CN109148047A - A kind of resistance value adjustment method of polystyrene foam bead surface utter misery - Google Patents

A kind of resistance value adjustment method of polystyrene foam bead surface utter misery Download PDF

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Publication number
CN109148047A
CN109148047A CN201811051099.2A CN201811051099A CN109148047A CN 109148047 A CN109148047 A CN 109148047A CN 201811051099 A CN201811051099 A CN 201811051099A CN 109148047 A CN109148047 A CN 109148047A
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resistance value
carbon black
polystyrene foam
foam bead
coating
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CN201811051099.2A
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CN109148047B (en
Inventor
梁勇明
胡益民
樊迪刚
李自强
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Nanjing aerospace Boping Electronic Technology Co., Ltd
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Nanjing Boping Electronic Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/0026Apparatus for manufacturing conducting or semi-conducting layers, e.g. deposition of metal
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20Conductive material dispersed in non-conductive organic material
    • H01B1/24Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B5/00Non-insulated conductors or conductive bodies characterised by their form
    • H01B5/14Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports

Abstract

The present invention relates to a kind of resistance value adjustment method of polystyrene foam bead surface utter misery, a kind of this method of the method that resistance value can be effectively reduced is.Acetylene carbon black and other structures charcoal are mixed, and glue is added to be mixed and made into coating liquid, is coated in polystyrene foam bead surface;The coating liquid raw material composition presses the weight percent of solid content are as follows: acetylene carbon black 25~40%, other structures charcoal, adhesive 45~55%, surplus are other non-conductive auxiliary agents;The wherein other structures charcoal are as follows: superconduction carbon black 3%~7%, expanded graphite 6%~18%, nano-graphite 6%~18% or carbon nanotube 3%~7%.This method can be substantially reduced resistance value, and sheet resistance value is measured after coating 4 times can reach 300~480 ohms, and every surface utter misery small spherical particles can be connected and resistance is lower.Compared with the coating situation for only with acetylene carbon black being conductive material, sheet resistance value reduces 10 times or so, is a kind of method of effectively debugging resistance value.

