CN108970165A - A kind of vapour gas separation method - Google Patents

A kind of vapour gas separation method Download PDF

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Publication number
CN108970165A
CN108970165A CN201810741645.9A CN201810741645A CN108970165A CN 108970165 A CN108970165 A CN 108970165A CN 201810741645 A CN201810741645 A CN 201810741645A CN 108970165 A CN108970165 A CN 108970165A
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CN
China
Prior art keywords
temperature
vapour
evaporator
separator
separation method
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810741645.9A
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Chinese (zh)
Inventor
贾枭
岳晓亮
王海涛
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Tianjin Bo Chang Energy Technology Development Co Ltd
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Tianjin Bo Chang Energy Technology Development Co Ltd
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Priority to CN201810741645.9A priority Critical patent/CN108970165A/en
Publication of CN108970165A publication Critical patent/CN108970165A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

The present invention provides a kind of vapour gas separation methods, belong to vapour gas separation technology field, solve prior art waste vapour waste heat because being mixed with incondensable gas impurity, the low technical problem of utilization rate of waste heat.This method are as follows: the vapour gas mixture of high parameter is passed through in evaporator, is condensed into air-water mixture in the heat exchanger of evaporator;Air-water mixture is passed through the liquid level of separator hereinafter, incondensable gas is discharged by the pressure limiting valve on separator top again, the liquid of separator lower part is back to evaporator by external pipe, externally confesses again by the saturated vapor that heat exchanger heating becomes low parameter.The present invention is separated using the method that separation, reflux combine to incondensable gas impurity is mixed in waste vapour waste heat, obtain pure steam, residual heat resources can preferably be utilized, achieve the purpose that energy conservation, increase economic benefit, avoid the unordered discharge of waste heat exhaust gas, expand UTILIZATION OF VESIDUAL HEAT IN direction, reduce " white cigarette ", meets the national white policy requirements that disappear at present.

