CN108970171A - A kind of extraction equipment and technique - Google Patents

A kind of extraction equipment and technique Download PDF

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Publication number
CN108970171A
CN108970171A CN201810887865.2A CN201810887865A CN108970171A CN 108970171 A CN108970171 A CN 108970171A CN 201810887865 A CN201810887865 A CN 201810887865A CN 108970171 A CN108970171 A CN 108970171A
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CN
China
Prior art keywords
spraying
layer
film
extracting
roller
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Granted
Application number
CN201810887865.2A
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Chinese (zh)
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CN108970171B (en
Inventor
徐锋
宋月阳
袁海朝
马文献
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Hebei Gellec New Energy Material Science and Technoloy Co Ltd
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Hebei Gellec New Energy Material Science and Technoloy Co Ltd
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Priority to CN201810887865.2A priority Critical patent/CN108970171B/en
Publication of CN108970171A publication Critical patent/CN108970171A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/02Solvent extraction of solids
    • B01D11/028Flow sheets
    • B01D11/0284Multistage extraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/02Solvent extraction of solids
    • B01D11/0292Treatment of the solvent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/38Separation; Purification; Stabilisation; Use of additives
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/403Manufacturing processes of separators, membranes or diaphragms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

The present invention provides a kind of extraction equipments, including spraying and extracting layer and the distillation layer being connected with the liquid outlet of the spraying and extracting layer;The spraying and extracting layer includes multiple upper live-rollers that top is arranged in, multiple lower driving rollers arranged at the bottom, the extractant spray port being arranged between upper live-roller and lower driving roller, liquid outlet arranged at the bottom and membrane inlet and film outlet that top is arranged in;The distillation layer includes heating device arranged at the bottom, and the exhaust outlet and leakage fluid dram arranged at the bottom at top is arranged in.The present invention carries out extraction processing to film to be processed using fountain extraction and instant evaporation, using spraying and extracting mode, can realize stable effect of extracting to avoid mutual pollution;High temperature distillation is carried out, can reduce extraction tank liquid storage amount, improves safety, while methylene chloride can be recycled, realization recycles, and reduces methylene chloride consumption.In addition, the application is designed using double-layer structure, it is convenient for process for producing/unit exception.

