CN108914110A - A kind of steel ring wheel surface phosphorization treatment process - Google Patents
A kind of steel ring wheel surface phosphorization treatment process Download PDFInfo
- Publication number
- CN108914110A CN108914110A CN201810781019.2A CN201810781019A CN108914110A CN 108914110 A CN108914110 A CN 108914110A CN 201810781019 A CN201810781019 A CN 201810781019A CN 108914110 A CN108914110 A CN 108914110A
- Authority
- CN
- China
- Prior art keywords
- steel ring
- ring wheel
- wheel surface
- treatment process
- nano diatomite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
- C23C22/44—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also fluorides or complex fluorides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
The invention discloses a kind of steel ring wheel surface phosphorization treatment process, are related to steel processing technology field, include the following steps：（1）Polishing；（2）Cleaning；（3）Corona treatment；（4）Phosphorating treatment；Phosphating process of the present invention handles steel ring wheel surface, it can be good at protecting steel ring wheel surface, film forming stability substantially increases well the compactness and uniformity of phosphating coat after phosphorating treatment, phosphating coat adhesive force is high, improve the corrosion resistance and wearability of steel ring wheel surface, phosphating coat purity is high, sediment easy to clean, not only shorten the time of conventional high-temperature surface granosealing, fast bonderizing can be realized under room temperature, without heating, it solves phosphating coat in conventional high-temperature phosphorating treatment and is easily mingled with precipitating, the problem of sediment difficulty is cleared up, improve the efficiency of phosphatization.
Description
Technical field
The invention belongs to steel processing technology fields, and in particular to a kind of steel ring wheel surface phosphorization treatment process.
Background technique
Steel ring wheel, that is, wheel hub, metal parts that be the drum-shaped that exterior feature supports tire in tire, that center is on axis,
Use environment span is very big, and some need often works long hours under rugged environment, it is therefore desirable to just completing the process
Steel ring wheel surface be surface-treated, to improve the surface mechanical performance of steel ring wheel, and existing steel ring wheel table
Surface treatment technique can not meet the demand to work long hours under certain adverse circumstances.
Currently, metal phosphorizing processing technique is widely used, it is multiple automobile, completion, electric appliance, machinery etc. have been applied to
Field is mainly used for antirust, Wear-resistant, lubrication, japanning bottom etc..Especially in coating metal surfaces field, dosage
Account for about the 60%-70% of the total industrial use of phosphorating treatment.Phosphatization before coating is that one in coated metal pre-treatment can not
Small master operation can significantly improve adhesive force, the protective capacities of coating, be the pipe fitting technology for guaranteeing coating quality, be vapour
Vehicle, household electrical appliances, machinery production necessary technique, but phosphatization film properties are general in existing phosphating process, and phosphatization speed is slow, the service life compared with
It is low.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of steel ring wheel surface phosphorization treatment process is provided.
The present invention is achieved by the following technical solutions：
A kind of steel ring wheel surface phosphorization treatment process, includes the following steps：
（1）Polishing：500#, 1200# sand paper is respectively adopted successively to polish to steel ring wheel surface；
（2）Cleaning：Steel ring wheel after polishing is successively immersed into sodium hydroxide solution, in hydrochloric acid solution, is then filtered, using going
Ionized water is cleaned to neutrality；
（3）Corona treatment：Treated steel ring wheel is sequentially placed on plasma conveyer belt, plasma is set
The standby electron ion generated by one layer of a high-field electrode, a cathode ground wire electrode, intermediate isolation high pressure resistant insulation layer is to steel
Circle wheel is two-sided while carrying out plasma modification processing, and corona treatment power is 1000W, steel ring wheel input and output material speed
Control the carry out plasma modification processing two-sided to steel ring wheel at 3.5m/min, normal pressure state；
（4）Phosphorating treatment：A certain amount of ozone is dissolved in into phosphating solution, is dissolved by every 100g steel ring wheel in alramenting liquid
0.0081g ozone immediately after immerses treated steel ring wheel in phosphating solution, carries out phosphorating treatment, handles the time
It for 5-6min, then takes out, is cleaned using deionized water to neutrality, drying to constant weight.
Further, the sodium hydroxide solution mass fraction is 8%, and soaking temperature is 80 DEG C.
