CN109004069A - A kind of production method of metal substrate LED chip - Google Patents

A kind of production method of metal substrate LED chip Download PDF

Info

Publication number
CN109004069A
CN109004069A CN201710473735.XA CN201710473735A CN109004069A CN 109004069 A CN109004069 A CN 109004069A CN 201710473735 A CN201710473735 A CN 201710473735A CN 109004069 A CN109004069 A CN 109004069A
Authority
CN
China
Prior art keywords
metal substrate
led chip
semiconductor layer
production method
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710473735.XA
Other languages
Chinese (zh)
Other versions
CN109004069B (en
Inventor
曾国涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Nationstar Semiconductor Co Ltd
Original Assignee
Foshan Nationstar Semiconductor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Nationstar Semiconductor Co Ltd filed Critical Foshan Nationstar Semiconductor Co Ltd
Priority to CN201710473735.XA priority Critical patent/CN109004069B/en
Publication of CN109004069A publication Critical patent/CN109004069A/en
Application granted granted Critical
Publication of CN109004069B publication Critical patent/CN109004069B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0095Post-treatment of devices, e.g. annealing, recrystallisation or short-circuit elimination
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Led Device Packages (AREA)
  • Led Devices (AREA)
  • Weting (AREA)

Abstract

The invention discloses a kind of production methods of metal substrate LED chip to form single LED chip using metal erosion corrosion metal substrate, compared with traditional laser cutting method, production method of the present invention is simple, and operation is easy, the expense for saving purchase laser cutting machine, reduces cost;In addition, cutting metal substrate using laser cutting method, thermal shock is generated to metal substrate, the occurrence of metal substrate is easy to appear sliver and bending, reduces the yield of LED chip, and production method of the invention avoids this, to improve LED chip yield.

