CN108821648A - A kind of construction material of fire-proof and thermal-insulation and preparation method thereof - Google Patents

A kind of construction material of fire-proof and thermal-insulation and preparation method thereof Download PDF

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CN108821648A
CN108821648A CN201810797340.XA CN201810797340A CN108821648A CN 108821648 A CN108821648 A CN 108821648A CN 201810797340 A CN201810797340 A CN 201810797340A CN 108821648 A CN108821648 A CN 108821648A
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fire
thermal
proof
insulation
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张建
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/08Producing shaped prefabricated articles from the material by vibrating or jolting
    • B28B1/087Producing shaped prefabricated articles from the material by vibrating or jolting by means acting on the mould ; Fixation thereof to the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/50Producing shaped prefabricated articles from the material specially adapted for producing articles of expanded material, e.g. cellular concrete
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/52Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
    • B28B1/525Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement containing organic fibres, e.g. wood fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/245Curing concrete articles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/26Bituminous materials, e.g. tar, pitch
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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Abstract

The present invention provides a kind of construction material and preparation method thereof of fire-proof and thermal-insulation, is related to the field of building materials, and the construction material of fire-proof and thermal-insulation includes following raw material:Nanometer silicon carbide, stearyl alcohol, sepiolite powder, asbestos, calcium silicate powder, polyurethane, fibroin fiber, 1,4 butylene glycols, waste polyethylene plastic, phosphorus ore slag, diatomite, active carbon particle, mineral wool, cementitious material, retarder, thickener, foaming agent, water-reducing agent and water;Preparation method includes the following steps:(1)Weigh raw material,(2)Crush,(3)Stirring,(4)Moulding by casting, demoulding, stacking and maintenance.The construction material of fire-proof and thermal-insulation produced by the present invention has the advantages that heat insulation property is good, fire line is good, environmental protection and energy saving and compression strength are high.

Description

A kind of construction material of fire-proof and thermal-insulation and preparation method thereof
Technical field
The invention belongs to the field of building materials, and in particular to a kind of construction material of fire-proof and thermal-insulation and preparation method thereof.
Background technique
The implementation and development of building energy conservation, the construction material of fire-proof and thermal-insulation are increasingly valued by people.And make at present The construction material of fire-proof and thermal-insulation is not ideal enough in various performances, especially in thermal insulation property.
A kind of nanometer construction material and preparation method thereof for fire-proof and thermal-insulation of Chinese patent literature that on October 5th, 2016 is announced (Application number CN201410550852.8), the nanometer construction material of the fire-proof and thermal-insulation includes following component by weight:Nanometer 19-33 parts of silicon carbide, 12-26 parts of stearyl alcohol, 34-52 parts of sepiolite powder, 14-23 parts of asbestos, 8-17 parts of calcium silicate powder, polyurethane 18-26 parts, 3-6 parts of fibroin fiber, 7-12 parts of 1,4- butylene glycol.Steps are as follows for preparation method:(1) by sepiolite Powder and calcium silicate powder crush respectively;(2) nanometer silicon carbide, stearyl alcohol, sepiolite powder, asbestos, calcium silicate powder, polyurethane are taken, is added Heat is stirred, and high-temperature stirring is uniform;(3) fibroin fiber, 1,4- butylene two is added into the mixture of step (2) again Alcohol carries out high-temperature stirring again;(4) mixture is poured into building board with mold high temperature, is cooled to room temperature receiving for fire-proof and thermal-insulation Rice construction material.
But it when being applied to the building of high standard, heat preservation and fire protecting performance cannot still reach its requirement, and its To be improved in terms of environmental protection and energy saving and compressive property, therefore, it is necessary to be formulated it and its manufacture craft improves.
Summary of the invention
The purpose of the present invention is in view of the above problems, provide a kind of construction material of fire-proof and thermal-insulation and its preparation side Method, it is excellent that the construction material of fire-proof and thermal-insulation obtained has that heat insulation property is good, fire line is good, environmental protection and energy saving and compression strength are high Point.
The present invention provides the following technical solutions:
A kind of construction material of fire-proof and thermal-insulation, the raw material including following parts by weight:20-32 parts of nanometer silicon carbide, stearyl alcohol 14-22 Part, 35-41 parts of sepiolite powder, 14-23 parts of asbestos, 8-14 parts of calcium silicate powder, 18-22 parts of polyurethane, fibroin fiber 3-5 Part, 7-11 parts of 1,4 butylene glycol, 22-30 parts of waste polyethylene plastic, 17-21 parts of phosphorus ore slag, 17-31 parts of diatomite, active carbon 17-25 parts of particle, 13-21 parts of mineral wool, 19-25 parts of cementitious material, 0.2-0.4 parts of retarder, 0.3-0.5 parts of thickener, hair 0.5-1.1 parts of infusion, 0.1-0.5 parts of water-reducing agent and 5-9 parts of water.