Description

A kind of resistance value adjustment method of polystyrene foam bead surface utter misery
Technical field
The present invention relates to a kind of resistance value adjustment methods of polystyrene foam bead surface utter misery.
Background technique
Resistance is the distinctive physical parameter of conductor, and the size of resistance and the material of conductor are related, resistance it is whether useful and What plays, is critical to see to bring what use done;Resistance is small and is easy to conduct the substance of electric current and is known as conductor, and resistance is greatly and not The substance for being good at conducting electric current is known as insulator, and the substance to fall between is known as semiconductor.
In order to increase the electric conductivity of substance, we will recognize that with metal, inorganic (ionization series, carbon system, metal oxide system), The conductive materials such as compound (inorganic-organic) type macromolecule conducting material, structural type macromolecule conducting material.But each material The applicable aspect of institute be also it is different, still must proceed from the reality, suitable one party is found in particular problem concrete analysis The conductive material of face demand.Present invention seek to address that the resistance value of polystyrene foam bead surface utter misery is reduced, in pre-stage test We are found by experiment that the increase with acetylene carbon black dosage only with single acetylene carbon black as conductive material in work Sheet resistance value is declined, but it is minimum also can only achieve 3600~4100 ohms, resistance value cannot reach expected effect Fruit, therefore cannot reach the demand of application, a kind of method reducing resistance value have to be developed.
Summary of the invention
The object of the present invention is to provide the resistance value adjustment method of polystyrene foam bead surface utter misery, a kind of reduction resistance value Method.
Present invention technical solution used in order to achieve the above object is:
A kind of resistance value adjustment method of polystyrene foam bead surface utter misery, is to mix acetylene carbon black and other structures charcoal Coating liquid is made in conjunction, is coated in polystyrene foam bead surface;The coating liquid raw material composition presses the weight percent of solid content Than are as follows: acetylene carbon black 25%~40%, other structures charcoal, adhesive 45%~55%, surplus are other non-conductive auxiliary agents;Wherein The other structures charcoal are as follows: superconduction carbon black 3%~7%, expanded graphite 6%~18%, nano-graphite 6%~18% or carbon nanometer Pipe 3%~7%.
In method of the invention, superconduction carbon black preferably 6%, expanded graphite preferably 9~12%, nano-graphite preferably 9%, carbon Nanotube preferably 6%.
In method of the invention, the preferred styrene-acrylic emulsion of adhesive is not lose powder and water resistance after guaranteeing coating 4 times, test It is minimum with 45% afterwards, therefore it is preferred that 45%.Other adhesive can be used to substitute.Conductive material of the invention is using acetylene carbon black and its The mixing of its structure charcoal, other structures charcoal use: high structural type superconduction carbon black section qin EC-600JD, expanded graphite (10 microns), Nano-graphite (0.5 micron), carbon nanotube (30-50 microns);By the acetylene carbon black of certain solid content mass percent and not Other structures charcoal with solid content mass percent matches mixing, using styrene-acrylic emulsion as adhesive, the coating that is prepared Liquid is coated in polystyrene foam bead surface, passes through test: being then not easy to stir drying, weight ratio according to weight ratio 10:9 10:7 then coats carbon amounts naturally relatively rarely, then determines to obtain optimal maximum mixed proportion using polystyrene foam bead It is 10:8 with coating liquid fixed weight ratio, coating pass is fixed as 4 times, measures quilt by QUICK499D sheet resistance tester The polystyrene foam bead surface resistance value that coating is 4 times, passes through measured value and the single coating situation pair using acetylene carbon black Than sheet resistance value is substantially reduced and can reach necessary requirement.Coating liquid of the present invention, mainly by acetylene carbon black point Water and dispersing agent high speed grinding is not added to mix with other structures charcoal, later, using styrene-acrylic emulsion as adhesive and addition Other non-conductive auxiliary agents, are dispersed with stirring according to constant weight ratio and are mixed into coating liquid.
In the present invention, the coated carrier used is polystyrene foam bead, density 20kg/m3, the small ball's diameter Between 1-4mm.
Coating method employed in the present invention is as follows, and every all over coat weight mixed proportion 10:8, (polystyrene foam is small Ball: coating liquid), it coats 4 times, according to device therefor and environment temperature and damp condition, guarantees that every time particle is substantially at dispersion State carries out next time coating again on this basis, coats 4 times and can carry out sheet resistance value survey after thorough drying overnight Amount.
In the present invention, after completing above-mentioned coating method, it is coated 4 times using the measurement of QUICK499D sheet resistance tester Polystyrene foam bead particle surface resistance value.Using the mixed of solid content weight acetylene carbon black 25%+ superconduction carbon black 6% Conjunction mode, measuring sheet resistance value is 350~450 ohm;Solid content weight acetylene carbon black 25%+ expanded graphite 9% or 12% Hybrid mode, measure sheet resistance value be 410~480 ohm;Solid content weight acetylene carbon black 25%+ nano-graphite 9% Hybrid mode, measuring sheet resistance value is 560~750 ohm;Solid content weight acetylene carbon black 25%+ carbon nanotube 6% is mixed Conjunction mode, measuring sheet resistance value is 300 ohms.
