CN109135459A - A kind of insulated paint eleostearic acid modifying cinepazid emulsion and preparation method thereof - Google Patents

A kind of insulated paint eleostearic acid modifying cinepazid emulsion and preparation method thereof Download PDF

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Publication number
CN109135459A
CN109135459A CN201810890513.2A CN201810890513A CN109135459A CN 109135459 A CN109135459 A CN 109135459A CN 201810890513 A CN201810890513 A CN 201810890513A CN 109135459 A CN109135459 A CN 109135459A
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CN
China
Prior art keywords
parts
acid
insulated paint
eleostearic acid
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810890513.2A
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Chinese (zh)
Inventor
周耀伟
徐劼
董旻
王关全
崔昕
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Jiaxing Jiasheng Insulation Material Co Ltd
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Jiaxing Jiasheng Insulation Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Jiaxing Jiasheng Insulation Material Co Ltd filed Critical Jiaxing Jiasheng Insulation Material Co Ltd
Priority to CN201810890513.2A priority Critical patent/CN109135459A/en
Publication of CN109135459A publication Critical patent/CN109135459A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04Acids; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes

Abstract

The invention discloses a kind of insulated paint eleostearic acid modifying cinepazid emulsions, are prepared by the raw material of following quality proportioning: 8.5-10.5 parts of eleostearic acid, 7.2-8.8 parts of methyl methacrylate, 4.5-5 parts of styrene, 4.2-5.2 parts of butyl acrylate, 5.5-7 parts of hydroxy-ethyl acrylate, 0.7-0.8 parts of methacrylic acid, 4-4.5 parts of tertiary carbonic acid glycidyl ester, 0.75-0.8 parts of azodiisobutyronitrile, 0.35-0.4 parts of lauryl mercaptan, 6.7-8 parts of isopropanol, 0.9-1.5 parts of diethanol amine and 47.45-60 parts of deionized water.The eleostearic acid that the present invention uses is renewable resource;The discharge for reducing oil product is diluted with water;The brittleness for changing styrene-acrylic emulsion keeps film more tough and tensile, and levelability and adhesive force are more preferably.