Description

A kind of production method of metal substrate LED chip
Technical field
The present invention relates to a kind of LED technology field more particularly to a kind of production methods of metal substrate LED chip.
Background technique
LED(Light Emitting Diode, light emitting diode) be it is a kind of using Carrier recombination when release energy to form hair The semiconductor devices of light, LED chip have that power consumption is low, coloration is pure, the service life is long, small in size, response time fast, energy conservation and environmental protection etc. is all More advantages.
In recent years, as that studies LED chip deepens continuously, technical staff is using different materials to Sapphire Substrate Transfer replacement is carried out, thus improves the heat dissipation performance of light emitting diode.It is existing since metal substrate has good heating conduction There is technology generally to carry out substrate transfer using metal substrates such as gold, silver, copper, nickel, but metal self character has ductility, It is cut in metal substrate LED chip, when forming single LED chip, is easy to appear sliver and bending, reduces product yield, Therefore the mass production of metal substrate LED chip is restricted.
Summary of the invention
Technical problem to be solved by the present invention lies in, a kind of production method of metal substrate LED chip is provided, convenient for operating, Yield is high, at low cost, can be mass-produced.
In order to solve the above-mentioned technical problems, the present invention provides a kind of production methods of metal substrate LED chip, comprising:
One metal substrate is provided;
Multiple light emitting structures are formed in the metal substrate surface, the light emitting structure includes being set to the metal substrate surface First semiconductor layer, set on the active layer and first electrode of first semiconductor layer surface, set on the active layer surface Second semiconductor layer, set on the second electrode of second semiconductor layer surface, the first electrode and the second electrode it Between mutually insulated;
In light emitting structure surface coating photoresist, and the photoresist of separating part between the light emitting structure is removed, obtains LED Wafer;
The LED wafer is fixed on mucous membrane, the mucous membrane is fixed on tiltable mobile platform;
The LED wafer side being fixed in the mobile platform, two groups of spray heads being set, two groups of spray heads include first spray head And second spray head, there is pre-determined distance between two groups of spray heads and the LED wafer;
The first spray head sprays the LED wafer ultrapure to the LED wafer metal injection corrosive liquid, the second spray head Water obtains single LED chip;
The first spray head removes glue to LED chip injection, and the second spray head sprays ultrapure water to the LED chip, Remove the photoresist;
The mucous membrane and the LED chip are dried, and the LED chip is sorted.
Preferably, the forming process of the light emitting structure are as follows:
First semiconductor layer is formed in the metal substrate arbitrary surfaces;
The active layer is formed in first semiconductor layer surface;
Second semiconductor layer is formed in the active layer surface;
It is using etching technics that the predeterminable area of first semiconductor layer surface is exposed;
The first electrode is formed in the predeterminable area of first semiconductor layer surface, and in second semiconductor layer surface Form the second electrode, mutually insulated between the first electrode and the second electrode.
Preferably, it is 20-80 degree that the mobile platform, which tilts down angle,.
Preferably, it is vertically arranged between two groups of spray heads and the mobile platform.
Preferably, the injection direction met and discussed is adjustable.
Preferably, the distance between described two groups of spray heads, the distance between the spray head and the mobile platform can be adjusted Section.
Preferably, the material of the metal substrate is one of gold, silver, copper, nickel, molybdenum, tungsten or above several metals.
Preferably, first semiconductor layer and the second semiconductor layer are gallium nitride-based semiconductor, the active layer For gallium nitride base active layer.
Preferably, the metal erosion liquid be potassium iodide, iron chloride, ammonium hydroxide, hydrogen peroxide, cerium ammonium nitrate, nitric acid, hydrochloric acid, One of sulfuric acid or the above several solns.
It is preferably, described that remove glue be one of acetone, isopropanol, alcohol, n-methyl-2-pyrrolidone or above several Kind solution.
The invention has the following beneficial effects:
1, the production method of a kind of metal substrate LED chip provided by the invention, uses metal erosion corrosion metal substrate, shape At single LED chip, compared with traditional laser cutting method, production method of the present invention is simple, and operation is easy, and saves purchase and swashs The expense of light cutting machine, reduces cost;In addition, cutting metal substrate using laser cutting method, heat punching is generated to metal substrate It hits, metal substrate is easy to appear sliver and bending, reduces the yield of LED chip, and production method of the invention avoids this situation Generation, to improve LED chip yield.
2, the production method of a kind of metal substrate LED chip provided by the invention, it is less to be related to equipment, wherein segmentation gold The equipment cost for belonging to substrate is low, and mobile platform and spray head are easily operated, and modulability is strong.
3, the production method of a kind of metal substrate LED chip provided by the invention, can only with traditional laser cutting method Cutting forms rectangular LED chip, and the present invention uses metal erosion corrosion metal substrate, by the photoetching for designing different graphic Glue can form LED chip of different shapes.
4, the production method of a kind of metal substrate LED chip provided by the invention, the recyclable recycling of the liquid of injection, Not only environmentally friendly, but also save cost.
Detailed description of the invention
Fig. 1 is a kind of flow chart of the production method of metal substrate LED chip of the embodiment of the present invention;