Preferably, the raw material including following parts by weight:26 parts of nanometer silicon carbide, 18 parts of stearyl alcohol, 38 parts of sepiolite powder, stone 18.5 parts of cotton, 11 parts of calcium silicate powder, 20 parts of polyurethane, 4 parts of fibroin fiber, 9 parts of 1,4 butylene glycol, waste polyethylene modeling Expect 26 parts, 19 parts of phosphorus ore slag, 24 parts of diatomite, 21 parts of active carbon particle, 17 parts of mineral wool, 22 parts of cementitious material, retarder 0.3 Part, 0.4 part of thickener, 0.8 part of foaming agent, 0.3 part of water-reducing agent and 7 parts of water.
Waste polyethylene plastic and phosphorus ore slag are added in raw material, these industrial wastes and construction waste are shelved on city for a long time City, does not only take up urban land, and pollutes local environment, now by these industrial wastes and construction waste cycling and reutilization, Energy-saving and environment-friendly purpose is reached.
Waste polyethylene plastic has good heat insulating effect.
Phosphorus ore slag can be improved the compression strength of the construction material of the fire-proof and thermal-insulation.
Active carbon particle can adsorb the poisonous and harmful substance of formaldehyde etc. in air.
There are many tiny holes, in heat preservation insulation, sound absorption properties, corrosion resistance and chemical stability inside mineral wool Performance is good.
Diatomite has natural micropore structure, can be realized breathing damping, adsorbs toxic and offensive gases, and it also has Have the advantages that bulk density is light, good-extensibility, impact strength are high, tensile strength is high, heat-resisting, heat-insulated and fire-retardant.
Preferably, the cementitious material is waterglass, cement or pitch.
Preferably, the retarder is sodium pyrophosphate.
Preferably, the thickener is methylcellulose.
Preferably, the foaming agent is sodium carbonate or sodium bicarbonate.
Preferably, the water-reducing agent is naphthalene series high-efficiency water-reducing agent or lignin sulfonate water-reducing agent.
A kind of preparation method of the construction material of fire-proof and thermal-insulation, includes the following steps:
(1)Raw material is weighed according to the parts by weight of the raw material of building materials of fire-proof and thermal-insulation;
(2)Waste polyethylene plastic is put into pulverizer and crushes 20-30min to get crushed material;
(3)By step(2)Middle crushed material, nanometer silicon carbide, stearyl alcohol, sepiolite powder, asbestos, calcium silicate powder, polyurethane, fibroin Azelon, 1,4 butylene glycols, phosphorus ore slag, diatomite, active carbon particle, mineral wool and cementitious material are added in blender and stir 30-50min is mixed, other surplus stocks are then placed into, continues to stir 15-20min to get the mixed slurry after stirring;
(4)By step(3)The mixed slurry of preparation pours into building board with mold high temperature, and temperature when casting is controlled in 150- 180 DEG C, when casting, is smoothly put into vinyl house together along with vibration, building board and mold, covers plastic foil, rests It is demoulded after 2-3d, carries out the covering of palletizing plastic film, be put into vinyl house using solar energy curing 10-12d, then open plastic foil certainly So maintenance 20-28d.
Compared with prior art, the beneficial effects of the invention are as follows:
1, the present invention is by adding phosphorus ore slag, diatomite, work in the formula of the construction material to existing immediate fire-proof and thermal-insulation Property charcoal particle, mineral wool, cementitious material, retarder, thickener, foaming agent and water-reducing agent, and have developed the fire-proof and thermal-insulation The preparation method of construction material, the construction material of fire-proof and thermal-insulation obtained is with heat insulation property is good, fire line is good, environmental protection and energy saving The high advantage with compression strength, and preparation method is easy to operate.
2, heretofore described cementitious material is waterglass, cement or pitch, passes through the construction material for the fire-proof and thermal-insulation that is gelled Raw material so that construction material bonding it is stronger, improve the compression strength of the construction material entirety of fire-proof and thermal-insulation.
3, heretofore described retarder is sodium pyrophosphate, can delay that the raw material of building materials of fire-proof and thermal-insulation hardens when Between, so that raw material is stirred by stirring more uniform.
4, heretofore described thickener is methylcellulose, when can adjust the raw material of building materials stirring of fire-proof and thermal-insulation Viscosity so that stirring when mixed liquor have the characteristics of stable, anti-settling and thixotroping.
5, heretofore described foaming agent is sodium carbonate or sodium bicarbonate, improves the construction material foaming effect of fire-proof and thermal-insulation Fruit enhances its heat insulating effect.
6, heretofore described water-reducing agent is naphthalene series high-efficiency water-reducing agent or lignin sulfonate water-reducing agent, can reduce and use water Amount, improves the workability of mixed raw material.
Specific embodiment
Embodiment 1
A kind of construction material of fire-proof and thermal-insulation, the raw material including following weight:Nanometer silicon carbide 32kg, stearyl alcohol 22kg, Hai Pao Mountain flour 41kg, it asbestos 23kg, calcium silicate powder 14kg, polyurethane 22kg, fibroin fiber 5kg, 1,4 butylene glycol 11kg, gives up Abandon vinyon 30kg, phosphorus ore slag 21kg, diatomite 31kg, active carbon particle 25kg, mineral wool 21kg, cementitious material 25kg, retarder 0.4kg, thickener 0.5kg, foaming agent 1.1kg, water-reducing agent 0.5kg and water 9kg.
Waste polyethylene plastic and phosphorus ore slag are added in raw material, these industrial wastes and construction waste are shelved on city for a long time City, does not only take up urban land, and pollutes local environment, now by these industrial wastes and construction waste cycling and reutilization, Energy-saving and environment-friendly purpose is reached.
Waste polyethylene plastic has good heat insulating effect.
Phosphorus ore slag can be improved the compression strength of the construction material of the fire-proof and thermal-insulation.
Active carbon particle can adsorb the poisonous and harmful substance of formaldehyde etc. in air.
There are many tiny holes, in heat preservation insulation, sound absorption properties, corrosion resistance and chemical stability inside mineral wool Performance is good.
Diatomite has natural micropore structure, can be realized breathing damping, adsorbs toxic and offensive gases, and it also has Have the advantages that bulk density is light, good-extensibility, impact strength are high, tensile strength is high, heat-resisting, heat-insulated and fire-retardant.
A kind of preparation method of the construction material of fire-proof and thermal-insulation, includes the following steps:
(1)Raw material is weighed according to the weight of the raw material of building materials of fire-proof and thermal-insulation;
(2)Waste polyethylene plastic is put into pulverizer and crushes 20-30min to get crushed material;
(3)By step(2)Middle crushed material, nanometer silicon carbide, stearyl alcohol, sepiolite powder, asbestos, calcium silicate powder, polyurethane, fibroin Azelon, 1,4 butylene glycols, phosphorus ore slag, diatomite, active carbon particle, mineral wool and cementitious material are added in blender and stir 30-50min is mixed, other surplus stocks are then placed into, continues to stir 15-20min to get the mixed slurry after stirring;
(4)By step(3)The mixed slurry of preparation pours into building board with mold high temperature, and temperature when casting is controlled in 150- 180 DEG C, when casting, is smoothly put into vinyl house together along with vibration, building board and mold, covers plastic foil, rests It is demoulded after 2-3d, carries out the covering of palletizing plastic film, be put into vinyl house using solar energy curing 10-12d, then open plastic foil certainly So maintenance 20-28d.
Cementitious material is waterglass, cement or pitch, by the raw material of the construction material for the fire-proof and thermal-insulation that is gelled, so that building Material bonds stronger, improves the compression strength of the construction material entirety of fire-proof and thermal-insulation.
Retarder is sodium pyrophosphate, the time that the raw material of building materials of fire-proof and thermal-insulation can be delayed to harden, so that by stirring It mixes the more uniform of raw material stirring.
Thickener is methylcellulose, can adjust the viscosity when raw material of building materials stirring of fire-proof and thermal-insulation, so that Mixed liquor when stirring has the characteristics of stable, anti-settling and thixotroping.
Foaming agent is sodium carbonate or sodium bicarbonate, improves the construction material foaming effect of fire-proof and thermal-insulation, enhances its thermal insulation separation Thermal effect.
Water-reducing agent is naphthalene series high-efficiency water-reducing agent or lignin sulfonate water-reducing agent, can reduce water consumption, and it is former to improve mixing The workability of material.
Embodiment 2
A kind of construction material of fire-proof and thermal-insulation, the raw material including following weight:Nanometer silicon carbide 26kg, stearyl alcohol 18kg, Hai Pao Mountain flour 38kg, it asbestos 18.5kg, calcium silicate powder 11kg, polyurethane 20kg, fibroin fiber 4kg, 1,4 butylene glycol 9kg, gives up Abandon vinyon 26kg, phosphorus ore slag 19kg, diatomite 24kg, active carbon particle 21kg, mineral wool 17kg, cementitious material 22kg, retarder 0.3kg, thickener 0.4kg, foaming agent 0.8kg, water-reducing agent 0.3kg and water 7kg.
Waste polyethylene plastic and phosphorus ore slag are added in raw material, these industrial wastes and construction waste are shelved on city for a long time City, does not only take up urban land, and pollutes local environment, now by these industrial wastes and construction waste cycling and reutilization, Energy-saving and environment-friendly purpose is reached.
