CN109090809A - For applying the application device component of composition - Google Patents

For applying the application device component of composition Download PDF

Info

Publication number
CN109090809A
CN109090809A CN201811061526.5A CN201811061526A CN109090809A CN 109090809 A CN109090809 A CN 109090809A CN 201811061526 A CN201811061526 A CN 201811061526A CN 109090809 A CN109090809 A CN 109090809A
Authority
CN
China
Prior art keywords
composition
container
application device
main part
includes
Prior art date
Application number
CN201811061526.5A
Other languages
Chinese (zh)
Inventor
W·D·默多克
M·科芬达弗
J·D·斯蒂尔
J·A·贝尔拉普施
Original Assignee
宝洁公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US201261639446P priority Critical
Priority to US61/639,446 priority
Application filed by 宝洁公司 filed Critical 宝洁公司
Priority to CN 201380022237 priority patent/CN104254262A/en
Publication of CN109090809A publication Critical patent/CN109090809A/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; MANICURING OR OTHER COSMETIC TREATMENT
    • A45D44/00Other toilet or cosmetic equipment, e.g. for hairdressers' rooms
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; MANICURING OR OTHER COSMETIC TREATMENT
    • A45D34/00Containers or accessories specially adapted for handling liquid toilet or cosmetic substances, e.g. perfumes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit, i.e. unitary, hand-held apparatus comprising a container and a discharge nozzle attached thereto, in which flow of liquid or other fluent material is produced by the muscular energy of the operator at the moment of use or by an equivalent manipulator independent from the apparatus
    • B05B11/0005Components or details
    • B05B11/0089Dispensing tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/28Nozzles, nozzle fittings or accessories specially adapted therefor
    • B65D83/285Nozzles, nozzle fittings or accessories specially adapted therefor for applying the contents, e.g. brushes, rollers, pads, spoons, razors, scrapers

Abstract

The present invention provides a kind of methods for delivering the composition to scalp comprising (a) provides composition in application device component, and the application device component includes the container that (i) is used to accommodate the composition;(ii) the extension top actuator being in fluid communication with the container, the top actuator that extends includes that (1) is configured to for the extension top actuator to be fluidly connected to the base part of the container;(2) it is configured to for base part to be fluidly connected to the main part of hollow needle;(iii) is used to deliver the engine of the composition from the container by the extension top actuator;And it (b) is assigned directly on scalp from the application device component by the composition.Tip includes positioned at the face in main part distal side.Tip includes the hole being in fluid communication with container.Tip has the projection length of about 0.5mm to about 100mm.

Description

For applying the application device component of composition

The application be the artificial Procter & Gamble of application, international filing date be on April 26th, 2013, application No. is It is 201380022237.3 (international application no PCT/US2013/038311), entitled " for applying the application device group of composition The divisional application of the PCT application for a patent for invention of part ".

Technical field

The present invention relates to the application device components and method for applying composition.More particularly it relates to have The application device component of container, the extension top actuator with hollow needle and the engine for applying composition, and its side Method.

Background technique

It has manufactured various for applying the composition to the device on scalp.Such device has been used in order to improve, clearly It is clean, dry and/or apply the purpose of one or more beneficial agents and apply composition.However, the design of presently commercially available device can It can lead to puzzled the effect of how using the device in this, the cause composition decline of consumer, and invalid delivering.

Based on described previously, a kind of unique delivery system is needed, effectively conveys how to use product to consumer, The effect of improving application composition, and optimal composition dosage is delivered to scalp.

Summary of the invention

According to one embodiment of present invention, it provides for the method to scalp delivering compositions comprising: (a) exist Composition is provided in application device component, the application device component includes: the container that (i) is used to accommodate the composition; (ii) the extension top actuator being in fluid communication with the container, extension top actuator include: that (1) be configured to will be described Extend the base part that top actuator is fluidly connected to the container;(2) it is configured to the base part fluidly It is connected to the main part of hollow needle, wherein the tip includes positioned at the face in the main part distal side, wherein the point Head includes the hole being in fluid communication with the container, and wherein the tip has the projection length of about 0.5mm to about 100mm; (iii) is used to deliver the engine of the composition from the container by the extension top actuator;And (b) from described The composition is assigned directly on scalp by application device component.

According to another embodiment of the invention, the application device component for delivering the composition to scalp is provided, It include: the container that (a) is used to accommodate the composition;(b) the extension top actuator being in fluid communication with the container, it is described to prolong Stretching top actuator includes: that (i) is configured to for the extension top actuator to be fluidly connected to the base part of the container; (ii) is configured to for the base part to be fluidly connected to the main part of hollow needle, wherein the tip includes being located at The face in the main part distal side, wherein the tip includes the hole being in fluid communication with the container, and the wherein tip With about 0.5mm to the projection length of about 100mm;(c) for being delivered by the extension top actuator from the container The engine of the composition.

By reading the disclosure, these and other features of the invention, aspect and advantage will to those skilled in the art It becomes apparent.

Detailed description of the invention

Although specification is summarized by claim, right of the invention is particularly pointed out and distinctly claimed, it is believed that The present invention will be better understood when from being described below for attached drawing of combination accompanying, in attached drawing:

Fig. 1 is the front perspective view of one embodiment of application device component;

Fig. 2 is the front view of the application device component of Fig. 1;

Fig. 2A is taken from the amplification front view of the extension top actuator in region included in the circle 2A of Fig. 2;

Fig. 3 is the top view of the application device component of Fig. 1;

Fig. 4 is the right side view of the application device component of Fig. 1.

Specific embodiment

In all embodiments of the invention, unless stated otherwise, it is total to press the composition for all percentage The poidometer of body.Unless stated otherwise, all ratios are weight ratio.All ranges are including end value and are It is combinative.The number of effective digital neither indicates the limitation to indicated amount, does not also indicate the limitation to measuring accuracy. Unless stated otherwise, all quantity is understood to be modified by " about " word.Unless otherwise specified, all measurements are managed Solution is carries out under 25 DEG C and environmental condition, wherein " environmental condition " refers in about atmospheric pressure and about 50% relative humidity Under the conditions of.Unless otherwise specified, all such weight relevant to ingredients listed are based on the content meter of active material, and not Including the carrier or by-product being possibly comprised in commercially available raw material.

As used herein, term " comprising/include " mean other steps for influencing final result and other can be added not Ingredient.The term includes term " Consists of " and "consisting essentially of ...".The compositions and methods of the invention/technique can be with Include, by with substantially by the element of invention as described herein and limitation and as described herein any additional or optional Ingredient, component, step or limitation composition.

As used herein, the terms "include", "comprise" and " containing " are intended to be non-limiting, and be interpreted as be respectively Refer to " having ", " having " and " covering ".

As used herein, term " scalp " includes the root of hair of hair.

The test method disclosed in the Test Methods section of present patent application should be used for determining applicant's invention parameter Analog value.

Unless otherwise specified, all components or composition levels refer to the active substance part of the component or composition, and It and does not include the impurity being likely to be present in the commercially available source of such component or composition, such as residual solvent or by-product Object.

Unless otherwise specified, all percentages and ratio are calculated by weight.Unless otherwise specified, all percentages and ratio Rate is based on total composition calculating.Herein, term " weight percent " is represented by " weight % ".

It should be appreciated that each greatest measure limit provided throughout the specification includes each lower numerical limitation, such as It is expressly written herein with such lower numerical limitation.The each minimum value limit provided in this specification It will include each higher numerical limitation, as such higher numerical limitation is expressly written herein.It is complete in this specification The each numberical range provided in text will include each narrower numberical range fallen into such wider numberical range, as such Narrower numberical range is expressly written herein.

A. container

Referring to Fig. 1, application device component 100 may include container 150.Container 150, which can have, to be suitable for accommodating composition Any type.In one embodiment, container 150 can be substantially rigid.When applying interior section vacuum to it, such as It does not collapse fruit under ambient exterior atmospheric pressure, then container 150 is substantially rigid.In one embodiment, container 150 can wrap Containing nonrigid material.Nonrigid material can be designed to be squeezed.

Container 150 can be made by any suitable material, the material be selected from plastics, metal, alloy, lamilate and it Combination.Container 150 can be any shape of suitable contained structure, and may include for accommodating at least one fluid At least one interior compartment.Container 150 can be the container that can be refilled, such as injection type or screw socket type container or container 150 can be it is disposable.Container 150 can also be can be from the removal of application device component 100.Alternatively select It selects, container 150 can form one with application device component 100.