Further, the hydrochloric acid solution mass fraction is 10%, and soaking temperature is 60 DEG C.
Further, the phosphating solution is made of following component by weight：Load calcium ion and sodium alginate are received
Rice diatomite 13-19, dodecanol 3, phosphoric acid 52, petroleum sodium sulfonate 2.2, nitric acid 56, sodium fluoride 1.1, zinc citrate 2, molybdic acid
Sodium 4.3, deionized water 200.
Further, the preparation method of the nano diatomite of the load calcium ion and sodium alginate is：
(1) nano diatomite is pressed into 120g：The ratio uniform of 350mL is distributed in the coupling agent solution that mass fraction is 9.5%,
Then the insulated and stirred 40min under 78 DEG C of heating water baths again, is then filtered, using deionized water to the nanometer diatom of suction filtration
Soil is cleaned, and then drying to constant weight；
(2) calcium nitrate is dissolved in deionized water, the calcium salt soln that mass fraction is 1.5-1.8% is configured to, by above-mentioned processing
Nano diatomite afterwards is added in calcium salt soln, obtains nano diatomite dispersion liquid, and nano diatomite dispersion liquid is first heated
To 55 DEG C, keeps the temperature and stirred 2 hours with 1800r/min revolving speed, be then again heated to 85 DEG C, keep the temperature and simultaneously carry out one using ultrasonic wave
Secondary processing 20-30s, then the sodium alginate of nano diatomite quality 4.5% is added, after mixing evenly, 80 DEG C are adjusted the temperature to, protected
Temperature simultaneously using ultrasonic wave carry out secondary treatment 35-40s, then filtered, drying to constant weight to get.
Further, the nano diatomite granularity is 100nm.
Further, the coupling agent solution is organo silane coupling agent solution.
Further, the calcium salt soln is calcium nitrate solution.
Further, the ultrasonic power of the single treatment is 500W, frequency 30kHz.
Further, the ultrasonic power of the secondary treatment is 800W, frequency 50kHz.
The present invention has the following advantages that compared with prior art：Phosphating process of the present invention handles steel ring wheel surface,
It can be good at protecting steel ring wheel surface, film forming stability substantially increases well the densification of phosphating coat after phosphorating treatment
Property and uniformity, phosphating coat adhesive force it is high, improve the corrosion resistance and wearability of steel ring wheel surface, phosphating coat purity is high,
Sediment easy to clean not only shortens the time of conventional high-temperature surface granosealing, can realize fast bonderizing under room temperature, be not necessarily to
The problem of heating solves phosphating coat in conventional high-temperature phosphorating treatment and is easily mingled with precipitating, and sediment difficulty is cleared up, improves phosphatization
Efficiency, the phosphating operation expense under equal conditions carried out using the etching solution prepared in the present invention is cheaper,
Economy is quite high；When phosphating process of the present invention carries out phosphorating treatment to steel ring wheel surface, by existing in a certain amount of ozone
Under, the nano diatomite for loading calcium ion and sodium alginate has structured sp act, easily polarization and deformation, it is easy to adsorb
In steel ring wheel surface, while more active sites are provided, form more nucleus, accelerates parkerizing process, phosphating coat
It forms speed and averagely reaches 0.86g/（m2·min）, and promote phosphatization crystallization refinement, corrosion resistance that is fine and close and improving film layer,
Phosphatization additive improves the warm-up movement that the percentage composition and reaction molecular of anakmetomeres are reacted in phosphating solution, can be in room temperature
Lower carry out phosphorating treatment avoids excessively high phosphorus the problem of causing the coarse loose, binding force of phosphatization membrane crystallization to be deteriorated, obtained of temperature
Change film weight 2.88g/m2, phosphating coat even compact, wearability height.