Description

A kind of insulated paint eleostearic acid modifying cinepazid emulsion and preparation method thereof
Technical field
The present invention relates to insulated paint fields, and in particular to a kind of insulated paint eleostearic acid modifying cinepazid emulsion and its preparation side Method.
Background technique
Styrene-acrylic emulsion (styrene-acrylate emulsion) is to be obtained by styrene and acrylate monomer through emulsion copolymerization. Styrene-acrylic emulsion has many advantages, such as that strong good film-forming property, adhesion strength, resistance to oxidation, cost performance are high, thus is widely used in coating, gluing The fields such as agent, leather finishing agent, glue used in paper-making and fabric finishing agent.But itself also there is inevitable, such as film Enbrittle, water resistance, weatherability it is poor, high and low temperature resistance and tensile strength can not be satisfactory.
1. preventing it from directly applying in insulated paint due to the brittleness of styrene-acrylic emulsion.
Based on the above situation, the invention proposes a kind of insulated paint eleostearic acid modifying cinepazid emulsions and preparation method thereof can Effectively solve problem above.
Summary of the invention
The purpose of the present invention is to provide a kind of insulated paint eleostearic acid modifying cinepazid emulsions and preparation method thereof.The present invention The eleostearic acid of use is renewable resource;The discharge for reducing oil product is diluted with water;The brittleness for changing styrene-acrylic emulsion makes to apply Film is more tough and tensile, and levelability and adhesive force are more preferably.
The present invention is achieved through the following technical solutions:
A kind of insulated paint eleostearic acid modifying cinepazid emulsion is prepared by the raw material of following quality proportioning:
8-10.8 parts of eleostearic acid;
7-9 parts of methyl methacrylate;
4-5.4 parts of styrene;
4-5.4 parts of butyl acrylate;
5-7.6 parts of hydroxy-ethyl acrylate;
0.6-0.9 parts of methacrylic acid;
3-4.5 parts of tertiary carbonic acid glycidyl ester;
0.7-0.9 parts of azodiisobutyronitrile;
0.3-0.45 parts of lauryl mercaptan;
6.7-8 parts of isopropanol;
0.9-1.5 parts of diethanol amine;
47.45-60 parts of deionized water.
As a preferred embodiment, it is prepared by the raw material of following quality proportioning:
8.5-10.5 parts of eleostearic acid;
7.2-8.8 parts of methyl methacrylate;
4.5-5 parts of styrene;
4.2-5.2 parts of butyl acrylate;
5.5-7 parts of hydroxy-ethyl acrylate;
0.7-0.8 parts of methacrylic acid;
4-4.5 parts of tertiary carbonic acid glycidyl ester;
0.75-0.8 parts of azodiisobutyronitrile;
0.35-0.4 parts of lauryl mercaptan;
7-7.5 parts of isopropanol;
1.2-1.5 parts of diethanol amine;
55-60 parts of deionized water.
As a preferred embodiment, the model E-109 of the tertiary carbonic acid glycidyl ester.
Insulated paint eleostearic acid modifying cinepazid emulsion the preparation method is as follows:
A, by 8.5-10.5 parts of eleostearic acid, 7.2-8.8 parts of methyl methacrylate, 4.5-5 parts of styrene, butyl acrylate 4.2-5.2 parts, 5.5-7 parts of hydroxy-ethyl acrylate, 0.7-0.8 parts of methacrylic acid, 4-4.5 parts of tertiary carbonic acid glycidyl ester, idol The 0.75-0.8 parts and isopropanol 6.7-8 parts mixing of nitrogen bis-isobutyronitrile, stir evenly, obtain mixed liquor;
B, the mixed liquor of 0.35-0.4 parts of lauryl mercaptan and 10% is added together in reaction kettle, heats, stirs It mixes, keeps the temperature 0.5 hour at 85 DEG C;
C, the remaining mixed liquor is added in reaction kettle by the way of being added dropwise, and 2-3 hours are added dropwise to complete, temperature Control is at 85-90 DEG C;
D, 1.5 hours are kept the temperature after dripping again, 0.9-1.5 parts of diethanol amine of 70 DEG C of investments is cooled to, throws after mixing evenly Enter 47.45-60 parts of deionized water, keeps the temperature 0.5 hour at 70 DEG C.
As a preferred embodiment, insulated paint eleostearic acid modifying cinepazid emulsion the preparation method is as follows:
A, by 8.5-10.5 parts of eleostearic acid, 7.2-8.8 parts of methyl methacrylate, 4.5-5 parts of styrene, butyl acrylate 4.2-5.2 parts, 5.5-7 parts of hydroxy-ethyl acrylate, 0.7-0.8 parts of methacrylic acid, 4-4.5 parts of tertiary carbonic acid glycidyl ester, idol The 0.75-0.8 parts and isopropanol 7-7.5 parts mixing of nitrogen bis-isobutyronitrile, stir evenly, obtain mixed liquor;
B, the mixed liquor of 0.35-0.4 parts of lauryl mercaptan and 10% is added together in reaction kettle, heats, stirs It mixes, keeps the temperature 0.5 hour at 85 DEG C;
C, the remaining mixed liquor is added in reaction kettle by the way of being added dropwise, and 2-3 hours are added dropwise to complete, temperature Control is at 85-90 DEG C;
D, 1.5 hours are kept the temperature after dripping again, 1.2-1.5 parts of diethanol amine of 70 DEG C of investments is cooled to, throws after mixing evenly Enter 55-60 parts of deionized water, keeps the temperature 0.5 hour at 70 DEG C.
As a preferred embodiment, the model E-109 of the tertiary carbonic acid glycidyl ester.
Compared with prior art, the present invention have the following advantages that and the utility model has the advantages that
The eleostearic acid that the present invention uses is renewable resource;The discharge for reducing oil product is diluted with water;Change phenylpropyl alcohol The brittleness of lotion keeps film more tough and tensile, and levelability and adhesive force are more preferably.
Specific embodiment
The present invention is described in further detail below with reference to embodiment, embodiments of the present invention are not limited thereto.
Test method described in following embodiments or test method are unless otherwise specified conventional method;The reagent And material is obtained from routine business approach, or prepare in conventional manner unless otherwise specified.
Embodiment 1:
A kind of insulated paint eleostearic acid modifying cinepazid emulsion is prepared by the raw material of following quality proportioning:
8-10.8 parts of eleostearic acid;
7-9 parts of methyl methacrylate;
4-5.4 parts of styrene;
4-5.4 parts of butyl acrylate;
5-7.6 parts of hydroxy-ethyl acrylate;
0.6-0.9 parts of methacrylic acid;
3-4.5 parts of tertiary carbonic acid glycidyl ester;
0.7-0.9 parts of azodiisobutyronitrile;
0.3-0.45 parts of lauryl mercaptan;
6.7-8 parts of isopropanol;
0.9-1.5 parts of diethanol amine;
47.45-60 parts of deionized water.
Embodiment 2:
A kind of insulated paint eleostearic acid modifying cinepazid emulsion is prepared by the raw material of following quality proportioning:
8.5-10.5 parts of eleostearic acid;
7.2-8.8 parts of methyl methacrylate;
4.5-5 parts of styrene;
4.2-5.2 parts of butyl acrylate;
5.5-7 parts of hydroxy-ethyl acrylate;
0.7-0.8 parts of methacrylic acid;
4-4.5 parts of tertiary carbonic acid glycidyl ester;
0.75-0.8 parts of azodiisobutyronitrile;
0.35-0.4 parts of lauryl mercaptan;
7-7.5 parts of isopropanol;
1.2-1.5 parts of diethanol amine;
55-60 parts of deionized water;
The model E-109 of the tertiary carbonic acid glycidyl ester.
Embodiment 3:
A kind of insulated paint eleostearic acid modifying cinepazid emulsion the preparation method is as follows:
A, by 8.5-10.5 parts of eleostearic acid, 7.2-8.8 parts of methyl methacrylate, 4.5-5 parts of styrene, butyl acrylate 4.2-5.2 parts, 5.5-7 parts of hydroxy-ethyl acrylate, 0.7-0.8 parts of methacrylic acid, 4-4.5 parts of tertiary carbonic acid glycidyl ester, idol The 0.75-0.8 parts and isopropanol 7-7.5 parts mixing of nitrogen bis-isobutyronitrile, stir evenly, obtain mixed liquor;
B, the mixed liquor of 0.35-0.4 parts of lauryl mercaptan and 10% is added together in reaction kettle, heats, stirs It mixes, keeps the temperature 0.5 hour at 85 DEG C;
C, the remaining mixed liquor is added in reaction kettle by the way of being added dropwise, and 2-3 hours are added dropwise to complete, temperature Control is at 85-90 DEG C;
D, 1.5 hours are kept the temperature after dripping again, 1.2-1.5 parts of diethanol amine of 70 DEG C of investments is cooled to, throws after mixing evenly Enter 55-60 parts of deionized water, keeps the temperature 0.5 hour at 70 DEG C.
As a preferred embodiment, the model E-109 of the tertiary carbonic acid glycidyl ester.
Embodiment 4:
Insulated paint eleostearic acid modifying cinepazid emulsion the preparation method is as follows:
A, by 8.5 parts of eleostearic acid, 7.2 parts of methyl methacrylate, 4.5 parts of styrene, 4.2 parts of butyl acrylate, propylene 5.5 parts of sour hydroxyl ethyl ester, 0.7 part of methacrylic acid, 4 parts of tertiary carbonic acid glycidyl ester, 0.75 part of azodiisobutyronitrile and isopropanol 7 Part mixing, stirs evenly, obtains mixed liquor;
B, the mixed liquor of 0.35 part of lauryl mercaptan and 10% is added together in reaction kettle, is heated, stirring, 85 DEG C keep the temperature 0.5 hour;
C, the remaining mixed liquor is added in reaction kettle by the way of being added dropwise, and 2-3 hours are added dropwise to complete, temperature Control is at 85-90 DEG C;
D, 1.5 hours are kept the temperature after dripping again, is cooled to 1.2 parts of diethanol amine of 70 DEG C of investments, investment is gone after mixing evenly 55 parts of ionized water, 0.5 hour is kept the temperature at 70 DEG C.
As a preferred embodiment, the model E-109 of the tertiary carbonic acid glycidyl ester.
Embodiment 5:
Insulated paint eleostearic acid modifying cinepazid emulsion the preparation method is as follows:
A, by 10.5 parts of eleostearic acid, 8.8 parts of methyl methacrylate, 5 parts of styrene, 5.2 parts of butyl acrylate, acrylic acid 7 parts of hydroxyl ethyl ester, 0.8 part of methacrylic acid, 4.5 parts of tertiary carbonic acid glycidyl ester, 0.8 part of azodiisobutyronitrile and isopropanol 7.5 Part mixing, stirs evenly, obtains mixed liquor;
B, the mixed liquor of 0.4 part of lauryl mercaptan and 10% is added together in reaction kettle, is heated, stirring, 85 DEG C keep the temperature 0.5 hour;
C, the remaining mixed liquor is added in reaction kettle by the way of being added dropwise, and 2-3 hours are added dropwise to complete, temperature Control is at 85-90 DEG C;
D, 1.5 hours are kept the temperature after dripping again, is cooled to 1.5 parts of diethanol amine of 70 DEG C of investments, investment is gone after mixing evenly 60 parts of ionized water, 0.5 hour is kept the temperature at 70 DEG C.
As a preferred embodiment, the model E-109 of the tertiary carbonic acid glycidyl ester.
Embodiment 6:
A kind of insulated paint eleostearic acid modifying cinepazid emulsion the preparation method is as follows:
A, by 9 parts of eleostearic acid, 8 parts of methyl methacrylate, 4.8 parts of styrene, 5 parts of butyl acrylate, acrylic acid hydroxyl second 6 parts of ester, 0.75 part of methacrylic acid, 4.2 parts of tertiary carbonic acid glycidyl ester, 0.78 part of azodiisobutyronitrile and 7.2 parts of isopropanol Mixing, stirs evenly, obtains mixed liquor;
B, the mixed liquor of 0.38 part of lauryl mercaptan and 10% is added together in reaction kettle, is heated, stirring, 85 DEG C keep the temperature 0.5 hour;
C, the remaining mixed liquor is added in reaction kettle by the way of being added dropwise, and 2-3 hours are added dropwise to complete, temperature Control is at 85-90 DEG C;
D, 1.5 hours are kept the temperature after dripping again, is cooled to 1.3 parts of diethanol amine of 70 DEG C of investments, investment is gone after mixing evenly 58 parts of ionized water, 0.5 hour is kept the temperature at 70 DEG C.
As a preferred embodiment, the model E-109 of the tertiary carbonic acid glycidyl ester.
The above is only presently preferred embodiments of the present invention, not does limitation in any form to the present invention, it is all according to According to technical spirit any simple modification to the above embodiments of the invention, equivalent variations, protection of the invention is each fallen within Within the scope of.