The present invention mixes acetylene carbon black with other structures charcoal respectively, and it is small to be coated in polystyrene foam after adding glue to mix Ball surface can be substantially reduced resistance value, and 300~480 ohms, every surface can be reached by measuring sheet resistance value after coating 4 times Utter misery small spherical particles can be connected and resistance is lower.Compared with the coating situation for only with acetylene carbon black being conductive material, using this The particle surface resistance value that 4 times polystyrene foam beads are coated after invention reduces 10 times or so, is a kind of effectively tune The method for trying resistance value.
Specific embodiment
Embodiment 1
1000 parts of coating liquid that acetylene carbon black accounts for solid content weight 25% are prepared, weighs 79.6 parts of acetylene carbon black by weight, Styrene-acrylic emulsion takes 287.1 parts when accounting for solid content weight 45%, 537.6 parts of water, dispersing agent and the non-conductive auxiliary agent of other routines are total 95.7 parts, first water, dispersing agent and acetylene carbon black high speed grinding are dispersed with grinder, other non-conductive auxiliary agents are then added and use and divide Machine dispersion is dissipated, styrene-acrylic emulsion SD-800 is eventually adding and is dispersed with stirring with dispersion machine and be uniformly mixed into coating liquid;It weighs by weight 100g polystyrene foam bead, takes 80 grams of coating liquids, pours into stirring container, stirs into dispersed by single planetary stirring machine State, this process are coating 1 time, then pour into 80 grams of coating liquids to the bead surface for being coated 1 time again in stirring container and carry out 2nd time coating after terminating the 2nd time coating, coats the 3rd time and the 4th time according to this method, the particle after coating 4 times needs overnight Sheet resistance value measurement thoroughly can be carried out after drying, is measured using QUICK499D sheet resistance tester and is applied with this formula The particle surface resistance value for covering 4 times polystyrene foam beads is 5600~6000 ohms, and acetylene carbon black accounts for solid content Weight 25%, 30%, 35%, 40%, the coating situation greater than 40% and analysis as shown in table 1, in order to other structures charcoal Reserved space is added, so acetylene carbon black is taken to account for solid content weight 25% as base when adding other structures charcoal and being compounded Plinth.It weighs 339.4 parts by weight when styrene-acrylic emulsion accounts for solid content weight 55%, 77.2 parts of acetylene carbon black, 521.9 parts of water, divides Powder and totally 61.5 parts of the non-conductive auxiliary agent of other routines.
Table 1
Embodiment 2
Preparation acetylene carbon black accounts for solid content weight 25% and superconduction carbon black accounts for 1000 parts of coating liquid of solid content weight 6%, 79.6 parts of acetylene carbon black are weighed by weight, and 19 parts of superconducting carbon black, styrene-acrylic emulsion takes 287.1 parts when accounting for solid content weight 45%, water 537.6 parts, dispersing agent and totally 76.7 parts of other non-conductive auxiliary agents, first with grinder by acetylene carbon black and superconduction carbon black Jia Shui and point The mixing of powder high speed grinding, the non-conductive auxiliary agent of other routines is added later and is dispersed with dispersing agent, is eventually adding styrene-acrylic emulsion and uses and divides Scattered machine, which is dispersed with stirring, is uniformly mixed into coating liquid;100g polystyrene foam bead is weighed by weight, is taken 80 grams of coating liquids, is poured into Stirring container stirs into dispersity by single planetary stirring machine, this process is coating 1 time, then in stirring container again It pours into 80 grams of coating liquids to the bead surface for being coated 1 time and carries out the 2nd time coating, after terminating the 2nd time coating, applied according to this method The 3rd time and the 4th time are covered, the particle after coating 4 times can carry out sheet resistance value measurement after needing thorough drying overnight, use The measurement of QUICK499D sheet resistance tester is coated the particle surface resistance of 4 times polystyrene foam beads with this formula Value is 350~450 ohms, and addition superconduction carbon black accounts for solid content weight 3%, 4%, 5%, 6%, 7%, 9% when compounding It coats situation and analysis is as shown in table 2.Weigh 339.4 parts by weight when styrene-acrylic emulsion accounts for solid content weight 55%, superconduction charcoal Black 18.6 parts, 77.2 parts of acetylene carbon black, 521.9 parts of water, dispersing agent and totally 42.9 parts of the non-conductive auxiliary agent of other routines.
Table 2
Embodiment 3
