CN109180328A - A kind of mixed type nanometer Selenium in Soil element activator and preparation method thereof - Google Patents

A kind of mixed type nanometer Selenium in Soil element activator and preparation method thereof Download PDF

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Publication number
CN109180328A
CN109180328A CN201811127699.2A CN201811127699A CN109180328A CN 109180328 A CN109180328 A CN 109180328A CN 201811127699 A CN201811127699 A CN 201811127699A CN 109180328 A CN109180328 A CN 109180328A
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fermentation
fertilizer
selenium
shell
shell powder
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Inventor
黄维
王道波
刘永贤
牛俊奇
吕其壮
任振兴
张玉
潘丽萍
宋岩
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Yulin Normal University
Agricultural Resource and Environment Research Institute of Guangxi Academy of Agricultural Sciences
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Yulin Normal University
Agricultural Resource and Environment Research Institute of Guangxi Academy of Agricultural Sciences
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00Fertilisers containing potassium
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Abstract

The invention discloses a kind of mixed type nanometer Selenium in Soil element activators and preparation method thereof.The preparation method includes: 1) to weigh following each components by weight ratio, spare: manioc waste 100-150, organic carbon fertilizer 50-100, shell powder 20-30, EM bacterium stoste 2-3 of cereal crops, organic selenium fertilizer 2-5, ocean zone shell animal shell powder 20-80, borax 15-25, potassium carbonate 20-30, calcium carbonate 15-20, trace element fertilizer 15-20;2) one time fermentation is carried out after mixing manioc waste, organic carbon fertilizer, the shell powder of cereal crops and EM bacterium stoste, obtains one time fermentation object;3) remaining each component is added into one time fermentation object, carries out secondary fermentation after mixing, obtains secondary fermentation object;4) secondary fermentation object is aged, dry, pulverize to get.The activator as made from the method for the invention can significantly improve the Se content in crops while improving crop yield.

Description

A kind of mixed type nanometer Selenium in Soil element activator and preparation method thereof
Technical field
The present invention relates to Selenium in Soil element activators, and in particular to a kind of mixed type nanometer Selenium in Soil element activator and its preparation Method.
Background technique
Selenium is micronutrient element needed by human, has anticancer, improves a variety of effects such as immunity, anti-aging, tool There are the laudatory titles such as " Promethean fire ", " king of anticancer ".The whole world has a countries and regions selenium deficiency, China more than 40 to have 2/3rds ground Area belongs to Selenium deficiency area, wherein 30% is serious selenium deficiency area.It is 50-200 μ g/d that human body selenium intake is recommended by Chinese Soclety of Nutrition, and Only 26-32 μ g/d, selenium intake are seriously relatively low for China's city dweller's intake.The distribution of global soil selenium element is extremely uneven, Guangxi It is China's only a few selenium-enriched area, only just up to 2,120,000 hectares of Gulf Area selenium-rich soil area are current regionals The maximum area drawn a circle to approve out of Geochemistry investigation work selenium-rich soil region in flakes.Inorganic selenium is converted to organic selenium using plant, Selenium In Foods content is improved, is the fundamental way for improving human body selemium nutrition.
In China, the research and development of Se-rich farm products is also in primary developing stage, and there are also most of food not Carry out selenium-rich metaplasia to produce and develop, selenium-rich industry has a extensive future.Agricultural product selenium-rich mainly has natural selenium-rich and artificial richness at present Selenium two ways.Wherein, natural selenium-rich refers to that crop absorbs the Available Selenium element in soil and reaches selenium-rich standard, but natural Selenium-rich is limited by Se content natural in nature and soil physico-chemical property.Soil physico-chemical property influences selenium in the soil Existing forms, to influence absorption of the crop to soil natural selenium element.
