CN109128582A - A kind of scaling powder reducing exhaust gas treatment - Google Patents

A kind of scaling powder reducing exhaust gas treatment Download PDF

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Publication number
CN109128582A
CN109128582A CN201811169884.8A CN201811169884A CN109128582A CN 109128582 A CN109128582 A CN 109128582A CN 201811169884 A CN201811169884 A CN 201811169884A CN 109128582 A CN109128582 A CN 109128582A
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China
Prior art keywords
rosin
acid
resin
exhaust gas
scaling powder
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CN201811169884.8A
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Chinese (zh)
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CN109128582B (en
Inventor
陈祖生
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Zixing Huihua Electronics Co Ltd
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Zixing Huihua Electronics Co Ltd
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3612Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with organic compounds as principal constituents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Electric Connection Of Electric Components To Printed Circuits (AREA)

Abstract

The present invention relates to a kind of scaling powders for reducing exhaust gas treatment, constitute modified rosin resin by rosin and rosin ester;Acrylate modified butadiene resin, polyethylene, polyurethane and furfural resin constitute film forming reinforcing agent;Octyl phenol polyoxyethylene ether, succinic acid, anhydrous citric acid, benzoic acid and dimethylbenzene compounding constitute organic acid for activating agent;Dimethylcarbinol, benzotriazole and hexamethylene diamine form solvent;Workshop condition can be improved using the present invention, prevent from scolding tin from largely aoxidizing, improve production efficiency again to be enterprise's saving cost of labor.

Description

A kind of scaling powder reducing exhaust gas treatment
Technical field
The present invention relates to a kind of scaling powders for reducing exhaust gas treatment.
Background technique
Open solder furnace, solder stick and common scaling powder are used by traditional soldering tin technique, solder stick is usually by tin Alloy and common scaling powder two parts composition, common scaling powder play improve solder stick auxiliary heat transfer in the welding process, Removal oxidation reduces soldered material surface tension, removes the effect for being soldered material surface and oil contaminant, increasing bonding area;It helps Solder flux, which is generallyd use, helps weldering by the rosin resin system that rosin, resin, the activating agent of halide, additive and organic solvent form Agent.Although this kind of scaling powder solderability is good, at low cost, after welding, there are exhaust gas when scolding tin to be full of in air, so that production The scolding tin smoke in workshop is pungent, while wasting scolding tin, also makes workshop condition severe, influences the health of worker.
Summary of the invention
The technical problem to be solved by the present invention is to need to provide a kind of scaling powder for reducing exhaust gas treatment, can subtract Few exhaust gas treatment, cost of labor can be saved again for enterprise by improving production efficiency, and can also promote product quality.That is: raw It produces efficiency and improves 30%, product quality improves about 18%, and air index has reached PM2.5.
In this regard, a kind of scaling powder for reducing exhaust gas treatment provided by the invention is transparent smokeless disposable dosage form;It is made For by weight percentage, following raw material: 10% rosin, 10% rosin ester, 7% acrylate modified butadiene is weighed Resin, 5% polyethylene, 5% polyurethane, 5% furfural resin, 1% octyl phenol polyoxyethylene ether, 2% succinic acid, 1.6% anhydrous citric acid, 1% benzoic acid, 0.4% dimethylbenzene, 50% dimethylcarbinol, 1% benzotriazole With 1% hexamethylene diamine;Wherein rosin and rosin ester are configured to modified rosin resin;Acrylate modified butadiene resin, poly- second Alkene, polyurethane and furfural resin constitute film forming reinforcing agent;Octyl phenol polyoxyethylene ether, succinic acid, anhydrous citric acid, benzoic acid and Dimethylbenzene compounding constitutes organic acid for activating agent;
Rosin and rosin ester are crushed by pulverizer, smashing fineness is 100 mesh;There to be octyl phenol polyoxy second at normal temperature Alkene ether, succinic acid, anhydrous citric acid, benzoic acid and dimethylbenzene, than mixing, are poured into equipped with dimethylcarbinol not by component formula It becomes rusty in steel container, stirs 0.5 hour, add benzotriazole and hexamethylene diamine stirs 0.5 hour;After standing 1 hour;Side is stirred again It mixes side and rosin and rosin ester mixed-powder material is added, until mixed-powder stops stirring after all dissolving, and stand 4~6 hours, obtain To transparent smokeless disposable scaling powder.
Compared with prior art, the beneficial effects of the present invention are: the present invention to use by acrylate modified butadiene tree The film forming reinforcing agent that rouge, polyethylene, polyurethane and furfural resin are constituted, softening point are suitable for that softening point is 90~100 DEG C, weldering It is non-yellowing, transparent clean to connect rear solder joint.Make in scolding tin that generated exhaust gas is considerably less, improving production efficiency can improve again Workshop condition, energy conservation and environmental protection avoids the health of damage worker, and can also promote product quality, and production efficiency improves 30%, product quality improves about 18%, and air index has reached PM2.5.
Specific embodiment
Preferably embodiment of the invention is described in further detail below.
In this regard, the used scaling powder of the present embodiment is a kind of scaling powder for being exclusively used in anti-oxidation solder furnace, it is transparent Smokeless disposable dosage form;It is prepared weighs following raw material by weight percentage: 10% rosin, 10% rosin ester, 7% Acrylate modified butadiene resin, 5% polyethylene, 5% polyurethane, 5% furfural resin, 1% octyl phenol polyoxy Vinethene, 2% succinic acid, 1.6% anhydrous citric acid, 1% benzoic acid, 0.4% dimethylbenzene, 50% dimethyl methyl Alcohol, 1% benzotriazole and 1% hexamethylene diamine;Wherein rosin and rosin ester are configured to modified rosin resin;Acrylate changes Property butadiene resin, polyethylene, polyurethane and furfural resin constitute film forming reinforcing agent;Octyl phenol polyoxyethylene ether, succinic acid, nothing Water citric acid, benzoic acid and dimethylbenzene compounding constitute organic acid for activating agent;
Rosin and rosin ester are crushed by pulverizer, smashing fineness is 100 mesh;There to be octyl phenol polyoxy second at normal temperature Alkene ether, succinic acid, anhydrous citric acid, benzoic acid and dimethylbenzene, than mixing, are poured into equipped with dimethylcarbinol not by component formula It becomes rusty in steel container, stirs 0.5 hour, add benzotriazole and hexamethylene diamine stirs 0.5 hour;After standing 1 hour;Side is stirred again It mixes side and rosin and rosin ester mixed-powder material is added, until mixed-powder stops stirring after all dissolving, and stand 4~6 hours, obtain To transparent smokeless disposable scaling powder.
The rosin ester is the polyol ester of rosin acid, is lurid transparent solid, softening point is at 90~110 DEG C, acid Value is 10~20.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that Specific implementation of the invention is only limited to these instructions.For those of ordinary skill in the art to which the present invention belongs, exist Under the premise of not departing from present inventive concept, a number of simple deductions or replacements can also be made, all shall be regarded as belonging to of the invention Protection scope.