B. extend actuator

Referring still to Fig. 1, application device component 100 may include extending top actuator 200.Extend top actuator 200 can be in fluid communication with container 150.Extend top actuator 200 may include base part 210, main part 220 and in Empty tip 225.Extending top actuator 200 can be made by any suitable material, and the material is selected from plastics, metal, alloy And their combination.Extension top actuator 200 can be can be from the removal of application device component 100.Alternatively Selection, one can be formed with application device component 100 by extending top actuator 200.

1.Base part

Referring to Fig. 1, extending top actuator 200 may include base part 210.Base part 210 may be configured to prolong It stretches top actuator 200 and is fluidly connected to container 150.Base part 210, which can be, to be removed from top actuator 200 is extended 's.Alternatively, base part 210 can form one with top actuator 200 is extended.

2.Main part

Referring still to Fig. 1, extending top actuator 200 may include main part 220.Main part 220 can construct Hollow needle 225 is fluidly connected at by base part 210.Main part 220 can be can from extension top actuator 200 It removes.Alternatively, main part 210 can form one with top actuator 200 is extended.

3.Hollow needle

Referring still to Fig. 1, extending top actuator 200 may include hollow needle 225.Hollow needle 225 may include Positioned at the face in 220 distal side of main part.Tip can also include the hole being in fluid communication with container 150.Tip can be can be from prolonging Stretch the removal of top actuator 200.Alternatively, tip can form one with top actuator 200 is extended.? In one embodiment, a hollow needle 225 can only be had by extending top actuator 200.

Referring now to Fig. 3, hollow needle 225 can have projection length 420.Projection length 420 is that hollow needle 225 is calm The outer profile of device 150 distance outstanding.In one embodiment, the projection length 420 that hollow needle 225 can have is about 0.5mm to about 100mm is perhaps that about 5mm to about 80mm is perhaps about 10mm to about 60mm or is about 15mm to about 55mm, Perhaps it is about 20mm to about 50mm and is about 25mm to about 45mm.In another embodiment, hollow needle 225 can It is about 0.5mm to about 30mm with the projection length 420 having, and is about 10mm to about 25mm.

Referring to fig. 4, application device component 100 can also include the longitudinal axis 300 passed through.In one embodiment In, the angle of hollow needle 225 and longitudinal axis 300 is about 20 ° to about 100 °, or with the angle of longitudinal axis 300 is about It to about 60 ° or with the angle of longitudinal axis 300 is about that 25 ° to about 70 °, which are perhaps about 30 ° with the angle of longitudinal axis 300, 35 ° to about 55 °, or with the angle of longitudinal axis 300 be about 45 °.In another embodiment, hollow needle 225 and longitudinal direction The angle of axis 300 is about 70 ° to about 110 °, be perhaps with the angle of longitudinal axis 300 about 80 ° to about 100 ° or with it is vertical Angle to axis 300 is about 85 ° to about 95 °, and is about 90 ° with the angle of longitudinal axis 300.Angle measurement can be from The top of longitudinal axis 300 shown in Fig. 4 calculates counterclockwise.

a.Face

Referring now to Fig. 2 and 2A, hollow needle 225 may include positioned at the main part 220 for extending top actuator 200 The face 226 in distal side.As described above, application device component 100 can also include the longitudinal axis 300 passed through.In a reality It applies in example, the angle of face 226 and longitudinal axis 300 is about 10 ° to about 30 °, or with the angle of longitudinal axis 300 is about 15 ° To about 25 °, perhaps it is about 20 ° to about 25 ° with the angle of longitudinal axis 300 and is about with the angle of longitudinal axis 300 23°.In another embodiment, the angle of face 226 and longitudinal axis 300 is about 35 ° to about 55 °, or with longitudinal axis 300 Angle be about 40 ° to about 50 °, be perhaps about 43 ° to about 48 ° and and longitudinal axis with the angle of longitudinal axis 300 300 angle is about 45 °.The angle measurement in face 226 can the top of longitudinal axis 300 as shown in Figure 4 calculate counterclockwise.

b.Hole

Referring still to Fig. 2 and 2A, hollow needle 225 may include the hole 227 being in fluid communication with container 150.Hole 227 can be with It is including but not limited to round or rectangular with any shape.

In one embodiment, each hole 227 can have the diameter of about 0.1mm to about 5mm.In another embodiment, Each hole 227 can have the diameter of about 0.2mm to about 2mm.In another embodiment, each hole 227 can have about 0.5mm extremely The diameter of about 1.5mm.

C. engine

Application device component 100 can also include for passing through extension 200 delivering compositions of top actuator from container 150 Engine.Engine can have any type for being suitable for that composition is distributed from container 150 comprising but it is not limited to mechanical pump, gas Colloidal sol or extruding.In one embodiment, engine can generate energy by that can convey any device of electricity.

In one embodiment, each complete stroke, engine can distribute the composition of about 0.05mL to about 4mL.Another In one embodiment, each complete stroke, engine can distribute the composition of about 0.1mL to about 1mL.In another embodiment In, each complete stroke, engine can distribute the composition of about 0.3mL to about 0.5mL.

In another embodiment, engine can deliver the dosage not measured.In this embodiment, consumer can pass through determination Such as how long button is pinned downwards, the dosage of delivering is controlled by application device component 100.

D. optional composition

Application device component 100 can also include composition.The composition can be rinse-off products or leave product, And various product forms can be configured to, including but not limited to liquid, foam, creams, gel, lotion, powder and mousse.

In one embodiment, the composition can have about 2,000cps to about 45,000cps, or about 9, 000cps to about 25,000cps, or about 9,000cps to about 12,000cps, or about 20,000cps to about 25,000cps, Or about 3,000 to about 10,000cps, and about 5,000 to about 8,000cps net viscosity.

The net viscosity of the composition is by measuring the composition 21Viscosity under the shear rate of/sec and determine. In scientific meaning, net viscosity is the ratio of shear stress and shear rate.Rheometer can be used in the net viscosity of the composition To measure.TA instrument AR2000 can be used to measure the shear stress curve of composition.

In one embodiment, the composition can have any class for being suitable for application to that human skin includes scalp Type.In another embodiment, it includes appointing for pet hair root of hair that the composition, which can have and be suitable for application to pet skin, What type.In another embodiment, the composition can have any type for being suitable for application to fabric and/or carpet.

In one embodiment, the composition, which may include, one or more becomes known for hair care product or individual The component of care product, as long as annexing ingredient can appropriately influence product stability, beauty or performance.Such optional member is most Typically be described in reference book such as " CTFA Cosmetic Ingredient Handbook " second edition (The Cosmetic, Those of Toiletries, and Fragrance Association, Inc.1988,1992) in.

Non-limitative example for the component in the composition includes conditioner (such as organosilicon, hydrocarbon ils, fat Ester), natural cationic deposition polymer, synthesizing cationic deposited polymer, dandruff removing agent, particle, granular tapioca, suspension Agent, paraffin hydrocarbon, propellant, viscosity improver, dyestuff, non-volatile solvents or diluent (water-soluble or water-insoluble), pearly-lustre Auxiliary agent, foam booster, surfactant or nonionic cosurfactant, pulicida, pH adjusting agent, fragrance, preservative, Protein, skin active agent, sun-screening agent, UV absorbent and vitamin.

1.Conditioner

In one embodiment, the composition may include one or more conditioners.Conditioner includes to hair Hair and/or scalp give the material of specific conditioning beneficial effect.The conditioner that can be used for the composition typically comprises shape At the water-insoluble of the liquid particles of emulsification, water dispersible, non-volatile liquid.It is suitable for what is used in the composition Conditioner is to be characterized in that organosilicon (such as organic silicone oil, cationic silicones, silicone gum, high refraction in general Organosilicon and organic siliconresin), oily those of (such as hydrocarbon ils, polyolefin and fatty ester) or the their combination conditioning of organic conditioning Agent, or it is additionally formed in aqueous surfactant matrix those of the particle conditioner of liquid, dispersion.

One or more conditioners can about 0.01 weight % to about 10 weight % by weight of the composition, or About 0.1 weight % to about 8 weight %, and about 0.2 weight % to about 4 weight % exist.

a.Organosilicon

The conditioner of the composition can be insoluble silicone conditioning agent.Silicone conditioning agent particle, which may include, to be waved Hair property organosilicon, non-volatile organosilicon or their combination.If there is volatile organosilicon, then they are usually incidentally used Make non-volatile organosilicon material the ingredient such as silicone gum and organic siliconresin of commercially available form solvent or Carrier.Silicone conditioning agent particle may include silicone fluid conditioner, and can also be such as organic comprising other ingredients Silicone resin, to improve silicone fluid deposition efficiency or enhancing hair luster.

