CN109135574A - A kind of anti-radiation building coating and preparation method containing anion - Google Patents

A kind of anti-radiation building coating and preparation method containing anion Download PDF

Info

Publication number
CN109135574A
CN109135574A CN201810646951.4A CN201810646951A CN109135574A CN 109135574 A CN109135574 A CN 109135574A CN 201810646951 A CN201810646951 A CN 201810646951A CN 109135574 A CN109135574 A CN 109135574A
Authority
CN
China
Prior art keywords
parts
mixture
added
containing anion
building coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810646951.4A
Other languages
Chinese (zh)
Inventor
刁萌萌
董建平
张倩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201810646951.4A priority Critical patent/CN109135574A/en
Publication of CN109135574A publication Critical patent/CN109135574A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The present invention relates to negative ion paint technical fields, a kind of anti-radiation building coating and preparation method containing anion is specifically disclosed, and coating includes following raw material: water-soluble resin, acrylic emulsion, carbamate, Paris white, barium sulfate, ferrosilite, nanometer ferrite, graphene, barium chloride, silica flour, defoaming agent, negative ion powder, PH agent, pigment.Preparation method: carbamate and graphene are stirred, and water-soluble resin and acrylic emulsion is added, obtains mixture a1;Paris white, barium sulfate, ferrosilite, nanometer ferrite, barium chloride are added into mixture a1, obtains mixture a2;Silica flour, defoaming agent are added into mixture a2, mixture a3 is obtained after stirring;Negative ion powder, PH agent, pigment is added into mixture a3 to get the coating.Coating of the present invention has the effect of good fresh air, radiation protection, can not only reduce harm of the electromagnetic wave to human body, moreover it is possible to be effectively improved indoor air environment.