Guangxi selenium-rich soil area is current Chinese multiple target regional geochemistry investigation work up to more than 2.12 ten thousand square kilometres The maximum area drawn a circle to approve out selenium-rich soil in flakes.But equally exist the quagmire of agricultural product " good few, more bad ".It is main Wanting reason is that Selenium in Soil element full dose content is high, but the overwhelming majority is mineral state, and plant cannot directly be absorbed and utilized.Therefore, having must Designing one kind can make soil chats states of matter selenium Selenium in Soil element activator carry out activating soil selenium element.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of mixed type nanometer Selenium in Soil element activator and preparation method thereof, The pH value of soil is adjusted in the mixed type nanometer Selenium in Soil element activator as made from the method for the invention, increases organic matter and contains Amount, significantly improves the Se content in crops while improving crop yield.
The preparation method of mixed type nanometer Selenium in Soil element activator of the present invention, comprising the following steps:
1) following each components are weighed by weight ratio, spare:
Manioc waste 100-150, organic carbon fertilizer 50-100, cereal crops shell powder 20-30, EM bacterium stoste 2-3, organic selenium fertilizer 2-5, ocean zone shell animal shell powder 20-80, borax 15-25, potassium carbonate 20-30, calcium carbonate 15-20, trace element fertilizer 15- 20;Wherein, the manioc waste is that the residue after alcohol, moisture content 55-75% are produced by raw material of cassava;
2) manioc waste, organic carbon fertilizer, the shell powder of cereal crops and EM bacterium stoste are taken, carries out one time fermentation after mixing, Obtain one time fermentation object;Wherein, fermentation carries out under the conditions of being less than or equal to 70 DEG C, and the time of fermentation is 10-15 days;It is fermenting In the process, when the moisture content of material >=30%, every 24-30h turning and throwing once;As the moisture content < 30% of material, every 10- 15h turning and throwing once;
3) into one time fermentation object be added organic selenium fertilizer, the shell powder of ocean zone shell animal, borax, potassium carbonate, calcium carbonate and Trace element fertilizer carries out secondary fermentation after mixing, obtains secondary fermentation object;Wherein, fermentation is being less than or equal to 70 DEG C of items It is carried out under part, the time of fermentation is 3-5 days;During the fermentation, every 3-5h turning and throwing once;
4) gained secondary fermentation object is aged, and be dry, pulverize, is obtained mixed type nanometer Selenium in Soil element activator.
In above-mentioned preparation method, the shell powder of the cereal crops is preferably selected from wheat husk powder, beans shell powder and rice husk powder A combination of one or more, partial size are preferably≤500 μm.
In above-mentioned preparation method, the shell powder of the ocean zone shell animal is preferably selected from oyster shell powder, shrimp shell meal and conch meal One or more of combination, partial size be preferably≤500 μm.
In above-mentioned preparation method, the organic carbon fertilizer is organic carbon fertilizer of effective carbon content in 18-25%, it is preferred to use deep The organic carbon fertilizer (effective carbon content is 20%) of ditch between fields city Ba Tian ecological engineering limited liability company production or Fujian oasis are biochemical Organic carbon fertilizer (effective carbon content is 20%) of Co., Ltd's production etc..The trace element fertilizer is Compound trace element fertilizer, It is preferred that using Sichuan Guo Guang company production state's light strengthen more board trace element fertilizers, Shanghai Hui Tian Industrial Co., Ltd. production it is micro Element Water soluble fertilizer or the organic selenium boron zinc-iron fertiliser containing magnesium of Shandong ploughing and weeding Fei Ye Development Co., Ltd production.
In above-mentioned preparation method, one time fermentation preferably uses trough type fermentation;Secondary fermentation preferably uses stacked to ferment, this When, rain-proof is carried out during the fermentation.
In above-mentioned preparation method, the temperature and time of the ageing is same as the prior art, preferably in 15-25 DEG C of condition Lower ageing 5-10 days.It after ageing, generallys use air-dried mode and resulting material is dried, until material is aqueous It is crushed when rate≤35%, is preferably crushed to partial size≤500 μm.
The invention also includes mixed type nanometer Selenium in Soil element activators prepared by the above method.
Mixed type nanometer Selenium in Soil element activator of the present invention when in use, preferably presses the weight ratio of 1:400-500 Crops are applied to after carrying out dissolved dilution, the mode of application can be root application or foliar spray.
Compared with prior art, the present invention selects special formulation and specific zymotechnique, makes gained mixed type nanometer soil Earth selenium element activator has the pH value for adjusting soil, improves soil physics structure, increases the micro members such as magnesium in soil, boron, calcium, selenium The nutrition supply of plain fertilizer, and play the role of significantly improving Se content in crops while improving crop yield, make agriculture Crop reaches selenium-rich crops standard.On the other hand, mixed type nanometer Selenium in Soil element activator of the present invention can improve in soil Microbial flora towards in advantageous soil selenium element activate direction develop, to reduce soil nematodes and various diseases, make to mix The microelements such as type nanometer Selenium in Soil element are more conducive to crop absorption.
Specific embodiment
The present invention is described in further detail combined with specific embodiments below, content to better understand the invention, but The present invention is not limited to following embodiments.
Manioc waste involved in following embodiment is to produce alcohol using High Pressure Gun peeling post-fermentation using cassava as raw material Residue afterwards.
Embodiment 1
1) following each components are weighed by formula, spare:
Manioc waste (moisture content 60%) 100Kg, organic carbon fertilizer (Batian Ecological Engineering Co., Ltd., Shenzhen, effectively Carbon content be 20%) 50Kg, cereal crops shell powder (rice husk powder, partial size be 250-300 μm) 20Kg, EM bacterium stoste 2.5Kg, have Machine selenium fertilizer (Bo Fa Science and Technology Ltd. of Nanning City) 5Kg, ocean zone shell animal shell powder (oyster shell powder, partial size be 200 μm) 80Kg, (state's light of Sichuan Guo Guang company production strengthens the micro member of more boards for borax 25Kg, potassium carbonate 30Kg, calcium carbonate 20Kg, trace element fertilizer Plain fertilizer) 20Kg;
2) manioc waste, organic carbon fertilizer, the shell powder of cereal crops and EM bacterium stoste are taken, carries out one time fermentation after mixing (trough type fermentation) obtains one time fermentation object;Wherein, fermentation carries out under the conditions of 65 DEG C, and the time of fermentation is 12 days;It was fermenting Cheng Zhong, when the moisture content of material >=30%, per turning and throwing once for 24 hours;As the moisture content < 30% of material, every 10h turns over throwing one It is secondary;
3) into one time fermentation object be added organic selenium fertilizer, the shell powder of ocean zone shell animal, borax, potassium carbonate, calcium carbonate and Trace element fertilizer carries out secondary fermentation (stacked ferments, and rain-proof measure is carried out in fermentation process) after mixing, obtains secondary Fermentation material;Wherein, fermentation carries out under the conditions of 65 DEG C, and the time of fermentation is 5 days;During the fermentation, every 3h turning is primary;
4) gained secondary fermentation object is aged 6 days under the conditions of 20-25 DEG C, and resulting material is air-dried to moisture content≤40%, so After be crushed to 300 μm, obtain mixed type nanometer Selenium in Soil element activator.
5 activator samples are prepared respectively by step described in the present embodiment, respectively by 5 activator samples with being equivalent to it 100 times of weight of water dissolved dilution respectively obtains the activator solution of 5 different numbers (T1, T2, T3, T4 and T5).
The fertilising of rice is respectively used to using the activator solution of above-mentioned 5 different numbers as 5 processing groups, control group is Do not deal with that (experimental period is on July 15th, 2017, and place is six shrimp village of Qinzhou Qinbei District plate cities and towns, rice the Two season rice, fertilising dosage be per acre rice application mixed type nanometer Selenium in Soil element activator 2Kg (be not dissolved in water before dilution Amount), fertilization mode is equal are as follows: when Rice Heading, activator solution is sprayed on blade face, the experimental plot area of each processing group is equal It is 0.5 mu), other unmentioned management are same as the prior art.Rice was in harvest on November 15 in 2017.To different groups of water The pH value in rice field and the data such as yield, the Se content of different groups of rice are detected, as a result as described in Table 1, processing group Entirely reach selenium-rich paddy standard.