The concentration of silicone conditioning agent can be by weight of the composition about 0.01% to about 10%, Huo Zheyue 0.1% to about 8%, perhaps about 0.1% to about 5% and about 0.2% to about 3%.Suitably silicone conditioning agent is non- Limitative examples and optional suspending agent for organosilicon are described in U.S. Reissue 34,584, United States Patent (USP) 5,104, 646 and United States Patent (USP) 5,106,609, it is herein incorporated by reference.For the silicone conditioning agent in the composition It can haveUnder be about 20 to about 2,000,000 centistokes(cst) (" csk "), or about 1,000 to about 1,800, 000csk, or about 50,000 to about 1,500,000csk, and about 100,000 to about 1,500,000csk viscosity.

Usually there is the silicone conditioning agent particle of dispersion the volume in about 0.01 micron to about 50 micron ranges to be averaged grain Diameter.For being applied to the little particle of hair, volume average particle size is typically about 0.01 micron to about 4 microns, or about 0.01 Micron to about 2 microns, and about 0.01 micron to about 0.5 micron in the range of.For being applied to the larger particles of hair, Volume average particle size is typically about 5 microns to about 125 microns, is perhaps about 10 microns to about 90 microns or is about 15 micro- 70 microns of meter Zhi Yue, and in the range of being about 20 microns to about 50 microns.

Background material in relation to organosilicon, including discuss silicone fluid, silicone gum and organic siliconresin and The part of organosilicon manufacture, it is seen that in " Encyclopedia of Polymer Science and Engineering " the 15th It rolls up in the 204-308 pages of second edition (John Wiley&Sons, Inc., 1989), the document is herein incorporated by reference.

i.Silicone oil

Silicone oil includes such silicone oil, has and measures at 25 DEG C, and viscosity is lower than 1,000,000csk, Huo Zheyue 5csk to about 1,000,000csk, and about 100csk to about 600,000csk flowable organosilicon material.For Suitable silicone oil in hair care composition includes poly- silicon substrate siloxanes, polyarylsiloxane, poly- alkaryl siloxanes, polyethers Silicone copolymers and their mixture.Also it can be used other insoluble non-volatile organic with hair conditioning properties Silicon liquid.

Silicone oil includes the polyalkylsiloxane or polyarylsiloxane for meeting lower formula (I):

Wherein R is aliphatic group, is in some embodiments alkyl, alkenyl or aryl, R can be it is substituted or unsubstituted, And x is the integer of 1 to about 8,000.R group suitable for the present composition includes but is not limited to: alkoxy, fragrant oxygen Aliphatic radical and virtue that base, alkaryl, aralkyl, aryl alkenyl, alkylamino and ether replace, hydroxyl replaces and that halogen replaces Base.Suitable R group further includes cationic amido and quaternary ammonium group.

Possible alkyl and alkenyl group include C1To C5Or C1To C4, and C1To C2Alkyl and alkenyl.Its Its aliphatic part (such as alkoxy, alkaryl and alkylamino) containing alkyl, alkenyl or alkynyl can be linear chain or branched chain, And it can be C1To C5, or be C1To C4, or be C1To C3, and be C1To C2.As described above, R substituent may be used also Can be primary amine, secondary amine or tertiary amine or quaternary ammonium comprising amido functional group (such as alkylamino group).These include mono-, two- The projection length of wherein aliphatic part chain can be as described above with three-alkyl aminos and alkoxy amino.

ii.Amido organosilicon and cationic silicones

Cationic silicones liquid suitable for the composition includes but is not limited to meet those of logical formula (II):

(R1)aG3-a-Si--(--OSiG2)n-(--OSiGb(R1)2-b)m--O--SiG3-a(R1)a

Wherein G is hydrogen, phenyl, hydroxyl or C1-C8Alkyl is methyl in some embodiments;A be 0 or value be 1 to 3 it is whole Number;B is 0 or 1;N is 0 to 1,999 or 49 to 499 number;M is 1 to 2,000 or integer of 1 to 10;The sum of n and m are 1 to 2,000 or 50 to 500 number;R1To meet general formula CqH2qThe univalent perssad of L, wherein q is the whole of the value with 2 to 8 Number, and L is selected from following group:

--N(R2)CH2--CH2--N(R2)2

--N(R2)2

--N(R2)3A-

--N(R2)CH2--CH2--NR2H2A-

Wherein R2It is hydrogen, phenyl, benzyl or saturated hydrocarbyl, is about C in some embodiments1To about C20Alkyl, and A- It is halogen ion.

In one embodiment, the cationic organosilicon of corresponding formula (II) is known as " trimethyl silyl ammonia generation The polymer of dimethyl silicone polymer " is shown in below in formula (III):

The other organosilicon cationic polymers that can be used in the composition are indicated by logical formula (IV):

Wherein R3It is C1To C18Monovalent hydrocarbon, be alkyl or alkenyl, such as methyl in some embodiments;R4It is alkyl, It is C in some embodiments1To C18Alkylidene group or C10To C18Polyoxyalkylene group or C1To C8Alkylene oxide group base Group;Q-It is halogen ion, is chloride ion in some embodiments;R is 2 to 20, is 2 to 8 average statistics in one embodiment Value;S be 20 to 200, in one embodiment for 20 to 50 average statistical value;A kind of such polymer is referred to as UCARE SILICONE ALEIt is available from Union Carbide.

iii.Silicone gum

Other organosilicon liquids suitable for the composition can be insoluble silicone gum.These silicone gums It is polysiloxane material, there is the viscosity for being greater than or equal to 1,000,000csk measured at 25 DEG C.Silicon rubber is pure Sizing material is described in United States Patent (USP) 4,152,416;" the Chemistry and Technology of of Noll and Walter Silicones " (New York:Academic Press, 1968);And " General Electric Silicone In Rubber Product Data Sheets " SE 30, SE 33, SE 54 and SE 76, these patents are by reference simultaneously Enter herein.Specific non-limitative example for the silicone gum in hair-care includes dimethyl silicone polymer, (poly- two Methylsiloxane) (methyl vinyl silicone) copolymer, poly- (dimethyl siloxane) (diphenyl siloxane) (methyl ethylene Siloxanes) copolymer and their mixture.

iv.High refractive index organosilicon

Other non-volatile insoluble silicone fluid conditioners suitable for hair care composition are known as " high Those of refractive index silicones " have at least about 1.46, at least about 1.52, at least about 1.48, or at least about 1.55 refraction Rate.The refractive index of polysiloxane fluid is generally less than about 1.70, generally less than about 1.60.In this context, polysiloxanes " stream Body " includes oil and natural gum.High refractive index polysiloxanes liquid includes poly- by those of general formula (I) expression, and ring-type Those of siloxanes, such as indicated by lower formula (V):

Wherein, R is as hereinbefore defined, and n is about 3 to about 7, or the number of about 3 to about 5.

High refractive index polysiloxanes liquid includes the amount for being enough to increase to refractive index expected degree as described herein R substituent containing aryl.In addition, R and n may be selected, so that the substance is non-volatile.

Substituent group comprising aryl include comprising those of alicyclic ring and five-ring heterocycles and hexa-atomic aromatic ring, and comprising five yuan or Those of hexa-atomic condensed ring.Aromatic ring itself can be substituted or unsubstituted.

In general, the degree containing aryl substituent having is at least about 15% by the silicone fluid of high refractive index, or At least about 20%, perhaps at least about 25% perhaps at least about 35% and at least about 50%.In general, aryl substituent Degree will be less than about 90%, more typically be less than about 85%, or about 55% to about 80%.In some embodiments, high refractive index Polyorganosiloxane fluid has phenyl or phenyl derivative substituents and alkyl substituent (is in some embodiments C1-C4Alkyl (being in some embodiments methyl)), hydroxyl or C1-C4Alkylamino (especially-R4NHR5NH2, wherein each R4And R5It is independent Ground is C1-C3Alkyl, alkenyl and/or alkoxy) combination.

When using high refractive index siloxanes in the composition, they can be with spreading agent such as organic siliconresin or surface Activating agent is used in composition together, reduces surface tension with significant quantity, enhancing is sprawled, to enhance with the compositions-treated Hair glossiness (dry after).

Silicone fluid suitable for the composition is disclosed in United States Patent (USP) 2,826,551, United States Patent (USP) 3,964, 500, United States Patent (USP) 4,364,837, British patent 849,433 and " Silicon Compounds " (Petrarch Systems, Inc., 1984) in, these documents are herein incorporated by reference.

v.Organic siliconresin

Organic siliconresin may include in the composition.These resins are highly cross-linked polymeric siloxane systems.Crosslinking is By during prepared by organic siliconresin by trifunctional and tetrafunctional SiClx alkane and monofunctional or Bifunctionalized silane or two Person mixes to introduce together.

Organosilicon material, especially organic siliconresin are known as in which can be convenient according to those of ordinary skill in the art The shorthand nomenclature system of " MDTQ " name identifies.Under this systems, according to the various siloxanes of existing composition organosilicon Monomeric unit describes organosilicon.In short, symbol M represents a functional unit (CH3)3SiO0.5;D represents difunctional unit (CH3)2SiO;T represents trifunctional units (CH3)SiO1.5;And Q represents season or tetrafunctional cell S iO2.The subscript of unit symbol Symbol (such as M', D', T' and Q') indicates substituent group rather than methyl, and for occurring every time, it is necessary to special definition.

It can include but is not limited to MQ, MT, MTQ, MDT and MDTQ resin for the organic siliconresin in the composition. Methyl is possible organosilicon substituents.In some embodiments, silicone resin is MQ resin, wherein the ratio of M:Q is about 0.5:1.0 to about 1.5:1.0, and the average molecular weight of the organic siliconresin is about 1000 to about 10,000.

When in use, especially when silicone oil component is dimethyl silicone polymer liquid or dimethyl silicone polymer as described above When liquid and the mixture of dimethyl silicone polymer glue, refractive index lower than 1.46 non-volatile silicone oil and silicone resin component Weight ratio can be about 4:1 to about 400:1, perhaps about 9:1 to about 200:1 and about 19:1 to about 100:1.Just have Machine silicone resin formed in its composition with for silicone fluid, that is, opsonic activity substance identical phase a part, in determination It should include the sum of the liquid and resin when silicone conditioning agent content in the composition.

b.Organic conditioning oil

The conditioner of the composition can also be individually or all with other conditioners comprising at least one organic conditioning oil Such as above-mentioned silicone combinations.

i.Hydrocarbon ils

Organic conditioning oil that conditioner is suitable as in the composition includes but is not limited to have at least about 10 carbon originals The hydrocarbon ils of son, such as cyclic hydrocarbon, linear aliphatic hydrocarbon (saturated or unsaturated) and branched aliphatic hydrocarbons (saturated or unsaturated), Including polymer and their mixture.Straight chain hydrocarbon ils can be about C12To about C19.Branched-chain hydrocarbons including hydrocarbon polymer Oil generally comprises the carbon atom more than 19.

ii.Polyolefin

For organic conditioning oil in the composition can also include liquid polyolefin or liquid poly-alpha-olefin or Person's hydrogenation of liquid poly-alpha-olefin.Polyolefin for this paper passes through C4To about C14, and about C in some embodiments6To about C12 The polymerization reaction of olefinic monomer prepare.

iii.Aliphatic ester

Other organic conditioning oil that conditioner is suitable as in hair care composition of the invention may include having extremely The aliphatic ester of few 10 carbon atoms.These aliphatic esters include with the ester from fatty acid or the hydrocarbyl chain of alcohol.Its rouge Alkyl in fat acid esters may include or other compatible functionalities with covalent bonding therewith, such as amide and alkoxy portion (such as ethyoxyl or ehter bond etc.).

iv.Fluorinated conditioning compound

Be suitable for organic conditioning oil to the fluorinated compound of hair or dermal delivery opsonic action include perfluoropolyether, Perfluorinated olefins, it is similar with aforementioned organic silicon liquid be fluid or elastomer form based on fluorine specialty polymer and Perfluorinated dimethicones.

v.Fatty alcohol

Other organic conditioning oil suitable for the composition can include but is not limited to have at least about 10 carbon originals Son or about 10 to about 22 carbon atoms and about 12 to about 16 carbon atoms fatty alcohol.

vi.Alkyl glucoside and alkyl glucoside derivatives

Organic conditioning oil suitable for the composition can include but is not limited to alkyl glucoside and alkyl glucoside Derivative.The specific non-limitative example of suitable alkyl glucoside and alkyl glucoside derivatives includes can be from Amerchol quotient Purchase the Glucam E-10 obtained, Glucam E-20, Glucam P-10 and Glucquat 125.

c.Other conditioners

i.Quaternary ammonium compound

The quaternary ammonium compound that conditioner is suitable as in the composition can include but is not limited to comprising having carbonyl portion Divide the hydrophilic quaternary ammonium compounds of the long chain substituents such as amide moieties or phosphonate moiety or similar hydrophilic parts.

The example of available hydrophilic quaternary ammonium compounds includes but is not limited to be named as castor-oil plant alcohol in CTFA cosmetics dictionary Sour amidopropyltrimonium chloride, ethyl sulfuric acid ricinoleic acid amide base trimethyl ammonium, methylsulfuric acid hydroxy stearate acylamino- The compound of oxypropyl trimethyl ammonium and hydroxy stearamidopropyl trimonium chloride or their combination.

ii.Polyethylene glycol

Can be used as herein conditioner other compounds include have at most about the polyethylene glycol of 2,000,000 molecular weight and Polypropylene glycol, such as CTFA entitled PEG-200, PEG-400, PEG-600, PEG-1000, PEG-2M, PEG-7M, PEG- Those of 14M, PEG-45M and their mixture.

iii.Cationic Deposition Polvmer

The composition can also include Cationic Deposition Polvmer.Any of natural or synthetic sun can be used herein Deposition polymers.Example includes being disclosed in United States Patent (USP) 6,649,155;U.S. Patent Application Publication 2008/0317698; 2008/0206355;With 2006/0099167 in those of polymer, the entirety is herein incorporated by reference.

To provide the beneficial effect of the composition, Cationic Deposition Polvmer with about 0.01 weight % to about 2 weight %, About 1.5 weight % to about 1.9 weight % in one embodiment, in another embodiment about 1.8 weight % to about 2.0 weights The content of amount % is comprised in the composition.

Cationic Deposition Polvmer can be water-soluble polymer, have about 0.5 milliequivalent/gram to about 12 milliequivalents/ Gram charge density.It can have about 100,000 dalton to about 5 for the Cationic Deposition Polvmer in the composition, The molecular weight of 000,000 dalton.The Cationic Deposition Polvmer can be low charge density cationic polymer.

In one embodiment, the Cationic Deposition Polvmer is synthesizing cationic deposited polymer.It can be used a variety of Synthesizing cationic deposited polymer, including monoalkyl chain and dialkyl group chain cationic surfactant.In one embodiment, it selects Select monoalkyl chain cationic surfactant, including such as monoalkyl quaternary ammonium salts and monoalkylamine.In another embodiment, make With dialkyl group chain cationic surfactant, and including such as dialkyl group (14-18) alkyl dimethyl ammonium chloride, two tallow alkyls two Ammonio methacrylate, dihydrogenated tallow alkyl dimethyl ammonium chloride, VARISOFT TA100, di-cetyl dimethyl chlorine Change ammonium and their mixture.

In another embodiment, the Cationic Deposition Polvmer is naturally derived cationic polymers.As used herein, Term " naturally derived cationic polymers " refers to the Cationic Deposition Polvmer obtained from natural source.The natural source can be poly- for polysaccharide Close object.Therefore, naturally derived cationic polymers can be selected from starch, guar gum, cellulose, cassia bark, locust bean gum, konjaku, tower drawing Glue, galactomannans, cassava and synthetic polymer.In another embodiment, Cationic Deposition Polvmer is selected from100S(Rhodia)、C17, poly- DADMAC, tapioca (Akzo), TriquatTMAnd they Mixture.

d.Anion emulsifier

It can be used for a variety of anion emulsifiers in the composition as described below.Anion emulsifier example and non- It restrictively include water soluble salt below: the different thiosulfate of alkyl sulfate, alkyl ether sulfate, alkyl, alkyl carboxylic acid Salt, alkyl sulfosuccinate, amber alkyl amide salts, alkyl sulfate (such as lauryl sodium sulfate, alkylsarcosines Salt), the alkyl derivative of protein hydrolysate, acylaspartic acid salt, alkyl or alkyl ether or alkylaryl ether phosphate, Lauryl sodium sulfate, phosphatide or lecithin or soap, odium stearate, potassium stearate or ammonium stearate, oleate or palmitinic acid Salt, alkylaryl sulfonates (such as neopelex), dialkyl sulfosuccinate sodium, dioctyl sodium sulfosuccinates acid Salt, sulfosuccinic acid dilauryl ester sodium, poly- (styrene sulfonic acid) sodium salt, isobutyiene-maieic anhydride copolymer, Arabic tree Glue, mosanom, carboxymethyl cellulose, cellulose sulfate and pectin, poly- (styrene sulfonate), isobutyiene-maieic anhydride are total Polymers, gum arabic, carrageenan, mosanom, pectic acid, bassora gum, almond glue and agar;Semi synthetic polymer such as carboxylic first Base cellulose, Cellulose sulfate, sulphation methylcellulose, carboxymethyl starch, phosphatization starch, lignin sulfonic acid;With Synthetic polymer such as copolymer-maleic anhydride (including its hydrolysate), polyacrylic acid, polymethylacrylic acid, acrylic acid-acrylic Butyl acrylate copolymer or crotonic acid homopolymer and copolymer, vinylbenzenesulfonic acid or 2- acrylamide-2-methyl propane sulfonic homopolymerization Object and copolymer and this quasi polymer and copolymer portion amide or part ester, carboxy-modified polyvinyl alcohol, sulfonic acid modified Polyvinyl alcohol and phosphoric acid-modification polyvinyl alcohol, phosphorylation or sulphation tristyrylphenol ethoxylates.

In addition, the anion emulsifier with acrylate-functional groups can also be used in the composition.For this paper's Anion emulsifier includes but is not limited to: poly- (methyl) acrylic acid;(methyl) acrylic acid is with it with C1-22 alkyl, C1-C8 alkane Base, butyl (methyl) acrylate copolymer;The copolymer of (methyl) acrylic acid and (methyl) acrylamide;Carboxy vinyl Based polyalcohol;Acrylate copolymer such as acrylate/acrylic acid C10-30 alkyl ester cross-linked polymer, acrylic acid/vinyl Ester copolymer/acrylate/isodecyl vinyl acetate cross-linked polymer, acrylate/- 25 acrylate of palmityl polyoxyethylene ether Copolymer, -20 itaconate copolymeric of acrylate/steareth and acrylate/ceteth - 20 itaconate copolymerics;Polystyrenesulfonate, the copolymer of methacrylic acid and acrylamido methylpropane sulfonic acid, Yi Jibing The copolymer of olefin(e) acid and acrylamido methylpropane sulfonic acid;Carboxymethyl cellulose;Carboxyl guar gum;The copolymerization of ethylene and maleic acid Object;And acrylate silicone polymer.Neutralizer be may include to neutralize the anion emulsifier of this paper.Such neutralizer Non-limitative example include sodium hydroxide, it is potassium hydroxide, ammonium hydroxide, monoethanolamine, diethanol amine, triethanolamine, two different Propanolamine, aminomethylpropanol, tromethamine, tetrahydroxypropyl ethylenediamine and their mixture.Commercially available Anion emulsifier includes the carbomer for example provided with trade name Carbopol 981 and Carbopol 980 by Noveon;Tool There are trade name Pemulen TR-1, Pemulen TR-2, Carbopol 1342, Carbopol 1382 and Carbopol ETD 2020 are purchased from acrylate/acrylic acid C10-30 alkyl ester cross-linked polymer of Noveon;It is mentioned with CMC series by Hercules The sodium carboxymethylcellulose of confession;And the acrylate copolymer provided with trade name Capigel by Seppic.At another In embodiment, anion emulsifier is carboxymethyl cellulose.

2.Beneficial agent

In one embodiment, the composition also includes one or more additional beneficial agents.The beneficial agent includes Selected from dandruff removing agent, vitamin, lipid soluble vitamins, chelating agent, fragrance, brightener, enzyme, sensory agent, attractant, antibacterial Agent, dyestuff, pigment, bleaching agent, hops, caffeine, resorcinol, detergent and their mixture.

a.Vitamin B3Compound

The composition may include vitamin b 3 compound.In one embodiment, vitamin b 3 compound is nicotinoyl Amine.Vitamin b 3 compound also has for adjusting skin, such as United States Patent (USP) 5, described in 939,082.In some embodiments In, the composition also includes the vitamin b 3 compound of about 0.1% to about 25%, in another embodiment, comprising about The vitamin b 3 compound of 0.5% to about 15%, and the dimension comprising about 3.5% to about 7.5% is raw in another embodiment Plain B3 compound.As used herein, " vitamin b 3 compound " refers to one or more compounds with following formula:

Wherein R is-CONH2(That is niacinamide) ,-COOH (i.e. niacin) or-CH2OH (i.e. nicotinic alcohol);Their derivative;It Mixture;And aforementioned any salt.

The Exemplary derivatives of foregoing vitamin B3 compound include nicotinate (including non-vasodilating nicotinate, example Such as tocopheryl nicotinate, niacin tetradecane ester), cigarette base amino acid, carboxylic acid cigarette base alcohol ester, nicotinic acid N-oxide and niacinamide N- Oxide.In addition illustrative vitamin b 3 compound derivative is shown in U.S. Patent application 11/897084, by the patent Shen Qing Publication is herein incorporated by reference.

b.Alcohol

In one embodiment, the composition can wrap alcohol-containing.Alcohol can be used for the composition dry and skin faster Skin infiltration.In a specific embodiment, alcohol of the composition comprising about 10% to about 90%, or about 15% to about 75% Alcohol, or the alcohol of about 25% to about 50%.Any suitable alcohol, such as ethyl alcohol can be used.

c.Dandruff removing agent

In one embodiment, the composition may include dandruff removing agent, can be anti-dandruff active material particle. Such anti-dandruff particle and should not should undeservedly damage the steady of product with the component physics of composition and chemically compatible Qualitative, aesthetics or performance.

In one embodiment, the dandruff removing agent can be selected from: pyrithione;Azole, such as ketoconazole, econazole and New health azoles;Selenium sulfide;Particle sulphur;Keratolytic such as salicylic acid;And their mixture.

Pyrithione can be suitable anti-dandruff active particle.In one embodiment, the anti-dandruff active matter It can be pyrithione salt, and be the form of particle.In one embodiment, Pyridinethione anti-dandruff particle Concentration in about 0.01 weight % to about 5 weight %, or about 0.1 weight % to about 3 weight %, or about 0.1 weight % to about 2 weights In the range of amount %.In one embodiment, pyrithione be by heavy metal such as zinc, tin, cadmium, magnesium, aluminium and zirconium (generally Zinc) it those of is formed, usually 1-hydroxy-2-pyridinethione zinc salt (referred to as " zinc pyrithione " or " ZPT "), usually sheet The pyrithione salt of particle form.In one embodiment, the pyrithione of flaky particle form Salt has at most about 20 microns, or at most about 5 microns, or at most about 2.5 microns of average particle size.By other cations such as sodium shape At salt be also suitable.Pyridinethione anti-dandruff active material is described in such as United States Patent (USP) 2,809,971;United States Patent (USP) 3, 236,733;United States Patent (USP) 3,753,196;United States Patent (USP) 3,761,418;United States Patent (USP) 4,345,080;United States Patent (USP) 4,323, 683;United States Patent (USP) 4,379,753;In United States Patent (USP) 4,470,982.

In one embodiment, in addition to selected from pyrithione multivalent metal salt anti-dandruff active with Outside, the composition can also include one or more antimycotic and/or anti-microbial active matter.In one embodiment, The anti-microbial active matter is selected from: coal tar, sulphur, charcoal, whitfield ointment, Ka Sitaila Nissl paint, chlorination Aluminium, gentian violet, Octopirox (piroctone amine), Ciclopirox oxyethylamine ketone, undecenoic acid and its metal salt, height Potassium manganate, selenium sulfide, sodium thiosulfate, propylene glycol, bitter orange oil, Carmol, griseofulvin, 8-hydroxyquinoline clioquinol, Thiobendazole, thiocarbamate, Haloprogin, polyene, Hydroxypyridinone, morpholine, benzylamine, allylamine are (as spy compares naphthalene It is fragrant), tea oil, clove leaf oil, coriander, palmarosa, jamaicin, thyme be red, cassia oil, cinnamic acid, citronellic acid, chamenol, Ammonium ichthosulfonate is white, Sensiva SC-50, Elestab HP-100, azelaic acid, lyase, iodopropynyl butyl carbamate (IPBC), isothiazolinone such as octylisothiazolinone and azole and their mixture.In one embodiment, described Antimicrobial is selected from: Itraconazole (itraconazole), ketoconazole, selenium sulfide, coal tar and their mixture.

In one embodiment, the Azole anti-microbials are imidazoles, are selected from: benzimidazole, benzothiazole, biphenyl Benzyl azoles, butunazole nitrate, Climbazole, clotrimazole, Crewe health azoles, Eberconazole, econazole, new health azoles, Fenticonazole, fluorine health Azoles, flutrimazole, Isoconazole, ketoconazole, lanoconazole, metronidazole, Miconazole, Neticonazole, Omoconazole, Oxiconazole nitric acid Salt, Sertaconazole, sulconazole nitrate, tioconazole, thiazole and their mixture or the Azole anti-microbials are three Azoles is selected from: terconazole, Itraconazole and their mixture.When being present in the composition, azole resists micro- life Active substances can about 0.01 weight % to about 5 weight %, or about 0.1 weight % to about 3 weight %, or about 0.3 weight % Amount to about 2 weight % exists.In one embodiment, the azole anti-microbial active material is ketoconazole.In a reality It applies in example, unique anti-microbial active matter is ketoconazole.