Fig. 2 a is that the metal substrate LED chip of the embodiment of the present invention forms the structural schematic diagram of multiple light emitting structures;
Fig. 2 b is that the metal substrate LED chip of the embodiment of the present invention forms the structural schematic diagram of LED wafer;
Fig. 2 c is that the LED wafer of the embodiment of the present invention is fixed on mucous membrane and the fixed structural representation on a mobile platform of mucous membrane Figure;
Fig. 2 d is the structural schematic diagram of two groups of spray heads of the embodiment of the present invention;
Fig. 2 e is that the metal substrate LED chip of the embodiment of the present invention forms the structural schematic diagram of single LED chip;
Fig. 2 f is the structural schematic diagram that the photoresist of the embodiment of the present invention removes;
Fig. 2 g is the structural schematic diagram of the LED chip of the embodiment of the present invention;
Fig. 3 is a kind of flow chart of the production method of light emitting structure provided by the embodiments of the present application.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, the present invention is made further below in conjunction with attached drawing Detailed description.
A kind of production method of metal substrate LED chip provided by the invention, flow chart is as shown in Figure 1, include following Step:
S1, a metal substrate is provided.
Metal substrate provided by the embodiments of the present application is one of gold, silver, copper, nickel, molybdenum, tungsten or above several metals; In addition to above-mentioned metal substrate, metal substrate can also be other metals in the application other embodiments, not do to this application Concrete restriction.
S2, multiple light emitting structures are formed in the metal substrate surface.
As shown in Figure 2 a, multiple light emitting structures 20 are formed on 10 surface of metal substrate, the light emitting structure 20 includes The first semiconductor layer 21 set on 10 surface of metal substrate, 22 He of active layer set on 21 surface of the first semiconductor layer First electrode 211, the second semiconductor layer 23 set on 22 surface of active layer, set on 23 surface of the second semiconductor layer Second electrode 212, mutually insulated between the first electrode 211 and the second electrode 212.
Specifically, as shown in figure 3, be a kind of flow chart of the production method of light emitting structure provided by the embodiments of the present application, Wherein, the forming process of light emitting structure are as follows:
S21, the first semiconductor layer is formed on any one surface of metal substrate.
S22, active layer is formed in the first semiconductor layer surface.
S23, the second semiconductor layer is formed in active layer back surface.
Specifically, the first semiconductor layer provided by the embodiments of the present application and the second semiconductor layer are gallium nitride-based semiconductor Layer, active layer are gallium nitride base active layer;In addition, the first semiconductor layer provided by the embodiments of the present application, the second semiconductor layer and The material of active layer can also be other materials, be not particularly limited to this application.
Wherein, the first semiconductor layer can be n type semiconductor layer, then the second semiconductor layer is p type semiconductor layer;Alternatively, First semiconductor layer is p type semiconductor layer, and the second semiconductor layer is n type semiconductor layer, for the first semiconductor layer and second The conduction type of semiconductor layer needs to be designed according to practical application, is not particularly limited to this application.
It is S24, using etching technics that the predeterminable area of the first semiconductor layer surface is exposed.
Predeterminable area is the region for forming first electrode, wherein and the area of first electrode is less than the area of predeterminable area, The laminations such as first electrode and active layer, the second semiconductor layer are avoided to contact.Etching technics provided by the embodiments of the present application can be Dry etch process, or wet-etching technology is not particularly limited this application, needs to be carried out according to practical application It chooses.
S25, the predeterminable area formation first electrode in the first semiconductor layer surface, and formed in the second semiconductor layer surface Second electrode, mutually insulated between first electrode and second electrode.
S3, in light emitting structure surface coating photoresist, and remove the photoresist of separating part between the light emitting structure, Obtain LED wafer.
As shown in Figure 2 b, the light emitting structure 20 is placed on rotary coating machine, it is equal on the light emitting structure surface One layer photoresist 30 of even coating, using ultraviolet lithography machine to the photoresist 30 carry out photoetching, remove the light emitting structure it Between separating part 31 photoresist, default separating part 31 is exposed, LED wafer is obtained.
Specifically, design needs of the photoresist according to LED chip, form the photoresist of corresponding pattern, shape is being applied In the present embodiment, the pattern of photoresist is not particularly limited.
Specifically, the photoresist protects the light emitting structure, below the step of in, prevent metal erosion liquid to shining Structure is corroded, and the photoelectric properties of light emitting structure are influenced.
It should be noted that the embodiment of the present application does not do specifically the arrangement of the separating part between light emitting structure and shape Limitation, needs this to be designed according to the needs of practical application.
S4, the LED wafer is fixed on mucous membrane, the mucous membrane is fixed on tiltable mobile platform.