Specific embodiment
Embodiment 1
A kind of steel ring wheel surface phosphorization treatment process, includes the following steps：
（1）Polishing：500#, 1200# sand paper is respectively adopted successively to polish to steel ring wheel surface；
（2）Cleaning：Steel ring wheel after polishing is successively immersed into sodium hydroxide solution, in hydrochloric acid solution, is then filtered, using going
Ionized water is cleaned to neutrality；
（3）Corona treatment：Treated steel ring wheel is sequentially placed on plasma conveyer belt, plasma is set
The standby electron ion generated by one layer of a high-field electrode, a cathode ground wire electrode, intermediate isolation high pressure resistant insulation layer is to steel
Circle wheel is two-sided while carrying out plasma modification processing, and corona treatment power is 1000W, steel ring wheel input and output material speed
Control the carry out plasma modification processing two-sided to steel ring wheel at 3.5m/min, normal pressure state；
（4）Phosphorating treatment：A certain amount of ozone is dissolved in into phosphating solution, is dissolved by every 100g steel ring wheel in alramenting liquid
0.0081g ozone immediately after immerses treated steel ring wheel in phosphating solution, carries out phosphorating treatment, handles the time
It for 5min, then takes out, is cleaned using deionized water to neutrality, drying to constant weight.
Further, the sodium hydroxide solution mass fraction is 8%, and soaking temperature is 80 DEG C.
Further, the hydrochloric acid solution mass fraction is 10%, and soaking temperature is 60 DEG C.
Further, the phosphating solution is made of following component by weight：Load calcium ion and sodium alginate are received
Rice diatomite 13, dodecanol 3, phosphoric acid 52, petroleum sodium sulfonate 2.2, nitric acid 56, sodium fluoride 1.1, zinc citrate 2, sodium molybdate
4.3, deionized water 200.
Further, the preparation method of the nano diatomite of the load calcium ion and sodium alginate is：
(1) nano diatomite is pressed into 120g：The ratio uniform of 350mL is distributed in the coupling agent solution that mass fraction is 9.5%,
Then the insulated and stirred 40min under 78 DEG C of heating water baths again, is then filtered, using deionized water to the nanometer diatom of suction filtration
Soil is cleaned, and then drying to constant weight；
(2) calcium nitrate is dissolved in deionized water, is configured to the calcium salt soln that mass fraction is 1.5%, it will be treated
Nano diatomite is added in calcium salt soln, obtains nano diatomite dispersion liquid, and nano diatomite dispersion liquid is first heated to 55
DEG C, it keeps the temperature and is stirred 2 hours with 1800r/min revolving speed, be then again heated to 85 DEG C, keep the temperature and simultaneously once located using ultrasonic wave
20s is managed, then adds the sodium alginate of nano diatomite quality 4.5%, after mixing evenly, 80 DEG C is adjusted the temperature to, keeps the temperature and use
Ultrasonic wave carry out secondary treatment 35s, then filtered, drying to constant weight to get.
Further, the nano diatomite granularity is 100nm.
Further, the coupling agent solution is organo silane coupling agent solution.
Further, the calcium salt soln is calcium nitrate solution.
Further, the ultrasonic power of the single treatment is 500W, frequency 30kHz.
Further, the ultrasonic power of the secondary treatment is 800W, frequency 50kHz.
Embodiment 2
A kind of steel ring wheel surface phosphorization treatment process, includes the following steps：
（1）Polishing：500#, 1200# sand paper is respectively adopted successively to polish to steel ring wheel surface；
（2）Cleaning：Steel ring wheel after polishing is successively immersed into sodium hydroxide solution, in hydrochloric acid solution, is then filtered, using going
Ionized water is cleaned to neutrality；
（3）Corona treatment：Treated steel ring wheel is sequentially placed on plasma conveyer belt, plasma is set
The standby electron ion generated by one layer of a high-field electrode, a cathode ground wire electrode, intermediate isolation high pressure resistant insulation layer is to steel
Circle wheel is two-sided while carrying out plasma modification processing, and corona treatment power is 1000W, steel ring wheel input and output material speed
Control the carry out plasma modification processing two-sided to steel ring wheel at 3.5m/min, normal pressure state；
（4）Phosphorating treatment：A certain amount of ozone is dissolved in into phosphating solution, is dissolved by every 100g steel ring wheel in alramenting liquid
0.0081g ozone immediately after immerses treated steel ring wheel in phosphating solution, carries out phosphorating treatment, handles the time
It for 6min, then takes out, is cleaned using deionized water to neutrality, drying to constant weight.
Further, the sodium hydroxide solution mass fraction is 8%, and soaking temperature is 80 DEG C.
Further, the hydrochloric acid solution mass fraction is 10%, and soaking temperature is 60 DEG C.
Further, the phosphating solution is made of following component by weight：Load calcium ion and sodium alginate are received
Rice diatomite 19, dodecanol 3, phosphoric acid 52, petroleum sodium sulfonate 2.2, nitric acid 56, sodium fluoride 1.1, zinc citrate 2, sodium molybdate
4.3, deionized water 200.
Further, the preparation method of the nano diatomite of the load calcium ion and sodium alginate is：
(1) nano diatomite is pressed into 120g：The ratio uniform of 350mL is distributed in the coupling agent solution that mass fraction is 9.5%,
Then the insulated and stirred 40min under 78 DEG C of heating water baths again, is then filtered, using deionized water to the nanometer diatom of suction filtration
Soil is cleaned, and then drying to constant weight；
(2) calcium nitrate is dissolved in deionized water, is configured to the calcium salt soln that mass fraction is 1.8%, it will be treated
Nano diatomite is added in calcium salt soln, obtains nano diatomite dispersion liquid, and nano diatomite dispersion liquid is first heated to 55
DEG C, it keeps the temperature and is stirred 2 hours with 1800r/min revolving speed, be then again heated to 85 DEG C, keep the temperature and simultaneously once located using ultrasonic wave
30s is managed, then adds the sodium alginate of nano diatomite quality 4.5%, after mixing evenly, 80 DEG C is adjusted the temperature to, keeps the temperature and use
Ultrasonic wave carry out secondary treatment 40s, then filtered, drying to constant weight to get.
Further, the nano diatomite granularity is 100nm.
Further, the coupling agent solution is organo silane coupling agent solution.
Further, the calcium salt soln is calcium nitrate solution.
Further, the ultrasonic power of the single treatment is 500W, frequency 30kHz.
Further, the ultrasonic power of the secondary treatment is 800W, frequency 50kHz.
Embodiment 3
A kind of steel ring wheel surface phosphorization treatment process, includes the following steps：
（1）Polishing：500#, 1200# sand paper is respectively adopted successively to polish to steel ring wheel surface；
（2）Cleaning：Steel ring wheel after polishing is successively immersed into sodium hydroxide solution, in hydrochloric acid solution, is then filtered, using going
Ionized water is cleaned to neutrality；
（3）Corona treatment：Treated steel ring wheel is sequentially placed on plasma conveyer belt, plasma is set
The standby electron ion generated by one layer of a high-field electrode, a cathode ground wire electrode, intermediate isolation high pressure resistant insulation layer is to steel
Circle wheel is two-sided while carrying out plasma modification processing, and corona treatment power is 1000W, steel ring wheel input and output material speed
Control the carry out plasma modification processing two-sided to steel ring wheel at 3.5m/min, normal pressure state；
（4）Phosphorating treatment：A certain amount of ozone is dissolved in into phosphating solution, is dissolved by every 100g steel ring wheel in alramenting liquid
0.0081g ozone immediately after immerses treated steel ring wheel in phosphating solution, carries out phosphorating treatment, handles the time
It for 5.5min, then takes out, is cleaned using deionized water to neutrality, drying to constant weight.
Further, the sodium hydroxide solution mass fraction is 8%, and soaking temperature is 80 DEG C.
Further, the hydrochloric acid solution mass fraction is 10%, and soaking temperature is 60 DEG C.
Further, the phosphating solution is made of following component by weight：Load calcium ion and sodium alginate are received
Rice diatomite 15, dodecanol 3, phosphoric acid 52, petroleum sodium sulfonate 2.2, nitric acid 56, sodium fluoride 1.1, zinc citrate 2, sodium molybdate
4.3, deionized water 200.
Further, the preparation method of the nano diatomite of the load calcium ion and sodium alginate is：
(1) nano diatomite is pressed into 120g：The ratio uniform of 350mL is distributed in the coupling agent solution that mass fraction is 9.5%,
Then the insulated and stirred 40min under 78 DEG C of heating water baths again, is then filtered, using deionized water to the nanometer diatom of suction filtration
Soil is cleaned, and then drying to constant weight；
(2) calcium nitrate is dissolved in deionized water, is configured to the calcium salt soln that mass fraction is 1.6%, it will be treated
Nano diatomite is added in calcium salt soln, obtains nano diatomite dispersion liquid, and nano diatomite dispersion liquid is first heated to 55
DEG C, it keeps the temperature and is stirred 2 hours with 1800r/min revolving speed, be then again heated to 85 DEG C, keep the temperature and simultaneously once located using ultrasonic wave
25s is managed, then adds the sodium alginate of nano diatomite quality 4.5%, after mixing evenly, 80 DEG C is adjusted the temperature to, keeps the temperature and use
Ultrasonic wave carry out secondary treatment 38s, then filtered, drying to constant weight to get.
Further, the nano diatomite granularity is 100nm.
Further, the coupling agent solution is organo silane coupling agent solution.
Further, the calcium salt soln is calcium nitrate solution.
Further, the ultrasonic power of the single treatment is 500W, frequency 30kHz.
Further, the ultrasonic power of the secondary treatment is 800W, frequency 50kHz.
Comparative example 1：It is only that the nano diatomite for loading calcium ion and sodium alginate replaces with the difference of embodiment 1 not locating
The nano diatomite of reason.
Comparative example 2：It is distinguished with embodiment 1 and is only that the nano diatomite of load calcium ion and sodium alginate replaces with load
The nano diatomite of sodium alginate.
Comparative example 3：It is distinguished with embodiment 1 and is only that the nano diatomite of load calcium ion and sodium alginate replaces with load
The nano diatomite of calcium ion.
Comparative example 4：It is distinguished with embodiment 1 and is only that the nano diatomite of load calcium ion and sodium alginate replaces with load
The nano-bentonite of calcium ion and sodium alginate, preparation method are constant.
Test
By embodiment and comparative example method respectively to carrying out phosphorating treatment under the steel ring wheel equivalent room temperature of same a collection of same size,
Time consistency is handled, surface phosphating coat adhesive force, phosphatization rate are compared：
Table 1
As can be seen from Table 1, present invention process has the phosphorating treatment of steel ring wheel in the phosphating coat that steel ring wheel surface is formed
There is higher adhesive force, while present invention process phosphatization rate is significantly improved.
Wearability：Under 1kg pressure, parkerized embodiment will be passed through in above-mentioned test and comparative example steel ring wheel tries
Sample measures its abrasion loss after reciprocal 40 polishings on 1000 mesh 18cm long sand paper respectively, as wearability evaluating basis：
Table 2
As can be seen from Table 2, present invention process has the phosphorating treatment of steel ring wheel in the phosphating coat that steel ring wheel surface is formed
There is higher wearability.
Claims (10)
1. a kind of steel ring wheel surface phosphorization treatment process, which is characterized in that include the following steps：
（1）Polishing：500#, 1200# sand paper is respectively adopted successively to polish to steel ring wheel surface；
（2）Cleaning：Steel ring wheel after polishing is successively immersed into sodium hydroxide solution, in hydrochloric acid solution, is then filtered, using going
Ionized water is cleaned to neutrality；
（3）Corona treatment：Treated steel ring wheel is sequentially placed on plasma conveyer belt, plasma is set
The standby electron ion generated by one layer of a high-field electrode, a cathode ground wire electrode, intermediate isolation high pressure resistant insulation layer is to steel
Circle wheel is two-sided while carrying out plasma modification processing, and corona treatment power is 1000W, steel ring wheel input and output material speed
Control the carry out plasma modification processing two-sided to steel ring wheel at 3.5m/min, normal pressure state；
（4）Phosphorating treatment：A certain amount of ozone is dissolved in into phosphating solution, is dissolved by every 100g steel ring wheel in alramenting liquid
0.0081g ozone immediately after immerses treated steel ring wheel in phosphating solution, carries out phosphorating treatment, handles the time
It for 5-6min, then takes out, is cleaned using deionized water to neutrality, drying to constant weight.
2. a kind of steel ring wheel surface phosphorization treatment process according to claim 1, which is characterized in that the sodium hydroxide
Liquid quality fraction is 8%, and soaking temperature is 80 DEG C.
3. a kind of steel ring wheel surface phosphorization treatment process according to claim 1, which is characterized in that the hydrochloric acid solution
Mass fraction is 10%, and soaking temperature is 60 DEG C.
4. a kind of steel ring wheel surface phosphorization treatment process according to claim 1, which is characterized in that the phosphating solution is pressed
Parts by weight meter is made of following component：Load nano diatomite 13-19, the dodecanol 3, phosphoric acid of calcium ion and sodium alginate
52, petroleum sodium sulfonate 2.2, nitric acid 56, sodium fluoride 1.1, zinc citrate 2, sodium molybdate 4.3, deionized water 200.
5. a kind of steel ring wheel surface phosphorization treatment process according to claim 4, which is characterized in that the load calcium from
Son and the preparation method of the nano diatomite of sodium alginate are：
(1) nano diatomite is pressed into 120g：The ratio uniform of 350mL is distributed in the coupling agent solution that mass fraction is 9.5%,
Then the insulated and stirred 40min under 78 DEG C of heating water baths again, is then filtered, using deionized water to the nanometer diatom of suction filtration
Soil is cleaned, and then drying to constant weight；
(2) calcium nitrate is dissolved in deionized water, the calcium salt soln that mass fraction is 1.5-1.8% is configured to, by above-mentioned processing
Nano diatomite afterwards is added in calcium salt soln, obtains nano diatomite dispersion liquid, and nano diatomite dispersion liquid is first heated
To 55 DEG C, keeps the temperature and stirred 2 hours with 1800r/min revolving speed, be then again heated to 85 DEG C, keep the temperature and simultaneously carry out one using ultrasonic wave
Secondary processing 20-30s, then the sodium alginate of nano diatomite quality 4.5% is added, after mixing evenly, 80 DEG C are adjusted the temperature to, protected
Temperature simultaneously using ultrasonic wave carry out secondary treatment 35-40s, then filtered, drying to constant weight to get.
6. a kind of steel ring wheel surface phosphorization treatment process according to claim 4 or 5, which is characterized in that the nanometer
Diatom soil granularity is 100nm.
7. a kind of steel ring wheel surface phosphorization treatment process according to claim 5, which is characterized in that the coupling agent is molten
Liquid is organo silane coupling agent solution.
8. a kind of steel ring wheel surface phosphorization treatment process according to claim 5, which is characterized in that the calcium salt soln
For calcium nitrate solution.
9. a kind of steel ring wheel surface phosphorization treatment process according to claim 5, which is characterized in that the single treatment
Ultrasonic power be 500W, frequency 30kHz.
10. a kind of steel ring wheel surface phosphorization treatment process according to claim 5, which is characterized in that the secondary place
The ultrasonic power of reason is 800W, frequency 50kHz.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810781019.2A CN108914110A (en) | 2018-07-17 | 2018-07-17 | A kind of steel ring wheel surface phosphorization treatment process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810781019.2A CN108914110A (en) | 2018-07-17 | 2018-07-17 | A kind of steel ring wheel surface phosphorization treatment process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108914110A true CN108914110A (en) | 2018-11-30 |
Family
ID=64414121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810781019.2A Pending CN108914110A (en) | 2018-07-17 | 2018-07-17 | A kind of steel ring wheel surface phosphorization treatment process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108914110A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112359353A (en) * | 2020-10-26 | 2021-02-12 | 山东贞元汽车车轮有限公司 | Phosphating liquid supply system and phosphating treatment process for surface of steel ring wheel |
| CN112458472A (en) * | 2020-10-26 | 2021-03-09 | 山东贞元汽车车轮有限公司 | Steel ring wheel surface treatment system and technology thereof |
| CN115852354A (en) * | 2022-11-28 | 2023-03-28 | 北京市三强钢筋预应力设备有限公司 | Processing technology of extrusion anchor |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101037769A (en) * | 2007-04-25 | 2007-09-19 | 上海大学 | Phosphatising method using ozone as steel iron phosphatising accelerator |