Description

A kind of anti-radiation building coating and preparation method containing anion
Technical field
The present invention relates to negative ion paint technical field more particularly to a kind of anti-radiation building coating and system containing anion Preparation Method.
Background technique
Currently, the inner wall of building in China all uses coating to fit up, paint finishing can be good at and wall in surface of wall The generation for phenomena such as being bonded together, forming complete firm protective film, reduce wall crackle, collapse.But so far, interior Wall coating is generally adopted by emulsion paint, and according to the difference of substrate, emulsion paint is generally divided into two kinds, is that polyvinyl acetate is molten respectively Liquid and acrylic acid milk solution.Both coating contain the pollutant being harmful to the human body and are up to more than ten kinds, and are also to cause interior The main reason for environmental pollution.In addition to this, with the development of science and technology the electronic products such as phone, mobile phone, computer, TV are prevailing, Either in working environment or domestic environment, these electronic products are seen everywhere, and can discharge the electromagnetism of different frequency Wave causes different degrees of damage to human body.Especially teenager and old man, constitution is weak, and resistivity is poor, is chronically in this way Environment in, it is easier to considerable degree of damage is caused to body.For modern increasing for quality of life, use Radiation protection, environmentally friendly interior wall coating are then optimal selections.
It is reported that the time in all one's life 72% of people is spent indoors, 68% disease is related to indoor environment, 80% Cancer it is related to living environment.And anion has improvement air environment, improves sleep quality, prevents respiratory disease, The effect improved the immunity of the human body, the high-quality life pursued with people mutually agree with.
Summary of the invention
For various defects existing for existing traditional radiation shielding coating on the market, it is an object of the present invention to provide one kind containing negative The anti-radiation building coating and preparation method of ion solve the problems, such as that indoor Radiation On Human body damages.The coating has On the one hand preferable radiation-proof effect can discharge anion, purify the air of a room.On the one hand indoor tv, electricity can be absorbed The electromagnetic radiation of the electric appliances such as brain, mobile phone release, provides guarantee for the health of people.
The present invention relates to a kind of anti-radiation building coating containing anion, it is composed of the following components according to parts by weight: water 30-40 parts of soluble resin, 10-20 parts of acrylic emulsion, 10-30 parts of carbamate, 10-15 parts of Paris white, barium sulfate 10- 15 parts, 3-6 parts of ferrosilite, 3-5 parts of nanometer ferrite, 0.5-1 parts of graphene, 3-5 parts of barium chloride, 5-15 parts of silica flour, defoaming 1-3 parts of agent, 5-7 parts of negative ion powder, 1-6 parts of PH agent, 2-5 parts of pigment.
The invention further relates to a kind of preparation methods of coating of anti-radiation building containing anion, include the following steps:
(1) carbamate is weighed respectively according to the proportion and graphene is added in reaction kettle, suitable quantity of water is added, at 50 DEG C Under the conditions of, it stirs 30-40 minutes, water-soluble resin and acrylic emulsion is then added into mixture, continue stirring 40 minutes, Obtain mixture a1;
(2) Paris white, barium sulfate, ferrosilite, nanometer ferrite, barium chloride are added into mixture a1, is uniformly mixed Afterwards, it at the uniform velocity stirs 20 minutes, mixing speed is 2000 revs/min, obtains a2;
(3) silica flour, defoaming agent are added into mixture a2, stirs 10-20 minutes, mixing speed is 2000 revs/min, After mixing, mixture a3 is obtained;
(4) mixture a3 is poured into homogenizer, adds negative ion powder and stirs 10-20 minutes, mixing speed 3000 Rev/min, after mixing, PH agent and appropriate pigment is added to get the anti-radiation building coating containing anion.
Preferably, the quality that water is added in the step (2) should be 2 times of mixture quality in step (1).
Preferably, it is added before Paris white, barium sulfate, ferrosilite, nanometer ferrite, barium chloride in the step (2) They should be crushed to 300 mesh of partial size respectively.
Preferably, in the step (3), the particle diameter of silica flour should be below 400 mesh.
Compared with prior art, the present invention have it is following the utility model has the advantages that
(1) building coating of the radiation protection of the present invention containing anion is applied to interior decoration, on the one hand can purify Air keeps indoor environment good, prevents human body respiration tract disease.On the one hand it can effectively absorb from computer, TV, mobile phone The electromagnetic wave of equal electric appliances, provides guarantee for the healthy living of people.The coating is without containing the noxious materials such as formaldehyde, Bu Huizao Adult body disease, it is safer, there is good application value.
(2) the anti-radiation building coating of the present invention containing anion contains negative ion powder, can stablize release bear from Son makes anion concentration in unit air reach 6000/cubic centimetre.The increase of anion can allow the people of indoor inhabitation Keeping clearheaded, breathing is smooth, and enhancing tissue metabolism improves immunity of organisms, improves skin oxidation resistance, It delays senescence.
(3) the anti-radiation building coating of the present invention containing anion contains graphene.Graphene is conjugated with lamella Structure, close structure effectively inhibit being impregnated with for water, so that coating has the performance of waterproof anti-corrosion.Simultaneously in graphene Portion's atom connects into honeycomb lattice arrangement, so that the suppleness of graphene increases.This lattice structure also allows graphene to be provided with Extremely strong heat resistance prevents the generation of family fire.
(4) it is opposite to contain graphene, ferrosilite, barium chloride etc. for the anti-radiation building coating of the present invention containing anion The biggish substance of molecular mass can effectively prevent the radiation of electromagnetic wave, so that coating has outstanding shielding property.
(5) the anti-radiation building Paint preparation technology of the present invention containing anion is simple, easily operated, condition temperature With, there is no polluted gas generation in preparation process, be suitable for large-scale industrial production.
Specific implementation method
The present invention is described in detail With reference to embodiment.
Embodiment 1:
The present invention relates to a kind of anti-radiation building coating containing anion, it is composed of the following components according to parts by weight: water 30 parts of soluble resin, 10 parts of acrylic emulsion, 20 parts of carbamate, 15 parts of Paris white, 10 parts of barium sulfate, 3 parts of ferrosilite, 3 parts of nanometer ferrite, 1 part of graphene, 3 parts of barium chloride, 10 parts of silica flour, 2 parts of defoaming agent, 7 parts of negative ion powder, 2 parts of PH agent, face 3 parts of material.
The invention further relates to a kind of preparation methods of coating of anti-radiation building containing anion, include the following steps:
(1) carbamate is weighed respectively according to the proportion and graphene is added in reaction kettle, suitable quantity of water is added, at 50 DEG C Under the conditions of, it stirs 30 minutes, water-soluble resin and acrylic emulsion is then added into mixture, continue stirring 40 minutes, obtain To mixture a1;
(2) Paris white, barium sulfate, ferrosilite, nanometer ferrite, barium chloride are added into mixture a1, is uniformly mixed Afterwards, it at the uniform velocity stirs 20 minutes, mixing speed is 2000 revs/min, obtains a2;
(3) silica flour, defoaming agent are added into mixture a2, stirs 15 minutes, mixing speed is 2000 revs/min, is mixed After closing uniformly, mixture a3 is obtained;
(4) mixture a3 is poured into homogenizer, adds anion and stirs 15 minutes, mixing speed is 3000 revs/min PH agent and pigment is added after mixing to get the anti-radiation building coating containing anion in clock.
Embodiment 2:
The present invention relates to a kind of anti-radiation building coating containing anion, it is composed of the following components according to parts by weight: water 40 parts of soluble resin, 20 parts of acrylic emulsion, 25 parts of carbamate, 12 parts of Paris white, 13 parts of barium sulfate, 5 parts of ferrosilite, 4 parts of nanometer ferrite, 0.5 part of graphene, 5 parts of barium chloride, 5 parts of silica flour, 1 part of defoaming agent, 5 parts of negative ion powder, PH agent is appropriate, 3 parts of pigment.
The invention further relates to a kind of preparation methods of coating of anti-radiation building containing anion, include the following steps:
(1) carbamate is weighed respectively according to the proportion and graphene is added in reaction kettle, suitable quantity of water is added, at 50 DEG C Under the conditions of, it stirs 40 minutes, water-soluble resin and acrylic emulsion is then added into mixture, continue stirring 40 minutes, obtain To mixture a1;
(2) Paris white, barium sulfate, ferrosilite, nanometer ferrite, barium chloride are added into mixture a1, is uniformly mixed Afterwards, it at the uniform velocity stirs 20 minutes, mixing speed is 2000 revs/min, obtains a2;
(3) silica flour, defoaming agent are added into mixture a2, stirs 20 minutes, mixing speed is 2000 revs/min, is mixed After closing uniformly, mixture a3 is obtained;
(4) mixture a3 is poured into homogenizer, adds anion and stirs 20 minutes, mixing speed is 3000 revs/min PH agent and appropriate pigment is added after mixing to get the anti-radiation building coating containing anion in clock.
The above is not that any type of limitation is done to the present invention only as reference example of the invention, and foundation Any modification or equivalent variations made by technical spirit of the invention, still fall within protection scope of the presently claimed invention.

