CN108884415A - Laundry detergent composition - Google Patents

Laundry detergent composition Download PDF

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CN108884415A
CN108884415A CN201780016754.8A CN201780016754A CN108884415A CN 108884415 A CN108884415 A CN 108884415A CN 201780016754 A CN201780016754 A CN 201780016754A CN 108884415 A CN108884415 A CN 108884415A
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laundry detergent
preferably
detergent composition
wt
aqueous liquid
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CN201780016754.8A
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S·N·巴切洛尔
J·M·伯德
A·D·格林
C·A·琼斯
A·J·帕里
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荷兰联合利华有限公司
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Priority to EP16161411.0 priority
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Priority to PCT/EP2017/053522 priority patent/WO2017162378A1/en
Publication of CN108884415A publication Critical patent/CN108884415A/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic, or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723Polyamines, polyalkyleneimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/06Ether- or thioether carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines

Abstract

The present invention provides an alkoxylated polyethylene imine polymer and surfactant formulation for use in domestic laundry.

Description

洗衣洗涤剂组合物 Laundry detergent composition

技术领域 FIELD

[0001] 本发明提供了用于家庭洗衣的烷氧基化聚乙烯亚胺聚合物和表面活性剂制剂。 [0001] The present invention provides an alkoxylated polyethyleneimine polymer and surfactant formulations for household laundry.

背景技术 Background technique

[0002] 含有直链烷基苯磺酸盐表面活性剂、烷基醚硫酸盐表面活性剂和低含量非离子表面活性剂和两性离子表面活性剂的家用洗衣液体制剂无处不在。 [0002] a straight-chain alkylbenzene sulfonate surfactants, alkyl ether sulfates liquid formulations for household laundry surfactant and a low content of non-ionic surfactants and zwitterionic surfactants everywhere. 为了增强清洗性能,烷氧基化聚乙烯亚胺聚合物,优选与对苯二甲酸乙二醇酯去污聚合物组合。 In order to enhance cleaning performance, the alkoxylated polyethyleneimine polymer, preferably an ester composition terephthalate soil release polymer. 加入这些聚合物大大降低了制剂的粘度。 These added polymers greatly reduces the viscosity of the formulation. 增加制剂粘度的有效方法是必需的,这不降低表面活性剂含量。 An effective method for increasing the viscosity of the formulation is necessary, which does not reduce the level of surfactant.

[0003] W02013/087286 (Unilever)公开了含有烷基醚羧酸,甜菜碱,阴离子表面活性剂, 非离子表面活性剂的液体制剂,用于提供软化有益效果。 [0003] W02013 / 087286 (Unilever) discloses compositions containing alkyl ether carboxylic acid, betaine, anionic surfactants, non-ionic liquid surfactant formulation for providing softening benefits.

[0004] W02014/060235 (Unilever)公开了洗衣洗涤剂组合物,其包含(a)非离子表面活性剂,(b)阴离子表面活性剂,(c)烷基醚羧酸或其羧酸盐,和(d)聚氨基葡萄糖或者氨基葡萄糖与N-乙酰氨基葡萄糖的共聚物;及其软化织物的用途。 [0004] W02014 / 060235 (Unilever) discloses a laundry detergent composition, comprising (a) a non-ionic surfactant, (b) an anionic surfactant, (c) alkyl ether carboxylic acid or carboxylate, and (d) a copolymer of poly-glucosamine or N- acetyl glucosamine and glucosamine; and fabric softening purposes.

发明内容 SUMMARY

[0005] 令人惊奇地,发现用烷基醚羧酸阴离子表面活性剂部分或完全替代烷基醚硫酸盐阴离子表面活性剂,增加了制剂的粘度。 [0005] Surprisingly, it was found anionic surfactants with alkyl ether carboxylate portion or complete replacement alkyl ether sulfate anionic surfactant, increasing the viscosity of the formulation.

[0006] 在一个方面,本发明提供了一种水性液体洗衣洗涤剂组合物,其包含: [0006] In one aspect, the present invention provides an aqueous liquid laundry detergent composition, comprising:

[0007] (i) 2至10重量%,优选2.5至5重量%的直链烷基苯阴离子磺酸盐表面活性剂; [0007] (i) 2 to 10 wt%, preferably 2.5 to 5 wt% of linear alkylbenzene sulfonate anionic surfactant;

[0008] (ii) 0.5至4重量%,优选1.5至2.5重量%的选自氧化胺和羧基甜菜碱(carbobetaine)的两性离子表面活性剂; [0008] (ii) 0.5 to 4 weight percent, preferably 1.5 to 2.5% by weight of amine oxides and carbobetaines selected (carbobetaine) zwitterionic surfactant;

[0009] (iii) 0 · 1至4重量%,优选0 · 5至2重量%的碱金属盐,优选氯化钠; [0009] (iii) 0 · 1 to 4 weight percent, preferably 0 to 2 wt 2.5% of an alkali metal salt, preferably sodium chloride;

[0010] (iv)l至5重量%,优选1.5至4重量%的烷氧基化聚乙烯亚胺,优选乙氧基化聚乙烯亚胺; [0010] (iv) l to 5% by weight, preferably 1.5 to 4% by weight of alkoxylated polyethyleneimines, preferably ethoxylated polyethyleneimines;

[0011] (V) 1至10重量%,优选2至6重量%,最优选3至5重量%的具有以下结构的烷基醚羧酸阴离子表面活性剂: [0011] (V) 1 to 10 wt%, preferably 2 to 6% by weight, most preferably 3 to 5% by weight of alkyl ether having the structure of carboxylic anionic surfactant:

[0012] R2- (OCH2CH2) n-0CH2_C00H, [0012] R2- (OCH2CH2) n-0CH2_C00H,

[0013] 其中: [0013] wherein:

[0014] R2选自饱和和单不饱和ClO至C26直链或支链烷基链,优选C12至C20直链烷基链, 最优选C16至C18直链烷基链,并且其中η选自:6至20,优选7至13,更优选8至12,最优选9.5 至10.5; [0014] R2 is selected from saturated and mono-unsaturated ClO to C26 straight chain or branched chain alkyl group, preferably C12 to C20 linear alkyl chain, most preferably C16 to C18 linear alkyl chain, and wherein η is selected from: 6-20, preferably 7-13, more preferably 8-12, most preferably from 9.5 to 10.5;

[0015] (Vi)O至10重量%,优选2.5至5重量%的烷基醚硫酸盐阴离子表面活性剂,具有0.5至1.5摩尔当量的乙氧基化,优选0.9至1.2; [0015] (Vi) O to 10 wt%, preferably 2.5 to 5% by weight of alkyl ether sulfate anionic surfactant, with 0.5 to 1.5 molar equivalents of ethoxylation, preferably from 0.9 to 1.2;

[0016] (Vii)O至2重量%,优选0.2至1重量%的对苯二甲酸酯聚酯去污聚合物; [0016] (Vii) O to 2% by weight, preferably 0.2 to 1 wt% of terephthalate polyester soil release polymers;

[0017] (viii) 0至4重量%,优选0至1重量%的非离子表面活性剂;和 [0017] (viii) 0 to 4%, preferably 0 to 1% by weight of nonionic surfactant; and

[0018] (ix) 0.0至0.2重量%,优选0.002至0.02重量%的蛋白酶,其中所述洗衣洗涤剂组合物总共包含10至20重量%的阴离子表面活性剂。 [0018] (ix) 0.0 to 0.2 wt%, preferably from 0.002 to 0.02% by weight of a protease, wherein said laundry detergent composition comprises a total of 10 to 20% by weight of an anionic surfactant.

[0019] 另一方面,本发明提供一种处理纺织品的家用方法,所述方法包括以下步骤: [0019] In another aspect, the present invention provides a domestic method of treating a textile, the method comprising the steps of:

[0020] (i)用lg/L以上的前述权利要求中任一项所定义的洗衣洗涤剂组合物的水溶液处理纺织品;和, [0020] (i) an aqueous solution of a laundry detergent composition as defined by any one or more of lg / L of the preceding claims treating textiles; and,

[0021] (ii)使所述水性洗衣洗涤剂溶液与所述纺织品保持接触10分钟至2天,然后漂洗和干燥所述纺织品。 [0021] (ii) the aqueous solution of laundry detergent is held in contact with the textile 10 to 2 minutes, and then rinsing and drying the textile.

[0022] 在本发明的方法方面,所用表面活性剂优选为如本发明的组合物方面所优选的。 [0022] In the method of the present invention, the surfactant is preferably a composition aspect of the present invention is preferred.

[0023] 家用方法优选在家用洗衣机中或通过手洗进行。 [0023] The method preferably home by hand or in a domestic washing machine. 洗涤温度优选为285至313K。 Washing temperature is preferably from 285 to 313K. 主洗时间优选为5至30分钟。 The main wash time is preferably 5-30 minutes.

[0024] 纺织品优选是衣服、床上用品或桌布的物品。 [0024] Preferably textile clothes, bedding or wallpaper items. 优选的衣服物品是含棉衬衫、裤子、 内衣和套头衫。 The preferred article of clothing is cotton shirts, pants, underwear and pullovers.

具体实施方式 Detailed ways

[0025] 直链烷基苯磺酸盐 [0025] The linear alkyl benzene sulphonate

[0026] 直链烷基苯磺酸盐的重量计算为质子化形式。 [0026] linear alkylbenzene sulfonate weight protonated form. 直链烷基苯磺酸盐的烷基链长为C8 至C15,优选C12至C14。 Linear alkyl benzene sulfonate alkyl chain length of C8 to C15, preferably C12 to C14.

[0027] 直链烷基苯磺酸盐(LAS)可以通过磺化可商购直链烷基苯(LAB)而得到;合适的LAB包括低级2-苯基LAB,例如由Sasol以商品名IsOChem®提供的那些或由Petresa以商品名Petrelab®提供的那些,其他合适的LAB包括高级2-苯基LAB,例如由Sasol以商品名Hyblene®提供的那些。 [0027] linear alkylbenzene sulphonate (LAS) by sulphonating commercially available linear alkyl benzenes (LAB) is obtained; suitable LAB include low 2-phenyl LAB, such for example, by Sasol under the tradename IsOChem those who ®, other suitable LAB or tradename Petrelab® supplied by Petresa include high 2-phenyl LAB, e.g. tradename Hyblene® those provided by the Sasol. 另一种合适的途径是通过DETAL催化方法获得的烷基苯磺酸盐, 优选具有8至15个碳原子。 Another suitable approach is alkyl benzene sulphonate obtained by DETAL catalyzed process, preferably having from 8 to 15 carbon atoms. 其他合成路线,例如HF,也可以是合适的。 Other synthetic routes such as HF, may also be suitable.

