101, CG-102, CG-103, CG-132,
The mixture of one or more of CG-152, CG-201, CG-202.
Metal powder above-mentioned is one or more of copper powder, nickel powder, palladium powder, molybdenum powder, aluminium powder mixture.
Unsaturated polyester (UP) above-mentioned is maleic anhydride, fumaric acid, M-phthalic acid, phthalic anhydride, right
One of phthalic acid and adipic acid.
Antistatic agent above-mentioned includes quaternary ammonium salt, amine salt, phosphate, sulfonate, polyalcohol, polyol fatty acid ester, gathers
One of ethylene oxide additives, quatemay ammonium inner salt, alanine salt are a variety of.
Reinforcing fiber above-mentioned is the non-twist glass rove of alkali-free or ceramic fibre.
Dispersing agent above-mentioned is one or more kinds of mixed in atoleine, glyceryl tristearate or ethylene bis stearamide
Close object.
The beneficial effects of the present invention are:
The present invention has excellent impact resistance and intensity, avoids housing failure to cause to replace significantly, is added simultaneously in the housing
Glass fibre, carbon fiber and reinforcing fiber effectively improve its impact resistance, and are mixed these three fibers according to test result
After conjunction, 160kJ/ ㎡ can be reached with resistance to 230 DEG C and -70 DEG C of temperature, impact strength, bending strength reaches 200MPa, stretches strong
Degree reaches 100MPa, has the advantages that high tenacity and high intensity;Metal powder is added in the present invention, can effectively improve intensity,
Longitudinal tensile strength and transverse tensile strength are all in 80MPa or more
Nylon resin is added in the present invention, has many advantages, such as strong tough and tensile, flexibility, binding force, wear-resisting, oil resistant, water-fast and antienzyme bacterium,
Polyurethane-graphene composite light foam stuffing is added, the objects such as heat resistance, wearability and the tension for improving nylon resin can be imitated
Rationality energy, antistatic agent can propose the antistatic property of material, and ZnOw is capable of the crocking resistance and toughness of reinforcing material;
Silane coupling agent is added in the present invention, and there are many mixing, can not only improve the adhesiveness of glass fibre and resin
Can, greatly improve the intensity of glass fibre reinforced composion, moreover it is possible to improve polyurethane-graphene composite light foam stuffing and
Dispersibility and bonding force of the metal powder in resin improve its compatibility between resin, improve the mechanical strength that material obtains
With the performances such as weatherability.
Specific embodiment
Embodiment 1
The present embodiment provides a kind of High Strength Wear-Resistance Material, component A and B component are mixed according to mass ratio 2:3, wherein A group
Divide includes following components according to the mass fraction: 100 parts of ABS, 10 parts of glass fibre, 50 parts of high density polyvinyl-chloride, unsaturation are poly-
6 parts of ester, 15 parts of graphite microparticles, 6 parts of polypropylene grafted maleic anhydride, 4 parts of ZnOw, 3 parts of coupling agent,
B component includes following components according to the mass fraction: 80 parts of nylon resin, 10 parts of carbon fiber, increases 30 parts of phenol-formaldehyde resin modified
Strong 30 parts of fiber, 50 parts of nano silica, 2 parts of metal powder, 4 parts of 2,6- di-t-butyl -4- methylphenol, peroxidating first
3 parts of ethyl ketone, polyurethane -10 parts of graphene composite light foam stuffing, 6 parts of Noryl, 3 parts of atoleine, antistatic agent
1 part;
Wherein coupling agent is silane coupling agent, which is, tri- kinds of mixtures of CG-103, CG-132, CG-152;Metal
Powder is four kinds of nickel powder, palladium powder, molybdenum powder, aluminium powder mixtures;Antistatic agent includes quaternary ammonium salt, polyol fatty acid ester and polyoxyethylene
Three kinds of mixtures of alkene additives.
Embodiment 2
The present embodiment provides a kind of High Strength Wear-Resistance Materials, are mixed by component A and B component according to mass ratio 2:3, wherein A
Component includes following components according to the mass fraction: 150 parts of ABS, 12 parts of glass fibre, 65 parts of high density polyvinyl-chloride, insatiable hunger
With 9 parts of polyester, 18 parts of graphite microparticles, 7 parts of polypropylene grafted maleic anhydride, 6 parts of ZnOw, 4 parts of coupling agent;
B component includes following components according to the mass fraction: 90 parts of nylon resin, 40 parts of phenol-formaldehyde resin modified, 13 parts of carbon fiber,
35 parts of reinforcing fiber, 60 parts of nano silica, 3 parts of metal powder, 4.5 parts of 2,6- di-t-butyl -4- methylphenol, peroxide
Change 5 parts of methyl ethyl ketone, polyurethane -15 parts of graphene composite light foam stuffing, 8 parts of Noryl, glyceryl tristearate 3.5
Part, 2 parts of antistatic agent;
Wherein coupling agent is silane coupling agent, which is tri- kinds of mixtures of CG-101, CG-102 and CG-103;Metal
Powder is four kinds of nickel powder, palladium powder, molybdenum powder, aluminium powder mixtures;Antistatic agent includes phosphate, sulfonate and three kinds of polyalcohol mixing
Object.
Embodiment 3
The present embodiment provides a kind of High Strength Wear-Resistance Materials, are mixed by component A and B component according to mass ratio 2:3, wherein A
Component includes following components according to the mass fraction: 180 parts of ABS, 13 parts of glass fibre, 70 parts of high density polyvinyl-chloride, insatiable hunger
With 10 parts of polyester, 20 parts of graphite microparticles, 8 parts of polypropylene grafted maleic anhydride, 8 parts of ZnOw, 5 parts of coupling agent;
B component includes following components according to the mass fraction: 100 parts of nylon resin, 45 parts of phenol-formaldehyde resin modified, carbon fiber 15
Part, 40 parts of reinforcing fiber, 65 parts of nano silica, 4 parts of metal powder, 5 parts of 2,6- di-t-butyl -4- methylphenol, peroxide
Change 7 parts of methyl ethyl ketone, polyurethane -18 parts of graphene composite light foam stuffing, 10 parts of Noryl, ethylene bis stearamide 4
Part, 3 parts of antistatic agent;
Wherein coupling agent is silane coupling agent, which is tri- kinds of mixtures of CG-152, CG-201 and CG-202;Metal
Powder is four kinds of nickel powder, palladium powder, molybdenum powder, aluminium powder mixtures;Antistatic agent includes two kinds of quatemay ammonium inner salt, alanine salt mixtures.
In addition to the implementation, the present invention can also have other embodiments.It is all to use equivalent substitution or equivalent transformation shape
At technical solution, fall within the scope of protection required by the present invention.
Claims (10)
1. a kind of High Strength Wear-Resistance Material, which is characterized in that be mixed by component A and B component according to mass ratio 2:3, A group
Divide includes following components: 100-200 parts of ABS, 10-13 parts of glass fibre, high density polyvinyl-chloride 50-80 according to the mass fraction
Part, 6-12 parts of unsaturated polyester (UP), 15-20 parts of graphite microparticles, 6-8 parts of polypropylene grafted maleic anhydride, 4-8 parts of ZnOw,
3-5 parts of coupling agent;
B component includes following components according to the mass fraction: 80-100 parts of nylon resin, 30-50 parts of phenol-formaldehyde resin modified, carbon fiber
Tie up 10-15 parts, 30-40 parts of reinforcing fiber, 50-70 parts of nano silica, 2-4 parts of metal powder, 2,6- di-t-butyl -4- first
4-5 parts of base phenol, 3-8 parts of methyl ethyl ketone peroxide, polyurethane -10-20 parts of graphene composite light foam stuffing, Noryl
6-10 parts, 3-5 parts of dispersing agent, 1-3 parts of antistatic agent.
2. High Strength Wear-Resistance Material according to claim 1, it is characterised in that: component A includes following according to the mass fraction
Component: 100 parts of ABS, 10 parts of glass fibre, 50 parts of high density polyvinyl-chloride, 6 parts of unsaturated polyester (UP), 15 parts of graphite microparticles, gather
6 parts of propylene graft maleic anhydride, 4 parts of ZnOw, 3 parts of coupling agent,
B component includes following components according to the mass fraction: 80 parts of nylon resin, 10 parts of carbon fiber, increases 30 parts of phenol-formaldehyde resin modified
Strong 30 parts of fiber, 50 parts of nano silica, 2 parts of metal powder, 4 parts of 2,6- di-t-butyl -4- methylphenol, peroxidating first
3 parts of ethyl ketone, polyurethane -10 parts of graphene composite light foam stuffing, 6 parts of Noryl, 3 parts of dispersing agent, antistatic agent 1
Part.
3. High Strength Wear-Resistance Material according to claim 1, it is characterised in that: component A includes following according to the mass fraction
Component: 150 parts of ABS, 12 parts of glass fibre, 65 parts of high density polyvinyl-chloride, 9 parts of unsaturated polyester (UP), 18 parts of graphite microparticles, gather
7 parts of propylene graft maleic anhydride, 6 parts of ZnOw, 4 parts of coupling agent;
B component includes following components according to the mass fraction: 90 parts of nylon resin, 40 parts of phenol-formaldehyde resin modified, 13 parts of carbon fiber,
35 parts of reinforcing fiber, 60 parts of nano silica, 3 parts of metal powder, 4.5 parts of 2,6- di-t-butyl -4- methylphenol, peroxide
Change 5 parts of methyl ethyl ketone, polyurethane -15 parts of graphene composite light foam stuffing, 8 parts of Noryl, 3.5 parts of dispersing agent, resist it is quiet
2 parts of electric agent.
4. High Strength Wear-Resistance Material according to claim 1, it is characterised in that: component A includes following according to the mass fraction
Component: 180 parts of ABS, 13 parts of glass fibre, 70 parts of high density polyvinyl-chloride, 10 parts of unsaturated polyester (UP), 20 parts of graphite microparticles,
8 parts of polypropylene grafted maleic anhydride, 8 parts of ZnOw, 5 parts of coupling agent;
B component includes following components according to the mass fraction: 100 parts of nylon resin, 45 parts of phenol-formaldehyde resin modified, carbon fiber 15
Part, 40 parts of reinforcing fiber, 65 parts of nano silica, 4 parts of metal powder, 5 parts of 2,6- di-t-butyl -4- methylphenol, peroxide
Change 7 parts of methyl ethyl ketone, polyurethane -18 parts of graphene composite light foam stuffing, 10 parts of Noryl, 4 parts of dispersing agent, resist it is quiet
3 parts of electric agent.
5. High Strength Wear-Resistance Material according to claim 1, it is characterised in that: the coupling agent is silane coupling agent,
The silane coupling agent is one or more of CG-101, CG-102, CG-103, CG-132, CG-152, CG-201, CG-202
Mixture.
6. High Strength Wear-Resistance Material according to claim 1, it is characterised in that: the metal powder is copper powder, nickel powder, palladium
One or more of powder, molybdenum powder, aluminium powder mixture.
7. High Strength Wear-Resistance Material according to claim 1, it is characterised in that:: the unsaturated polyester (UP) is maleic two
One of acid anhydrides, fumaric acid, M-phthalic acid, phthalic anhydride, terephthalic acid (TPA) and adipic acid.
8. High Strength Wear-Resistance Material according to claim 1, it is characterised in that: the antistatic agent include quaternary ammonium salt,
Amine salt, phosphate, sulfonate, polyalcohol, polyol fatty acid ester, polyethylene glycol oxide additives, quatemay ammonium inner salt, in alanine salt
It is one or more.
9. High Strength Wear-Resistance Material according to claim 1, it is characterised in that: the reinforcing fiber is the non-twist glass of alkali-free
Glass rove or ceramic fibre.
10. High Strength Wear-Resistance Material according to claim 1, it is characterised in that: the dispersing agent is atoleine, three hard
One or more kinds of mixtures in glycerol or ethylene bis stearamide.
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CN201811046164.2A CN109251467A (en) | 2018-09-07 | 2018-09-07 | A kind of High Strength Wear-Resistance Material |
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CN201811046164.2A CN109251467A (en) | 2018-09-07 | 2018-09-07 | A kind of High Strength Wear-Resistance Material |
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Cited By (1)
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CN111849116A (en) * | 2020-07-17 | 2020-10-30 | 浙江王氏科技有限公司 | High-strength plastic and processing technology thereof |
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