Claims (7)

1. the present invention relates to a kind of anti-radiation building coating and preparation method containing anion, which is characterized in that in parts by weight It counts composed of the following components: 30-40 parts of water-soluble resin, 10-20 parts of acrylic emulsion, 10-30 parts of carbamate, calcium carbonate 10-15 parts of powder, 10-15 parts of barium sulfate, 3-6 parts of ferrosilite, 3-5 parts of nanometer ferrite, 0.5-1 parts of graphene, barium chloride 3-5 Part, 5-15 parts of silica flour, 1-3 parts of defoaming agent, 5-7 parts of negative ion powder, 1-6 parts of PH agent, 2-5 parts of pigment.
2. the anti-radiation building coating according to claim 1 containing anion, which is characterized in that building of the invention applies Material release anion quantity is 6000/cubic centimetre.
3. the anti-radiation building coating according to claim 1 containing anion, which is characterized in that coating of the invention is matched The various composition of Fang Suoshu meets professional standard.
4. a kind of method for preparing the anti-radiation building coating containing anion as claimed in claim 1, which is characterized in that packet Include following steps:
(1) carbamate is weighed respectively according to the proportion and graphene is added in reaction kettle, suitable quantity of water is added, in 50 DEG C of conditions Under, it stirs 30-40 minutes, water-soluble resin and acrylic emulsion is then added into mixture, continue stirring 40 minutes, obtain Mixture a1;
(2) Paris white, barium sulfate, ferrosilite, nanometer ferrite, barium chloride are added into mixture a1, it is after mixing, even Speed stirring 20 minutes, mixing speed are 2000 revs/min, obtain a2;
(3) silica flour, defoaming agent are added into mixture a2, stirs 10-20 minutes, mixing speed is 2000 revs/min, mixing After uniformly, mixture a3 is obtained;
(4) mixture a3 is poured into homogenizer, adds anion and stirs 10-20 minutes, mixing speed is 3000 revs/min PH agent and appropriate pigment is added after mixing to get the anti-radiation building coating containing anion in clock.
5. the preparation method of the anti-radiation building coating according to claim 4 containing anion, which is characterized in that described The quality that water is added in step (2) should be 2 times of mixture quality in step (1).
6. the preparation method of the anti-radiation building coating according to claim 4 containing anion, which is characterized in that described They should be crushed to grain respectively before Paris white, barium sulfate, ferrosilite, nanometer ferrite, barium chloride is added in step (2) 300 mesh of diameter.
7. the preparation method of the anti-radiation building coating according to claim 6 containing anion, which is characterized in that quartz The particle diameter of powder should be below 400 mesh.
CN201810646951.4A 2018-06-11 2018-06-11 A kind of anti-radiation building coating and preparation method containing anion Pending CN109135574A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810646951.4A CN109135574A (en) 2018-06-11 2018-06-11 A kind of anti-radiation building coating and preparation method containing anion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810646951.4A CN109135574A (en) 2018-06-11 2018-06-11 A kind of anti-radiation building coating and preparation method containing anion