[0028] 烷基醚硫酸盐 [0028] alkyl ether sulfates

[0029] 烷基醚硫酸盐的重量计算为质子化形式,R1- (OCH2CH2) m-0S03H。 [0029] The weight of alkyl ether sulfates protonated form, R1- (OCH2CH2) m-0S03H. 优选吣是(:10至C22 饱和或不饱和直链烷基链,更优选饱和C12至C16直链烷基链,最优选C12直链烷基链(月桂基)。每摩尔表面活性剂的平均乙氧基化摩尔数为m,m优选为0.5至1.5。 Qin is preferably (: average 10 to C22 saturated or unsaturated linear alkyl chain, more preferably a saturated C12 to C16 linear alkyl chain, most preferably C12 straight chain alkyl group (lauryl group) per mole of surfactant. ethoxylation molar number m, m is preferably from 0.5 to 1.5.

[0030] 烷基醚羧酸 [0030] alkyl ether carboxylic acid

[0031] 烷基醚羧酸的重量计算为质子化形式,R2- (OCH2CH2) n-0CH2C00H。 [0031] alkyl ether carboxylic acid by weight calculated as protonated form, R2- (OCH2CH2) n-0CH2C00H. 它们可以以盐形式使用,例如钠盐或胺盐。 They may be used in the form of a salt, such as sodium or amine salts.

[0032] 烷基链可以是直链或支链的,优选是直链的。 [0032] The alkyl chain may be straight-chain or branched, preferably straight chain.

[0033] 烷基链可以是脂族的或含有一个顺式或反式双键。 [0033] The alkyl chain may be aliphatic or contains a cis or trans double bonds.

[0034] 烷基链优选选自CH3 (CH2) 15,CH3 (CH2) π,CH3 (CH2) 7CH=CH (CH2) 8-。 [0034] The alkyl chain is preferably selected from CH3 (CH2) 15, CH3 (CH2) π, CH3 (CH2) 7CH = CH (CH2) 8-.

[0035] 烷基醚羧酸最优选具有以下结构: [0035] Most alkyl ether carboxylate preferably has the following structure:

[0036] CH3 (CH2) 7CH=CH (CH2) 8 (OCH2CH2) IqOCH2COOH。 [0036] CH3 (CH2) 7CH = CH (CH2) 8 (OCH2CH2) IqOCH2COOH.

[0037] 烧基醚羧酸可从Kao( AkypO⑧),Huntsman( Empicol® ^PClariant (E'm.ulsogen®)获得。 [0037] ether carboxylic acids may be burning, Huntsman (Empicol® ^ PClariant (E'm.ulsogen®) available from Kao (AkypO⑧).

[0038] 两性离子表面活性剂 [0038] Zwitterionic surfactants

[0039] 两性离子表面活性剂含有直链C8至C16脂族烷基链和表面活性剂分子内的带正和负电荷的原子。 [0039] Zwitterionic surfactants contain positively and negatively charged atoms in the straight-chain aliphatic C8 to C16 alkyl chains and surfactant molecules. 优选的两性离子表面活性剂是甜菜碱和氧化胺。 Preferred zwitterionic surfactants are betaines and amine oxides.

[0040]氧化胺优选具有以下结构: Amine oxide [0040] preferably has the following structure:

Figure CN108884415AD00061

[0042] 优选R3是C12至C14,最优选C12 (月桂基)。 [0042] Preferably, R3 is C12 to C14, most preferably C12 (lauryl). 氧化胺可从Huntsman获得,例如Empigen®〇B〇 Amine oxides available from Huntsman, e.g. Empigen®〇B〇

[0043]甜菜碱优选是羧基甜菜碱。 [0043] The betaine is preferably betaine. 羧基甜菜碱优选选自以下结构: Carboxybetaine preferably selected from the following structures:

Figure CN108884415AD00062

[0045] 优选R4是C12至C14,最优选C12 (月桂基)。 [0045] R4 is preferably C12 to C14, most preferably C12 (lauryl). 甜菜碱可从Huntsman获得,例如Empigeil®BB。 Betaine available from Huntsman, e.g. Empigeil®BB. 最优选椰油酰胺丙基甜菜碱(Cas-No 61789-40-0)。 Most preferably cocamidopropyl betaine (Cas-No 61789-40-0).

[0046] 两性离子最优选为羧基甜菜碱。 [0046] The most preferred zwitterionic betaine.

[0047] 非离子表面活性剂 [0047] Nonionic surfactant

[0048] 水性液体洗衣洗涤剂可包含非离子表面活性剂,优选烷基乙氧基化非离子表面活性剂。 [0048] The aqueous liquid laundry detergent may contain a non-ionic surfactant, preferably an alkyl ethoxylated nonionic surfactant.

[0049] 可以使用的合适的非离子洗涤剂化合物特别包括具有脂族疏水基团和反应性氢原子的化合物(例如脂族醇、酸或酰胺)尤其是与单独的环氧乙烷或者环氧乙烷和环氧丙烷的反应产物。 [0049] Suitable nonionic detergent compounds which may be used include, in particular aliphatic compound and a hydrophobic group having a reactive hydrogen atoms (e.g. aliphatic alcohols, acids or amides), especially ethylene oxide either alone or with propylene reaction products of ethylene oxide and propylene oxide. 优选的非离子洗涤剂化合物是脂族C8至C18直链或支链伯或仲醇与环氧乙烷的缩合产物。 Preferred nonionic detergent compounds are aliphatic C8 to C18 linear or branched condensation products of primary or secondary alcohols with ethylene oxide.

[0050] 优选地,烷基乙氧基化非离子表面活性剂是C8至C18伯醇,具有7E0至9E0单元的摩尔平均乙氧基化。 [0050] Preferably, the alkyl ethoxylated non-ionic surfactant is a C8 to C18 primary alcohol having an average ethoxylation molar 7E0 to 9E0 cells.

[0051] 优选地,分数(非离子的重量%)/(阴离子表面活性剂的重量%)为0至0.2,更优选为0至0.05。 [0051] Preferably, fraction (% by weight of nonionic) / (wt% anionic surfactant) from 0 to 0.2, more preferably from 0 to 0.05. 最优选地,制剂不含非离子的。 Most preferably, the formulation is free of non-ionic.

[0052] 另外的表面活性剂 [0052] Further surfactants

[0053] 水性液体洗衣洗涤剂可包含0至4重量%的另外的表面活性剂,例如“Surface Active Agents”,卷I,Schwartz&Perry,Intersciencel949;卷2,Schwartz,Perry&Berch, Interscience 1958 !Manufacturing Confectioners Company 出版的“McCutcheon ' s Emulsifiers and Detergents” 的当前版本,或“Tenside-Taschenbuch”,H. Stache,第2版, Carl Hauser Verlag,1981,或Helmut W. Stache编辑的Anionic Surfactants : Organic Chemistry (Marcel Dekker 1996)中描述的表面活性剂。 [0053] The aqueous liquid laundry detergent may contain 0 to 4 wt% of additional surfactant, e.g. "Surface Active Agents", Volume I, Schwartz & amp; Perry, Intersciencel949; Volume 2, Schwartz, Perry & amp; Berch, Interscience 1958! . Manufacturing Confectioners Company publication "McCutcheon 's Emulsifiers and Detergents" current version, or "Tenside-Taschenbuch", H Stache, 2nd Ed., Carl Hauser Verlag, 1981, edited by Helmut W. Stache, or Anionic Surfactants: Organic Chemistry surfactants (Marcel Dekker 1996) described.

[0054] 合适的另外的阴离子洗涤剂化合物的实例是烷基硫酸盐,特别是通过硫酸化直链或支链C8至C18醇得到的那些;皂;烧基(优选甲基)酯磺酸盐,及其混合物。 [0054] Further examples of suitable anionic detergent compounds are the alkyl sulfates, especially those obtained by sulfating the straight-chain or branched-chain C8 to C18 alcohols; soap; burn group (preferably methyl) ester sulfonates and mixtures thereof.

[0055] 烷氧基化聚乙烯亚胺 [0055] The alkoxylated polyethyleneimines

[0056] 烷氧基化聚乙烯亚胺包含聚乙烯亚胺骨架,其中聚乙烯亚胺骨架的改性旨在使聚合物不经季铵化。 [0056] The alkoxylated polyethyleneimine backbone comprises a polyethyleneimine, modified polyethyleneimine backbone wherein the polymer is intended without quaternized. 这样的材料可以表示为PEI (X) YAO,其中X表示未改性的PEI的分子量,Y表示未取代的聚乙烯亚胺骨架中每个可用NH的烷氧基化(AO)的平均摩尔数。 Such a material may be expressed as PEI (X) YAO, wherein X represents the molecular weight of the unmodified PEI, Y represents an unsubstituted average alkoxylation of the polyethyleneimine backbone of each of the available NH (AO) of the number of moles . Y优选为7至40, 更优选为16至26,最优选为18至223选自约300至约10000重均分子量,优选为约600。 Y is preferably 7-40, more preferably 16-26, and most preferably from 18 to 223 selected from about 300 to about 10000 weight average molecular weight, preferably about 600.

[0057] 烷氧基化优选选自乙氧基化或丙氧基化,或两者的组合,最优选乙氧基化。 [0057] The alkoxylation is preferably selected from ethoxylated or propoxylated, or a combination thereof, most preferably ethoxylated. 烷氧基链可以用选自以下的基团封端:出013;303_;0120)0_;?032_;(:2抱;正丙基,异丙基;正丁基;叔丁基;和磺基琥珀酸盐,最优选H。 Alkoxy chain may be terminated with a group selected from: a 013; 303_; 0120) 032 0 _ _ ;?; (: 2 hold; n-propyl, isopropyl; n-butyl; t-butyl; and sulfonamide succinate, most preferably H.