As shown in Figure 2 c, being fixed on the LED wafer on mucous membrane 40, the mucous membrane 40 are fixed on tiltable movement On platform 50.Specifically, the mucous membrane two sides all has viscosity, the light emitting structure and institute's mobile platform are formed into fixed company It connects.In addition, in the application other embodiments, the light emitting structure can also be formed with institute mobile platform using other modes It is fixedly connected, this application is not particularly limited.Wherein, the mobile platform carries out horizontal linear movement, passes through mobile institute Mobile platform is stated, the solution for ejecting spray head is injected in the place for needing to spray, and reduces injecting time, saves solution.This Outside, it is 20-80 degree that the mobile platform, which tilts down angle,.In the present embodiment, the mobile platform tilts down angle most Excellent is 45 degree, below the step of in, when liquid injection is on the light emitting structure, extra liquid along it is inclined move it is flat Platform flows to recyclable device, reusable using purification, not only environmentally friendly, but also saves cost.
S5, two groups of spray heads of the light emitting structure side setting are fixed in the mobile platform, two groups of spray heads include First spray head and second spray head have pre-determined distance between two groups of spray heads and the light emitting structure.
As shown in Figure 2 d, the LED wafer side being fixed in the mobile platform 50, two groups of spray heads 60 are set, described two Group spray head 60 includes first spray head 61 and second spray head 62.Specifically, described two groups are met and discussed and 60 are had with the mobile platform 50 A certain distance, the material of thickness and metal substrate with specific reference to light emitting structure position two groups of spray heads and mobile platform The distance between.Wherein, the injection direction of the spray head 60 is adjustable, when ejected between when extending, pass through and adjust spray head Injection direction avoids solution concentration from being injected on a certain position.Between the first spray head 61 and the second spray head 62 away from From adjustable, first spray head and institute are adjusted with specific reference to the distance between the size of the light emitting structure, the light emitting structure State the distance between second spray head, below the step of in, make solution fully with the metal substrate and the light emitting structure Contact.Specifically, be vertically arranged between two groups of spray heads and the mobile platform, below the step of in, keep solution abundant Ground is contacted with the metal substrate and the light emitting structure.In the other embodiments of the application, as needed, settable multiple groups Spray head, the sprayable a variety of solution of spray head.
S6, the first spray head are to the LED wafer metal injection corrosive liquid, and the second spray head is to the LED wafer Ultrapure water is sprayed, single LED chip is formed.
As shown in Figure 2 e, the first spray head 61 is to the LED wafer metal injection corrosive liquid, metal erosion liquid edge Separating part between light emitting structure 20 enter the metal substrate 10, the exposed gold in separating part of metal erosion corrosion Belong to substrate, the exposed metal substrate in separating part is corroded segmentation, forms list LED chip, and the second spray head 62 is right The LED wafer sprays ultrapure water, cleans the metal erosion liquid being attached on light emitting structure and avoids residue in step below Metal erosion liquid reacted with glue is removed, influence the removal of photoresist, thus avoid influence LED chip photoelectric properties.Specifically , the ultrapure water be resistivity reach 18M Ω * cm(25 DEG C) water, the metal erosion liquid include but is not limited to potassium iodide, One of iron chloride, ammonium hydroxide, hydrogen peroxide, cerium ammonium nitrate, nitric acid, hydrochloric acid, sulfuric acid or the above several solns.
S7, the first spray head remove glue to LED chip injection, and the second spray head sprays the LED chip Ultrapure water removes the photoresist.
As shown in figure 2f, the first spray head 61 removes glue to the LED chip 20 injection, removes on light emitting structure 20 Photoresist 30, then two spray head 62 to the LED chip 20 spray ultrapure water, cleaning be attached on light emitting structure 20 Glue is removed, the photoelectric properties for influencing LED chip are avoided.It is preferably, described that remove glue include but is not limited to acetone, isopropanol, wine One of essence, n-methyl-2-pyrrolidone or the above several solns.
S8, the mucous membrane and the LED chip are dried, and the LED chip is sorted.
As shown in Figure 2 g, the mucous membrane 40 and the LED chip are dried, the mucous membrane during drying, Viscosity is lost, is separated automatically with the LED chip, is sorted by sorting machine according to the photoelectric properties of LED chip.
The invention has the following beneficial effects:
1, the production method of a kind of metal substrate LED chip provided by the invention, uses metal erosion corrosion metal substrate, shape At single LED chip, compared with traditional laser cutting method, production method of the present invention is simple, and operation is easy, and saves purchase and swashs The expense of light cutting machine, reduces cost;In addition, cutting metal substrate using laser cutting method, heat punching is generated to metal substrate It hits, metal substrate is easy to appear sliver and bending, reduces the yield of LED chip, and production method of the invention avoids this situation Generation, to improve LED chip yield.
2, the production method of a kind of metal substrate LED chip provided by the invention, it is less to be related to equipment, wherein segmentation gold The equipment cost for belonging to substrate is low, and mobile platform and spray head are easily operated, and modulability is strong.
3, the production method of a kind of metal substrate LED chip provided by the invention, can only with traditional laser cutting method Cutting forms rectangular LED chip, and the present invention uses metal erosion corrosion metal substrate, by the photoetching for designing different graphic Glue can form LED chip of different shapes.
4, the production method of a kind of metal substrate LED chip provided by the invention, the recyclable recycling of the liquid of injection, Not only environmentally friendly, but also save cost.
Above disclosed is only a preferred embodiment of the present invention, cannot limit the power of the present invention with this certainly Sharp range, therefore equivalent changes made in accordance with the claims of the present invention, are still within the scope of the present invention.