The embodiment of composition can also include the combination of anti-microbial active matter.In one embodiment, resist micro- life The combination of active substances is selected from the combination being made up of: Octopirox and zinc pyrithione, pine tree tar and sulphur, bigcatkin willow Acid and zinc pyrithione, salicylic acid and Xin Kang azoles, zinc pyrithione and Xin Kang azoles, zinc pyrithione and climbasole, hydroxyl first Pungent pyrrone and climbasole, salicylic acid and Octopirox and their mixture.

In one embodiment, the composition includes a effective amount of bedded substance containing zinc.In one embodiment, by institute The total weight of composition is stated, the composition includes about 0.001 weight % to about 10 weight %, or about 0.01 weight % is to about 7 weight %, or about 0.1 weight % is to the bedded substance containing zinc of about 5 weight %.

Stratified material containing zinc can be mainly those of progress crystal growth on two-dimensional surface.Conventionally layer structure is retouched It states as wherein not only all atoms those of are incorporated into specific layer, but also is wherein the presence of referred to as tunnel ion between layers The lewis' acid of (A.F Wells, " Structural Inorganic Chemistry ", Clarendon Press, 1975) Those of.Bedded substance containing zinc (ZLM) can have the zinc being incorporated into layer and/or can be tunnel ion component.Following classification ZLM represent example more typical in total classification, and be not intended to it is wider array of to range meet this definition substance make rising limit System.

Many ZLM occur in the form of minerals in nature.In one embodiment, the ZLM is selected from: marionite (zinc carbonate hydroxide), aurichalcite (zinc copper carbonate hydroxide), rosasite (copper carbonate zinc hydroxide), with And their mixture.Relevant zinc-bearing mineral matter also may include in the composition.Natural ZLM also may be present, wherein Anion layer substance such as clay-type minerals matter (such as phyllosilicate) includes the zinc tunnel ion of ion exchange.All these natural goods Matter can also be obtained by synthesis, or be formed in situ in the composition or during production process.

The common class ZLM that another kind generally but not always synthesizes acquisition is layered double-hydroxide.In one embodiment In, the ZLM is meeting formula [M2+ 1-xM3+ x(OH)2]x+Am- x/m·nH2The layered double-hydroxide of O, some or all of them Divalent ion (M2+) it is zinc ion (Crepaldi, EL, Pava, PC, Tronto, J, Valim, JB J.Colloid Interfac.Sci.2002,248,429-42).

Can prepare the ZLM of another category, referred to as hydroxy double salts (Morioka, H., Tagaya, H., Karasu, M, Kadokawa, J, Chiba, K Inorg.Chem., 1999,38,4211-6).In one embodiment, the ZLM is meeting formula [M2+ 1-xM2+ 1+x(OH)3(1-y)]+An- (1=3y)/n·nH2The hydroxy double salts of O, two of them metal ion (M2+) may be the same or different. If they are identical and are indicated by zinc, the formula is reduced to [Zn1+x(OH)2]2x+2x A-·nH2O.The rear formula represents (its Middle x=0.4) substance such as hydroxy chloride zinc and hydroxyl zinc nitrate.In one embodiment, the ZLM be hydroxy chloride zinc and/or Hydroxyl zinc nitrate.These are also related to marionite, and wherein dianion is instead of univalent anion.These substances can also combine It is formed in situ in object or in process of production or during production process.

In the embodiment with bedded substance containing zinc and pyrithione or pyrithione multivalent metal salt In, the ratio of the multivalent metal salt of bedded substance containing zinc and pyrithione or pyrithione be about 5:100 extremely About 10:1, or about 2:10 to about 5:1, or about 1:2 to about 3:1.

At least about 1 μ g/cm is deposited as on the scalp of anti-dandruff active material2.To ensure that anti-dandruff active material reaches it It is able to carry out the scalp of its function, deposits and is important on the scalp of anti-dandruff active material.In one embodiment, anti-dandruff Active material is deposited as at least about 1.5 μ g/cm on scalp2, or at least about 2.5 μ g/cm2, or at least about 3 μ g/cm2, or extremely Few about 4 μ g/cm2, or at least about 6 μ g/cm2, or at least about 7 μ g/cm2, or at least about 8 μ g/cm2, or at least about 8 μ g/cm2, or At least about 10 μ g/cm2.By according to conventional wash scheme, by composition of the specialist cosmetology teacher comprising anti-dandruff active material Such as cleaning compositions individual hair according to the present invention, it deposits on the scalp to measure anti-dandruff active material.Then scalp Hair on region separates, so that the glass cylinder of open-ended can retain on the surface, while being added and extracting composition etc. Divide sample, and stir, then recycle, and measurement anti-dandruff active content is analyzed by conventional method such as HPLC.

d.Fatty alcohol gel network

The embodiment of composition can also include fatty alcohol gel network, be used for beauty creams and hair-conditioning for many years In agent.These gel networks by by fatty alcohol and surfactant with about 1:1 to about 40:1 (or about 2:1 to about 20:1, and And about 3:1 to about 10:1) ratio mixing and formed.The formation of gel network is related to the dispersion by fatty alcohol in water It is heated above the temperature of the fusing point of fatty alcohol with surfactant.During mixed process, fatty alcohol melting makes surface-active Agent can separate fatty alcohol drop.Water is therewith carried in fatty alcohol by surfactant.This makes isotropic fat Alcohol drops becomes liquid crystalline phase drops.When being cooled to mixture lower than chain melting temperature, the liquid crystal phase transition is at solid knot Brilliant gel network.Gel network is provided to beauty creams and hair conditioner stablizes beneficial effect.In addition, they also deliver hair The conditioning sense beneficial effect of conditioner.

Therefore, according to one embodiment, by weight, fatty alcohol is with about 0.05 weight % to the content packet of about 14 weight % Contained in fatty alcohol gel network.For example, fatty alcohol can about 1 weight % to about 10 weight %, and about 6 weight % extremely Amount within the scope of about 8 weight % exists.

Can be used for this paper fatty alcohol be have about 10 to about 40 carbon atoms, about 12 to about 22 carbon atoms, about 16 to Those of about 22 carbon atoms, or about 16 to about 18 carbon atoms.These fatty alcohols can be linear chain or branched chain alcohol, and can be full And/or it is unsaturated.The non-limitative example of fatty alcohol includes hexadecanol, stearyl alcohol, docosanol and their mixing Object.Ratio be about 20:80 to the hexadecanol of about 80:20 and the mixture of stearyl alcohol be suitable.

Can be used for this paper fatty alcohol be have about 10 to about 40 carbon atoms, about 12 to about 22 carbon atoms, about 16 to Those of about 22 carbon atoms, or about 16 to about 18 carbon atoms.These fatty alcohols can be linear chain or branched chain alcohol, and can be full And/or it is unsaturated.The non-limitative example of fatty alcohol includes hexadecanol, stearyl alcohol, docosanol and their mixing Object.Ratio be about 20:80 to the hexadecanol of about 80:20 and the mixture of stearyl alcohol be suitable.

E. the method for distribution

Application device component 100 described above can also use in the method for distributing composition.For distribution Method may include providing above-mentioned application device component 100, by composition distribution in application device component 100, and activates and applies With device assembly 100.In one embodiment, the activation of application device component 100 may include starting mechanical pump, aerosol appearance Device or squeeze-type container.

In one embodiment, the method can be used for being assigned directly to scalp from application device component by the composition On.

In another embodiment, the method can also be used in the effect of improving the composition after being delivered to scalp.

F. data

Referring to table 1, it is desirable that the consumer that 30 ages are 22 to 55 years old evaluates following scalp application device.Spraying application dress Set is for composition to be applied to application device in the common shop of scalp.Unicuspid head application device is for applying composition To the embodiment of the present invention of scalp.It is required that consumer, with 1 to 10 grade assessment application device, 10 be that scalp is applied most It is useful, and 1 is most useful to apply for hair.Then average value is calculated, is listed in table 1.Using student's T method, 95% Confidence level under, applying the consumer preference of the most useful unicuspid head application device for scalp, there are aobvious in statistical significance Write sex differernce.

Table 1: for the validity of scalp application

Application device It is average
Unicuspid head 5.90
It is spraying 2.83

Referring to table 2, it is desirable that the consumer that 30 ages are 22 to 55 years old evaluates following scalp application device.Spraying application dress Set is for composition to be applied to application device in the common shop of scalp.Unicuspid head application device is for applying composition To the embodiment of the present invention of scalp.It is required that consumer, with 1 to 10 grade assessment application device, 10 be to be easiest to composition It is applied to scalp, and 1 is most to be difficult to composition being applied to scalp.Then average value is calculated, is listed in table 2.Use student T Method, under 95% confidence level, for being easiest to for composition to be applied to the consumer of the unicuspid head application device of scalp There are the significant differences in statistical significance for preference.