[0058] 最优选地,烷氧基化PEI是PEI (600) 20E0。 [0058] Most preferably, the alkoxylated is PEI PEI (600) 20E0.

[0059] 对苯二甲酸酯聚酯去污聚合物 [0059] terephthalate polyester soil release polymer

[0060] 对苯二甲酸酯聚酯去污聚合物包括芳族二羧酸和亚烷基二醇的聚合物(包括含有聚亚烷基二醇的聚合物),如W02009/153184,EP2692842和W02014/019903中所述。 [0060] terephthalate soil release polymers include polyesters of aromatic dicarboxylic acids and alkylene glycols polymers (including polymers containing polyalkylene glycols), such as W02009 / 153184, EP2692842 and W02014 / 019903 in the.

[0061] 对苯二甲酸酯聚酯去污聚合物的实例是由Rhodia提供的REPEL-0-ΤΕΧ®聚合物系列,包括REPEL-0-TEX®SRP6和RETOL-0-TEX®SF-2。 [0061] Examples of terephthalate polyester soil release polymers are supplied by Rhodia REPEL-0-ΤΕΧ® series polymers, including REPEL-0-TEX®SRP6 and RETOL-0-TEX®SF-2 . 其他合适的去污聚合物包括TexCare® 聚合物1 〇〇,TexCare® SRN-17(),TexCare® srn-24 (),TexCare® srn-3()()和丁exCare ⑧ SRN-325,全部由Clar iant 提供。 Other suitable soil release polymers include polymers TexCare® thousand and 1, TexCare® SRN-17 (), TexCare® srn-24 (), TexCare® srn-3 () () and butylated exCare ⑧ SRN-325, all by Clar iant.

[0062] 优选的结构是-[⑵ a-0-0C-Ar-C0_] b和⑵ a-0_0C- [Ar-CO-O-C3H6-O-OC] b-Ar-C〇-0-⑵a,其中Ar选自I,4_取代的亚苯基和I,3-取代的亚苯基,其在5位被磺酸盐(SO厂)基团取代;Z选自乙氧基;丙氧基;和乙氧基和丙氧基的混合物;a为5至100,b为2至40。 [0062] Preferred structures are - [⑵ a-0-0C-Ar-C0_] b and ⑵ a-0_0C- [Ar-CO-O-C3H6-O-OC] b-Ar-C〇-0-⑵a wherein Ar is selected from I, 4_ substituted phenylene and I, 3--substituted phenylene group, which is substituted at the 5-position sulfonate (SO plant) group; the Z is selected from ethoxy; propoxy group; and a mixture of ethoxy and propoxy groups; a is 5 to 100, b is 2 to 40. C3H6是异丙基。 C3H6 is isopropyl.

[0063] 烷氧基链用选自以下的基团封端:H; CH3; S03_; CH2C00_; Pot; C2H5;正丙基,异丙基;正丁基;叔丁基;和磺基琥珀酸盐。 [0063] alkyloxy chain terminated with a group selected from: H; CH3; S03_; CH2C00_; Pot; C2H5; n-propyl, isopropyl; n-butyl; t-butyl; sulfosuccinate salt.

[0064] 最优选地,对苯二甲酸酯聚酯去污聚合物是: [0064] Most preferably, the terephthalate polyester soil release polymers are:

Figure CN108884415AD00071

[0066] 其中c是4至9;d是1至3;e是40至50。 [0066] c wherein from 4 to 9; d 1 to 3; e is 40 to 50.

[0067] 聚合物 [0067] Polymer

[0068] 组合物可包含一种或多种另外的聚合物。 [0068] The composition may comprise one or more additional polymers. 实例是羧甲基纤维素,聚(乙二醇),聚(乙烯醇),聚羧酸盐如聚丙烯酸盐,马来酸/丙烯酸共聚物和甲基丙烯酸月桂酯/丙烯酸共聚物。 Examples are carboxymethylcellulose, poly (ethylene glycol), poly (vinyl alcohol), polycarboxylates such as polyacrylates, maleic / acrylic acid copolymers and lauryl methacrylate / acrylic acid copolymers.

[0069] 可存在用于防止染料沉积的聚合物,例如聚(乙烯基吡咯烷酮),聚(乙烯基吡啶_ N-氧化物)和聚(乙烯基咪唑)。 [0069] which may be present to prevent dye deposition polymers, such as poly (vinyl pyrrolidone), poly (vinylpyridine-N-_-oxide) and poly (vinylimidazole).

[0070] 这样的聚合物的含量优选低于0.5重量%。 Content [0070] Such polymer is preferably less than 0.5 wt%.

[0071] 组合物优选不含硅酮聚合物和带有季铵化N基团的聚合物。 [0071] The composition is preferably free silicone polymers and polymers with quaternary ammonium groups N.

[0072] 助洗剂和螯合剂 [0072] The builder and a chelant

[0073] 洗涤剂组合物还可任选含有相对低含量的有机洗涤剂助洗剂或螯合剂材料。 [0073] The detergent compositions may also optionally an organic detergent builder or sequestrant materials containing relatively low levels. 实例包括碱金属,柠檬酸盐,琥珀酸盐,丙二酸盐,羧甲基琥珀酸盐,羧酸盐,多羧酸盐和聚乙酰基羧酸盐。 Examples include the alkali metal, citrates, succinates, malonates, carboxymethyl succinates, carboxylates, polycarboxylates and polyacetyl carboxylates. 具体实例包括氧二琥珀酸、苯六甲酸(mellitic acid)、苯多羧酸、乙二胺四乙酸、二乙烯三胺五乙酸、烷基或烯基琥珀酸、次氮基三乙酸和柠檬酸的钠、钾和锂盐。 Specific examples include oxydisuccinic acid, mellitic acid (mellitic acid), benzene polycarboxylic acids, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, alkyl- or alkenylsuccinic acid, nitrilotriacetic acid and citric acid sodium, potassium and lithium salts. 其他实例是由Monsanto销售的有机膦酸盐型螯合剂DEQUEST™,和烷烃羟基膦酸盐。 Other examples are organic phosphonate type chelating agents DEQUEST ™, and hydroxy alkane phosphonate marketed by Monsanto's.

[0074] 其它合适的有机助洗剂包括已知具有助洗剂性质的较高分子量聚合物和共聚物。 [0074] Other suitable organic builders known to have builder properties include higher molecular weight polymers and copolymers. 例如,这样的材料包括合适的聚丙烯酸,聚马来酸和聚丙烯酸/聚马来酸共聚物及其盐,例如由BASF以商品名S0KALAN™销售的那些。 For example, such materials include appropriate polyacrylic acid, polymaleic acid and polyacrylic / polymaleic acid copolymers and their salts, for example, from BASF under the tradename those sold S0KALAN ™.

[0075] 如果使用,则水性液体洗衣洗涤剂制剂包含0.1 %至2.0 %重量的助洗剂和螯合剂材料。 [0075] If used, the aqueous liquid laundry detergent formulation comprising from 0.1 to 2.0% by weight of builder and a chelant materials. 柠檬酸盐是最优选的。 Citrate is the most preferred.

[0076] 调色染料 [0076] The hueing dye

[0077] 染料在Color Chemistry Synthesis ,Properties and Applications of Organic Dyes and Pigments (H Zollinger,Wiley VCH,Zurich,2003)和Industrial Dyes Chemistry1Properties Applications (K Hunger(ed),Wiley-VCH Weinheim 2003)中描述。 [0077] The dyes of Organic Dyes and Pigments (H Zollinger, Wiley VCH, Zurich, 2003) describe (K Hunger (ed), Wiley-VCH Weinheim 2003) in Color Chemistry Synthesis, Properties and Applications, and Industrial Dyes Chemistry1Properties Applications.

[0078] 用于洗衣洗涤剂的调色染料优选在可见光范围(400_700nm)中的最大吸收处具有大于5000L morVnf1,优选大于10000L morVnr1的消光系数。 Hueing dye [0078] preferably used in laundry detergents at the absorption maximum (400_700nm) 5000L morVnf1 is greater than in the visible range, preferably greater than the extinction coefficient 10000L morVnr1. 染料的颜色是蓝色或紫色。 Color dyes are blue or violet.

[0079] 优选的调色染料发色团是偶氮,吖嗪,蒽醌和三苯甲烷。 [0079] Preferred hueing dye chromophore azo, azine, anthraquinone, and triphenylmethane.

[0080] 优选的单偶氮染料含有杂环,最优选噻吩染料。 [0080] Preferred monoazo dye-containing heterocycle, most preferably a thiophene dye. 单偶氮染料优选被烷氧基化,并且优选在pH = 7时不带电荷或带阴离子电荷。 Monoazo dyes are preferably alkoxylated and preferably at pH = uncharged or anionic charge 7:00. 烷氧基化噻吩染料在W0/2013/142495和WO/ 2008/087497中讨论。 Alkoxylated thiophene dye discussed in W0 / 2013/142495 and WO / 2008/087497. 噻吩染料的优选实例如下所示: Preferable examples of the dye thiophene as follows:

Figure CN108884415AD00081

[0082] 吖嗪染料优选选自磺化吩嗪染料和阳离子吩嗪染料。 [0082] azine dyes are preferably selected from phenazine dyes and sulfonated cationic phenazine dyes. 优选的实例是酸性蓝98,酸性紫50,具有CAS-No 72749-80-5的染料,酸性蓝59。 Preferred examples are acid blue 98, acid violet 50, having a CAS-No dye, Acid Blue 5972749-80-5 of.

[0083] 调色染料以0.0001至0.5重量%、优选0.001至0.1重量%的范围存在于组合物中。 [0083] The hueing dye 0.0001 to 0.5% by weight, preferably from 0.001 to 0.1% by weight in the composition. 取决于调色染料的性质,存在取决于调色染料的效力的优选范围,所述调色染料的效力取决于类别和任何特定类别内的具体效力。 Depending on the nature of the hueing dye, the preferred range is present depending on the effectiveness of the hueing dye, the efficacy of the dye depends on the effectiveness of the toner in the category and any particular class. 如上所述,调色染料是蓝色或紫色调色染料。 As described above, the toner dyes are blue or violet shading dye.

[0084] 可以使用调色染料的混合物。 [0084] The hueing dye mixture may be used.