Description

A kind of extraction equipment and technique
Technical field
The invention belongs to abstraction technique field more particularly to a kind of extraction equipment and techniques.
Background technique
Lithium ion battery separator wet method preparation process utilizes Thermal inactive principle, and polyethylene and small molecule agent are mixed and added Heat forms the polyethylene sheet with micropore after extrusion after over-quenching, micron order film is made after stretching, then pass through extraction work Sequence replaces the small molecule agent in diaphragm, then so that extractant is reached boiling point and is gasified by high temperature, finally prepares lithium-ion electric Pond diaphragm.
In extraction process, common extractant is methylene chloride, methylene chloride density 1.33g/cm3, 39.8 DEG C of boiling point, Highly volatile.Extraction process used at present is immersion type extraction, i.e., extracts diaphragm immersion in methylene chloride.It is this There are distinct disadvantages for extraction process: 1, methylene chloride consumption is big, consumes 1.0~1.5 tons daily;2, liquid storage amount is big, safety guarantee It is weak;3, exception can not be handled in time, and if extract liquor is contaminated, bearing damage etc., maintenance delays the plenty of time.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of extraction equipment and technique, extraction equipment provided by the invention , it can be achieved that methylene chloride recycles when for extracting the small molecule agent in lithium ion battery separator, it can reduce consumption, subtracting Few liquid storage amount.
The present invention provides a kind of extraction equipments, are connected including spraying and extracting layer and with the liquid outlet of the spraying and extracting layer Logical distillation layer;
The spraying and extracting layer include multiple upper live-rollers that top is set, multiple lower driving rollers arranged at the bottom, Extractant spray port between upper live-roller and lower driving roller, liquid outlet arranged at the bottom are set and the thin of top is set Film entrance and film outlet;
The distillation layer includes heating device arranged at the bottom, be arranged in top exhaust outlet and row arranged at the bottom Liquid mouth.
In one embodiment, the spraying and extracting layer further includes the scraping fluid being arranged between upper live-roller and lower driving roller Roller, when film is run from the supreme live-roller of lower driving roller, liquid sweeping roller is located at film surface.
In one embodiment, the distillation layer further includes the overflow port that side is arranged in.
In one embodiment, further includes: the condensing unit being connected with the exhaust outlet of the distillation layer.
In one embodiment, the liquid outlet of the condensing unit is sprayed by the extractant of mixing arrangement and spraying and extracting layer Leaching mouth is connected.
In one embodiment, including sequentially connected multiple units, each unit include spraying and extracting layer and with it is described The distillation layer that the liquid outlet of spraying and extracting layer is connected;
The spraying and extracting layer include multiple upper live-rollers that top is set, multiple lower driving rollers arranged at the bottom, Extractant spray port between upper live-roller and lower driving roller, liquid outlet arranged at the bottom are set and the thin of top is set Film entrance and film outlet;
The distillation layer includes heating device arranged at the bottom, be arranged in top exhaust outlet and row arranged at the bottom Liquid mouth;
The membrane inlet of the latter unit is connected with the outlet of the film of previous element.
In one embodiment, the distillation layer is located at below spraying and extracting layer.
The present invention also provides a kind of extracting process, comprising the following steps:
Extraction equipment described in above-mentioned technical proposal is provided;
Film to be processed is successively exported by upper live-roller, lower driving roller to film by membrane inlet, while with white Oil and methylene chloride mixing are sprayed out by extractant spray port as extractant and are extracted to film to be processed;
In extraction process, the heating device of distillation layer is opened, the extraction of distillation layer will be flow to by spraying and extracting layer liquid outlet Agent heating, makes methylene chloride gasify, and be discharged by exhaust outlet.
In one embodiment, the heating temperature of the heating device is 60~80 DEG C.
Extraction equipment provided by the invention includes spraying and extracting layer and is connected with the liquid outlet of the spraying and extracting layer Distill layer;The spraying and extracting layer includes multiple upper live-rollers that top is arranged in, multiple lower driving rollers arranged at the bottom, sets Set extractant spray port, liquid outlet arranged at the bottom and the film that top is set between upper live-roller and lower driving roller Entrance and film outlet;The distillation layer includes heating device arranged at the bottom, and the exhaust outlet and setting that top is arranged in exist The leakage fluid dram of bottom.The present invention carries out extraction processing to film to be processed using fountain extraction and instant evaporation, using spray Extraction mode is drenched, can realize stable effect of extracting to avoid mutual pollution;High temperature distillation is carried out, can reduce extraction tank storage Liquid measure improves safety, while can recycle methylene chloride, and realization recycles, and reduces methylene chloride consumption.In addition, this Shen It please be designed using double-layer structure, be convenient for process for producing/unit exception.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of extraction equipment provided in an embodiment of the present invention.
Specific embodiment
The present invention provides a kind of extraction equipments, are connected including spraying and extracting layer and with the liquid outlet of the spraying and extracting layer Logical distillation layer;
The spraying and extracting layer include multiple upper live-rollers that top is set, multiple lower driving rollers arranged at the bottom, Extractant spray port between upper live-roller and lower driving roller, liquid outlet arranged at the bottom are set and the thin of top is set Film entrance and film outlet;
The distillation layer includes heating device arranged at the bottom, be arranged in top exhaust outlet and row arranged at the bottom Liquid mouth.
Referring to Fig. 1, Fig. 1 is the structural schematic diagram of extraction equipment provided in an embodiment of the present invention;Wherein, 1 is spraying and extracting Layer, 11 be membrane inlet, and 12 export for film, and 13 be upper live-roller, and 14 be lower driving roller, and 15 be extractant spray port, and 16 are Liquid outlet, 17 be liquid sweeping roller;2 be distillation layer, and 21 be heating device, and 22 be exhaust outlet, and 23 be leakage fluid dram, and 24 be overflow port.
Extraction equipment provided by the invention includes spraying and extracting layer 1, spraying and extracting layer 1 include be arranged in top it is multiple on Live-roller 13, multiple lower driving rollers 14 arranged at the bottom, the extractant being arranged between upper live-roller 13 and lower driving roller 14 Spray port 15, liquid outlet arranged at the bottom 16 and membrane inlet 11 and film outlet 12 that top is set.Film to be processed Entered by membrane inlet 11, successively by first upper live-roller, first lower driving roller, second upper live-roller, second Live-roller and when lower driving roller in lower driving roller ... process, the extractant between upper live-roller and lower driving roller sprays out Extraction processing is carried out in mouth spraying and extracting agent to film to be processed, then drops to the liquid outlet 16 of bottom.
In one embodiment, the spraying and extracting layer further includes the scraping fluid being arranged between upper live-roller and lower driving roller Roller 17, when film is run from the supreme live-roller of lower driving roller, liquid sweeping roller is located at film surface and wipes the extractant on surface off, drippage To the liquid outlet 16 of bottom.
Extraction equipment provided by the invention includes distillation layer 2, and distillation, 2 include heating device 21 arranged at the bottom, setting Exhaust outlet 22 and leakage fluid dram arranged at the bottom 23 at top.Extractant is dropped in distillation layer by liquid outlet 16, heating dress It sets and extractant is heated, methylene chloride therein is made to gasify and be discharged by exhaust outlet, white oil is then discharged by leakage fluid dram 23.
In one embodiment, the distillation layer further includes overflow port 24, and white oil is discharged by overflow port 24.
In one embodiment, the distillation layer further includes fluid infusion.
In one embodiment, further includes: the condensing unit being connected with the exhaust outlet of the distillation layer (does not show in figure Out), the methylene chloride condensing recovery for that will gasify.
In one embodiment, the liquid outlet of the condensing unit is sprayed by the extractant of mixing arrangement and spraying and extracting layer Leaching mouth is connected, and is re-used for extracting after the methylene chloride of recycling is mixed with white oil.
In one embodiment, the extraction equipment includes sequentially connected multiple units, and each unit includes spray extraction The distillation layer for taking layer and being connected with the liquid outlet of the spraying and extracting layer;
The spraying and extracting layer include multiple upper live-rollers that top is set, multiple lower driving rollers arranged at the bottom, Extractant spray port between upper live-roller and lower driving roller, liquid outlet arranged at the bottom are set and the thin of top is set Film entrance and film outlet;
The distillation layer includes heating device arranged at the bottom, be arranged in top exhaust outlet and row arranged at the bottom Liquid mouth;
The membrane inlet of the latter unit is connected with the outlet of the film of previous element.
When extraction equipment includes multiple units, control of the vapo(u)rizing temperature realization of each unit to technique can be controlled respectively System.
In one embodiment, the distillation layer is located at below spraying and extracting layer, and double-layer structure is convenient for process for producing/equipment It is abnormal.
Extraction equipment provided by the invention is used to extract the small molecule agent in wet process preparing lithium ion battery membrane, and principle is such as Under:
Film to be processed is entered by membrane inlet 11, successively by first upper live-roller, first lower driving roller, the Live-roller and when lower driving roller on two upper live-rollers, second lower driving roller ... process, positioned at upper live-roller and underdrive Extraction processing is carried out in extractant discharge outlet spraying and extracting agent to film to be processed between roller, then drops to going out for bottom Liquid mouth 16, wherein film to be processed is prepared in accordance with the following methods:
By polyethylene and small molecule agent Hybrid Heating, the polyethylene sheet with micropore is formed after extrusion after over-quenching, is drawn Micron order film made of after stretching;
Extractant drops to distillation layer 2 by liquid outlet 16, and opening heating device separates methylene chloride evaporation with white oil, from And realize the recycling and reusing of methylene chloride and white oil.
The present invention also provides a kind of extracting process, comprising the following steps:
Extraction equipment described in above-mentioned technical proposal is provided;
Film to be processed is successively exported by upper live-roller, lower driving roller to film by membrane inlet, while with white Oil and methylene chloride mixing are sprayed out by extractant spray port as extractant and are extracted to film to be processed;
In extraction process, the heating device of distillation layer is opened, the extraction of distillation layer will be flow to by spraying and extracting layer liquid outlet Agent heating, makes methylene chloride gasify, and be discharged by exhaust outlet.
In one embodiment, the heating temperature of the heating device is 60~80 DEG C.
When the extraction equipment includes multiple units, the vapo(u)rizing temperature of each unit can be different.
In distillation, residual dichloromethane level in white oil is set to be less than or equal to 3% by controlling vapo(u)rizing temperature;Entire technique is white Oil residual is less than or equal to 0.5%.
Extraction equipment provided by the invention includes spraying and extracting layer and is connected with the liquid outlet of the spraying and extracting layer Distill layer;The spraying and extracting layer includes multiple upper live-rollers that top is arranged in, multiple lower driving rollers arranged at the bottom, sets Set extractant spray port, liquid outlet arranged at the bottom and the film that top is set between upper live-roller and lower driving roller Entrance and film outlet;The distillation layer includes heating device arranged at the bottom, and the exhaust outlet and setting that top is arranged in exist The leakage fluid dram of bottom.The present invention carries out extraction processing to film to be processed using fountain extraction and instant evaporation, using spray Extraction mode is drenched, can realize stable effect of extracting to avoid mutual pollution;High temperature distillation is carried out, can reduce extraction tank storage Liquid measure improves safety, while can recycle methylene chloride, and realization recycles, and reduces methylene chloride consumption.In addition, this Shen It please be designed using double-layer structure, be convenient for process for producing/unit exception.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (9)