Claims (2)

1. a kind of scaling powder for reducing exhaust gas treatment, for transparent smokeless disposable dosage form;It is characterized by: by weight percentage Meter, weighs following raw material: 10% rosin, 10% rosin ester, 7% acrylate modified butadiene resin, 5% poly- second Alkene, 5% polyurethane, 5% furfural resin, 1% octyl phenol polyoxyethylene ether, 2% succinic acid, 1.6% anhydrous lemon Lemon acid, 1% benzoic acid, 0.4% dimethylbenzene, 50% dimethylcarbinol, 1% benzotriazole and 1% hexamethylene diamine; Wherein rosin and rosin ester are configured to modified rosin resin;Acrylate modified butadiene resin, polyethylene, polyurethane and furfural Resin constitutes film forming reinforcing agent;Octyl phenol polyoxyethylene ether, succinic acid, anhydrous citric acid, benzoic acid and dimethylbenzene compounding are constituted Organic acid for activating agent;
Rosin and rosin ester are crushed by pulverizer, smashing fineness is 100 mesh;There to be octyl phenol polyoxy second at normal temperature Alkene ether, succinic acid, anhydrous citric acid, benzoic acid and dimethylbenzene, than mixing, are poured into equipped with dimethylcarbinol not by component formula It becomes rusty in steel container, stirs 0.5 hour, add benzotriazole and hexamethylene diamine stirs 0.5 hour;After standing 1 hour;Side is stirred again It mixes side and rosin and rosin ester mixed-powder material is added, until mixed-powder stops stirring after all dissolving, and stand 4~6 hours, obtain To transparent smokeless disposable scaling powder.
2. a kind of scaling powder for reducing exhaust gas treatment according to claim 1, it is further characterized in that: the rosin ester It is the polyol ester of rosin acid, is lurid transparent solid, for softening point at 90~110 DEG C, acid value is 10~20.
CN201811169884.8A 2018-10-08 2018-10-08 Soldering flux for reducing waste gas emission treatment Active CN109128582B (en)

Priority Applications (1)

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CN201811169884.8A CN109128582B (en) 2018-10-08 2018-10-08 Soldering flux for reducing waste gas emission treatment

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Application Number Priority Date Filing Date Title
CN201811169884.8A CN109128582B (en) 2018-10-08 2018-10-08 Soldering flux for reducing waste gas emission treatment

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CN109128582A true CN109128582A (en) 2019-01-04
CN109128582B CN109128582B (en) 2024-02-09

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109014484A (en) * 2018-10-08 2018-12-18 资兴市慧华电子有限公司 A kind of full-automatic anti-oxidation solder furnace reducing exhaust gas treatment and dedicated scaling powder
CN110877171A (en) * 2019-11-11 2020-03-13 华南理工大学 Soldering flux for solder wire and preparation method thereof
CN111777944A (en) * 2020-07-01 2020-10-16 云南锡业锡材有限公司 Solder ball surface treating agent for chip packaging and preparation method thereof

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Publication number Priority date Publication date Assignee Title
US5127968A (en) * 1989-08-16 1992-07-07 Yuho Chemicals Inc. Additive for fluxes and soldering pastes
US5382299A (en) * 1993-02-01 1995-01-17 Cookson Group Plc Soldering flux
CN101062536A (en) * 2007-06-01 2007-10-31 中南大学 Non-halide cleaning-free welding flux for leadless solder
CN101073862A (en) * 2007-06-08 2007-11-21 北京工业大学 Low-rosin and cleaning-free welding accessory without halogen for lead-free welding grease
CN101214594A (en) * 2007-12-28 2008-07-09 潘惠凯 Environment-friendly type lead-free solder water-based scaling powder and preparation thereof
CN101239428A (en) * 2008-03-05 2008-08-13 东莞市普赛特电子科技有限公司 Mildew resistant antimicrobial type low corrosion water-based scaling powder
CN101653876A (en) * 2009-08-19 2010-02-24 浙江一远电子材料研究院 Low-silver halogen free soldering paste
CN102350599A (en) * 2011-08-25 2012-02-15 华南理工大学 Halogen-free high-impedance water-based washing-free scaling powder as well as preparation method and application thereof
CN103008920A (en) * 2012-12-13 2013-04-03 郴州金箭焊料有限公司 Leadless rosin core no-clean scaling powder
CN103128461A (en) * 2011-11-23 2013-06-05 郴州金箭焊料有限公司 Scaling powder for lead-free solder wire
JP2013173156A (en) * 2012-02-24 2013-09-05 Mitsubishi Materials Corp Method for producing solder paste, and the solder paste produced by the same
CN106271217A (en) * 2016-09-23 2017-01-04 工业和信息化部电子第五研究所华东分所 A kind of disposable halogen-free scaling powder and low temperature solder stick
CN107175431A (en) * 2017-07-04 2017-09-19 合肥市大卓电力有限责任公司 A kind of efficient scaling powder and preparation method thereof
CN108526756A (en) * 2018-04-11 2018-09-14 苏州龙腾万里化工科技有限公司 A kind of cleaning-free scaling powder

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5127968A (en) * 1989-08-16 1992-07-07 Yuho Chemicals Inc. Additive for fluxes and soldering pastes
US5382299A (en) * 1993-02-01 1995-01-17 Cookson Group Plc Soldering flux
CN101062536A (en) * 2007-06-01 2007-10-31 中南大学 Non-halide cleaning-free welding flux for leadless solder
CN101073862A (en) * 2007-06-08 2007-11-21 北京工业大学 Low-rosin and cleaning-free welding accessory without halogen for lead-free welding grease
CN101214594A (en) * 2007-12-28 2008-07-09 潘惠凯 Environment-friendly type lead-free solder water-based scaling powder and preparation thereof
CN101239428A (en) * 2008-03-05 2008-08-13 东莞市普赛特电子科技有限公司 Mildew resistant antimicrobial type low corrosion water-based scaling powder
CN101653876A (en) * 2009-08-19 2010-02-24 浙江一远电子材料研究院 Low-silver halogen free soldering paste
CN102350599A (en) * 2011-08-25 2012-02-15 华南理工大学 Halogen-free high-impedance water-based washing-free scaling powder as well as preparation method and application thereof
CN103128461A (en) * 2011-11-23 2013-06-05 郴州金箭焊料有限公司 Scaling powder for lead-free solder wire
JP2013173156A (en) * 2012-02-24 2013-09-05 Mitsubishi Materials Corp Method for producing solder paste, and the solder paste produced by the same
CN103008920A (en) * 2012-12-13 2013-04-03 郴州金箭焊料有限公司 Leadless rosin core no-clean scaling powder
CN106271217A (en) * 2016-09-23 2017-01-04 工业和信息化部电子第五研究所华东分所 A kind of disposable halogen-free scaling powder and low temperature solder stick
CN107175431A (en) * 2017-07-04 2017-09-19 合肥市大卓电力有限责任公司 A kind of efficient scaling powder and preparation method thereof
CN108526756A (en) * 2018-04-11 2018-09-14 苏州龙腾万里化工科技有限公司 A kind of cleaning-free scaling powder

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109014484A (en) * 2018-10-08 2018-12-18 资兴市慧华电子有限公司 A kind of full-automatic anti-oxidation solder furnace reducing exhaust gas treatment and dedicated scaling powder
CN109014484B (en) * 2018-10-08 2024-02-23 资兴市慧华电子有限公司 Full-automatic anti-oxidation soldering tin stove for reducing exhaust emission treatment and special soldering flux
CN110877171A (en) * 2019-11-11 2020-03-13 华南理工大学 Soldering flux for solder wire and preparation method thereof
CN110877171B (en) * 2019-11-11 2021-03-30 华南理工大学 Soldering flux for solder wire and preparation method thereof
CN111777944A (en) * 2020-07-01 2020-10-16 云南锡业锡材有限公司 Solder ball surface treating agent for chip packaging and preparation method thereof

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