Claims (6)

1. a kind of insulated paint eleostearic acid modifying cinepazid emulsion, it is characterised in that: prepared by the raw material of following quality proportioning:
8-10.8 parts of eleostearic acid;
7-9 parts of methyl methacrylate;
4-5.4 parts of styrene;
4-5.4 parts of butyl acrylate;
5-7.6 parts of hydroxy-ethyl acrylate;
0.6-0.9 parts of methacrylic acid;
3-4.5 parts of tertiary carbonic acid glycidyl ester;
0.7-0.9 parts of azodiisobutyronitrile;
0.3-0.45 parts of lauryl mercaptan;
6.7-8 parts of isopropanol;
0.9-1.5 parts of diethanol amine;
47.45-60 parts of deionized water.
2. insulated paint according to claim 1 eleostearic acid modifying cinepazid emulsion, it is characterised in that: by following quality proportioning Raw material preparation:
8.5-10.5 parts of eleostearic acid;
7.2-8.8 parts of methyl methacrylate;
4.5-5 parts of styrene;
4.2-5.2 parts of butyl acrylate;
5.5-7 parts of hydroxy-ethyl acrylate;
0.7-0.8 parts of methacrylic acid;
4-4.5 parts of tertiary carbonic acid glycidyl ester;
0.75-0.8 parts of azodiisobutyronitrile;
0.35-0.4 parts of lauryl mercaptan;
7-7.5 parts of isopropanol;
1.2-1.5 parts of diethanol amine;
55-60 parts of deionized water.
3. insulated paint according to claim 1 or 2 eleostearic acid modifying cinepazid emulsion, it is characterised in that: the versatic acid The model E-109 of ethylene oxidic ester.
4. insulated paint according to claim 1 eleostearic acid modifying cinepazid emulsion, it is characterised in that: the insulated paint uses paulownia Oleic acid modifying cinepazid emulsion the preparation method is as follows:
A, by 8.5-10.5 parts of eleostearic acid, 7.2-8.8 parts of methyl methacrylate, 4.5-5 parts of styrene, butyl acrylate 4.2- 5.2 parts, 5.5-7 parts of hydroxy-ethyl acrylate, 0.7-0.8 parts of methacrylic acid, 4-4.5 parts of tertiary carbonic acid glycidyl ester, azo two 0.75-0.8 parts and isopropanol 6.7-8 parts mixing of isobutyronitrile, stir evenly, obtain mixed liquor;
B, the mixed liquor of 0.35-0.4 parts of lauryl mercaptan and 10% is added together in reaction kettle, is heated, stirring, 85 DEG C keep the temperature 0.5 hour;
C, the remaining mixed liquor is added in reaction kettle by the way of being added dropwise, and 2-3 hours are added dropwise to complete, temperature control At 85-90 DEG C;
D, 1.5 hours are kept the temperature after dripping again, is cooled to 0.9-1.5 parts of diethanol amine of 70 DEG C of investments, investment is gone after mixing evenly 47.45-60 parts of ionized water, 0.5 hour is kept the temperature at 70 DEG C.
5. insulated paint according to claim 2 eleostearic acid modifying cinepazid emulsion, it is characterised in that: the insulated paint uses paulownia Oleic acid modifying cinepazid emulsion the preparation method is as follows:
A, by 8.5-10.5 parts of eleostearic acid, 7.2-8.8 parts of methyl methacrylate, 4.5-5 parts of styrene, butyl acrylate 4.2- 5.2 parts, 5.5-7 parts of hydroxy-ethyl acrylate, 0.7-0.8 parts of methacrylic acid, 4-4.5 parts of tertiary carbonic acid glycidyl ester, azo two 0.75-0.8 parts and isopropanol 7-7.5 parts mixing of isobutyronitrile, stir evenly, obtain mixed liquor;
B, the mixed liquor of 0.35-0.4 parts of lauryl mercaptan and 10% is added together in reaction kettle, is heated, stirring, 85 DEG C keep the temperature 0.5 hour;
C, the remaining mixed liquor is added in reaction kettle by the way of being added dropwise, and 2-3 hours are added dropwise to complete, temperature control At 85-90 DEG C;
D, 1.5 hours are kept the temperature after dripping again, is cooled to 1.2-1.5 parts of diethanol amine of 70 DEG C of investments, investment is gone after mixing evenly 55-60 parts of ionized water, 0.5 hour is kept the temperature at 70 DEG C.
6. insulated paint according to claim 4 or 5 eleostearic acid modifying cinepazid emulsion, it is characterised in that: the versatic acid The model E-109 of ethylene oxidic ester.
CN201810890513.2A 2018-08-07 2018-08-07 A kind of insulated paint eleostearic acid modifying cinepazid emulsion and preparation method thereof Pending CN109135459A (en)