1. a kind of extraction equipment, which is characterized in that be connected including spraying and extracting layer and with the liquid outlet of the spraying and extracting layer Distillation layer;
The spraying and extracting layer includes multiple upper live-rollers that top is arranged in, multiple lower driving rollers arranged at the bottom, setting Extractant spray port, liquid outlet arranged at the bottom between upper live-roller and lower driving roller and the film that top is arranged in enter Mouth and film outlet;
The distillation layer includes heating device arranged at the bottom, be arranged in top exhaust outlet and drain arranged at the bottom Mouthful.
2. extraction equipment according to claim 1, which is characterized in that the spraying and extracting layer further includes being arranged in upper transmission Liquid sweeping roller between roller and lower driving roller, when film is run from the supreme live-roller of lower driving roller, liquid sweeping roller is located at film surface.
3. extraction equipment according to claim 1, which is characterized in that the distillation layer further includes the overflow that side is arranged in Mouthful.
4. extraction equipment according to claim 1, which is characterized in that further include: it is connected with the exhaust outlet of the distillation layer Logical condensing unit.
5. extraction equipment according to claim 4, which is characterized in that the liquid outlet of the condensing unit passes through mixing arrangement It is connected with the extractant spray port of spraying and extracting layer.
6. extraction equipment according to claim 4, which is characterized in that including sequentially connected multiple units, each unit Including spraying and extracting layer and the distillation layer being connected with the liquid outlet of the spraying and extracting layer;
The spraying and extracting layer includes multiple upper live-rollers that top is arranged in, multiple lower driving rollers arranged at the bottom, setting Extractant spray port, liquid outlet arranged at the bottom between upper live-roller and lower driving roller and the film that top is arranged in enter Mouth and film outlet;
The distillation layer includes heating device arranged at the bottom, be arranged in top exhaust outlet and drain arranged at the bottom Mouthful;
The membrane inlet of the latter unit is connected with the outlet of the film of previous element.
7. extraction equipment according to claim 1, which is characterized in that the distillation layer is located at below spraying and extracting layer.
8. a kind of extracting process, which comprises the following steps:
Extraction equipment described in claim 1 is provided;
Film to be processed is successively exported by upper live-roller, lower driving roller to film by membrane inlet, at the same with white oil and Methylene chloride mixing, which is sprayed out as extractant by extractant spray port, extracts film to be processed;
In extraction process, the heating device of distillation layer is opened, the extractant for flowing to distillation layer by spraying and extracting layer liquid outlet is added Heat makes methylene chloride gasify, and is discharged by exhaust outlet.
9. extracting process according to claim 8, which is characterized in that the heating temperature of the heating device is 60~80 ℃。
CN201810887865.2A 2018-08-07 2018-08-07 Extraction equipment and process Active CN108970171B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810887865.2A CN108970171B (en) 2018-08-07 2018-08-07 Extraction equipment and process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810887865.2A CN108970171B (en) 2018-08-07 2018-08-07 Extraction equipment and process