[0085] 调色染料最优选是与烷氧基化聚乙烯亚胺共价连接的活性蓝色蒽醌染料。 [0085] Most preferably the hueing dye is an anthraquinone dye reactive blue connection alkoxylated polyethyleneimines covalent. 烷氧基化优选选自乙氧基化和丙氧基化,最优选丙氧基化。 Alkoxylated preferably selected from ethoxylated and propoxylated, most preferably propoxylated. 优选地,通过丙氧基化将聚乙烯亚胺中80至95摩尔%的^!1基团替换为异丙醇基团。 Preferably, the imine 80 to 95 mole% of propoxylated polyethylene by ^! 1 group is replaced isopropyl group. 优选地,在与染料反应和丙氧基化之前,聚乙烯亚胺的分子量为600至1800。 Preferably, prior to reaction with the dye and propoxylated polyethyleneimine of molecular weight 600-1800.

[0086] 共价连接到丙氧基化聚乙烯亚胺的优选活性蒽醌的实例结构是: [0086] covalently linked to a propoxylated polyethyleneimine Examples of preferred active anthraquinone structure is:

Figure CN108884415AD00091

[0088] (结构I)。 [0088] (Structure I).

[0089] 优选的活性蒽醌染料是:活性蓝1,活性蓝2,活性蓝4,活性蓝5,活性蓝6,活性蓝12,活性蓝16,反应性蓝19,活性蓝24,活性蓝27,活性蓝29,活性蓝36,活性蓝44,活性蓝46, 活性蓝47,活性蓝49,活性蓝50,活性蓝53,活性蓝55,活性蓝61,活性蓝66,活性蓝68,活性蓝69,活性蓝74,活性蓝86,活性蓝93,活性蓝94,活性蓝101,活性蓝103,活性蓝114,活性蓝117,活性蓝125,活性蓝141,活性蓝142,活性蓝145,活性蓝149,活性蓝155,活性蓝164,活性蓝166,活性蓝177,活性蓝181,活性蓝185,活性蓝188,活性蓝189,活性蓝206,活性蓝208,活性蓝246,活性蓝247,活性蓝258,活性蓝261,活性蓝262,活性蓝263和活性蓝172。 [0089] Preferred active anthraquinone dyes are: Reactive Blue 1, reactive blue 2, reactive blue 4, reactive blue 5, Reactive Blue 6, Reactive Blue 12, Reactive Blue 16, Reactive Blue 19, Reactive Blue 24, Reactive Blue 27, reactive blue 29, reactive blue 36, reactive blue 44, reactive blue 46, reactive blue 47, reactive blue 49, reactive blue 50, reactive blue 53, reactive blue 55, reactive blue 61, reactive blue 66, reactive blue 68, reactive blue 69, reactive blue 74, reactive blue 86, reactive blue 93, reactive blue 94, reactive blue 101, reactive blue 103, reactive blue 114, reactive blue 117, reactive blue 125, reactive blue 141, reactive blue 142, reactive blue 145, reactive blue 149, reactive blue 155, reactive blue 164, reactive blue 166, reactive blue 177, reactive blue 181, reactive blue 185, reactive blue 188, reactive blue 189, reactive blue 206, reactive blue 208, reactive blue 246, reactive blue 247, reactive blue 258, reactive blue 261, reactive blue 262, reactive blue 263 and reactive blue 172.

[0090] 染料根据颜色指数(Society of Dyers and Colourists/American Association of Textile Chemists and Colorists)分类列出。 [0090] The dyes according to the color index (Society of Dyers and Colourists / American Association of Textile Chemists and Colorists) a breakdown.

[0091] 蛋白酶 [0091] Protease

[0092] 蛋白酶水解肽和蛋白质内的键,在洗衣环境中,这导致对含有蛋白质或肽的污渍的去除增强。 [0092] Hydrolysis of peptide bonds within protein and, in a laundry environment, which results in the removal of stains comprising proteins or peptides is enhanced. 合适的蛋白酶家族的实例包括天冬氨酸蛋白酶,半胱氨酸蛋白酶,谷氨酸蛋白酶,天冬酰胺(aspargine)肽裂解酶,丝氨酸蛋白酶和苏氨酸蛋白酶。 Suitable examples of aspartic protease family of proteases include, cysteine ​​proteases, glutamic proteases, asparagine (aspargine) peptide lyase, serine proteases and threonine proteases. 这样的蛋白酶家族在MEROPS肽酶数据库(http: //merops. sanger. ac. uk/)中描述。 Such a family of proteases in the MEROPS peptidase database (http: // merops sanger ac uk /...) Are described. 丝氨酸蛋白酶是优选的。 Serine protease is preferred. 枯草杆菌酶(subtilase)型丝氨酸蛋白酶是更优选的。 Subtilase (subtilase) type serine protease is more preferable. 根据Siezen等,Protein Engng.4 (1991) 719-737和Siezen等,Protein Science 6 (1997) 501-523,术语“枯草杆菌酶”是指丝氨酸蛋白酶的亚组。 Subgroup of serine proteases according to Siezen like, Protein Engng.4 (1991) 719-737 and Siezen et, Protein Science 6 (1997) 501-523, the term "subtilases" refer to. 丝氨酸蛋白酶是特征在于在活性位点具有丝氨酸的蛋白酶的亚组,该丝氨酸与底物形成共价加合物。 Serine proteases are characterized by having a sub-group of the serine protease active site, the substrate is formed with serine covalent adduct. 枯草杆菌酶可以分为6个亚分类,即枯草杆菌蛋白酶(SubtiIisin) 家族,嗜热蛋白酶(Thermitase)家族,蛋白酶K家族,羊毛硫氨酸抗生素(Lantibiotic)肽酶家族,Kexin家族和Pyrolysin家族。 Subtilisin enzyme may be classified into six subgroups, i.e. subtilisin (SubtiIisin) family, thermophilic proteinase (Thermitase) family, the Proteinase K family, lantibiotic (lantibiotic) peptidase family, Pyrolysin Kexin family and the family.

[0093] 枯草杆菌酶的实例是源自芽孢杆菌例如在US7262042和W009/021867中描述的迟缓芽孢杆菌,嗜碱芽孢杆菌,枯草芽孢杆菌,解淀粉芽孢杆菌,短小芽孢杆菌和吉氏芽孢杆菌的那些,以及在W089/06279中描述的迟缓枯草杆菌蛋白酶(subtilisin Ientus),枯草杆菌蛋白酶Novo,枯草杆菌蛋白酶CarIsberg,地衣芽孢杆菌,枯草杆菌蛋白酶BPN',枯草杆菌蛋白酶309,枯草杆菌蛋白酶147和枯草杆菌蛋白酶168,以及在W093/18140中描述的蛋白酶HH38。 [0093] Examples of subtilases are derived from Bacillus lentus as described for example in US7262042 and W009 / 021867, Bacillus halodurans, Bacillus subtilis, Bacillus amyloliquefaciens, Bacillus pumilus and Bacillus gibsonii those, and slow subtilisin (subtilisin Ientus) described in W089 / 06279, the subtilisin Novo, subtilisin CarIsberg, Bacillus licheniformis, subtilisin BPN ', subtilisin 309, subtilisin 147 and subtilisin 168 Bacillus proteases, and protease HH38 described in W093 / 18140. 其它有用的蛋白酶可以是TO92/175177,TO01/016285,TO02/026024和TO02/016547 中描述的那些。 Other useful protease may be TO92 / 175177, TO01 / 016285, the TO02 / 026024 and TO02 / 016547 those described. 胰蛋白酶样蛋白酶的实例是W089/06270,W094/25583和W005/040372中描述的胰蛋白酶(例如,猪或牛来源的)和镰刀菌蛋白酶,以及在W005/052161和W005/052146中描述的源自纤维单胞菌属(Cellumonas)的糜蛋白酶。 Examples of trypsin-like proteases are trypsin (e.g., of porcine or bovine origin) and the Fusarium protease W089 / 06270, W094 / 25583 and W005 / 040372 is described, and a source described in W005 / 052161 and W005 / 052146 in from Cellulomonas (Cellumonas) chymotrypsin.

[0094] 有用的蛋白酶的另一些实例是在W092/19729,W096/034946,W098/20115,W098/ 20116,W099/011768,W001/44452,W003/006602,W004/03186,W004/041979,W007/006305, W011/036263,W011/036264中描述的变体,特别是具有在使用BNP'编号的以下位置的一个或多个中的置换的变体:3,4,9,15,27,36,57,68,76,87,95,96,97,98,99,100,101,102, 103,104,106,118,120,123,128,129,130,160,167,170,194,195,199,205,206,217,218, 222,224,232,235,236,245,248,252和274。 [0094] Useful other examples of proteases are in W092 / 19729, W096 / 034946, W098 / 20115, W098 / 20116, W099 / 011768, W001 / 44452, W003 / 006602, W004 / 03186, W004 / 041979, W007 / 006305, W011 / 036263, W011 / 036264 describes a variant, especially a variant having substitutions at one or more usage BNP 'numbers in the following locations: 3,4,9,15,27,36, 57,68,76,87,95,96,97,98,99,100,101,102, 103,104,106,118,120,123,128,129,130,160,167,170,194,195,199,205,206,217,218, 222,224,232,235,236,245,248,252 and 274. 更优选的枯草杆菌酶变体可以包含以下突变: S3T,V4I,S9R,A15T,K27R,*36D,V68A,N76D,N87S,R,*97E,A98S,S99G,D,A,S99AD,S101G,M,R S103A,V104I,Y,N,S106A,G118V,R,H120D,N,N123S,S128L,P129Q,S130A,G160D,Y167A, R170S,A194P,G195E,V199M,V205I,L217D,N218D,M222S,A232V,K235L,Q236H,Q245R, N252K,T274A (使用BNP' 编号)。 More preferred subtilase variant may comprise the following mutations: S3T, V4I, S9R, A15T, K27R, * 36D, V68A, N76D, N87S, R, * 97E, A98S, S99G, D, A, S99AD, S101G, M , R S103A, V104I, Y, N, S106A, G118V, R, H120D, N, N123S, S128L, P129Q, S130A, G160D, Y167A, R170S, A194P, G195E, V199M, V205I, L217D, N218D, M222S, A232V, K235L, Q236H, Q245R, N252K, T274A (using BNP 'numbering).