Description

A kind of vapour gas separation method
Technical field
The present invention relates to heat recovery technology fields, more particularly, to a kind of vapour gas separation method.
Background technique
Currently, waste heat includes more than high-temp waste gas waste heat, cooling medium waste heat, waste vapour waste water residual heat, high-temperature product and clinker Heat, chemical reaction waste heat, combustible exhaust gas waste liquid and waste material waste heat and high-pressure fluid overbottom pressure etc., according to investigation, every profession and trade it is remaining Hot total resources account for about the 17%-67% of its fuel consumption total amount, and the residual heat resources of recoverable are about waste heat total resources 60%, so heat recovery is widely used in respectively as raising Energy economy quality, a fuel-saving important channel A field.
Applicants have discovered that at least there is following technical problem in the prior art: having largely in field of waste heat utilization containing non-condensing The impure net pressurized vapor of gas, vapour gas mixture can only be used to heat supply at present, and residual heat resources could not be fully used, if directly Connect by vapour gas mixture introduce steam turbine acting then efficiency it is lower and unfavorable to equipment, so by not coagulating in vapour gas mixture It is necessary for utilize to steam waste heat again after the impurity separation such as knot gas.
Summary of the invention
The purpose of the present invention is to provide a kind of vapour gas separation methods, to solve existing waste vapour waste heat because being mixed with non-condensing gas Body impurity, the low technical problem of utilization rate of waste heat.Optimal technical scheme in many technical solutions provided by the invention can produce Raw many technical effects elaboration as detailed below.
To achieve the above object, the present invention provides following technical schemes:
The present invention provides a kind of vapour gas separation methods, include the following steps:
Temperature is T by S11, pressure P1Vapour gas mixture be passed through in evaporator and condense, obtaining temperature is T2Air water Mixture;
The temperature is T by S22Air-water mixture be passed through separator, the pressure isolated be P2Non-condensing gas Body and temperature are T3Unsaturated water;
The temperature is T by S33Unsaturated water the evaporator is back to by external pipe;
The temperature is T in the evaporator by S43Unsaturated water be warming up to temperature be T4, pressure P3It is full It is externally confessed with steam.
Preferably, temperature is T in the S11The vapour gas mixture carried out by the heat exchanger that is set in evaporator Condensation.
Preferably, temperature T1>T2>T3, and T1>T4, T4>T3
Preferably, filling into temperature to the separator in the S2 is T5Unsaturated water carry out heat exchange cooling, T2 is dropped Temperature is to T3.
Preferably, the incondensable gas isolated in the S2 is discharged by pressure limiting valve.
Preferably, the incondensable gas isolated is gathered in above the separator interior, as incondensable gas pressure P2 The pressure limiting valve is opened when greater than the setting pressure of the pressure limiting valve.
Preferably, temperature is T in the S33Unsaturated water steamed by the flow-limiting valve adjustment being arranged on the external pipe Send out liquid level in device.
Preferably, temperature is T in the S43Unsaturated water T is warming up to by heat exchanger4Saturated vapor after externally supply Out.
Preferably, the step further include:
The sewage of S5, the evaporator and the separator is discharged by sewage draining exit.
Preferably, by the sewage draining exit, the pressure limiting valve and the common adjustment effect of the flow-limiting valve, make the separator In liquid level fluctuated in scheduled water level range.
The present invention relates to a kind of vapour gas separation methods to have the following beneficial effects: compared with prior art
A kind of vapour gas separation method provided by the invention, is passed through evaporator and separator for vapour gas mixture, obtains pure Saturated vapor is externally confessed, and the impurity such as incondensable gas are efficiently separated, and preferably utilizes residual heat resources, is reached energy conservation, is increased Add the purpose of economic benefit, while improving the quality of a large amount of impure high temperature pressurized vapors, avoids the unordered of waste heat exhaust gas UTILIZATION OF VESIDUAL HEAT IN direction is expanded in discharge, reduces " white cigarette ", meets the national white policy requirements that disappear at present.
Detailed description of the invention
It, below will be to institute in description of the prior art in order to illustrate more clearly of the present invention or technical solution in the prior art Attached drawing to be used is needed to be briefly described, it should be apparent that, the accompanying drawings in the following description is only the embodiment of the present invention, right For those of ordinary skill in the art, without creative efforts, it can also be obtained according to these attached drawings His attached drawing.
Fig. 1 is the flow chart of vapour gas separation method of the present invention;
1, evaporator in figure;11, heat exchanger;12,T2Air-water mixture;13,T4Unsaturated water;14, evaporator sewage draining exit; 2, separator;21,T3Unsaturated water;22, separator sewage draining exit;3, vapour gas mixture;4, saturated vapor;5,T5Unsaturated water;6, Incondensable gas;7, external pipe;8, pressure limiting valve;9, flow-limiting valve.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, technical solution of the present invention will be carried out below Detailed description.Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Base Embodiment in the present invention, those of ordinary skill in the art are obtained all without making creative work Other embodiment belongs to the range that the present invention is protected.
In the description of the present invention, it is to be understood that, term " center ", " lateral ", " length ", " width ", " height ", The instructions such as "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside", " side " Orientation or positional relationship is to be merely for convenience of description of the present invention and simplification of the description based on orientation or positional relationship shown in FIG. 1, Rather than the equipment or element of indication or suggestion meaning must have a particular orientation, is constructed and operated in a specific orientation, because This is not considered as limiting the invention.