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CN108970171A true CN108970171A (en) 2018-12-11
CN108970171B CN108970171B (en) 2021-06-15

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111668425A (en) * 2020-04-26 2020-09-15 河北金力新能源科技股份有限公司 Meta-aramid diaphragm and preparation method thereof
CN115400448A (en) * 2022-08-30 2022-11-29 华东理工大学 Application of No. 5 industrial white oil as MTBE (methyl tert-butyl ether) extraction anti-coking agent and MTBE desulfurization method
CN115475408A (en) * 2022-08-31 2022-12-16 中材锂膜(宁乡)有限公司 Wet-process diaphragm extraction device and process

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105932199A (en) * 2016-05-26 2016-09-07 上海双奥能源技术有限公司 Self-sieve plate extraction device and technology in wet lithium-ion battery membrane production technology
CN107252572A (en) * 2017-07-24 2017-10-17 河北金力新能源科技股份有限公司 A kind of efficient low-consume water seal lithium ion cell film extraction process
WO2018098410A1 (en) * 2016-11-26 2018-05-31 George Stantchev Portable extraction device
CN208583007U (en) * 2018-08-01 2019-03-08 河北金力新能源科技股份有限公司 A kind of spray distillation extraction equipment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105932199A (en) * 2016-05-26 2016-09-07 上海双奥能源技术有限公司 Self-sieve plate extraction device and technology in wet lithium-ion battery membrane production technology
WO2018098410A1 (en) * 2016-11-26 2018-05-31 George Stantchev Portable extraction device
CN107252572A (en) * 2017-07-24 2017-10-17 河北金力新能源科技股份有限公司 A kind of efficient low-consume water seal lithium ion cell film extraction process
CN208583007U (en) * 2018-08-01 2019-03-08 河北金力新能源科技股份有限公司 A kind of spray distillation extraction equipment

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111668425A (en) * 2020-04-26 2020-09-15 河北金力新能源科技股份有限公司 Meta-aramid diaphragm and preparation method thereof
CN115400448A (en) * 2022-08-30 2022-11-29 华东理工大学 Application of No. 5 industrial white oil as MTBE (methyl tert-butyl ether) extraction anti-coking agent and MTBE desulfurization method
CN115475408A (en) * 2022-08-31 2022-12-16 中材锂膜(宁乡)有限公司 Wet-process diaphragm extraction device and process
CN115475408B (en) * 2022-08-31 2024-01-19 中材锂膜(宁乡)有限公司 Wet diaphragm extraction device and process

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