Table 1:
Embodiment 2
1) following each components are weighed by formula, spare:
Manioc waste (moisture content 70%) 150Kg, organic carbon fertilizer (Batian Ecological Engineering Co., Ltd., Shenzhen, effectively Carbon content be 20%) 100Kg, cereal crops shell powder (rice husk powder, partial size be 300 μm) 30Kg, EM bacterium stoste 3Kg, organic selenium Fertilizer (Bo Fa Science and Technology Ltd. of Nanning City) 3Kg, ocean zone shell animal shell powder (oyster shell powder, partial size be 200 μm) 60Kg, borax 20Kg, potassium carbonate 25Kg, calcium carbonate 15Kg, the trace element fertilizer (trace element water-soluble of Shanghai Hui Tian Industrial Co., Ltd. production Fertilizer) 15Kg;
2) manioc waste, organic carbon fertilizer, the shell powder of cereal crops and EM bacterium stoste are taken, carries out one time fermentation after mixing (trough type fermentation) obtains one time fermentation object;Wherein, fermentation carries out under the conditions of 65 DEG C, and the time of fermentation is 13 days;It was fermenting Cheng Zhong, when the moisture content of material >=30%, every 26h turning and throwing once;As the moisture content < 30% of material, every 15h turns over throwing one It is secondary;
3) into one time fermentation object be added organic selenium fertilizer, the shell powder of ocean zone shell animal, borax, potassium carbonate, calcium carbonate and Trace element fertilizer carries out secondary fermentation (stacked ferments, and rain-proof measure is carried out in fermentation process) after mixing, obtains secondary Fermentation material;Wherein, fermentation carries out under the conditions of 65 DEG C, and the time of fermentation is 5 days;During the fermentation, every 5h turning is primary;
4) gained secondary fermentation object is aged 6 days under the conditions of 15-20 DEG C, and resulting material is air-dried to moisture content≤35%, so After be crushed to 200 μm, obtain mixed type nanometer Selenium in Soil element activator.
5 activator samples are prepared respectively by step described in the present embodiment, respectively by 5 activator samples with being equivalent to it 100 times of weight of water dissolved dilution respectively obtains the activator solution of 5 different numbers (T1, T2, T3, T4 and T5).
The fertilising of lichee is respectively used to using the activator solution of above-mentioned 5 different numbers as 5 processing groups, control group is Do not deal with (experimental period be on August 15th, 2017, place be Guangxi Pubei County gantry town gantry village lichee, kind is osmanthus Taste, fertilising dosage are lichee application mixed type nanometer Selenium in Soil element activator 1Kg (be not dissolved in water dilution before amount) per acre, Fertilization mode is equal are as follows: in lichee bud stage, by activator solvent application in root, the litchi of each processing group is 10 (be 15-year-old and growing way similar in litchi)), other unmentioned management are same as the prior art.Rice was in 2018 Harvest on June 25.PH value to different groups of lichee root soil and the data such as yield, the Se content of different groups of rice are carried out Detection, as a result as described in Table 2, processing group entirely reaches rich selenium fruit standard.
Table 2:
Embodiment 3
1) following each components are weighed by formula, spare:
Manioc waste (moisture content 70%) 120Kg, organic carbon fertilizer (Batian Ecological Engineering Co., Ltd., Shenzhen, effectively Carbon content be 20%) 80Kg, cereal crops shell powder (rice husk powder, partial size be 300 μm) 20Kg, EM bacterium stoste 2Kg, organic selenium fertilizer (Bo Fa Science and Technology Ltd. of Nanning City) 4Kg, ocean zone shell animal shell powder (shrimp shell meal, partial size be 250 μm) 80Kg, borax 25Kg, potassium carbonate 30Kg, calcium carbonate 20Kg, trace element fertilizer (state's light of Sichuan Guo Guang company production strengthens more board trace element fertilizers) 15Kg;
2) manioc waste, organic carbon fertilizer, the shell powder of cereal crops and EM bacterium stoste are taken, carries out one time fermentation after mixing (trough type fermentation) obtains one time fermentation object;Wherein, fermentation carries out under the conditions of 70 DEG C, and the time of fermentation is 15 days;It was fermenting Cheng Zhong, when the moisture content of material >=30%, per turning and throwing once for 24 hours;As the moisture content < 30% of material, every 12h turns over throwing one It is secondary;
3) into one time fermentation object be added organic selenium fertilizer, the shell powder of ocean zone shell animal, borax, potassium carbonate, calcium carbonate and Trace element fertilizer carries out secondary fermentation (stacked ferments, and rain-proof measure is carried out in fermentation process) after mixing, obtains secondary Fermentation material;Wherein, fermentation carries out under the conditions of 50 DEG C, and the time of fermentation is 4 days;During the fermentation, every 4h turning is primary;
4) gained secondary fermentation object is aged 5 days under the conditions of 15-20 DEG C, and resulting material is air-dried to moisture content≤35%, so After be crushed to 250 μm, obtain mixed type nanometer Selenium in Soil element activator.
