CN109054329B - 一种阻燃3d打印复合材料及其制备方法 - Google Patents
一种阻燃3d打印复合材料及其制备方法 Download PDFInfo
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- CN109054329B CN109054329B CN201810610827.2A CN201810610827A CN109054329B CN 109054329 B CN109054329 B CN 109054329B CN 201810610827 A CN201810610827 A CN 201810610827A CN 109054329 B CN109054329 B CN 109054329B
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- parts
- flame
- retardant
- composite material
- printing composite
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- 238000010146 3D printing Methods 0.000 title claims abstract description 37
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 239000003063 flame retardant Substances 0.000 title claims abstract description 33
- 239000002131 composite material Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- -1 polybutylene carbonate Polymers 0.000 claims abstract description 25
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 claims abstract description 25
- 229940116357 potassium thiocyanate Drugs 0.000 claims abstract description 25
- PBLNBZIONSLZBU-UHFFFAOYSA-N 1-bromododecane Chemical compound CCCCCCCCCCCCBr PBLNBZIONSLZBU-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000005977 Ethylene Substances 0.000 claims abstract description 23
- WTBIAPVQQBCLFP-UHFFFAOYSA-N N.N.N.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O Chemical compound N.N.N.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O WTBIAPVQQBCLFP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000003365 glass fiber Substances 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 238000012545 processing Methods 0.000 claims abstract description 11
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 30
- 238000001035 drying Methods 0.000 claims description 30
- 238000002156 mixing Methods 0.000 claims description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- 239000011259 mixed solution Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 18
- 238000007664 blowing Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 238000007873 sieving Methods 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 abstract description 9
- 230000017525 heat dissipation Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 238000013473 artificial intelligence Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010041 electrostatic spinning Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
- C08K5/3725—Sulfides, e.g. R-(S)x-R' containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
Description
项目 | 导热系数W/m·K | 拉伸强度MPa | 弹性模量MPa | 冲击强度KJ/m<sup>2</sup> | 氧指数 |
实施例1 | 2.15 | 91 | 1325 | 18.31 | 37 |
实施例2 | 2.24 | 95 | 1412 | 18.54 | 35 |
实施例3 | 2.51 | 105 | 1763 | 19.26 | 38 |
实施例4 | 2.47 | 101 | 1585 | 18.95 | 34 |
实施例5 | 2.35 | 93 | 1356 | 19.16 | 36 |
对比例1 | 1.15 | 65 | 1121 | 16.15 | 31 |
对比例2 | 1.20 | 68 | 1247 | 14.31 | 30 |
对比例3 | 1.02 | 57 | 1102 | 13.12 | 29 |
对比例4 | 1.25 | 65 | 1254 | 16.56 | 31 |
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810610827.2A CN109054329B (zh) | 2018-06-14 | 2018-06-14 | 一种阻燃3d打印复合材料及其制备方法 |
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CN201810610827.2A CN109054329B (zh) | 2018-06-14 | 2018-06-14 | 一种阻燃3d打印复合材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN109054329A CN109054329A (zh) | 2018-12-21 |
CN109054329B true CN109054329B (zh) | 2020-10-23 |
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CN (1) | CN109054329B (zh) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105176043A (zh) * | 2015-10-19 | 2015-12-23 | 福建师范大学 | 一种用于3d打印的pbc材料及其制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101768319B1 (ko) * | 2015-09-11 | 2017-08-16 | 롯데케미칼 주식회사 | 생분해성 수지 조성물 및 그 제조방법 |
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2018
- 2018-06-14 CN CN201810610827.2A patent/CN109054329B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105176043A (zh) * | 2015-10-19 | 2015-12-23 | 福建师范大学 | 一种用于3d打印的pbc材料及其制备方法 |
Also Published As
Publication number | Publication date |
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CN109054329A (zh) | 2018-12-21 |
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Effective date of registration: 20200924 Address after: 242000 Guangming industrial concentration zone, Shuiyang Town, Xuanzhou District, Xuancheng City, Anhui Province Applicant after: Anhui concrete construction new material technology Co.,Ltd. Address before: 450000 University Science Park Incubation Park of Zhengzhou High-tech Zone, Henan Province Applicant before: Chen Benhai |
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Denomination of invention: A flame-retardant 3D printing composite material and its preparation method Effective date of registration: 20231205 Granted publication date: 20201023 Pledgee: Xuancheng Zhenxuan Financing Guarantee Group Co.,Ltd. Pledgor: Anhui concrete construction new material technology Co.,Ltd. Registration number: Y2023980069374 |
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