Table 2: it is easy to apply

Referring to table 3, it is desirable that 236 consumers use and are sprayed application device to spraying application device delivering product beneficial to effect The ability of fruit scores.Spraying application device is for composition to be applied to application device in the common shop of scalp.It is required that 100 consumers use, and score the ability of unicuspid head application device delivering product beneficial effect.Unicuspid head application dress Setting is the embodiment of the present invention for composition to be applied to scalp.It is required that consumer is applied with 1 to 100 grade assessment scalp With device, 100 be deliver product beneficial effect ability it is maximum, and 1 be delivering product beneficial effect ability it is minimum.Then it counts Average value is calculated to be listed in table 3.Using 85% confidence level, consumer is maximum for the ability for delivering product beneficial effect There are the significant differences in statistical significance in the scoring of unicuspid head application device.

Table 3: delivering product beneficial effect

Application device It is average
Unicuspid head 52
It is spraying 43

Referring to table 4, it is desirable that 10 consumers use spraying application device or unicuspid head application device.Application device is by spraying For composition to be applied to application device in the common shop of scalp.Unicuspid head application device is for composition to be applied to head The embodiment of the present invention of skin.Then the product on every consumer's scalp will be spread over by using fluorescent reagents and image point Analysis is quantified.Average value is listed in Table 4 below.Unicuspid head application device delivers significantly more than spraying application device as the result is shown Product improves 62.9% than spraying application device to scalp-coverage rate.

Table 4: areal intensity coverage rate

Application device It is average
Unicuspid head 6,830,561.4
It is spraying 4,192,614.3

G. areal intensity coverage rate test method

1) expert applies the production with fluorescer (curcumin) using delivery system on themselves wet hair scalp Product.

2) expert wipes product on their scalp, as will be during normal use instructed to.

3) cut short by the hair-that hairdresser cuts short them must be for all experts all by expert.

4) it is taken pictures using conventional cameras and black light to show that fluorescer (curcumin) is passed with determination in four different angles Send the scalp coverage rate between system.

5) all images are analyzed using the Image J of computer program, measurement area (with pixel record) and should The fluorescer intensity of area.The value of areal intensity coverage rate is calculated by area multiplied by intensity.

Dimension disclosed herein and value are not to be construed as being strictly limited to cited exact value.On the contrary, unless in addition referring to Bright, each such dimension is intended to indicate that described value and the range functionally equivalent around the value.For example, disclosed dimension " 40mm " is intended to indicate that " about 40mm ".

Unless expressly excluded or in other words it is limited, each document cited herein, including any intersection is drawn With or related patents or patent application, be incorporated by reference and be incorporated herein accordingly.The reference of any file is not to it Relative to any invention disclosed in this invention or claimed this paper or its individually, or with it is any other Referring to or bibliography, introduction, suggestion or disclosed any such invention any combination of prior art approval.In addition, If any meaning of term or definition and any times for being herein incorporated by reference in the literature same term in this document What meaning or definition mutually conflict, and will be subject to the meaning or definition that term is assigned in this document.

It is aobvious and easy for those skilled in the art although the particular embodiment of the present invention has been illustrated and described See, many other variations and variations can be made without departing from the spirit and scope of the present invention.Therefore, appended All these changes and the modification belonged in the scope of the invention is intended to include in claim.

Claims (1)

1. a kind of for delivering the composition to the application device component of scalp, comprising:
A. for accommodating the container of the composition, the container has the longitudinal axis for extending through it;
B. the extension top actuator being in fluid communication with the container, extension top actuator include:
I. it is configured to for the extension top actuator to be fluidly connected to the base part of the container;With
Ii. single main part, the single main part includes top surface and hollow needle, so that the top surface and institute Hollow needle is stated with single movement;
Wherein the main part is configured to the base part being fluidly connected to hollow needle;
Wherein the main part and the tip form single structure;And wherein the base part is surrounded and is received described A part of main part;
The single structure is mobile relative to the base part at the time of activation;
Wherein the main part moves into the base part at the time of activation;
Wherein the top surface includes the cavity opposite with the extension of the hollow needle, and the tip is relative to the longitudinal axis Line forms 25 ° to 75 ° of angle, and the top surface and the longitudinal axis are formed by angle than the tip and the longitudinal axis It is steeper that line is formed by angle;And
Wherein the tip includes positioned at the face in the main part distal side, wherein the tip includes connecting with the container fluid Logical hole.
CN201811061526.5A 2012-04-27 2013-04-26 For applying the application device component of composition CN109090809A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US201261639446P true 2012-04-27 2012-04-27
US61/639,446 2012-04-27
CN 201380022237 CN104254262A (en) 2012-04-27 2013-04-26 Applicator assembly for applying a composition

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN 201380022237 Division CN104254262A (en) 2012-04-27 2013-04-26 Applicator assembly for applying a composition

Publications (1)

Publication Number Publication Date
CN109090809A true CN109090809A (en) 2018-12-28

Family

ID=48237297

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201811061526.5A CN109090809A (en) 2012-04-27 2013-04-26 For applying the application device component of composition
CN 201380022237 CN104254262A (en) 2012-04-27 2013-04-26 Applicator assembly for applying a composition

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN 201380022237 CN104254262A (en) 2012-04-27 2013-04-26 Applicator assembly for applying a composition

Country Status (7)

Country Link
US (1) US20130284195A1 (en)
EP (1) EP2840928A1 (en)
JP (2) JP2015515495A (en)
CN (2) CN109090809A (en)
CA (1) CA2870208A1 (en)
MX (1) MX2014011551A (en)
WO (1) WO2013163491A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105228583A (en) 2013-05-16 2016-01-06 宝洁公司 Hair thickening compositions and methods of use
EP2996775A1 (en) 2013-05-16 2016-03-23 The Procter and Gamble Company Hair thickening compositions and methods of use
US9402792B2 (en) 2013-05-16 2016-08-02 The Procter & Gamble Company Hair thickening compositions and methods of use
US9610233B2 (en) 2013-05-16 2017-04-04 The Proctor & Gamble Company Hair thickening compositions and methods of use
US9456969B2 (en) 2013-09-05 2016-10-04 The Procter & Gamble Company Scalp care composition
USD747973S1 (en) 2014-03-28 2016-01-26 The Procter & Gamble Company Foam dispenser
JP2017511347A (en) 2014-04-24 2017-04-20 ザ プロクター アンド ギャンブル カンパニー Scalp care composition
JP2018511638A (en) * 2015-04-23 2018-04-26 ザ プロクター アンド ギャンブル カンパニー Delivery of surfactant soluble anti-dandruff agents
USD811894S1 (en) * 2017-02-10 2018-03-06 The Procter & Gamble Company Container with a pump dispenser
USD849230S1 (en) * 2017-07-17 2019-05-21 Yoanna Gouchtchina Dermal treatment atomizer