5 activator samples are prepared respectively by step described in the present embodiment, respectively by 5 activator samples with being equivalent to it 100 times of weight of water dissolved dilution respectively obtains the activator solution of 5 different numbers (T1, T2, T3, T4 and T5).
The fertilising of cherry and tomato, control are respectively used to using the activator solution of above-mentioned 5 different numbers as 5 processing groups Not deal with, (experimental period is on September 12nd, 2016 to group, and place is the Guangxi Qinnan District town Jiu Long high hill village, and fertilising dosage is equal Mixed type nanometer Selenium in Soil element activator 3Kg (amount before the dilution that is not dissolved in water), fertilization mode are applied for cherry and tomato per acre It is equal are as follows: when cherry and tomato is bloomed for the first time, activator solution is sprayed on blade face, the experimental plot area of each processing group is equal It is 0.5 mu, cherry and tomato ridge culture, row spacing 70cm, furrow width 30cm, two rows, line-spacing 60cm, spacing in the rows 30cm are planted in every ridge), it is other Unmentioned management is same as the prior art.Cherry and tomato was in harvest on March 15 in 2017.To different groups of cherry and tomato root The pH value of soil and the data such as yield, the Se content of different groups of cherry and tomatos are detected, as a result as described in Table 3, place Reason group entirely reaches rich selenium fruit standard.
Table 3:
Embodiment 4
1) following each components are weighed by formula, spare:
Manioc waste (moisture content 70%) 125Kg, organic carbon fertilizer (Fujian oasis biochemistry Co., Ltd production organic carbon fertilizer, Effective carbon content be 20%) 90Kg, cereal crops shell powder (beans shell powder, partial size are 250-300 μm) 30Kg, EM bacterium stoste 2.5Kg, organic selenium fertilizer (Bo Fa Science and Technology Ltd. of Nanning City) 5Kg, ocean zone shell animal shell powder (conch meal, partial size 200 μm) 80Kg, borax 20Kg, potassium carbonate 25Kg, calcium carbonate 18Kg, trace element fertilizer (Shandong ploughing and weeding Fei Ye Development Co., Ltd life The organic selenium boron zinc-iron fertiliser containing magnesium of production) 18Kg;
2) manioc waste, organic carbon fertilizer, the shell powder of cereal crops and EM bacterium stoste are taken, carries out one time fermentation after mixing (trough type fermentation) obtains one time fermentation object;Wherein, fermentation carries out under the conditions of 65 DEG C, and the time of fermentation is 14 days;It was fermenting Cheng Zhong, when the moisture content of material >=30%, every 28h turning and throwing once;As the moisture content < 30% of material, every 15h turns over throwing one It is secondary;
3) into one time fermentation object be added organic selenium fertilizer, the shell powder of ocean zone shell animal, borax, potassium carbonate, calcium carbonate and Trace element fertilizer carries out secondary fermentation (stacked ferments, and rain-proof measure is carried out in fermentation process) after mixing, obtains secondary Fermentation material;Wherein, fermentation carries out under the conditions of 60 DEG C, and the time of fermentation is 4 days;During the fermentation, every 3h turning is primary;
4) gained secondary fermentation object is aged 8 days under the conditions of 25 DEG C, and resulting material is air-dried to moisture content≤35%, then powder 300 μm are broken to, mixed type nanometer Selenium in Soil element activator is obtained.