| CN106086853A (en) * | 2016-05-30 | 2016-11-09 | 五河县黄淮粮油机械有限公司 | A kind of cornmill discaling roll surface plasma processes technique |
| CN106868487A (en) * | 2016-12-31 | 2017-06-20 | 马鞍山市川金属科技有限公司 | A kind of corrosion-resistant automobile storage battery support |
-
2018
- 2018-07-17 CN CN201810781019.2A patent/CN108914110A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101037769A (en) * | 2007-04-25 | 2007-09-19 | 上海大学 | Phosphatising method using ozone as steel iron phosphatising accelerator |
| CN106086853A (en) * | 2016-05-30 | 2016-11-09 | 五河县黄淮粮油机械有限公司 | A kind of cornmill discaling roll surface plasma processes technique |
| CN106868487A (en) * | 2016-12-31 | 2017-06-20 | 马鞍山市川金属科技有限公司 | A kind of corrosion-resistant automobile storage battery support |
Non-Patent Citations (1)
| Title |
|---|
| 盛敏奇: "臭氧对碳钢表面磷化的影响", 《腐蚀与防护》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112359353A (en) * | 2020-10-26 | 2021-02-12 | 山东贞元汽车车轮有限公司 | Phosphating liquid supply system and phosphating treatment process for surface of steel ring wheel |
| CN112458472A (en) * | 2020-10-26 | 2021-03-09 | 山东贞元汽车车轮有限公司 | Steel ring wheel surface treatment system and technology thereof |
| CN112359353B (en) * | 2020-10-26 | 2021-06-15 | 山东贞元汽车车轮有限公司 | Phosphating liquid supply system and phosphating treatment process for surface of steel ring wheel |
| CN115852354A (en) * | 2022-11-28 | 2023-03-28 | 北京市三强钢筋预应力设备有限公司 | Processing technology of extrusion anchor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108914110A (en) | A kind of steel ring wheel surface phosphorization treatment process | |
| JP7105004B2 (en) | Method of applying an ultra-fine phosphated crystalline coating | |
| CN104988485B (en) | A kind of environmentally friendly universal metal surface pretreatment liquid and application method | |
| Lu et al. | Adhesion enhancement between electroless nickel and polyester fabric by a palladium-free process | |
| MX2011004989A (en) | Method for coating surfaces with particles and use of the coatings produced by this method. | |
| Luo et al. | Electroless copper plating on PC engineering plastic with a novel palladium-free surface activation process | |
| CN107012453B (en) | A kind of method that green low temperature quickly prepares phosphating coat | |
| CN102010136A (en) | Chemical plating Ni-P alloy technology of glass micro beads | |
| Capelossi et al. | Influence of sonication on anticorrosion properties of a sulfursilane film dopped with Ce (IV) on galvannealed steel | |
| CN102011114B (en) | Phosphorous ion-free treating agent for treating steel plate | |
| CN113493619A (en) | Graphene surface-coated silicon dioxide composite material and preparation method and application thereof | |
| CN1130925A (en) | Pre-rinsing liquid for phosphating metal surfaces | |
| Zhang et al. | Titanium Carbon Oxide Flakes with Tunable Interlayer Spacing for Efficient Capacitive Deionization | |
| CN106835093A (en) | A kind of Q types POSS modified metal surface pretreating reagent and preparation method thereof, application | |
| CN106591799A (en) | Preparation method of diamond coating layer and diamond coating layer blade | |
| CN109468620A (en) | A kind of process of flaky metallic material surface silanization processing | |
| CN108554755B (en) | A kind of automobile parts surface intensified technique | |
| CN106011814A (en) | Surface phosphating treatment technique for steel | |
| CN113461354B (en) | Si with function of improving microwave absorption performance of asphalt concrete pavement3N4Preparation method and application of/Fe composite powder | |
| CN106010148B (en) | Highly conductive coating of silvering graphite olefinic carbon pipe compound resin and preparation method thereof | |
| CN102101974A (en) | Novel process for improving organic film treatment metal surface | |
| WO2022033192A1 (en) | Method for preparing metal surface chemical conversion film | |
| CN113512723A (en) | Method for improving corrosion resistance of phosphorus-free pretreatment agent | |
| CN104404441A (en) | Preparation method for copper-plated steel band | |
| CN112247153B (en) | Preparation method of metal-fullerene composite nano powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181130 |
|
| RJ01 | Rejection of invention patent application after publication |