The present invention provides a kind of vapour gas separation methods, and process is as shown in Figure 1, include the following steps:
Temperature is T by S11, pressure P1Vapour gas mixture be passed through in evaporator and condense, obtaining temperature is T2Air water Mixture;
The temperature is T by S22Air-water mixture be passed through separator, the pressure isolated be P2Non-condensing gas Body and temperature are T3Unsaturated water;
The temperature is T by S33Unsaturated water the evaporator is back to by external pipe;
The temperature is T in the evaporator by S43Unsaturated water be warming up to temperature be T4, pressure P3It is full It is externally confessed with steam.
Wherein, incondensable gas refers to the gas being mixed among vapor including air, flue gas etc..Specifically, this implementation The vapour gas separation method of example is based on vapour gas separating device, and vapour gas separating device includes evaporator 1 and separator 2, evaporator 1 and separator 2 be the tank structure that inside is cavity, and the two is connected, and vapour gas mixture 3 is carried out cold by the heat exchanger 11 in evaporator 1 It is solidifying, obtain air-water mixture 12, air-water mixture 12 is passed through 2 liquid level of separator hereinafter, obtaining unsaturated water 21, unsaturated water 21 It is back to evaporator 1 by external pipe 7, after heat exchanger 11, saturated vapor 4 is obtained and externally confesses, wherein insatiable hunger It is discharged with the incondensable gas 6 in water 21 by separator.
A kind of vapour gas separation method provided by the invention, is passed through evaporator 1 for vapour gas mixture and condenses, after separator 2 Make water and incondensable gas 6 by two different path separation, finally obtains pure saturated vapor 4 and externally confess, and will not The impurity such as noncondensing gas 6 efficiently separate, and solve waste vapour waste heat because being mixed with incondensable gas impurity, the low disadvantage of utilization rate of waste heat End preferably utilizes residual heat resources, achievees the purpose that energy conservation, increases economic benefit.
As optional embodiment, temperature is T in S11Vapour gas mixture 3 condensed by heat exchanger 11, with changing Hot device 11 can both have been realized to the condensation of mixed vapour 3 as condensing plant, work as T3But also as heating when unsaturated water 21 flows back Equipment saves resource, saves space.
In the present embodiment, temperature T1>T2>T3, and T1>T4, T4>T3, temperature is by T1Drop to T3It is in order to which steam to be condensed into not Saturated water is separated according to incondensable gas and water states of matter difference, incondensable gas is discharged in separator 2.
As optional embodiment, filling into temperature to the separator 2 in S2 is T5Unsaturated water 5 carry out heat exchange drop Temperature, temperature T2Air-water mixture 12 exchange heat in the separator after, temperature drop to T3, filling into temperature is T5Unsaturation Water 5 be first in order to which the water temperature in separator 2 is dropped to predetermined temperature, followed by order to supplement the water level in separator 2, due to Impurity in mixture needs to discharge by separator sewage draining exit 22, can reduce the water in separator 2 and cause not can guarantee There is sufficient water to enter in evaporator 1 and generates steam.Wherein, if needing to be passed through separator 2 temperature is T5Unsaturated water 5 Depend primarily on the fluid temperature and water level in separator 2.
As optional embodiment, the incondensable gas 6 isolated in S2 is discharged by pressure limiting valve 8.
Specifically, when temperature is T2Air-water mixture 12 when being passed through under 2 liquid level of separator, incondensable gas 6 and water root According to states of matter difference natural separation, temperature T3, pressure P2Incondensable gas be gathered in 2 top of separator, when isolating not Pressure limiting valve 8 is opened when the pressure of noncondensing gas is higher than the setting pressure of pressure limiting valve 8, at this time T3Lower than discharge pressure P2Under saturation Vapor (steam) temperature T6, to guarantee not making when discharge that flash distillation occurs and causes thermal loss in separator 2.
As optional embodiment, temperature is T in S33Unsaturated water pass through the flow-limiting valve 9 that is arranged on external pipe 7 Adjust liquid level in evaporator 1.
It can make the temperature T in separator 2 by external pipe 73The reflux of unsaturated water, flow-limiting valve 9 plays pressure release Effect, flow-limiting valve 9 can also adjust liquid level in evaporator in addition to can control backflow water yield, specifically, working as heat exchange area After determining with water in evaporator 1, the temperature of reflux is T3Unsaturated water 21 temperature can be directly become by heat exchanger 11 For T4Saturated vapor.
Wherein, temperature is T in S43Unsaturated water 21 T is warming up to by heat exchanger 114Saturated vapor after externally confess, It can be achieved the vapour gas mixture 3 of high parameter is become low parameter saturated vapor 4 to be used to generate electricity.Wherein, incondensable gas discharge pressure Power P2The pressure limiting valve 8 discharged by control incondensable gas determines, can be manually adjusted, P2Saturation temperature T is corresponded under pressure6> T3
As optional embodiment, step further include: the sewage of S5, evaporator 1 and separator 2 is arranged by sewage draining exit It puts.
By sewage draining exit, pressure limiting valve 8 and the common adjustment effect of flow-limiting valve 9, make the liquid level in separator 2 in scheduled water level Fluctuation in range, wherein liquid level is determined by parameter when device fabrication and field working conditions.
A kind of vapour gas separation method provided by the invention, is passed through evaporator 1 for vapour gas mixture 3 and condenses, after separator 2 Make water and incondensable gas by two different path separation, is finally reached incondensable gas impurity and effectively discharges, it is pure full The purpose externally confessed with steam 4 solves waste vapour waste heat because being mixed with incondensable gas impurity, the low drawback of utilization rate of waste heat; Heat exchanger 11, which is used, as condensing plant can both realize that the condensation to mixed vapour saved resource but also as heating equipment, save Space;The unlatching of the pressure limiting valve 8 of control discharge incondensable gas, ensure that does not make that flash distillation occurs and makes in separator 2 when discharge At thermal loss.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.

Claims (10)

1. a kind of vapour gas separation method, which comprises the steps of:
Temperature is T by S11, pressure P1Vapour gas mixture be passed through in evaporator and condense, obtaining temperature is T2Mixing wastewater with air Object;
The temperature is T by S22Air-water mixture be passed through separator, the pressure isolated be P2Incondensable gas and Temperature is T3Unsaturated water;
The temperature is T by S33Unsaturated water the evaporator is back to by external pipe;
The temperature is T in the evaporator by S43Unsaturated water be warming up to temperature be T4, pressure P3Saturation steam Vapour is externally confessed.
2. a kind of vapour gas separation method according to claim 1, which is characterized in that temperature is T in the S11The vapour Gas mixture is condensed by the heat exchanger being set in evaporator.
3. a kind of vapour gas separation method according to claim 1, which is characterized in that temperature T1>T2>T3, and T1>T4, T4>T3
4. a kind of vapour gas separation method according to claim 1, which is characterized in that filled into the S2 to the separator Temperature is T5Unsaturated water carry out heat exchange cooling.
5. a kind of vapour gas separation method according to claim 1, which is characterized in that non-condensing by what is isolated in the S2 Gas is discharged by pressure limiting valve.
6. a kind of vapour gas separation method according to claim 5, which is characterized in that the incondensable gas isolated is gathered in Above the separator interior, as incondensable gas pressure P2The pressure limiting valve is opened when greater than the setting pressure of the pressure limiting valve It opens.
7. a kind of vapour gas separation method according to claim 1, which is characterized in that temperature is T in the S33Unsaturation Water adjusts liquid level in evaporator by the flow-limiting valve being arranged on the external pipe.
8. a kind of vapour gas separation method according to claim 1, which is characterized in that temperature is T in the S43Unsaturation Water is warming up to T by heat exchanger4Saturated vapor after externally confess.
9. a kind of vapour gas separation method according to claim 1, which is characterized in that the step further include:
The sewage of S5, the evaporator and the separator is discharged by sewage draining exit.
10. a kind of vapour gas separation method according to claim 9, which is characterized in that pass through the sewage draining exit, the pressure limiting Valve and the common adjustment effect of the flow-limiting valve, fluctuate the liquid level in the separator in scheduled water level range.
CN201810741645.9A 2018-07-06 2018-07-06 A kind of vapour gas separation method Pending CN108970165A (en)

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CN201810741645.9A CN108970165A (en) 2018-07-06 2018-07-06 A kind of vapour gas separation method

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116735187A (en) * 2023-07-08 2023-09-12 上海阀门厂股份有限公司 A high-parameter unsaturated water preparation device and preparation method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4372765A (en) * 1980-02-26 1983-02-08 Kabushiki Kaisha Kobe Seiko Sho Air liquefaction and separation process and equipment
CN201373699Y (en) * 2009-01-22 2009-12-30 东方电机控制设备有限公司 Combined secondary steam heat energy recovery device for heat pipe phase change heat exchanger of mechanical compression heat pump
CN202692016U (en) * 2012-07-06 2013-01-23 上海伏波环保设备有限公司 Flue gas waste heat recovery system for concurrent boiler

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4372765A (en) * 1980-02-26 1983-02-08 Kabushiki Kaisha Kobe Seiko Sho Air liquefaction and separation process and equipment
CN201373699Y (en) * 2009-01-22 2009-12-30 东方电机控制设备有限公司 Combined secondary steam heat energy recovery device for heat pipe phase change heat exchanger of mechanical compression heat pump
CN202692016U (en) * 2012-07-06 2013-01-23 上海伏波环保设备有限公司 Flue gas waste heat recovery system for concurrent boiler

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116735187A (en) * 2023-07-08 2023-09-12 上海阀门厂股份有限公司 A high-parameter unsaturated water preparation device and preparation method

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