Publications (1)

Publication Number Publication Date
CN109135574A true CN109135574A (en) 2019-01-04

Family

ID=64802191

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810646951.4A Pending CN109135574A (en) 2018-06-11 2018-06-11 A kind of anti-radiation building coating and preparation method containing anion

Country Status (1)

Country Link
CN (1) CN109135574A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110484050A (en) * 2019-07-23 2019-11-22 四川亿家云享科技有限公司 A kind of graphene anion phase-transition heat-preserving building coating and its application

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110484050A (en) * 2019-07-23 2019-11-22 四川亿家云享科技有限公司 A kind of graphene anion phase-transition heat-preserving building coating and its application

Similar Documents

Publication Publication Date Title
CN104895206B (en) A kind of composite evacuated heat insulating board and long-acting breathing mud thereof
CN108546054B (en) High Jiang Ziqing clean water surface layer mortar and preparation method thereof
CN106045403A (en) Pervious recycled aggregate concrete with microwave absorbing function and preparation method of pervious recycled aggregate concrete
CN110982307A (en) Ecological shell powder interior wall coating and preparation method thereof
CN106116401A (en) A kind of negative oxygen ion function coating, preparation method and application
CN109336512A (en) A kind of nano metal organic frame wall material and preparation method thereof
CN105504901A (en) Environmental-friendly wall mask material and preparation method thereof
CN109135574A (en) A kind of anti-radiation building coating and preparation method containing anion
CN106519645B (en) A kind of preparation method of the extraordinary synthetic paper with formaldehyde adsorption function
CN108753064A (en) A kind of liquid shell powder paint and preparation method thereof
CN106916476A (en) A kind of concave convex rod surface lacquer and preparation method
CN103254696B (en) A kind of have inhale ripple, the environmental friendly indoor dry powder paint and preparation method thereof of anti-flaming function and constructional method
CN109385129A (en) A kind of environment-friendly health type inner wall putty powder and its preparation process
CN107011782A (en) A kind of indoor radiation shielding coating and preparation method
CN111943586A (en) Heat insulation material for building exterior wall and preparation method thereof
CN106349796A (en) Heat-insulating and flame-retardant putty for building wall body
CN103571286A (en) Preparation method of color powder coating
CN107227074A (en) Nano thermal insulation sound-absorbing anti-nuclear radiation coating material
CN109370274A (en) A kind of oyster shell whiting biology coating and preparation method
CN107555893A (en) A kind of anion mortar of construction wall and preparation method thereof
CN109437961A (en) A kind of concrete light aggregate and preparation method thereof and concrete
CN109735018A (en) A kind of antibacterial ceiling composite material and preparation method
CN107352855A (en) A kind of diatom ooze wall material and its construction method for inducing anion
CN108751791A (en) A kind of fireproof and heat-insulating material and preparation method thereof
CN107459307A (en) A kind of building materials diatom complex material and preparation method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190104

WD01 Invention patent application deemed withdrawn after publication