Claims (10)

1. a kind of production method of metal substrate LED chip, comprising:
One metal substrate is provided;
Multiple light emitting structures are formed in the metal substrate surface, the light emitting structure includes being set to the metal substrate surface First semiconductor layer, set on the active layer and first electrode of first semiconductor layer surface, set on the active layer surface Second semiconductor layer, set on the second electrode of second semiconductor layer surface, the first electrode and the second electrode it Between mutually insulated;
In light emitting structure surface coating photoresist, and the photoresist of separating part between the light emitting structure is removed, obtains LED Wafer;
The LED wafer is fixed on mucous membrane, the mucous membrane is fixed on tiltable mobile platform;
The LED wafer side being fixed in the mobile platform, two groups of spray heads being set, two groups of spray heads include first spray head And second spray head, there is pre-determined distance between two groups of spray heads and the LED wafer;
The first spray head sprays the LED wafer ultrapure to the LED wafer metal injection corrosive liquid, the second spray head Water obtains single LED chip;
The first spray head removes glue to LED chip injection, and the second spray head sprays ultrapure water to the LED chip, Remove the photoresist;
The mucous membrane and the LED chip are dried, and the LED chip is sorted.
2. the production method of metal substrate LED chip according to claim 1, which is characterized in that the light emitting structure Forming process are as follows:
First semiconductor layer is formed in the metal substrate arbitrary surfaces;
The active layer is formed in first semiconductor layer surface;
Second semiconductor layer is formed in the active layer surface;
It is using etching technics that the predeterminable area of first semiconductor layer surface is exposed;
The first electrode is formed in the predeterminable area of first semiconductor layer surface, and in second semiconductor layer surface Form the second electrode, mutually insulated between the first electrode and the second electrode.
3. the production method of metal substrate LED chip according to claim 1, which is characterized in that the mobile platform to Lower tilt angle is 20-80 degree.
4. the production method of metal substrate LED chip according to claim 1, which is characterized in that two groups of spray heads with It is vertically arranged between the mobile platform.
5. the production method of metal substrate LED chip according to claim 1, which is characterized in that the injection met and discussed Direction is adjustable.
6. the production method of metal substrate LED chip according to claim 1, which is characterized in that two groups of spray heads it Between distance it is adjustable, the distance between the spray head and the mobile platform are adjustable.
7. the production method of metal substrate LED chip according to claim 1, which is characterized in that the metal substrate Material is one of gold, silver, copper, nickel, molybdenum, tungsten or above several metals.
8. the production method of metal substrate LED chip according to claim 1, which is characterized in that first semiconductor Layer and second semiconductor layer are gallium nitride-based semiconductor, and the active layer is gallium nitride base active layer.
9. the production method of metal substrate LED chip according to claim 1, which is characterized in that the metal erosion liquid For one of potassium iodide, iron chloride, ammonium hydroxide, hydrogen peroxide, cerium ammonium nitrate, nitric acid, hydrochloric acid, sulfuric acid or the above several solns.
10. the production method of metal substrate LED chip according to claim 1, which is characterized in that it is described go glue be third One of ketone, isopropanol, alcohol, n-methyl-2-pyrrolidone or the above several solns.
CN201710473735.XA 2017-06-21 2017-06-21 Manufacturing method of metal substrate LED chip Active CN109004069B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710473735.XA CN109004069B (en) 2017-06-21 2017-06-21 Manufacturing method of metal substrate LED chip

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710473735.XA CN109004069B (en) 2017-06-21 2017-06-21 Manufacturing method of metal substrate LED chip

Publications (2)