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CN201810890513.2A CN109135459A (en) 2018-08-07 2018-08-07 A kind of insulated paint eleostearic acid modifying cinepazid emulsion and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110483681A (en) * 2019-08-29 2019-11-22 安徽龙腾瑞兴科技有限公司 Film-covered iron is copolymerized epoxy miniemulsion and its preparation and application with methyl eleostearate

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5922904A (en) * 1982-07-30 1984-02-06 Japan Synthetic Rubber Co Ltd Manufacture of polymer latex
CN101395190A (en) * 2006-03-06 2009-03-25 Upm-基米因公司 Composites containing acrylate hybride resin based on natural fatty acids
CN102702437A (en) * 2012-06-29 2012-10-03 上海东升新材料有限公司 Styrene-acrylic emulsion as well as preparation method and application thereof
CN103130943A (en) * 2013-01-31 2013-06-05 景立秋 Preparation method of water-borne acrylic resin emulsion for wood paint
CN104151485A (en) * 2014-07-17 2014-11-19 江苏十松新材料科技有限公司 Long-chain unsaturated fatty acid-modified acrylate emulsion and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5922904A (en) * 1982-07-30 1984-02-06 Japan Synthetic Rubber Co Ltd Manufacture of polymer latex
CN101395190A (en) * 2006-03-06 2009-03-25 Upm-基米因公司 Composites containing acrylate hybride resin based on natural fatty acids
CN102702437A (en) * 2012-06-29 2012-10-03 上海东升新材料有限公司 Styrene-acrylic emulsion as well as preparation method and application thereof
CN103130943A (en) * 2013-01-31 2013-06-05 景立秋 Preparation method of water-borne acrylic resin emulsion for wood paint
CN104151485A (en) * 2014-07-17 2014-11-19 江苏十松新材料科技有限公司 Long-chain unsaturated fatty acid-modified acrylate emulsion and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
朱万强: "《涂料基础教程》", 30 June 2012, 西南交通大学出版社 *
陈昭琼: "《精细化工产品配方、合成及应用》", 31 October 1999, 国防工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110483681A (en) * 2019-08-29 2019-11-22 安徽龙腾瑞兴科技有限公司 Film-covered iron is copolymerized epoxy miniemulsion and its preparation and application with methyl eleostearate

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