5 activator samples are prepared respectively by step described in the present embodiment, respectively by 5 activator samples with being equivalent to it 100 times of weight of water dissolved dilution respectively obtains the activator solution of 5 different numbers (T1, T2, T3, T4 and T5).
The fertilising of capsicum is respectively used to using the activator solution of above-mentioned 5 different numbers as 5 processing groups, control group is Do not deal with (experimental period be on October 12nd, 2016, place be the Qinzhou Qinnan District rhinoceros horn town village great Ping, fertilising use Amount is capsicum application mixed type nanometer Selenium in Soil element activator 3Kg (be not dissolved in water dilution before amount) per acre, fertilization mode It is equal are as follows: when capsicum blooms for the first time, activator solution is sprayed on blade face, the experimental plot area of each processing group is 0.5 mu, capsicum ridge culture, row spacing 60cm, furrow width 30cm, two rows, line-spacing 45cm, spacing in the rows 20cm are planted in every ridge), it is other not refer to Management it is same as the prior art.Capsicum was in harvest on March 15 in 2017.PH value to different groups of capsicum root soil and right The data such as yield, the Se content of different capsicums are detected, and as a result as described in Table 4, processing group entirely reaches rich selenium fruit Standard.
Table 4:
Embodiment 5
1) following each components are weighed by formula, spare:
Manioc waste (moisture content 70%) 120Kg, organic carbon fertilizer (Fujian oasis biochemistry Co., Ltd production organic carbon fertilizer, Effective carbon content be 20%) 80Kg, cereal crops shell powder (wheat husk powder, partial size are 250-300 μm) 20Kg, EM bacterium stoste 2.5Kg, organic selenium fertilizer (Bo Fa Science and Technology Ltd. of Nanning City) 3Kg, ocean zone shell animal shell powder (oyster shell powder, partial size 250 μm) 60Kg, borax 20Kg, potassium carbonate 25Kg, calcium carbonate 15Kg, (state's light of Sichuan Guo Guang company production is strong more for trace element fertilizer Board trace element fertilizer) 15Kg;
2) manioc waste, organic carbon fertilizer, the shell powder of cereal crops and EM bacterium stoste are taken, carries out one time fermentation after mixing (trough type fermentation) obtains one time fermentation object;Wherein, fermentation carries out under the conditions of 60 DEG C, and the time of fermentation is 12 days;It was fermenting Cheng Zhong, when the moisture content of material >=30%, per turning and throwing once for 24 hours;As the moisture content < 30% of material, every 10h turns over throwing one It is secondary;
3) into one time fermentation object be added organic selenium fertilizer, the shell powder of ocean zone shell animal, borax, potassium carbonate, calcium carbonate and Trace element fertilizer carries out secondary fermentation (stacked ferments, and rain-proof measure is carried out in fermentation process) after mixing, obtains secondary Fermentation material;Wherein, fermentation carries out under the conditions of 65 DEG C, and the time of fermentation is 4 days;During the fermentation, every 4h turning is primary;
4) gained secondary fermentation object is aged 10 days at 20 °C, and resulting material is air-dried to moisture content≤35%, then 300 μm are crushed to, mixed type nanometer Selenium in Soil element activator is obtained.
5 activator samples are prepared respectively by step described in the present embodiment, respectively by 5 activator samples with being equivalent to it 100 times of weight of water dissolved dilution respectively obtains the activator solution of 5 different numbers (T1, T2, T3, T4 and T5).
The fertilising of rice is respectively used to using the activator solution of above-mentioned 5 different numbers as 5 processing groups, control group is Do not deal with that (experimental period is on July 18th, 20167, and place is the Qinzhou Qinnan District Kangxu ridge town village Shi Jia, and rice is Second season rice, fertilising dosage is that (be not dissolved in water rice application mixed type nanometer Selenium in Soil element activator 2Kg dilution per acre Preceding amount), fertilization mode is equal are as follows: when Rice Heading, activator solution is sprayed on blade face, the experimental plot area of each processing group It is 0.5 mu), other unmentioned management are same as the prior art.Rice was in harvest on November 11 in 2017.To different groups The pH value of paddy field and the data such as yield, the Se content of different groups of rice are detected, as a result as described in Table 1, processing Group entirely reaches selenium-rich paddy standard.