Family Cites Families (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US34584A (en) 1862-03-04 Improvement in rakes for harvesters
US2826551A (en) 1954-01-04 1958-03-11 Simoniz Co Nontangling shampoo
US2809971A (en) 1955-11-22 1957-10-15 Olin Mathieson Heavy-metal derivatives of 1-hydroxy-2-pyridinethiones and method of preparing same
GB849433A (en) 1957-08-22 1960-09-28 Raymond Woolston Hair washing preparations
US3236733A (en) 1963-09-05 1966-02-22 Vanderbilt Co R T Method of combatting dandruff with pyridinethiones metal salts detergent compositions
US3761418A (en) 1967-09-27 1973-09-25 Procter & Gamble Detergent compositions containing particle deposition enhancing agents
US3753196A (en) 1971-10-05 1973-08-14 Kulite Semiconductor Products Transducers employing integral protective coatings and supports
US3964500A (en) 1973-12-26 1976-06-22 Lever Brothers Company Lusterizing shampoo containing a polysiloxane and a hair-bodying agent
US4273144A (en) * 1975-07-02 1981-06-16 Shila Morganroth Hair parting and liquid spreading device
US4152416A (en) 1976-09-17 1979-05-01 Marra Dorothea C Aerosol antiperspirant compositions delivering astringent salt with low mistiness and dustiness
US4379753A (en) 1980-02-07 1983-04-12 The Procter & Gamble Company Hair care compositions
US4345080A (en) 1980-02-07 1982-08-17 The Procter & Gamble Company Pyridinethione salts and hair care compositions
US4323683A (en) 1980-02-07 1982-04-06 The Procter & Gamble Company Process for making pyridinethione salts
US4470982A (en) 1980-12-22 1984-09-11 The Procter & Gamble Company Shampoo compositions
US4364837A (en) 1981-09-08 1982-12-21 Lever Brothers Company Shampoo compositions comprising saccharides
US4671306A (en) * 1982-10-25 1987-06-09 Donald Spector Nail-polish-removing thimble
JPH0457642B2 (en) * 1984-09-10 1992-09-14 Oosaka Eyazooru Kogyo Kk
JPS61174945U (en) * 1985-04-18 1986-10-31
DE69027051D1 (en) * 1989-07-25 1996-06-20 Oreal Delivery device for at least one liquid product
US5104646A (en) 1989-08-07 1992-04-14 The Procter & Gamble Company Vehicle systems for use in cosmetic compositions
US5227503A (en) * 1990-02-13 1993-07-13 Chesebrough Pond's Usa Co., Division Of Conopco, Inc. Cosmetic composition
US5106609A (en) 1990-05-01 1992-04-21 The Procter & Gamble Company Vehicle systems for use in cosmetic compositions
JPH0626572B2 (en) * 1990-11-30 1994-04-13 大阪エヤゾール工業株式会社 Aerosol container
US5168833A (en) * 1992-02-14 1992-12-08 Spears James W Dog grooming kit apparatus
US7278590B1 (en) * 1992-02-24 2007-10-09 Homax Products, Inc. Systems and methods for applying texture material to ceiling surfaces
US5555899A (en) * 1994-10-31 1996-09-17 Foreman; Karen A. Hair liquid applicator
US5939082A (en) 1995-11-06 1999-08-17 The Procter & Gamble Company Methods of regulating skin appearance with vitamin B3 compound
US5772077A (en) * 1996-05-07 1998-06-30 Tafur; Jose J. Hair styling implement and valve actuator attachment for aerosol and pump dispensers
JP3722574B2 (en) * 1996-12-19 2005-11-30 大正製薬株式会社 Jetting structure of the aerosol container
US5848598A (en) * 1998-06-22 1998-12-15 Walz; David K. Hair treatment dispensing container
JP2000334046A (en) * 1999-03-23 2000-12-05 Yoko Watabe Device for applying liquid medicine to skin portion having hair
US6649155B1 (en) 1999-05-03 2003-11-18 The Procter & Gamble Company Anti-dandruff and conditioning shampoos containing certain cationic polymers
US6283946B1 (en) * 1999-12-06 2001-09-04 Ultradent Products, Inc. Long stem syringe apparatus for dispensing compositions and related methods
FR2805442B1 (en) * 2000-02-25 2003-02-14 Oreal Device for packaging and applying a hair composition
JP5044069B2 (en) * 2000-09-26 2012-10-10 株式会社東芝 Medical diagnostic imaging apparatus
US6526987B1 (en) * 2001-11-02 2003-03-04 Sun R. Gioia Self-applicator for hair coloring
JP2003226375A (en) * 2002-01-31 2003-08-12 Yoshino Kogyosho Co Ltd Applying container with comb
FR2836902B1 (en) * 2002-03-05 2004-05-28 Oreal Dispensing head has movable cannula intended to equip a packaging and dispensing device
US20080206355A1 (en) 2002-06-04 2008-08-28 The Procter & Gamble Company Composition comprising a particulate zinc material, a pyrithione or a polyvalent metal salt of a pyrithione and a synthetic cationic polymer
DE10226468B4 (en) * 2002-06-14 2004-11-04 Kpss-Kao Professional Salon Services Gmbh container
AU2003259389A1 (en) * 2002-07-24 2004-02-09 Koninklijke Philips Electronics N.V. Hair coloring device with detachably connected base part
CH695412A5 (en) * 2004-10-19 2006-05-15 Labo Cosprophar Ag Method and kit particularly for applying a cosmetic product.
US20060099167A1 (en) 2004-11-05 2006-05-11 Staudigel James A Personal care composition containing a non-guar galactomannan polymer derivative
DE102004061468A1 (en) * 2004-12-17 2006-06-22 Henkel Kgaa Dispensing system e.g. for color-modifying agents, has two containers each having spatially isolated outlets and contains different hair dye-modifying agents with multi-colored streaks applied in one step with dispensing system
US7661562B2 (en) * 2005-10-11 2010-02-16 Kimberly-Clark Worldwide, Inc. Micro powered dispensing device
US8349300B2 (en) 2007-04-19 2013-01-08 The Procter & Gamble Company Personal care compositions containing at least two cationic polymers and an anionic surfactant
CN102088950A (en) * 2008-04-30 2011-06-08 宝洁公司 Hair care compositions for preventing oxidative damage to hair, methods of use, and methods of marketing such compositions
CN103394142B (en) * 2008-05-08 2015-08-19 迷你泵有限责任公司 The implantable drug delivery device apparatus and method for filling the apparatus with the
JP5872752B2 (en) * 2009-02-19 2016-03-01 株式会社ツツミプランニング Hair tonic with sebum cured dissolvability
EP2407144A1 (en) * 2010-07-13 2012-01-18 The Procter and Gamble Company Aerosol hairspray product for styling and/or shaping hair
US20120097180A1 (en) * 2010-10-21 2012-04-26 Henkel Consumer Goods Inc. Actuator for dispensing aerosol hair care products closer to the scalp
US20120152270A1 (en) * 2010-12-17 2012-06-21 Rita Hazan Method & apparatus for applying hair root concealer
CA2848525A1 (en) * 2011-10-21 2013-04-25 Leo Pharma A/S Dispensing systems
JP2015517852A (en) * 2012-04-27 2015-06-25 ザ プロクター アンド ギャンブルカンパニー Applicator assembly for applying a composition

Also Published As

Publication number Publication date
CA2870208A1 (en) 2013-10-31
EP2840928A1 (en) 2015-03-04
CN104254262A (en) 2014-12-31
MX2014011551A (en) 2014-11-14
US20130284195A1 (en) 2013-10-31
JP2015515495A (en) 2015-05-28
WO2013163491A1 (en) 2013-10-31
JP2017225838A (en) 2017-12-28

Similar Documents

Publication Publication Date Title
CA2519433C (en) Augmentation of pyrithione activity or a polyvalent metal salt of pyrithione activity by zinc-containing layered material
AU2003273285B2 (en) Shampoo containing a gel network
US8491877B2 (en) Composition comprising zinc-containing layered material with a high relative zinc lability
JP3043816B2 (en) Hair treatment composition
CA2487124C (en) Composition containing a cationic polymer with a high charge density and a conditioning agent
CN1646124B (en) Use of materials having zinc ionophoric behavior
CA2484974C (en) Conditioning shampoo containing aminosilicone
EP2694016B1 (en) Shampoo compositions with increased deposition of polyacrylate microcapsules
EP1924238B1 (en) Shampoo containing a gel network
JP4175488B2 (en) Personal care compositions containing cleansing phase and benefit phase
US20080152611A1 (en) Shampoo Containing a Gel Network
CA2704046C (en) Personal care compositions comprising undecyl sulfates
EP2355775B1 (en) Personal care composition in the form of an article having a hydrophobic surface-resident coating
US20060078527A1 (en) Multi phase personal care composition comprising a conditioning phase and a water continuous benefit phase
US7531497B2 (en) Personal care composition containing a cleansing phase and a benefit phase
US6451298B1 (en) Cosmetic compositions comprising at least one silicone copolymer and at least one cationic polymer, and uses thereof
AU2002301098B2 (en) Cosmetic compositions containing a methacrylic acid copolymer, a silicone and a cationic polymer, and uses thereof
US20080020004A1 (en) Hair-Treatment Agent Comprising Terpolymer Of Vinylpyrrolidone, Methacrylamide And Vinylimidazole And Active Ingredients And Additives
US20010031270A1 (en) Cosmetic compositions comprising an amphoteric starch and a cationic conditioner, and uses thereof
US20060078524A1 (en) Multi phase personal care composition comprising a conditioning phase and an oil continuous benefit phase
AU2002223756B2 (en) Composition for treating keratinous materials comprising a cationic associative polyurethane polymer and a protecting or conditioning agent
EP1171080A2 (en) Mousse forming hair treatment composition
US8936796B2 (en) Hair care compositions comprising sucrose polyesters
JP2002543105A (en) Polyalkylene glycols and cationic polymer-containing anti-dandruff and conditioning shampoos
KR20050057244A (en) Compositions of anionic polymeric rheology modifiers and cationic materials

Legal Events

Date Code Title Description
PB01 Publication
SE01 Entry into force of request for substantive examination