[0095] 最优选地,蛋白酶是枯草杆菌蛋白酶(EC 3.4.21.62)。 [0095] Most preferably, the protease is a subtilisin (EC 3.4.21.62).

[0096] 枯草杆菌酶的实例是源自芽孢杆菌例如在US7262042和W009/021867中描述的迟缓芽孢杆菌,嗜碱芽孢杆菌,枯草芽孢杆菌,解淀粉芽孢杆菌,短小芽孢杆菌和吉氏芽孢杆菌的那些,以及在W089/06279中描述的迟缓枯草杆菌蛋白酶,枯草杆菌蛋白酶Novo,枯草杆菌蛋白酶Carlsberg,地衣芽孢杆菌,枯草杆菌蛋白酶BPN',枯草杆菌蛋白酶309,枯草杆菌蛋白酶147和枯草杆菌蛋白酶168,以及在W093/18140中描述的蛋白酶PD138。 [0096] Examples of subtilases are derived from Bacillus lentus as described for example in US7262042 and W009 / 021867, Bacillus halodurans, Bacillus subtilis, Bacillus amyloliquefaciens, Bacillus pumilus and Bacillus gibsonii those, and slow subtilisin described in W089 / 06279, subtilisin Novo, subtilisin Carlsberg, Bacillus licheniformis, subtilisin BPN ', subtilisin 309, subtilisin 147 and subtilisin 168, and PD138 protease described in W093 / 18140. 优选地,枯草杆菌蛋白酶源自芽孢杆菌,优选迟缓芽孢杆菌,嗜碱芽孢杆菌,枯草芽孢杆菌,解淀粉芽孢杆菌,短小芽孢杆菌和吉氏芽孢杆菌,如US 6,312,936B1,US 5,679,630,US 4,760,025, US7,262,042和W009/021867中所述。 Preferably, subtilisin derived from Bacillus, preferably Bacillus lentus, Bacillus halodurans, Bacillus subtilis, Bacillus amyloliquefaciens, Bacillus pumilus and Bacillus gibsonii, such as US 6,312,936B1, US 5,679,630, US 4,760,025, US7,262,042 and W009 / 021867 in the. 最优选地,枯草杆菌蛋白酶源自吉氏芽孢杆菌或迟缓芽孢杆菌。 Most preferably, a subtilisin derived from Bacillus gibsonii, or Bacillus lentus.

[0097] 合适的可商购蛋白酶包括以商品名 [0097] Suitable commercially available protease enzymes include the tradename

Figure CN108884415AD00101

Figure CN108884415AD00102

Figure CN108884415AD00111

Figure CN108884415AD00112

1销售的那些,所有都可作为Ultra⑧或Evity_® (Novozymes A/S)销售。 1 those sold, can be used as all or Ultra⑧ Evity_® (Novozymes A / S) sales.

[0098] 由Gen encor Internationa 1以商品名] [0098] 1 under the trade name of Gen encor Internationa]

Figure CN108884415AD00113

Figure CN108884415AD00114

Figure CN108884415AD00115

_售的那些。 _ The sale of those.

[0099] 以商品名 [0099] under the trade name

Figure CN108884415AD00116

,

Figure CN108884415AD00117

Figure CN108884415AD00118

(Gist-Brocases NV)销售的那些。 Those (Gist-Brocases NV) sales.

[0100] 可获自Henkel/Kemira的那些,S卩BLAP (在US 5,352,604附图29中示出的序列,具有以下突变:S99D+S101R+S103A+V104I+G159S;在下文中称为BLAP),BLAP R (具有S3T+V4I+ V199M+V205I+L217D的BLAP),BLAP X (具有S3T+V4I+V205I的BLAP)和BLAP F49(具有S3T+ V4I+A194P+V199M+V205I+L217D的BLAP),所有都来自Henkel/Kemira;以及KAP (具有A230V+ S256G+S259N突变的嗜碱芽孢杆菌枯草杆菌蛋白酶),来自Kao。 Those, S Jie BLAP [0100] available from Henkel / Kemira of (29 in US 5,352,604 in the sequence shown in the drawings, with the following mutations: S99D + S101R + S103A + V104I + G159S; hereinafter BLAP), BLAP R (with S3T + V4I + V199M + V205I + L217D the BLAP), BLAP X (with S3T + V4I + V205I the BLAP) and BLAP F49 (with S3T + V4I + A194P + V199M + V205I + L217D the BLAP), all from Henkel / Kemira; and associated KAP (basophils having A230V + S256G + S259N mutant Bacillus subtilisin) from Kao.

[0101] 在制剂中包含蛋白酶增强清洁。 [0101] A protease in the formulation to enhance cleaning.

[0102] 另外的酶 [0102] Further enzymes

[0103] —种或多种另外的酶优选存在于本发明的洗衣组合物中和当实施本发明的方法时。 [0103] - one or more additional enzymes preferably present in the laundry composition of the present invention when the method and embodiment of the present invention.

[0104] 优选地,本发明的洗衣组合物中每种酶的含量为0.0001重量%至0.1重量%蛋白质。 [0104] Preferably, the content of each enzyme laundry compositions of the present invention is 0.0001 wt% to 0.1 wt% protein.

[0105] 优选地,另外的酶选自:α-淀粉酶;脂肪酶;和纤维素酶。 [0105] Preferably, the further enzyme is selected from: α- amylase;; lipases and cellulases.

[0106] 合适的脂肪酶包括具有细菌或真菌来源的那些。 [0106] Suitable lipases include those of bacterial or fungal origin having. 包括化学修饰的或蛋白质工程化的突变体。 Chemically modified or protein engineered mutants. 有用的脂肪酶的实例包括来自以下的脂肪酶:腐质霉(Humicola)(同义词嗜热真菌(Thermomyces)),例如来自EP 258 068 和EP 305 216 中所述的H. lanuginosa (T. lanuginosus)或来自WO 96/13580中所述的H. insolens;假单胞菌脂肪酶,例如来自产碱假单胞菌(P.alcaligenes)或假产碱假单胞菌(P.pseudoalcaligenes) (EP 218 272)、洋葱假单胞菌(P.cepacia) (EP331 376)、施氏假单胞菌(P.stutzeri) (GB 1,372,034)、焚光假单胞菌(P.fluorescens),假单胞菌菌株SD 705 (W0 95/06720 和W096/27002)、 P.wisconsinensis (W0 96/12012);芽孢杆菌脂肪酶,例如来自枯草芽孢杆菌(B.subtilis) (Dartois等(1993) ,Biochemica et Biophysica Acta, 1131,253-360)、嗜热脂肪芽抱杆菌(B.stearothermophilus) (JP 64/744992)或短小芽抱杆菌(B.pumilus) (W0 91/16422)。 Examples of useful lipases include lipases derived from the following: Humicola insolens (Humicola) (synonym Thermomyces sp (Thermomyces)), in the example from 305 216 EP 258 068 and EP of H. lanuginosa (T. lanuginosus) or from H. insolens as described in WO 96/13580; Pseudomonas lipase, e.g. from P. alcaligenes or false base P. yield (P.alcaligenes) (P.pseudoalcaligenes) (EP 218 272), P. cepacia (P.cepacia) (EP331 376), Pseudomonas stutzeri (P.stutzeri) (GB 1,372,034), P. burning light (P. fluorescens), Pseudomonas strain SD 705 (W0 95/06720 and W096 / 27002), P.wisconsinensis (W0 96/12012); a Bacillus lipase, e.g. from B. subtilis (B.subtilis) (Dartois et (1993), Biochemica et Biophysica Acta , 1 131, 253-360), Bacillus stearothermophilus spores (B.stearothermophilus) (JP 64/744992) or Bacillus spores short (B.pumilus) (W0 91/16422).

[0107] 其他实例是脂肪酶变体,例如在WO 92/05249、W0 94/0154UEP 407 225、EP 260 105、W0 95/35381、W0 96/00292、W0 95/30744、W0 94/25578、W0 95/14783、W0 95/22615、 WO 97/04079和W097/07202、W0 00/60063中描述的那些。 [0107] Other examples are lipase variants such as in WO 92/05249, W0 94 / 0154UEP 407 225, EP 260 105, W0 95/35381, W0 96/00292, W0 95/30744, W0 94/25578, W0 95/14783, W0 95/22615, WO 97/04079 and W097 / 07202, W0 00/60063, those described.

[0108] 优选的可商购脂肪酶包括Lipolase™和LipoIase Ultra™、Lipex™和Lipoclean™ (Novozymes A/S) 〇 [0108] Preferred commercially available lipase enzymes include Lipolase ™ and LipoIase Ultra ™, Lipex ™, and Lipoclean ™ (Novozymes A / S) square

[0109] 本发明的方法可以在分类为EC 3.1.1.4和/或EC 3.1.1.32的磷脂酶存在下进行。 [0109] The method of the present invention may be in the presence of phospholipase classified as EC 3.1.1.4 and / or EC 3.1.1.32 performed. 如在本文中所使用的,术语磷脂酶是对磷脂具有活性的酶。 As used herein, the term phospholipase is an enzyme having phospholipase activity.

[0110] 磷脂,例如卵磷脂或磷脂酰胆碱,由在外部(sn-Ι)和中间(sn-2)位置被两个脂肪酸酯化,并在第三位置被磷酸酯化的甘油组成;磷酸反过来可以被酯化成氨基醇。 [0110] phospholipids, such as lecithin or phosphatidylcholine, a (sn-2) position in the outer (sn-Ι) and the intermediate two are esterified with fatty acids, and in the third position of the glycerol phosphate ; phosphoric acid in turn may be esterified to an amino alcohol. 磷脂酶是参与磷脂水解的酶。 Phospholipase is an enzyme involved in the hydrolysis of phospholipids. 可以区分磷脂酶活性的多种类型,包括磷脂酶AdPA2,其水解一个脂肪酰基(分别在sn-Ι和sn-2位置)以形成溶血磷脂;和溶血磷脂酶(或磷脂酶B),其可以水解溶血磷脂中剩余的脂肪酰基。 Phospholipase activity can be distinguished in a variety of types, including phospholipases AdPA2, which hydrolyze one fatty acyl group (in the sn-Ι and sn-2 position) to form lysophospholipid; and lysophospholipase (or phospholipase B), which can be hydrolysis lysophospholipid remaining fatty acyl group. 磷脂酶C和磷脂酶D (磷酸二酯酶)分别释放二酰基甘油或磷脂酸。 Phospholipase C and phospholipase D (phosphodiesterases) release diacyl glycerol or phosphatidic acid.