Table 5:

Claims (7)

1. a kind of preparation method of mixed type nanometer Selenium in Soil element activator, comprising the following steps:
1) following each components are weighed by weight ratio, spare:
Manioc waste 100-150, organic carbon fertilizer 50-100, shell powder 20-30, EM bacterium stoste 2-3 of cereal crops, organic selenium fertilizer 2-5, Shell powder 20-80, borax 15-25, potassium carbonate 20-30, calcium carbonate 15-20, the trace element fertilizer 15-20 of ocean zone shell animal;Its In, the manioc waste is that the residue after alcohol, moisture content 55-75% are produced by raw material of cassava;
2) manioc waste, organic carbon fertilizer, the shell powder of cereal crops and EM bacterium stoste are taken, one time fermentation is carried out after mixing, obtains One time fermentation object;Wherein, fermentation carries out under the conditions of being less than or equal to 70 DEG C, and the time of fermentation is 10-15 days;In fermentation process In, when the moisture content of material >=30%, every 24-30h turning and throwing once;As the moisture content < 30% of material, every 10-15h is turned over It throws primary;
3) organic selenium fertilizer, the shell powder of ocean zone shell animal, borax, potassium carbonate, calcium carbonate and micro are added into one time fermentation object Element fertilizer, carries out secondary fermentation after mixing, obtains secondary fermentation object;Wherein, fermentation is under the conditions of being less than or equal to 70 DEG C It carries out, the time of fermentation is 3-5 days;During the fermentation, every 3-5h turning and throwing once;
4) gained secondary fermentation object is aged, and be dry, pulverize, is obtained mixed type nanometer Selenium in Soil element activator.
2. according to the method described in claim 1, it is characterized by: the shell powder of the cereal crops is selected from wheat husk powder, beans shell The combination of one or more of powder and rice husk powder.
3. according to the method described in claim 1, it is characterized by: the partial size of the shell powder of the cereal crops is≤500 μm.
4. according to the method described in claim 1, it is characterized by: the shell powder of the ocean zone shell animal be selected from oyster shell powder, The combination of one or more of shrimp shell meal and conch meal.
5. according to the method described in claim 1, it is characterized by: the partial size of the shell powder of the ocean zone shell animal is≤500 μ m。
6. according to the method described in claim 1, it is characterized by: in step 4), the ageing under the conditions of 15-25 DEG C into Row, the time of ageing are 5-10 days.
7. the mixed type nanometer Selenium in Soil element activator that any one of claim 1-6 the method is prepared.
CN201811127699.2A 2018-09-27 2018-09-27 A kind of mixed type nanometer Selenium in Soil element activator and preparation method thereof Withdrawn CN109180328A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110419404A (en) * 2019-08-28 2019-11-08 广西壮族自治区农业科学院 A kind of activator of vegetable growing special-purpose soil selenium activation
CN110432106A (en) * 2019-08-28 2019-11-12 广西壮族自治区农业科学院 A kind of cultural method for the activator and selenium-rich chive that Selenium in Soil activates
CN111621302A (en) * 2020-06-29 2020-09-04 广西壮族自治区农业科学院 Selenium activation functional microbial inoculum for acid soil and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110419404A (en) * 2019-08-28 2019-11-08 广西壮族自治区农业科学院 A kind of activator of vegetable growing special-purpose soil selenium activation
CN110432106A (en) * 2019-08-28 2019-11-12 广西壮族自治区农业科学院 A kind of cultural method for the activator and selenium-rich chive that Selenium in Soil activates
CN111621302A (en) * 2020-06-29 2020-09-04 广西壮族自治区农业科学院 Selenium activation functional microbial inoculum for acid soil and preparation method thereof

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Application publication date: 20190111