Preparation acetylene carbon black accounts for solid content weight 25% and expanded graphite accounts for 1000 parts of coating liquid of solid content weight 9%, 79.6 parts of acetylene carbon black are weighed by weight, 28.6 parts of expanded graphite, styrene-acrylic emulsion takes 286.8 parts when accounting for solid content weight 45%, 537.6 parts of water, dispersing agent and totally 67.4 parts of other non-conductive auxiliary agents, first with grinder by acetylene carbon black and superconduction carbon black add water and The mixing of dispersing agent high speed grinding, the non-conductive auxiliary agent of other routines is added later and is dispersed with dispersing agent, is eventually adding styrene-acrylic emulsion use Dispersion machine, which is dispersed with stirring, is uniformly mixed into coating liquid;100g polystyrene foam bead is weighed by weight, takes 80 grams of coating liquids, Enter stirring container, dispersity is stirred by single planetary stirring machine, this process is coating 1 time, then in stirring container 80 grams of coating liquids to the bead surface for being coated 1 time is poured into again and carries out the 2nd time coating, after terminating the 2nd time coating, according to this method The 3rd time and the 4th time are coated, the particle after coating 4 times can carry out sheet resistance value measurement after needing thorough drying overnight, use The measurement of QUICK499D sheet resistance tester is coated the particle surface resistance of 4 times polystyrene foam beads with this formula Value is 410~480 ohms, when compounding addition expanded graphite account for solid content weight 6%, 9%, 12%, 15%, 18%, it is big It is as shown in table 3 in 18% coating situation and analysis.339.4 are weighed by weight when styrene-acrylic emulsion accounts for solid content weight 55% Part, 27.6 parts of expanded graphite, 77.2 parts of acetylene carbon black, 521.9 parts of water, dispersing agent and the non-conductive auxiliary agent of other routines totally 33.9 Part.
Table 3
Embodiment 4
Preparation acetylene carbon black accounts for solid content weight 25% and nano-graphite accounts for 1000 parts of coating liquid of solid content weight 9%, 79.6 parts of acetylene carbon black are weighed by weight, 28.6 parts of nano-graphite, styrene-acrylic emulsion takes 286.8 parts when accounting for solid content weight 45%, 537.6 parts of water, dispersing agent and totally 67.4 parts of the non-conductive auxiliary agent of other routines are first added acetylene carbon black and superconduction carbon black with grinder Water and the mixing of dispersing agent high speed grinding, other non-conductive auxiliary agents are added later and are dispersed with dispersion machine, are eventually adding styrene-acrylic emulsion use Dispersion machine, which is dispersed with stirring, is uniformly mixed into coating liquid;100g polystyrene foam bead is weighed by weight, takes 80 grams of coating liquids, Enter stirring container, dispersity is stirred by single planetary stirring machine, this process is coating 1 time, then in stirring container 80 grams of coating liquids to the bead surface for being coated 1 time is poured into again and carries out the 2nd time coating, after terminating the 2nd time coating, according to this method The 3rd time and the 4th time are coated, the particle after coating 4 times can carry out sheet resistance value measurement after needing thorough drying overnight, use The measurement of QUICK499D sheet resistance tester is coated the particle surface resistance of 4 times polystyrene foam beads with this formula Value is 560~750 ohms, when compounding addition nano-graphite account for solid content weight 6%, 9%, 12%, 15%, 18%, it is big It is as shown in table 4 in 18% coating situation and analysis.339.4 are weighed by weight when styrene-acrylic emulsion accounts for solid content weight 55% Part, 27.6 parts of nano-graphite, 77.2 parts of acetylene carbon black, 521.9 parts of water, dispersing agent and the non-conductive auxiliary agent of other routines totally 33.9 Part.
Table 4
Embodiment 5
Preparation acetylene carbon black accounts for solid content weight 25% and carbon nanotube accounts for 1000 parts of coating liquid of solid content weight 6%, 79.6 parts of acetylene carbon black are weighed by weight, and 19 parts of carbon nanotube, styrene-acrylic emulsion takes 287.1 parts when accounting for solid content weight 45%, water 537.6 parts, acetylene carbon black and superconduction carbon black are first added water with grinder by dispersing agent and totally 76.7 parts of the non-conductive auxiliary agent of other routines It is mixed with dispersing agent high speed grinding, other non-conductive auxiliary agents is added later and are dispersed with dispersion machine, be eventually adding styrene-acrylic emulsion and use and divide Scattered machine, which is dispersed with stirring, is uniformly mixed into coating liquid;100g polystyrene foam bead is weighed by weight, is taken 80 grams of coating liquids, is poured into Stirring container stirs into dispersity by single planetary stirring machine, this process is coating 1 time, then in stirring container again It pours into 80 grams of coating liquids to the bead surface for being coated 1 time and carries out the 2nd time coating, after terminating the 2nd time coating, applied according to this method The 3rd time and the 4th time are covered, the particle after coating 4 times can carry out sheet resistance value measurement after needing thorough drying overnight, use The measurement of QUICK499D sheet resistance tester is coated the particle surface resistance of 4 times polystyrene foam beads with this formula Value is 300 ohms, and addition carbon nanotube accounts for the coating feelings of solid content weight 3%, 4%, 5%, 6%, 7%, 9% when compounding Condition and analysis are as shown in table 5.Weigh 339.4 parts by weight when styrene-acrylic emulsion accounts for solid content weight 55%, carbon nanotube 18.6 Part, 77.2 parts of acetylene carbon black, 521.9 parts of water, dispersing agent and totally 42.9 parts of the non-conductive auxiliary agent of other routines.
Table 5

Claims (8)

1. a kind of resistance value adjustment method of polystyrene foam bead surface utter misery, which is characterized in that by acetylene carbon black and other Structure charcoal is mixed and made into coating liquid, is coated in polystyrene foam bead surface;The coating liquid raw material composition is by solid content Weight percent are as follows: acetylene carbon black 25~40%, other structures charcoal, adhesive 45~55%, surplus are other non-conductive auxiliary agents; The wherein other structures charcoal are as follows: superconduction carbon black 3%~7%, expanded graphite 6%~18%, nano-graphite 6%~18% or carbon Nanotube 3%~7%.
2. the resistance value adjustment method of polystyrene foam bead surface utter misery as described in claim 1, which is characterized in that acetylene Carbon black loading is 25%.
3. the resistance value adjustment method of polystyrene foam bead surface utter misery as described in claim 1, which is characterized in that described Other structures charcoal are as follows: superconduction carbon black section qin EC-600JD, 10 microns of expanded graphite, 0.5 micron of nano-graphite or 30-50 are micro- The carbon nanotube of rice.
4. the resistance value adjustment method of polystyrene foam bead surface utter misery as described in claim 1, which is characterized in that other The ratio of structure charcoal are as follows: superconduction carbon black 6%, expanded graphite 9-12%, nano-graphite 9%, carbon nanotube 6%.
5. the resistance value adjustment method of polystyrene foam bead surface utter misery as described in claim 1, which is characterized in that described Adhesive is styrene-acrylic emulsion, and its ratio be 45%.
6. the resistance value adjustment method of polystyrene foam bead surface utter misery as described in claim 1, which is characterized in that described Polystyrene foam bead, density 20kg/m3, the small ball's diameter is between 1-4mm.
7. the resistance value adjustment method of polystyrene foam bead surface utter misery as described in claim 1, which is characterized in that described Every time coat weight mixed proportion is by polystyrene foam bead: coating liquid 10:8 is coated 4 times.
8. a kind of resistance value adjustment method of polystyrene foam bead surface utter misery, which is characterized in that according to the requirement of following sheet resistance Design raw material proportioning, it may be assumed that when sheet resistance value being needed to reach 300 ohms, then use solid content weight acetylene carbon black 25%+ The hybrid mode proportion of carbon nanotube 6%+ styrene-acrylic emulsion 45% carries out coating 4 times;Sheet resistance value is needed to reach 350~450 When ohm, then coating 4 times is carried out using the hybrid mode proportion of acetylene carbon black 25%+ superconduction carbon black 6%+ styrene-acrylic emulsion 45%; When sheet resistance value being needed to reach 410~480 ohm, then acetylene carbon black 25%+ expanded graphite 9%+ styrene-acrylic emulsion 45% is used Hybrid mode proportion carry out coating 4 times;When sheet resistance value being needed to reach 560~750 ohm, then acetylene carbon black 25% is used The hybrid mode proportion of+nano-graphite 9%+ styrene-acrylic emulsion 45% carries out coating 4 times.
CN201811051099.2A 2018-09-10 2018-09-10 Resistance value debugging method for surface carbon coating of polystyrene foam pellets Active CN109148047B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101253231A (en) * 2005-08-23 2008-08-27 巴斯夫欧洲公司 Method for producing foamed slabs
US20100304075A1 (en) * 2009-05-28 2010-12-02 Nova Chemicals Inc. Enhanced expanded polystyrene foam insulation
CN103408788A (en) * 2013-08-06 2013-11-27 南京洛普电子工程研究所 Flame-retardance wave-absorbing polystyrene foam material and preparation method thereof
CN103911628A (en) * 2014-03-30 2014-07-09 复旦大学 Nano Si/TiO2 ordered array compound photocatalytic water splitting hydrogen preparing cathode material and preparation method thereof
CN107428984A (en) * 2015-03-13 2017-12-01 巴斯夫欧洲公司 Conductive particle foam based on thermoplastic elastomer (TPE)

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101253231A (en) * 2005-08-23 2008-08-27 巴斯夫欧洲公司 Method for producing foamed slabs
US20100304075A1 (en) * 2009-05-28 2010-12-02 Nova Chemicals Inc. Enhanced expanded polystyrene foam insulation
CN103408788A (en) * 2013-08-06 2013-11-27 南京洛普电子工程研究所 Flame-retardance wave-absorbing polystyrene foam material and preparation method thereof
CN103911628A (en) * 2014-03-30 2014-07-09 复旦大学 Nano Si/TiO2 ordered array compound photocatalytic water splitting hydrogen preparing cathode material and preparation method thereof
CN107428984A (en) * 2015-03-13 2017-12-01 巴斯夫欧洲公司 Conductive particle foam based on thermoplastic elastomer (TPE)

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