[0111] 本发明的方法可以在分类为EC 3.1.1.74的角质酶的存在下进行。 Method [0111] The present invention can be performed under classified as EC 3.1.1.74 in the presence of cutinase. 根据本发明使用的角质酶可以具有任何来源。 The cutinase used according to the present invention may have any origin. 优选地,角质酶具有微生物来源,特别是细菌、真菌或酵母来源。 Preferably, cutinases with microbial origin, in particular of bacterial, fungal or yeast origin.

[0112] 合适的淀粉酶(α和/或β)包括具有细菌或真菌来源的那些。 [0112] Suitable amylases ([alpha] and / or beta]) include those of bacterial or fungal origin. 包括化学修饰的或蛋白质工程化的突变体。 Chemically modified or protein engineered mutants. 淀粉酶包括例如获自芽孢杆菌,如在GB 1,296,839中更详细描述的地衣芽孢杆菌的特殊菌株,或在WO 95/026397或WO 00/060060中公开的芽孢杆菌菌株的α-淀粉酶。 Amylases include, for example, obtained from Bacillus, a special strain of Bacillus licheniformis as described in more detail in GB 1,296,839, or the Bacillus strain WO 00/060060 or WO 95/026397 disclosed in the α- amylase enzyme. 可商购的淀粉酶是 Commercially available amylases are

Figure CN108884415AD00121

Figure CN108884415AD00122

[0113] 合适的纤维素酶包括具有细菌或真菌来源的那些。 [0113] Suitable cellulases include those of bacterial or fungal origin having. 包括化学修饰的或蛋白质工程化的突变体。 Chemically modified or protein engineered mutants. 合适的纤维素酶包括来自以下的纤维素酶:芽孢杆菌属、假单胞菌属、腐质霉属、镰刀菌属、梭孢壳属、支顶孢属,例如从公开于US 4,435,307、US 5,648,263、US 5,691, 178、US 5,776,757、W0 89/09259、W0 96/029397和WO 98/012307的特异腐质霉、太瑞斯梭孢壳霉、嗜热毁丝霉和尖孢镰刀菌产生的真菌纤维素酶。 Suitable cellulases include cellulases from the genera: Bacillus, Pseudomonas, Humicola, Fusarium, Thielavia, Acremonium, e.g. from the disclosure in US 4,435,307, US 5,648,263, US 5,691, 178, US 5,776,757, W0 89/09259, W0 96/029397 and WO 98/012307 of Humicola insolens, Thielavia sp too Reese, Myceliophthora thermophila and Fusarium oxysporum generated fungal cellulase. 可商购的纤维素酶包括Cel Iuzyme™、Carezyme™、Cel Iuclean™、Endolase™、Renozyme™ (Novozymes A/S)、 Clazinase™和Puradax HA™ (Genencor International Inc.)和KAC-500 (B) ™ (Kao Corporation) Xelluclean™是优选的。 Commercially available cellulases include Cel Iuzyme ™, Carezyme ™, Cel Iuclean ™, Endolase ™, Renozyme ™ (Novozymes A / S), Clazinase ™, and Puradax HA ™ (Genencor International Inc.), and KAC-500 (B) ™ (Kao Corporation) Xelluclean ™ are preferred.

[0114] 合适的过氧化物酶/氧化酶包括具有植物、细菌或真菌来源的那些。 [0114] Suitable peroxidases / oxidases include those of plant, bacterial or fungal origin. 包括化学修饰的或蛋白质工程化的突变体。 Chemically modified or protein engineered mutants. 有用的过氧化物酶的实例包括来自鬼伞属,例如来自灰盖鬼伞的过氧化物酶,及其变体,如在WO 93/24618、W0 95/10602和WO 98/15257中所述的那些。 Examples of useful peroxidases include peroxidases from Coprinus, e.g., from Coprinus cinereus peroxidase, and variants thereof, as described in WO 93/24618, W0 95/10602 and in WO 98/15257 of those. 可商购的过氧化物酶包括Guardzyme™和Novozym™51004 (Novozymes A/S) Commercially available peroxidases include Guardzyme ™ and Novozym ™ 51004 (Novozymes A / S)

[0115] 另外的适用的酶在W02009/087524、W02009/090576、W02009/107091、W02009/ 111 258 和W02009/148983 中讨论。 [0115] Further suitable enzymes are discussed in W02009 / 087524, W02009 / 090576, W02009 / 107091, W02009 / 111 258 and W02009 / 148983 in.

[0116] 酶稳定剂 [0116] Enzyme Stabilizers

[0117] 存在于组合物中的任何酶可以使用常规的稳定剂稳定化,例如多元醇,如丙二醇或甘油;糖或糖醇;乳酸;硼酸或硼酸衍生物,例如芳族硼酸酯,或苯基硼酸衍生物,如4-甲酰基苯基硼酸,并且组合物可以如例如WO 92/19709和WO 92/19708中所述配制。 [0117] Any enzyme present in the composition may be stabilized using conventional stabilizing of, e.g., a polyol such as propylene glycol or glycerol; sugar or sugar alcohol; lactic acid; boric acid or a boric acid derivative, e.g., an aromatic borate ester, or phenyl boronic acid derivative, such as 4-formylphenyl boronic acid, and the composition may, for example, as WO 92/19709 and WO 92/19708.

[0118] 当烷基足够长以形成支链或环状链时,烷基包括支链、环状和直链烷基链。 [0118] When the alkyl group is long enough to form a branched chain or cyclic, the alkyl groups include branched, cyclic and linear alkyl chain. 烷基优选是直链或支链的,更优选直链的。 Group is preferably straight-chain or branched, more preferably straight chain.

[0119] 荧光剂 [0119] phosphor

[0120] 组合物优选包含荧光剂(光亮剂)。 [0120] The composition preferably comprises a fluorescent agent (brightener). 荧光剂是众所周知的,并且许多这样的荧光剂是可商购的。 Fluorescent agents are well known and many such fluorescent agents are available commercially. 通常,这些荧光剂以其碱金属盐,例如钠盐的形式提供和使用。 Usually, these fluorescent agents their alkali metal salts, e.g. sodium salt to provide and use.

[0121] 荧光剂的优选类别是:二苯乙烯基联苯化合物,如Tinopal (商标)CBS_X,二胺芪二磺酸化合物,如Tinopal DMS pure Xtra和Blankophor (商标)HRH,以及卩比卩坐啉化合物,如Blankophor SN0 [0121] Preferred classes of fluorescer are: Di-styryl biphenyl compounds, such as Tinopal (Trade Mark) CBS_X, diamine stilbene disulfonic acid compound, such as Tinopal DMS pure Xtra and Blankophor (trademark) HRH, and take the ratio Jie Jie morpholine compounds such as Blankophor SN0

[0122] 优选的荧光剂是:2-(4-苯乙烯基-3-磺基苯基)-2!1-萘并(11&?让〇1)[1,2-(1]三唑钠、4,4'_双{[ (4-苯胺基-6- (N-甲基-N-2-羟乙基)氨基-1,3,5_三嗪-2-基)]氨基}芪-2-2 ' -二磺酸二钠、4,4 ' -双{[ (4-苯胺基-6-吗啉基-1,3,5-三嗪-2-基)]氨基}芪-2-2 ' -二磺酸二钠以及4,4'_双(2-磺基苯乙烯基)联苯二钠。 [0122] Preferred fluorescers are:! 2- (4-styryl-3-sulfophenyl) -2 and 1-naphthyl (11 & amp ;? so 〇1) [1,2 (1] triazole sodium, 4,4'_ bis {[(4-anilino--6- (N- methyl -N-2- hydroxyethyl) amino -1,3,5_ triazin-2-yl)] amino} stilbene-2-2 '- disulphonate, disodium 4,4' - bis {[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)] amino} stilbene 2-2 '- disulphonate, disodium 4,4'_ and bis (2-sulfostyryl) biphenyl.

[0123] 组合物中使用的一种或多种荧光剂的总量优选为0.0001至0.5重量%,更优选0.005至2重量%,最优选0.05至0.25重量%。 Preferably the total amount of one or more fluorescent agents [0123] used in the composition is from 0.0001 to 0.5 wt%, more preferably from 0.005 to 2 wt%, most preferably 0.05 to 0.25 wt%.

[0124] 优选的是方法中使用的水溶液具有荧光剂存在。 [0124] Preferably, the aqueous solution used in the method has a fluorescer present. 当荧光剂存在于方法中使用的水溶液中时,其优选在〇. 〇〇〇Ig/L至0.1g/L,优选0.001至0.02g/L的范围内。 When a fluorescent agent is present in the aqueous solution used in the method, which is preferably in the square inner 〇〇〇Ig / L to 0.1 g of / L, preferably in the range of 0.001 to 0.02g L /.

[0125] #|4 [0125] # | 4

[0126] 组合物包含香料。 [0126] The composition comprises a perfume. 香料优选为0.001至3重量%,更优选0.05至0.5重量%,最优选0.1至1重量%。 The perfume is preferably 0.001 to 3 wt%, more preferably 0.05 to 0.5% by weight, most preferably 0.1 to 1 wt%. 在由CFTA Publications出版的CTFA (Cosmetic,Toiletry and Fragrance Association) 1992International Buyers Guide和由Schnell Publishing Co.出版的OPD 1993Chemicals Buyers Directory 80th Annual Edition中提供了香料的许多合适实例。 It provides many examples of suitable fragrances published by CFTA Publications in the CTFA (Cosmetic, Toiletry and Fragrance Association) 1992International Buyers Guide and the Schnell Publishing Co. published OPD 1993Chemicals Buyers Directory 80th Annual Edition of.

[0127] 优选地,香料包含以下的至少一种香型(note)(化合物):α-异甲基紫罗酮,水杨酸苄酯;香茅醇;香豆素;己基肉桂醛;芳樟醇;2-甲基戊酸乙基酯;辛醛;乙酸苄酯;3,7_二甲基-1,6-辛二烯-3-醇3-乙酸酯;2-(1,1_二甲基乙基)-环己醇1-乙酸酯;δ-大马酮(damascone) ;β_紫罗酮;乙酸三环癸稀酯(verdyl acetate);十二醛;己基肉桂醛(hexyl cinnamic aldehyde);环十五内酯;苯乙酸2-苯基乙基酯;水杨酸戊酯;β-石竹稀;^ 碳稀酸乙酯;邻氨基苯甲酸香叶酯;α-鸢尾酮;β-苯基乙基苯甲酸酯;α-檀香醇;雪松醇;乙酸柏木酯;甲酸柏木酯(cedry formate);水杨酸环己酯;γ-十二内酯,和β-苯乙基苯基乙酸酯。 [0127] Preferably, the fragrance comprising at least one flavor (Note) (Compound): α- iso methyl ionone, benzyl salicylate; citronellol; coumarin; hexyl cinnamic aldehyde; aryl camphor alcohol; 2-methylpentanoic acid ethyl ester; octanal; benzyl acetate; 3,7_-dimethyl-1,6-octadiene-3-ol 3- acetate; 2- (1, 1_-dimethylethyl) - 1-acetate cyclohexanol; delta-Damascone (damascone); β_ ionone; tricyclodecane dilute acetic acid ester (verdyl acetate); dodecanal; hexyl cinnamaldehyde aldehyde (hexyl cinnamic aldehyde); cyclopentadecanolide; acid 2-phenylethyl ester; amyl salicylate; [beta] pink dilute; ^ carbon dilute acid ethyl ester; geranyl anthranilate; [alpha] - irone; [beta] phenylethyl benzoate; alpha] santalol; cedrol; cedryl acetate; cedryl formate ester (cedry formate); cyclohexyl salicylate; dodecalactone [gamma], and β- phenylethyl phenyl acetate.

[0128] 香料的可用组分包括天然和合成来源二者的材料。 [0128] available components of the perfume include materials of both natural and synthetic origin. 它们包括单一化合物和混合物。 They include single compounds and mixtures. 这样的组分的具体实例可见于现有文献,例如,Fenaroli's Handbook of Flavor Ingredients,1975,CRC Press;Synthetic Food Adjuncts,1947,M·B·Jacobs著,Van Nostrand编辑;或Perfume and Flavor Chemicals,S.Arctander^, 1969,Montclair,NJ (USA)中。 Specific examples of such components may be found in the literature, for example, Fenaroli's Handbook of Flavor Ingredients, 1975, CRC Press; Synthetic Food Adjuncts, 1947, M · B · Jacobs with, Van Nostrand edit; or Perfume and Flavor Chemicals, S .Arctander ^, 1969, Montclair, NJ (USA) in.

[0129] 在制剂中存在多种香料组分是常见的。 [0129] There are a number of common perfume ingredients in the formulation. 在本发明的组合物中,设想将存在四种或更多种、优选五种或更多种、更优选六种或更多种、或甚至七种或更多种不同的香料组分。 In the compositions of the present invention, it is envisaged there will be four or more, preferably five or more, more preferably six or more or even seven or more different perfume components.

[0130] 在香料混合物中,优选15至25重量%是头香。 [0130] In perfume mixtures preferably 15 to 25 wt% are top notes. 头香是由Poucher (Journal of the Society of Cosmetic Chemists 6(2) :80[1955])所定义的。 Top notes by Poucher (Journal of the Society of Cosmetic Chemists 6 (2): 80 [1955]) as defined above. 优选的头香选自柑桔油、芳樟醇、乙酸芳樟酯、薰衣草、二氢月桂烯醇、氧化玫瑰和顺-3-己醇。 Preferred top-notes are selected from citrus oils, linalool, linalyl acetate, lavender, dihydromyrcenol, rose oxide and cis-3-hexanol.

[0131] 国际日用香精香料协会已在2011年发布了香氛成分(香料)的清单。 [0131] International Consumer Flavors & Fragrances Association has released a list of fragrance ingredients (spices) in 2011. (http:// www.ifraorg.org/en_us/ingredients#.U7Z4hPldWzk)〇 (Http: // www.ifraorg.org/en_us/ingredients#.U7Z4hPldWzk)〇

[0132] 国际日用香料研究所提供了具有安全性信息的香料(香氛)数据库。 [0132] International Institute for Fragrance offers spices (fragrance) database with information security.

[0133] 香料头香可用于提示本发明的白度和亮度益处。 [0133] fragrance top note may be used to cue the whiteness benefit of the present invention and brightness.

[0134] —些或所有香料可以被包封,有利于包封的典型香料组分包括具有相对低的沸点的那些,优选沸点小于300°C,优选为100_250°C的那些。 [0134] - Some or all of the perfume may be encapsulated, typical perfume encapsulated beneficial components include those having a boiling point of preferably relatively low boiling point less than 300 ° C, preferably of those 100_250 ° C. 包封具有低Clog P (S卩,将具有更高的被分配到水中的倾向的那些),优选具有小于3.0的CLog P的香料组分也是有利的。 Encapsulant having a low Clog P (S Jie, will have a higher tendency to be allocated to those of the water), preferably having a perfume component CLog P less than 3.0 is also advantageous. 这些具有相对低沸点和相对低CLog P的材料已经被称为“延迟释香(delayed blooming)”的香料成分,并且包含以下材料中的一种或多种:己酸烯丙酯、乙酸戊酯、丙酸戊酯、茴香醛、苯甲醚、苯甲醛、乙酸苄酯、节基丙酮、苯甲醇、甲酸苄酯、异戊酸苄酯、丙酸苄酯、β-γ己烯醇、 樟脑胶、左旋-香序酮、d-香序酮、肉桂醇、甲酸肉桂酯(cinamyl formate)、顺-茉莉酮、顺-3-己烯基乙酸酯、枯茗醇、cyclal c、二甲基苄基甲醇、二甲基苄基甲醇乙酸酯、乙酸乙酯、 乙酰乙酸乙酯、乙基戊基酮、苯甲酸乙酯、丁酸乙酯、乙基己基酮、乙基苯基乙酸酯、桉树脑、 丁香酸、乙酸蔚酯(fenchyl acetate)、flor acetate (三环癸稀基乙酸酯)、frutene (三环癸烯基丙酸酯)、香叶醇、己烯醇、乙酸己烯酯、乙酸己酯、甲酸己酯、龙葵醇(hydratropic alcohol)、轻基香茅醛、讳酮、异戊醇、异薄 These materials have a relatively low boiling point and relatively low CLog P has been referred to as "delayed flavor release (delayed blooming)" perfume ingredients, and materials comprising one or more of: allyl caproate, amyl acetate , amyl propionate, anisic aldehyde, anisole, benzaldehyde, benzyl acetate, acetone section, benzyl alcohol, benzyl formate, benzyl iso valerate, benzyl propionate, β-γ-hexenol, camphor gum, L - sequence fragrant ketone, d- sequence fragrant ketone, cinnamyl alcohol, cinnamyl formate (cinamyl formate), cis - jasmone, cis-3-hexenyl acetate, cuminic alcohol, cyclal c, dimethyl benzyl alcohol, dimethyl benzyl carbinol acetate, ethyl acetate, ethyl acetoacetate, ethyl amyl ketone, ethyl benzoate, ethyl butyrate, ethyl hexyl ketone, ethyl phenyl acetate acetate, cineole, eugenol, Wei acid ester (fenchyl acetate), flor acetate (tricyclo decyl lean-yl acetate), frutene (tricyclo decenyl propionate), geraniol, hexenol, hexenyl acetate, hexyl acetate, hexyl formate ester, Solanum nigrum alcohol (hydratropic alcohol), a light-yl citronellal, taboo ketone, isoamyl alcohol, isobutyl thin 荷酮、乙酸异胡薄荷酯(isopulegyl acetate)、 异喹啉酮、女贞醛、芳樟醇、芳樟醇氧化物、甲酸芳樟酯、薄荷酮、薄荷基苯乙酮(menthyl acetphenone)、甲基戊基酮、邻氨基苯甲酸甲酯、苯甲酸甲酯、甲基苄基乙酸酯(methy 1 benyl acetate)、甲基丁香酸、甲基庚稀酮、甲基庚炔碳酸酯(methyl heptine carbonate)、甲基庚基酮、甲基己基酮、甲基苯基甲基乙酸酯、水杨酸甲酯、甲基-η-甲基邻氨基苯甲酸酯、橙花醇、辛内酯、辛醇、对甲酚、对甲酚甲基醚、对甲氧基苯乙酮、对甲基苯乙酮、苯氧乙醇、苯基乙醛、苯基乙基乙酸酯、苯基乙基醇、苯基乙基二甲基甲醇、乙酸异戊二稀酯、propyl bornate、胡薄荷酮、氧化玫瑰、黄樟素、4-碗品稀醇(4-terpinenol)品烯醇和/或苯乙醛二甲醇缩醛(viridine)。 Dutch ketone, acetic acid ester isopulegol (isopulegyl acetate), isoquinolone, triplal, linalool, linalool oxide, linalyl formate, menthone, menthyl acetophenone (menthyl acetphenone), methyl amyl ketone, methyl anthranilate, methyl benzoate, methyl benzyl acetate (methy 1 benyl acetate), acid, methyl eugenol, methyl heptene ketone, methyl heptyl carbonate alkyne ( methyl heptine carbonate), methyl heptyl ketone, methyl hexyl ketone, methyl phenyl methyl acetate, methyl salicylate, methyl -η- methyl anthranilate, nerol, octalactone, octyl alcohol, p-cresol, p-cresol methyl ether, p-methoxy acetophenone, p-methyl acetophenone, phenoxy ethanol, phenyl acetaldehyde, phenyl ethyl acetate, phenylethyl alcohol, phenylethyl dimethyl carbinol, isoprene acid ester, propyl bornate, pulegone, rose oxide, safrole, 4 dilute alcohol product bowl (4-terpinenol) enol product and / or phenylacetaldehyde dimethylacetal acetal (viridine). 多种香料组分存在于制剂中是常见的。 More perfume ingredients present in the formulation are common. 在本发明的组合物中,设想将有来自上文给出的延迟释香香料的给定列表的四种或更多种,优选五种或更多种,更优选六种或更多种,或甚至七种或更多种不同的香料组分存在于香料中。 In the compositions of the present invention, it is envisaged there will be given a list of four delayed flavor release from the flavor given above or more, preferably five or more, more preferably six or more, or even seven or more different perfume components present in the perfume.

[0135] 可以与本发明一起应用的另一组香料是所谓的“芳香疗法”材料。 [0135] Another group of perfumes with the present invention can be applied with so-called 'aromatherapy' materials. 这些包括也用于香水中的许多组分,包括精油的组分如鼠尾草、桉树、天竺葵、薰衣草、肉豆蔻干皮(Mace)提取物、橙花油、肉豆蔻、留兰香、甜紫罗兰叶和缬草。 These also include a number of components used in perfumery, including components of essential oils such as sage, eucalyptus, geranium, lavender, mace (Mace) Extract, Neroli, Nutmeg, Spearmint, Sweet Violet leaf and valerian.

[0136] 优选的是洗衣处理组合物不含过氧漂白剂,例如过碳酸钠,过硼酸钠和过酸。 [0136] Preferably, the laundry treatment composition does not contain a peroxygen bleach, e.g., sodium percarbonate, sodium perborate, and peracid.

[0137] 除非另有规定,否则如本文中所用不定冠词“一个/种(a或an)”及其对应的定冠词“所述/该(the) ”指的是至少一个/种,或一个/种或多个/种。 [0137] Unless otherwise specified, as used herein, the indefinite article "a / species (a or AN)" and its corresponding definite article "the / the (The)" refers to at least a / species, or one / or more species / species.

[0138] 适验 [0138] Suitable test

[0139] 制备以下制剂,具有不同水平的盐和SRP添加。 [0139] The following formulations were prepared salts, having different horizontal and SRP added.

[0140] [0140]

Figure CN108884415AD00151

[0142] 所用的EPEI (乙氧基化聚乙烯亚胺)是600分子量的PEI,具有20摩尔乙氧基化物/ 基础PEI上的NH;它可以作为Sokalan HP20从BASF获得。 [0142] As used EPEI (ethoxylated polyethyleneimine) is a 600 molecular weight PEI, with the NH 20 mole ethoxylate / base the PEI; it can be used as Sokalan HP20 available from BASF.

[0143] SRP (去污聚合物)的使用量为0.0重量%和0.5重量%。 [0143] SRP (soil release polymer) is used in an amount of 0.0 wt% and 0.5 wt%. 所用的SRP是: SRP is used:

Figure CN108884415AD00152

[0145] SRP如W02014/019903 (Unilever)中所述。 [0145] SRP as W02014 / 019903 (Unilever) in the.

[0146] 使用Paar Physica MCR300测量制剂的粘度,其是商业应力流变仪。 Viscosity [0146] A Paar Physica MCR300 measured formulation, which is commercially stress rheometer.

[0147] 对于不存在SRP聚合物(0.0重量%)的制剂,结果列于下表中。 [0147] For the formulation does not exist SRP polymer (0.0 wt%) The results are shown in the following table.

[0148] [0148]

Figure CN108884415AD00161

[0149] 含有烷基醚羧酸的本发明制剂Fl和F2具有比具有单独的月桂基醚硫酸钠的对照更高的粘度。 [0149] Fl and F2 formulations of the present invention contains the alkyl ether carboxylic acid having a higher than the control alone of the viscosity of sodium lauryl ether sulfate.

[0150] 对于存在SRP聚合物(0.5重量%)的制剂,结果列于下表中。 [0150] SRP for the presence of the polymer formulation (0.5 wt%) The results are shown in the following table.

[0151] [0151]

Figure CN108884415AD00162

[0152] 含有烷基醚羧酸的本发明制剂Fl和F2具有比具有单独的月桂基醚硫酸钠的对照更高的粘度。 [0152] Fl and F2 formulations of the present invention contains the alkyl ether carboxylic acid having a higher than the control alone of the viscosity of sodium lauryl ether sulfate.

Claims (11)

1. 水性液体洗衣洗涤剂组合物,所述组合物包含: (i) 2至10重量%的直链烷基苯阴离子磺酸盐表面活性剂; (ii) 0 · 5至4重量%的选自氧化胺和羧基甜菜碱的两性离子表面活性剂; (iii) 0 · 1至4重量%的碱金属盐; (iv) 1至5重量%的烷氧基化聚乙烯亚胺; (V)I至10重量%的具有以下结构的烷基醚羧酸阴离子表面活性剂: R2- (OCH2CH2) H-OCH2-COOH 其中: R2选自饱和和单不饱和ClO至C26直链或支链烷基链,优选Cl 2至C20直链烷基链,最优选C16至C18直链烷基链,并且其中η选自6至20; (vi) 0至10重量%的烷基醚硫酸盐阴离子表面活性剂,其具有0.5至1.5摩尔当量的乙氧基化; (Vii)O至2重量%的对苯二甲酸酯聚酯去污聚合物; (viii) 0至4重量%的非离子表面活性剂;和, (ix) 0.0至0.2重量%的蛋白酶,其中所述洗衣洗涤剂组合物总共包含10至20重量%的阴离子表面活性剂。 An aqueous liquid laundry detergent composition, said composition comprising: (i) 2 to 10 wt% of linear alkylbenzene sulfonate anionic surfactant; (ii) 0 · 5 to 4 weight percent selected from the group from amine oxide and betaine zwitterionic surfactants; (iii) 0 · 1 to 4 weight percent of an alkali metal salt; (iv) 1 to 5 wt% of an alkoxylated polyethyleneimine; (V) I to 10% by weight of anionic alkyl ether carboxylate surfactant having the following structure: R2- (OCH2CH2) H-OCH2-COOH wherein: R2 is selected from saturated and mono-unsaturated ClO to C26 straight chain or branched chain alkyl chain, preferably Cl 2 to C20 linear alkyl chain, most preferably C16 to C18 linear alkyl chain, and wherein η is selected. 6 to 20; (vi) 0 to 10 wt% of an alkyl ether sulfate anionic surfactant agent, having a 0.5 to 1.5 molar equivalents of ethoxylation; (Vii) O to 2% by weight of polyester terephthalate soil release polymer; (VIII) nonionic surfactants 0-4% by weight agent; and, (ix) 0.0 to 0.2 wt% of a protease, wherein said laundry detergent composition comprises a total of 10 to 20% by weight of an anionic surfactant.
2. 根据权利要求1所述的水性液体洗衣洗涤剂组合物,其中所述组合物包含1.5至2.5重量%的两性离子表面活性剂和0.5至2重量%的碱金属盐。 The aqueous liquid laundry detergent composition according to claim 1, wherein the composition comprises 1.5 to 2.5 wt% zwitterionic surfactant, and 0.5 to 2% by weight alkali metal salt.
3. 根据权利要求1或2所述的水性液体洗衣洗涤剂组合物,其中所述组合物包含2.5至5重量%的烷基醚硫酸盐阴离子表面活性剂。 The aqueous liquid laundry detergent composition according to claim 1, wherein said composition comprises from 2.5 to 5 wt% of an alkyl ether sulfate anionic surfactant.
4. 根据前述权利要求中任一项所述的水性液体洗衣洗涤剂组合物,其中所述组合物包含3至5重量%的烷基醚羧酸阴离子表面活性剂。 4. The aqueous liquid laundry detergent composition according to any one of the preceding claims, wherein the composition comprises 3-5 wt% of alkyl ether carboxylate anionic surfactant.
5. 根据前述权利要求中任一项所述的水性液体洗衣洗涤剂组合物,其中所述组合物包含2.5至5重量%的直链烷基苯阴离子磺酸盐表面活性剂。 The aqueous liquid laundry detergent composition according to any one of the preceding claims, wherein said composition comprises from 2.5 to 5% by weight of linear alkyl benzene sulfonate anionic surfactant.
6. 根据前述权利要求中任一项所述的水性液体洗衣洗涤剂组合物,其中所述烷氧基化聚乙烯亚胺是乙氧基化聚乙烯亚胺。 6. The aqueous liquid laundry detergent composition according to any one of the preceding claims, wherein the alkoxylated polyethyleneimine, ethoxylated polyethyleneimine.
7. 根据前述权利要求中任一项所述的水性液体洗衣洗涤剂组合物,其中所述组合物包含0.2至1重量%的对苯二甲酸酯聚酯去污聚合物。 7. The aqueous liquid laundry detergent composition according to any one of the preceding claims, wherein said composition comprises from 0.2 to 1 wt% soil release polymer is a polyester terephthalate.
8. 根据权利要求7所述的水性液体洗衣洗涤剂组合物,其中所述对苯二甲酸酯聚酯去污聚合物是: The aqueous liquid laundry detergent composition according to claim 7, wherein said soil release polymer is polyester terephthalate:
Figure CN108884415AC00021
其中c是4至9; d是1到3; e是40到50。 Wherein c 4 to 9; d 1 to 3; e is 40 to 50.
9. 根据前述权利要求中任一项所述的水性液体洗衣洗涤剂组合物,其中η选自8至12,并且R2选自饱和和单不饱和C16至C18直链烷基链。 9. The aqueous liquid laundry detergent composition according to any one of the preceding claims, wherein η is selected from 8-12, and R2 is selected from saturated and mono-unsaturated C16 to C18 linear alkyl chain.
10. 根据前述权利要求中任一项所述的水性液体洗衣洗涤剂组合物,其中所述碱金属盐是氯化钠。 10. The aqueous liquid laundry detergent composition according to any one of the preceding claims, wherein the alkali metal salt is sodium chloride.
11. 一种处理纺织品的家用方法,所述方法包括以下步骤: ⑴用lg/L以上的前述权利要求中任一项所定义的洗衣洗涤剂组合物的水溶液处理纺织品;和, (ii)使所述水性洗衣洗涤剂溶液与所述纺织品保持接触10分钟至2天,然后漂洗和干燥所述纺织品。 11. A domestic method of treating a textile, the method comprising the steps of: treating a textile with an aqueous solution as defined in any one of the laundry detergent composition with the above ⑴ lg / L of the preceding claims; and, (ii) that the the aqueous laundry detergent solution to remain in contact with the textile 10 to 2 minutes, and then rinsing and drying the textile.
CN201780016754.8A 2016-03-21 2017-02-16 Laundry detergent composition CN108884415A (en)

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