Publication Number Publication Date
CN109004069A true CN109004069A (en) 2018-12-14
CN109004069B CN109004069B (en) 2020-10-27

Family

ID=64574000

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710473735.XA Active CN109004069B (en) 2017-06-21 2017-06-21 Manufacturing method of metal substrate LED chip

Country Status (1)

Country Link
CN (1) CN109004069B (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101840965A (en) * 2009-05-08 2010-09-22 晶能光电(江西)有限公司 Method for cutting substrate of light emitting diode manufactured on metallic substrate
CN204230209U (en) * 2014-09-23 2015-03-25 安徽省大富光电科技有限公司 Etch, develop, clean and take off film device, spray treatment facility
CN104737285A (en) * 2012-09-28 2015-06-24 等离子瑟姆有限公司 Method for dicing a substrate with back metal
CN104752571A (en) * 2013-12-31 2015-07-01 晶能光电(江西)有限公司 Cutting method of wafer grade white-light LED chip
CN105140167A (en) * 2015-07-28 2015-12-09 合肥鑫晟光电科技有限公司 Carrying device, wet etching equipment and application method of wet etching equipment
CN205177793U (en) * 2015-10-09 2016-04-20 上海天马有机发光显示技术有限公司 Etching board

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101840965A (en) * 2009-05-08 2010-09-22 晶能光电(江西)有限公司 Method for cutting substrate of light emitting diode manufactured on metallic substrate
CN104737285A (en) * 2012-09-28 2015-06-24 等离子瑟姆有限公司 Method for dicing a substrate with back metal
CN104752571A (en) * 2013-12-31 2015-07-01 晶能光电(江西)有限公司 Cutting method of wafer grade white-light LED chip
CN204230209U (en) * 2014-09-23 2015-03-25 安徽省大富光电科技有限公司 Etch, develop, clean and take off film device, spray treatment facility
CN105140167A (en) * 2015-07-28 2015-12-09 合肥鑫晟光电科技有限公司 Carrying device, wet etching equipment and application method of wet etching equipment
CN205177793U (en) * 2015-10-09 2016-04-20 上海天马有机发光显示技术有限公司 Etching board

Also Published As

Publication number Publication date
CN109004069B (en) 2020-10-27

Similar Documents

Publication Publication Date Title
CN101471534B (en) Method for making high brightness semiconductor conical laser/amplifier
CN101371338B (en) Method for fabricating and separating semiconductor devices
CN103311395B (en) A kind of laser lift-off film LED and preparation method thereof
JP2017510992A5 (en)
JP2003051614A5 (en)
CN105428230A (en) Etching method, method of manufacturing article and semiconductor device, and etching solution
JP2016506076A (en) Manufacturing method of adjacent region including LED wire and apparatus obtained by the manufacturing method
CN103774239B (en) A kind of monocrystal silicon silicon chip cleaning and texturing technique
CN105428474B (en) A kind of simple making method of efficient LED chip
CN102082199A (en) Groove notching and grid burying method for crystalline silicon solar cell
CN108190830A (en) A kind of production method of high-aspect-ratio diamond micro nano structure
CN102527676B (en) Cleaning process method for etching resistant mask slurry
CN110518074A (en) Alternate high current GaN Schottky diode of anode and cathode and preparation method thereof
CN101017772A (en) The cleaning method for removing the impure ion from the semiconductor pipe core assembly
CN101777605A (en) Crystalline silicon solar battery edge etching process
WO2017101535A1 (en) Wet corrosion method of group iii nitride
KR101399419B1 (en) method for forming front electrode of solar cell
CN109004069A (en) A kind of production method of metal substrate LED chip
CN104377301A (en) III-V group compound semiconductor Hall element and manufacturing method thereof
CN104659165A (en) Method for preparing GaN-based light emitting diode chip
CN109755367A (en) A kind of method of roughening of reversed polarity AlGaInP quaternary LED chip
CN102560496A (en) Etching method of seed layer
CN104613732A (en) Before-epitaxy polished section rapid drying method after cleaning
CN102437242B (en) Method for opening passivation layer on back surface of solar cell
TWI690089B (en) Sequential etching treatment for solar cell fabrication

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant