CN109143098A - A kind of lithium ion battery life estimation method and device - Google Patents

A kind of lithium ion battery life estimation method and device Download PDF

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Publication number
CN109143098A
CN109143098A CN201811131200.5A CN201811131200A CN109143098A CN 109143098 A CN109143098 A CN 109143098A CN 201811131200 A CN201811131200 A CN 201811131200A CN 109143098 A CN109143098 A CN 109143098A
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China
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life
same
lithium ion
operating condition
under
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王克坚
张雅琨
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CH Auto Technology Co Ltd
Beijing Changcheng Huaguan Automobile Technology Development Co Ltd
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Beijing Changcheng Huaguan Automobile Technology Development Co Ltd
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Abstract

Embodiment of the present invention discloses a kind of lithium ion battery life estimation method and device.Method includes: the same life experiment operating condition n repeated sample of setting for lithium ion battery, and obtains the life test data of n repeated sample, and wherein n is the positive integer for being at least 5;The probability distribution curve to fail using Wei Buer probability distribution curve as lithium ion battery under same life experiment operating condition, the life test data of quasi- n repeated sample is to obtain the form parameter for the probability distribution curve that lithium ion battery fails under same life experiment operating condition and be expressed as the scale parameter of characteristics life, the battery life function under same life experiment operating condition is determined based on form parameter and scale parameter, and wherein battery life argument of function is failure probability;The failure probability particular value under same life experiment operating condition is received, and determines the battery life of the failure probability particular value corresponded under same life experiment operating condition based on the battery life function under same life experiment operating condition.

Description

A kind of lithium ion battery life estimation method and device
Technical field
Embodiment of the present invention is related to automobile technical field, in particular to a kind of lithium ion battery life estimation method and dress It sets.
Background technique
Have in national newest standards " term and definition of automobile and trailer type " (GB/T 3730.1-2001) to automobile Such as give a definition: by power drive, the vehicle of the non-track carrying with 4 or 4 or more wheels is mainly used for: carrying personnel And (or) cargo;Draw the vehicle of carrying personnel and (or) cargo;Specific use.Energy shortage, oil crisis and environmental pollution It grows in intensity, brings tremendous influence to people's lives, be directly related to the sustainable development of national economy and society.The world is each State is all in active development new energy technology.
Lithium ion (Li+) battery is a kind of secondary cell (rechargeable battery), it relies primarily on lithium ion in anode and cathode Between it is mobile come work.In charge and discharge process, Li+Insertion and deintercalation back and forth between two electrodes: when charging, Li+From anode Deintercalation is embedded in cathode by electrolyte, and cathode is in lithium-rich state;It is then opposite when electric discharge.The advance of lithium ion battery technology With the application in emerging key market (electric car field), the research and development upsurge in global range is excited, lithium ion battery will Critical positions are occupied in electric car and new energy field.It is phosphorus using more lithium ion battery at present in electric car Sour lithium iron battery, its thermal stability and safety is preferable, while price is relatively cheap.
Current lithium ion battery life estimation method mainly establishes life model using based on previous experiments data, in turn Predict battery life.However, the decline of lithium ion battery service life also includes other than following the aging rule under applying working condition Uncertain and randomness, the failure probability of lithium ion battery are gradually increasing with the increase of use time.Lithium ion battery During making and using, all there is inconsistency, the failure that this inconsistency will lead to lithium ion battery will not be stringent Concentrate on a time point.
In the battery service life model establishment process of the prior art, the processing to life experiment result is usually to take same operating The lifetime results average value of lower difference battery thinks that reasonable lifetime results are modeled as life characteristic values.However, This life model lacks considering for failure probability, has ignored the randomness and contingency of sample inconsistency and failure.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of lithium ion battery life estimation method and devices, to consider Lithium ion battery failure randomness, improves life estimate accuracy rate.
The technical solution of embodiment of the present invention is as follows:
A kind of lithium ion battery life estimation method, comprising:
N repeated sample is set for the same life experiment operating condition of lithium ion battery, and obtains the n repeated sample Life test data, wherein n be at least 5 positive integer;
It fails using Wei Buer probability distribution curve as lithium ion battery described under the same life experiment operating condition general Rate distribution curve, it is described under the same life experiment operating condition to obtain to be fitted the life test data of the n repeated sample The form parameter of the probability distribution curve of lithium ion battery failure and the scale parameter for being expressed as characteristics life, are based on the shape Parameter and the scale parameter determine the battery life function under the same life experiment operating condition, wherein the battery life letter Several independents variable is failure probability;
The failure probability particular value under the same life experiment operating condition is received, and is based on the same life experiment operating condition Under battery life function determine correspond to the same life experiment operating condition under failure probability particular value battery life.
In one embodiment, the battery life function under the same life experiment operating condition is T (f), and wherein f is to lose Imitate probability;
Wherein m is form parameter, and η is scale parameter;Ln is natural logrithm.
In one embodiment, the same life experiment operating condition includes at least one of following:
Same temperature and same depth of discharge;
Same temperature and same discharge-rate;
Same temperature, same depth of discharge and same discharge-rate;
Same depth of discharge and same discharge-rate.
In one embodiment, this method further include:
Scale parameter function is determined using scheduled modeling pattern, wherein the scale parameter argument of function is the service life Experiment condition parameter;
The probability to fail using Wei Buer probability distribution curve as lithium ion battery described under different life experiment operating conditions point Cloth curve, be fitted the life test data of the n repeated sample with obtain under the different life experiment operating condition lithium from The form parameter of the probability distribution curve of sub- battery failure;It is lost based on the lithium ion battery under the different life experiment operating conditions The form parameter of the probability distribution curve of effect and the scale parameter function determine the electricity under the different life experiment operating conditions Pond lifetime function, wherein the battery life argument of function under the difference life experiment operating condition is life experiment operating condition ginseng Number.
In one embodiment, the scale parameter function is η (T, DOD), in which:
η (T, DOD)=exp (13.0538854971714+0.00236583998482005*T- 0.0594247691002157*DOD-(T-23.3333333333333)*((T-23.3333333333333)* 0.00174559910640996)-(T-23.3333333333333)*((DOD-85)*0.000250796508614118)+ (DOD-85) * ((DOD-85) * 0.000100081224917486)), wherein T is temperature parameter;DOD is depth of discharge parameter; Exp is exponential function.
A kind of lithium ion battery life estimate device, comprising:
Data acquisition module sets n repeated sample for the same life experiment operating condition for lithium ion battery, and obtains The life test data of the n repeated sample is obtained, wherein n is the positive integer for being at least 5;
Battery life function determination module, for using Wei Buer probability distribution curve as the same life experiment operating condition Under lithium ion battery failure probability distribution curve, be fitted the life test data of the n repeated sample to obtain It states the form parameter of the probability distribution curve of the lithium ion battery failure and expression under same life experiment operating condition and is characterized the longevity The scale parameter of life determines the battery longevity under the same life experiment operating condition based on the form parameter and the scale parameter Function is ordered, wherein the battery life argument of function is failure probability;
Battery life estimation block, for receiving the failure probability particular value under the same life experiment operating condition, and base Battery life function under the same life experiment operating condition determines the failure corresponded under the same life experiment operating condition The battery life of probability particular value.
In one embodiment, the battery life function under the same life experiment operating condition is T (f), and wherein f is to lose Imitate probability;
Wherein m is form parameter, and η is scale parameter;Ln is natural logrithm.
In one embodiment, the same life experiment operating condition includes at least one of following:
Same temperature and same depth of discharge;
Same temperature and same discharge-rate;
Same temperature, same depth of discharge and same discharge-rate;
Same depth of discharge and same discharge-rate.
In one embodiment, further includes:
Scale parameter function determination module, for determining scale parameter function using scheduled modeling pattern, wherein described Scale parameter argument of function is life experiment duty parameter;
The wherein battery life function determination module is also used to real using Wei Buer probability distribution curve as the different service life The probability distribution curve for testing lithium ion battery failure under operating condition, be fitted the life test data of the n repeated sample with Obtain the form parameter of the probability distribution curve of the lithium ion battery failure under the different life experiment operating conditions;Based on described The form parameter of the probability distribution curve of the lithium ion battery failure and the scale parameter letter under different life experiment operating conditions Number determines the battery life function under the different life experiment operating conditions, wherein the electricity under the difference life experiment operating condition The independent variable of pond lifetime function is life experiment duty parameter.
In one embodiment, the scale parameter function is η (T, DOD), in which:
η (T, DOD)=exp (13.0538854971714+0.00236583998482005*T- 0.0594247691002157*DOD-(T-23.3333333333333)*((T-23.3333333333333)* 0.00174559910640996)-(T-23.3333333333333)*((DOD-85)*0.000250796508614118)+ (DOD-85) * ((DOD-85) * 0.000100081224917486)), wherein T is temperature parameter;DOD is depth of discharge parameter; Exp is exponential function.
It can be seen from the above technical proposal that the same life experiment operating condition for lithium ion battery sets n repeating sample This, and the life test data of n repeated sample is obtained, wherein n is the positive integer for being at least 5;It is bent with Wei Buer probability distribution The probability distribution curve that line fails as lithium ion battery under same life experiment operating condition intends the life test of n repeated sample Data are to obtain the form parameter for the probability distribution curve that lithium ion battery fails under same life experiment operating condition and be expressed as spy The scale parameter for levying the service life, determines the battery life function under same life experiment operating condition based on form parameter and scale parameter, Wherein battery life argument of function is failure probability;The failure probability particular value under same life experiment operating condition is received, and Determine that the failure probability corresponded under same life experiment operating condition is special based on the battery life function under same life experiment operating condition The battery life of definite value.As it can be seen that embodiment of the present invention failed using Wei Buer probability distribution curve as lithium ion battery it is general Rate distribution curve, by lithium ion battery failure randomness and contingency introduce lithium ion battery life model, improve lithium from The life estimate accuracy rate of sub- battery can be used for instructing cost estimate, use, maintenance and the replacement of Vehicular dynamic battery.
Moreover, in embodiments of the present invention, by the way that characteristics life is modeled as variable relevant to aging effects factor, And then failure probability and battery life under different operating conditions are obtained, improve applicability.
Detailed description of the invention
Only illustratively description and explain the present invention for the following drawings, not delimit the scope of the invention.
Fig. 1 is lithium ion battery life estimation method flow chart according to the present invention.
Fig. 2 is according to the probability density curve signal that lithium ion battery fails under the operating condition of η=892 of the present invention, m=20 Figure.
Fig. 3 is according to the probability distribution curve signal that lithium ion battery fails under the operating condition of η=892 of the present invention, m=20 Figure.
The probability density that it is 25 DEG C that Fig. 4, which is according to temperature of the present invention, lithium ion battery fails under the operating condition that DOD is 100 is bent Line schematic diagram.
The probability distribution that it is 25 DEG C that Fig. 5, which is according to temperature of the present invention, lithium ion battery fails under the operating condition that DOD is 100 is bent Line schematic diagram.
Fig. 6 is lithium ion battery life estimate structure drawing of device according to the present invention.
Specific embodiment
In order to which the technical features, objects and effects of invention are more clearly understood, the Detailed description of the invention present invention is now compareed Specific embodiment, identical label indicates identical part in the various figures.
It is succinct and intuitive in order to what is described, hereafter by describing several representative embodiments come to side of the invention Case is illustrated.A large amount of details is only used for helping to understand the solution of the present invention in embodiment.However, it will be apparent that of the invention Technical solution can be not limited to these details when realizing.In order to avoid unnecessarily having obscured the solution of the present invention, Yi Xieshi It applies mode not described meticulously, but only gives frame.Hereinafter, " comprising " refers to " including but not limited to ", " root According to ... " refer to " according at least to ..., but be not limited to according only to ... ".Due to the speech habits of Chinese, hereinafter without spy When not pointing out the quantity of an ingredient, it is meant that the ingredient is either one or more, or can be regarded as at least one.
In embodiments of the present invention, consider lithium ion battery failure randomness, establish the battery longevity for considering failure probability Model is ordered to predict battery life, cost estimate, use, maintenance and the replacement of Vehicular dynamic battery can be instructed.Wherein, with Wei The probability distribution curve that boolean's (Weibull) probability distribution curve fails as lithium ion battery, by lithium ion battery failure Randomness and contingency introduce lithium ion battery life model.
Fig. 1 is lithium ion battery life estimation method flow chart according to the present invention.
As shown in Figure 1, this method comprises:
Step 101: setting n repeated sample for the same life experiment operating condition of lithium ion battery, and obtain n repetition The life test data of sample, wherein n is the positive integer for being at least 5.
Step 102: failing using Wei Buer probability distribution curve as lithium ion battery under same life experiment operating condition general Rate distribution curve, the life test data of fitting n repeated sample are lost with obtaining lithium ion battery under same life experiment operating condition The form parameter of the probability distribution curve of effect and the scale parameter for being expressed as characteristics life, it is true based on form parameter and scale parameter Battery life function under fixed same life experiment operating condition, wherein battery life argument of function is failure probability.
Step 103: receiving the failure probability particular value under same life experiment operating condition, and be based on same life experiment operating condition Under battery life function determine correspond to same life experiment operating condition under failure probability particular value battery life.
In one embodiment, the battery life function under same life experiment operating condition is T (f), and wherein f is that failure is general Rate;
Wherein m is form parameter, and η is scale parameter;Ln is natural logrithm.
In one embodiment, same life experiment operating condition includes: same temperature and same depth of discharge;Same temperature With same discharge-rate;Same temperature, same depth of discharge and same discharge-rate;Same depth of discharge and same electric discharge times Rate, etc..
In one embodiment, this method further include: scale parameter function is determined using scheduled modeling pattern, wherein Scale parameter argument of function is life experiment duty parameter;Using Wei Buer probability distribution curve as different life experiment works The probability distribution curve that lithium ion battery fails under condition, the life test data of fitting n repeated sample is to obtain the different service life The form parameter for the probability distribution curve that lithium ion battery fails under experiment condition;Based on lithium ion under different life experiment operating conditions The form parameter and scale parameter function of the probability distribution curve of battery failure, determine the battery under different life experiment operating conditions Lifetime function, wherein the battery life argument of function under different life experiment operating conditions is life experiment duty parameter.
Preferably, scale parameter function is η (T, DOD), in which: η (T, DOD)=exp (13.0538854971714+ 0.00236583998482005*T-0.0594247691002157*DOD-(T-23.3333333333333)*((T- 23.3333333333333)*0.00174559910640996)-(T-23.3333333333333)*((DOD-85)* 0.000250796508614118)+(DOD-85) * ((DOD-85) * 0.000100081224917486)), wherein T is temperature ginseng Number;DOD is depth of discharge parameter;Exp is exponential function.
Specifically, the algorithm of embodiment of the present invention is described in detail below.
Firstly, setting multiple repeated samples for the same life experiment operating condition, life experimental data is obtained.Then, it walks Suddenly with Wei Buer Probability Distribution Fitting life experimental data, the form parameter m and scale ginseng in life failure new probability formula are obtained Number η;Further according to failure probabilityBattery life under failure probability of interestThe longevity Different functions may be implemented according to life experiment complexity for life model.
For example, the same experiment condition sets N number of (N >=5) repeated sample in life experiment, experimental result is obtained, Middle N value is bigger, and experimental result precision is higher.
Then, the probability distribution curve to be failed using Wei Buer probability distribution curve as lithium ion battery;
Wherein: m is form parameter;η is scale parameter, indicates characteristics life;T is battery life;F (t) is failure probability Function.It is fitted the lifetime data of the N number of sample obtained in the same experiment condition, Wei Buer probability distribution curve ginseng can be obtained M and η in number.
For example, lithium ion battery characteristics service life η=892 time recycle under certain operating condition, failure probability form parameter m=20.Fig. 2 For the probability density curve schematic diagram to be failed according to lithium ion battery under the operating condition of η=892 of the present invention, m=20.Fig. 3 is this hair Bright η=892, m=20 operating condition under lithium ion battery fail probability distribution curve schematic diagram.
Different functions may be implemented according to life experiment complexity for the life model.Such as: under single operating condition Life experiment, the failure probability under certain service life can be calculated, the service life under certain failure probability can also be calculated.Specifically, base InIt can calculate under the same experiment condition, when specific circulating battery number (i.e. battery life) Failure probability.Moreover, the inverse function T (f) for calculating F (t) can be calculated under the same experiment condition, specific failure is general Battery life when rate particular value,Wherein T (f) is the battery life function under same life experiment operating condition, F is failure probability.
Moreover, the failure probability under different operating conditions and battery longevity can also be obtained by combining with other modeling for life Life.
It, then can will be special for example, establish the applying working condition under certain orthogonal form in conjunction with statistics experimental design in example Sign service life η is modeled as variable relevant to aging effects factor, and then obtains the failure probability service life under different operating conditions.
Table 1 is the service life under lithium ion battery 1C discharge-rate under different temperatures and depth of discharge (DOD).
Table 1
Citing is based on 1 data of table, can be modeled, be obtained using Response Surface Method to the battery life under different operating conditions:
η=exp (13.0538854971714+0.00236583998482005*T-0.059424769100215 7*DOD- (T-23.3333333333333)*((T-23.3333333333333)*0.00174559910640996)-(T- 23.3333333333333)*((DOD-85)*0.000250796508614118)+(DOD-85)*((DOD-85)* 0.000100081224917486));
Then, battery core failure probability is modeled with Weibull formula, utilizes the longevity of the n repeated sample obtained in step 101 Life test data is fitted to obtain the battery life failure conditions under any probability, obtains fitting battery characteristics life failure formula:
Wherein m=54.68, exp (13.0538854971714+ 0.00236583998482005*T-0.0594247691002157*DOD-(T-23.3333333333333)*(T- 23.3333333333333)*0.00174559910640996)-(T-23.3333333333333)*(DOD-85)* 0.000250796508614118)+(DOD-85)*((DOD-85)*0.000100081224917486))。
In the above description, it is modeled using Response Surface Method and determines scale parameter function.Those skilled in the art can anticipate Know, embodiment of the present invention can also determine scale parameter using other modeling patterns such as exponential function, polynomial function Function, embodiment of the present invention is to specific modeling pattern and is not limited.
In this way, the battery characteristics service life in temperature range [0,45] DOD range [70,100] can be obtained.For specific Operating condition, such as 25 DEG C, DOD 100, bring temperature and DOD into above-mentioned formula, then η=1315.5.
The probability density that it is 25 DEG C that Fig. 4, which is according to temperature of the present invention, lithium ion battery fails under the operating condition that DOD is 100 is bent Line schematic diagram.The probability distribution that it is 25 DEG C that Fig. 5, which is according to temperature of the present invention, lithium ion battery fails under the operating condition that DOD is 100 is bent Line schematic diagram.
Further, it is possible to set concern failure probability (such as 0.03), thenThen obtain t=1234.So far, be calculated specific operation (25 DEG C, DOD It is 1234 circulations (cycles) for the battery life under 100) when cumulative failure probability 0.03.
Embodiment of the present invention also proposed a kind of lithium ion battery life estimate device.
Fig. 6 is lithium ion battery life estimate structure drawing of device according to the present invention.
As shown in fig. 6, the device includes:
Data acquisition module 601 sets n repeated sample for the same life experiment operating condition for lithium ion battery, And the life test data of the n repeated sample is obtained, wherein n is the positive integer for being at least 5;
Battery life function determination module 602, for using Wei Buer probability distribution curve as the same life experiment The probability distribution curve of the lithium ion battery failure, is fitted the life test data of the n repeated sample to obtain under operating condition It takes the form parameter of the probability distribution curve of the lithium ion battery failure under the same life experiment operating condition and is expressed as spy The scale parameter for levying the service life, determines the electricity under the same life experiment operating condition based on the form parameter and the scale parameter Pond lifetime function, wherein the battery life argument of function is failure probability;
Battery life estimation block 603, for receiving the failure probability particular value under the same life experiment operating condition, and The mistake corresponded under the same life experiment operating condition is determined based on the battery life function under the same life experiment operating condition Imitate the battery life of probability particular value.
In one embodiment, the battery life function under same life experiment operating condition is T (f), and wherein f is that failure is general Rate;
Wherein m is form parameter, and η is scale parameter;Ln is natural logrithm.
In one embodiment, same life experiment operating condition includes at least one of following:
Same temperature and same depth of discharge;
Same temperature and same discharge-rate;
Same temperature, same depth of discharge and same discharge-rate;
Same depth of discharge and same discharge-rate.
In one embodiment, further includes:
Scale parameter function determination module 604, for determining scale parameter function using scheduled modeling pattern, wherein institute Stating scale parameter argument of function is life experiment duty parameter;
Wherein battery life function determination module 602 is also used to real using Wei Buer probability distribution curve as the different service life The probability distribution curve for testing lithium ion battery failure under operating condition, be fitted the life test data of the n repeated sample with Obtain the form parameter of the probability distribution curve of the lithium ion battery failure under the different life experiment operating conditions;Based on described The form parameter of the probability distribution curve of the lithium ion battery failure and the scale parameter letter under different life experiment operating conditions Number determines the battery life function under the different life experiment operating conditions, wherein the electricity under the difference life experiment operating condition The independent variable of pond lifetime function is life experiment duty parameter.
In one embodiment, scale parameter function is η (T, DOD), in which:
η (T, DOD)=exp (13.0538854971714+0.00236583998482005*T- 0.0594247691002157*DOD-(T-23.3333333333333)*((T-23.3333333333333)* 0.00174559910640996)-(T-23.3333333333333)*((DOD-85)*0.000250796508614118)+ (DOD-85) * ((DOD-85) * 0.000100081224917486)), wherein T is temperature parameter;DOD is depth of discharge parameter; Exp is exponential function.
Can by embodiment of the present invention proposes lithium ion battery life estimation method and device be applied to various types Electric car in, for example be applied to mixed power electric car (HEV), pure electric automobile (BEV), fuel cell electric vehicle (FCEV) and other new energy (such as supercapacitor, flywheel high-efficiency energy storage vehicle) automobiles etc..
In conclusion the same life experiment operating condition for lithium ion battery sets n repeated sample, and obtain n weight The life test data of duplicate sample sheet, wherein n is the positive integer for being at least 5;Using Wei Buer probability distribution curve as the same service life The probability distribution curve that lithium ion battery fails under experiment condition, the life test data for intending n repeated sample are same to obtain The form parameter for the probability distribution curve that lithium ion battery fails under life experiment operating condition and the scale ginseng for being expressed as characteristics life Number, determines the battery life function under same life experiment operating condition based on form parameter and scale parameter, wherein battery life letter Several independents variable is failure probability;The failure probability particular value under same life experiment operating condition is received, and real based on the same service life Test the battery life that the battery life function under operating condition determines the failure probability particular value corresponded under same life experiment operating condition. As it can be seen that the probability distribution curve that embodiment of the present invention is failed using Wei Buer probability distribution curve as lithium ion battery, by lithium The randomness and contingency of ion battery failure introduce lithium ion battery life model, improve the life estimate of lithium ion battery Accuracy rate can be used for instructing cost estimate, use, maintenance and the replacement of Vehicular dynamic battery.
Moreover, in embodiments of the present invention, by the way that characteristics life is modeled as variable relevant to aging effects factor, And then failure probability and battery life under different operating conditions are obtained, improve applicability.
It should be noted that step and module not all in above-mentioned each process and each structure chart be all it is necessary, can To ignore certain steps or module according to the actual needs.Each step execution sequence be not it is fixed, can according to need into Row adjustment.The division of each module is intended merely to facilitate the division functionally that description uses, and in actual implementation, a module can It is realized with point by multiple modules, the function of multiple modules can also be realized by the same module, these modules can be located at same In a equipment, it can also be located in different equipment.
Hardware module in each embodiment mechanically or can be realized electronically.For example, a hardware module It may include that the permanent circuit specially designed or logical device (such as application specific processor, such as FPGA or ASIC) are specific for completing Operation.Hardware module also may include programmable logic device or circuit by software provisional configuration (as included general procedure Device or other programmable processors) for executing specific operation.Mechanical system is used as specific, or using dedicated permanent Property circuit, or hardware module is realized using the circuit (such as being configured by software) of provisional configuration, can according to cost and Temporal consideration is to determine.
The present invention also provides a kind of machine readable storage medium, storage is for making a machine execute side as described herein The instruction of method.Specifically, system or device equipped with storage medium can be provided, store in realization on the storage medium State the software program code of the function of any embodiment in embodiment, and make the system or device computer (or CPU or MPU the program code being stored in a storage medium) is read and executed.Further, it is also possible to be made by the instruction based on program code Operating system of hands- operation etc. is calculated to complete partly or completely practical operation.It can also will read from storage medium The expansion being connected to a computer is write in memory set in the expansion board in insertion computer or write to program code In the memory being arranged in exhibition unit, then the instruction based on program code makes to be mounted on expansion board or expanding element CPU etc. comes execution part and whole practical operations, to realize the function of any embodiment in above embodiment.
Storage medium embodiment for providing program code include floppy disk, hard disk, magneto-optic disk, CD (such as CD-ROM, CD-R, CD-RW, DVD-ROM, DVD-RAM, DVD-RW, DVD+RW), tape, non-volatile memory card and ROM.Selectively, It can be by communication network from download program code on server computer or cloud.
It should be noted that step and module not all in above-mentioned each process and each system construction drawing is all necessary , certain steps or module can be ignored according to the actual needs.Each step execution sequence be not it is fixed, can be according to need It is adjusted.System structure described in the various embodiments described above can be physical structure, be also possible to logical construction, that is, have A little modules may be realized by same physical entity, be realized alternatively, some modules may divide by multiple physical entities, alternatively, can be with It is realized jointly by certain components in multiple autonomous devices.
In the above various embodiments, hardware cell mechanically or can be realized electrically.For example, a hardware list Member may include permanent dedicated circuit or logic (such as special processor, FPGA or ASIC) to complete corresponding operating.Firmly Part unit can also include programmable logic or circuit (such as general processor or other programmable processors), can by software into The interim setting of row is to complete corresponding operating.Concrete implementation mode (mechanical system or dedicated permanent circuit or is faced When the circuit that is arranged) can be determined based on cost and temporal consideration.
Detailed displaying and explanation carried out to the present invention above by attached drawing and preferred embodiment, however the present invention is not limited to These embodiments having revealed that, base could be aware that with above-mentioned multiple embodiment those skilled in the art, can combine above-mentioned difference Code audit means in embodiment obtain the more embodiments of the present invention, these embodiments also protection scope of the present invention it It is interior.

Claims (10)

1. a kind of lithium ion battery life estimation method characterized by comprising
N repeated sample is set for the same life experiment operating condition of lithium ion battery, and obtains the longevity of the n repeated sample Test data is ordered, wherein n is the positive integer for being at least 5;
The probability to fail using Wei Buer probability distribution curve as lithium ion battery described under the same life experiment operating condition point Cloth curve, be fitted the life test data of the n repeated sample with obtain under the same life experiment operating condition lithium from The form parameter of the probability distribution curve of sub- battery failure and the scale parameter for being expressed as characteristics life are based on the form parameter The battery life function under the same life experiment operating condition is determined with the scale parameter, wherein the battery life function Independent variable is failure probability;
The failure probability particular value under the same life experiment operating condition is received, and based under the same life experiment operating condition Battery life function determines the battery life of the failure probability particular value corresponded under the same life experiment operating condition.
2. lithium ion battery life estimation method according to claim 1, which is characterized in that the same life experiment work Battery life function under condition is T (f), and wherein f is failure probability;
Wherein m is form parameter, and η is scale parameter;Ln is natural logrithm.
3. lithium ion battery life estimation method according to claim 1, which is characterized in that the same life experiment work Condition includes at least one of following:
Same temperature and same depth of discharge;
Same temperature and same discharge-rate;
Same temperature, same depth of discharge and same discharge-rate;
Same depth of discharge and same discharge-rate.
4. lithium ion battery life estimation method according to claim 1, which is characterized in that this method further include:
Scale parameter function is determined using scheduled modeling pattern, wherein the scale parameter argument of function is life experiment Duty parameter;
The probability distribution to fail using Wei Buer probability distribution curve as lithium ion battery described under different life experiment operating conditions is bent Line is fitted the life test data of the n repeated sample to obtain the lithium-ion electric under the different life experiment operating conditions The form parameter of the probability distribution curve of pond failure;Based on the lithium ion battery failure under the different life experiment operating conditions The form parameter of probability distribution curve and the scale parameter function determine the battery longevity under the different life experiment operating conditions Function is ordered, wherein the battery life argument of function under the difference life experiment operating condition is life experiment duty parameter.
5. lithium ion battery life estimation method according to claim 4, which is characterized in that the scale parameter function is η (T, DOD), in which:
η (T, DOD)=exp (13.0538854971714+0.00236583998482005*T-0.059424769100215 7* DOD-(T-23.3333333333333)*((T-23.3333333333333)*0.00174559910640996)-(T- 23.3333333333333)*((DOD-85)*0.000250796508614118)+(DOD-85)*((DOD-85)* 0.000100081224917486)), wherein T is temperature parameter;DOD is depth of discharge parameter;Exp is exponential function.
6. a kind of lithium ion battery life estimate device characterized by comprising
Data acquisition module sets n repeated sample for the same life experiment operating condition for lithium ion battery, and obtains institute The life test data of n repeated sample is stated, wherein n is the positive integer for being at least 5;
Battery life function determination module, for using Wei Buer probability distribution curve as institute under the same life experiment operating condition The probability distribution curve for stating lithium ion battery failure, it is described same to obtain to be fitted the life test data of the n repeated sample The form parameter of the probability distribution curve of lithium ion battery failure and characteristics life is expressed as under one life experiment operating condition Scale parameter determines the battery life letter under the same life experiment operating condition based on the form parameter and the scale parameter Number, wherein the battery life argument of function is failure probability;
Battery life estimation block for receiving the failure probability particular value under the same life experiment operating condition, and is based on institute The battery life function stated under same life experiment operating condition determines the failure probability corresponded under the same life experiment operating condition The battery life of particular value.
7. lithium ion battery life estimate device according to claim 6, which is characterized in that the same life experiment work Battery life function under condition is T (f), and wherein f is failure probability;
Wherein m is form parameter, and η is scale parameter;Ln is natural logrithm.
8. lithium ion battery life estimate device according to claim 6, which is characterized in that the same life experiment work Condition includes at least one of following:
Same temperature and same depth of discharge;
Same temperature and same discharge-rate;
Same temperature, same depth of discharge and same discharge-rate;
Same depth of discharge and same discharge-rate.
9. lithium ion battery life estimate device according to claim 1, which is characterized in that further include:
Scale parameter function determination module, for determining scale parameter function using scheduled modeling pattern, wherein the scale The independent variable of parametric function is life experiment duty parameter;
The wherein battery life function determination module is also used to using Wei Buer probability distribution curve as different life experiment works The probability distribution curve of the lithium ion battery failure, is fitted the life test data of the n repeated sample to obtain under condition The form parameter of the probability distribution curve of the lithium ion battery failure under the difference life experiment operating condition;Based on the difference The form parameter of the probability distribution curve of the lithium ion battery failure and the scale parameter function under life experiment operating condition, really The battery life function under the different life experiment operating conditions is made, wherein the battery life under the difference life experiment operating condition Argument of function is life experiment duty parameter.
10. lithium ion battery life estimate device according to claim 9, which is characterized in that the scale parameter function For η (T, DOD), in which:
η (T, DOD)=exp (13.0538854971714+0.00236583998482005*T-0.059424769100215 7* DOD-(T-23.3333333333333)*((T-23.3333333333333)*0.00174559910640996)-(T- 23.3333333333333)*((DOD-85)*0.000250796508614118)+(DOD-85)*((DOD-85)* 0.000100081224917486)), wherein T is temperature parameter;DOD is depth of discharge parameter;Exp is exponential function.
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