Waste polyethylene plastic has good heat insulating effect.
Phosphorus ore slag can be improved the compression strength of the construction material of the fire-proof and thermal-insulation.
Active carbon particle can adsorb the poisonous and harmful substance of formaldehyde etc. in air.
There are many tiny holes, in heat preservation insulation, sound absorption properties, corrosion resistance and chemical stability inside mineral wool Performance is good.
Diatomite has natural micropore structure, can be realized breathing damping, adsorbs toxic and offensive gases, and it also has Have the advantages that bulk density is light, good-extensibility, impact strength are high, tensile strength is high, heat-resisting, heat-insulated and fire-retardant.
A kind of preparation method of the construction material of fire-proof and thermal-insulation, includes the following steps:
(1)Raw material is weighed according to the weight of the raw material of building materials of fire-proof and thermal-insulation;
(2)Waste polyethylene plastic is put into pulverizer and crushes 20-30min to get crushed material;
(3)By step(2)Middle crushed material, nanometer silicon carbide, stearyl alcohol, sepiolite powder, asbestos, calcium silicate powder, polyurethane, fibroin Azelon, 1,4 butylene glycols, phosphorus ore slag, diatomite, active carbon particle, mineral wool and cementitious material are added in blender and stir 30-50min is mixed, other surplus stocks are then placed into, continues to stir 15-20min to get the mixed slurry after stirring;
(4)By step(3)The mixed slurry of preparation pours into building board with mold high temperature, and temperature when casting is controlled in 150- 180 DEG C, when casting, is smoothly put into vinyl house together along with vibration, building board and mold, covers plastic foil, rests It is demoulded after 2-3d, carries out the covering of palletizing plastic film, be put into vinyl house using solar energy curing 10-12d, then open plastic foil certainly So maintenance 20-28d.
Cementitious material is waterglass, cement or pitch, by the raw material of the construction material for the fire-proof and thermal-insulation that is gelled, so that building Material bonds stronger, improves the compression strength of the construction material entirety of fire-proof and thermal-insulation.
Retarder is sodium pyrophosphate, the time that the raw material of building materials of fire-proof and thermal-insulation can be delayed to harden, so that by stirring It mixes the more uniform of raw material stirring.
Thickener is methylcellulose, can adjust the viscosity when raw material of building materials stirring of fire-proof and thermal-insulation, so that Mixed liquor when stirring has the characteristics of stable, anti-settling and thixotroping.
Foaming agent is sodium carbonate or sodium bicarbonate, improves the construction material foaming effect of fire-proof and thermal-insulation, enhances its thermal insulation separation Thermal effect.
Water-reducing agent is naphthalene series high-efficiency water-reducing agent or lignin sulfonate water-reducing agent, can reduce water consumption, and it is former to improve mixing The workability of material.
Embodiment 3
A kind of construction material of fire-proof and thermal-insulation, the raw material including following weight:Nanometer silicon carbide 20kg, stearyl alcohol 14kg, Hai Pao Mountain flour 35kg, it asbestos 14kg, calcium silicate powder 8kg, polyurethane 18kg, fibroin fiber 3kg, 1,4 butylene glycol 7kg, discards Vinyon 22kg, phosphorus ore slag 17kg, diatomite 17kg, active carbon particle 17kg, mineral wool 13kg, cementitious material 19kg, Retarder 0.2kg, thickener 0.3kg, foaming agent 0.5kg, water-reducing agent 0.1kg and water 5kg.
Waste polyethylene plastic and phosphorus ore slag are added in raw material, these industrial wastes and construction waste are shelved on city for a long time City, does not only take up urban land, and pollutes local environment, now by these industrial wastes and construction waste cycling and reutilization, Energy-saving and environment-friendly purpose is reached.
Waste polyethylene plastic has good heat insulating effect.
Phosphorus ore slag can be improved the compression strength of the construction material of the fire-proof and thermal-insulation.
Active carbon particle can adsorb the poisonous and harmful substance of formaldehyde etc. in air.
There are many tiny holes, in heat preservation insulation, sound absorption properties, corrosion resistance and chemical stability inside mineral wool Performance is good.
Diatomite has natural micropore structure, can be realized breathing damping, adsorbs toxic and offensive gases, and it also has Have the advantages that bulk density is light, good-extensibility, impact strength are high, tensile strength is high, heat-resisting, heat-insulated and fire-retardant.
A kind of preparation method of the construction material of fire-proof and thermal-insulation, includes the following steps:
(1)Raw material is weighed according to the weight of the raw material of building materials of fire-proof and thermal-insulation;
(2)Waste polyethylene plastic is put into pulverizer and crushes 20-30min to get crushed material;
(3)By step(2)Middle crushed material, nanometer silicon carbide, stearyl alcohol, sepiolite powder, asbestos, calcium silicate powder, polyurethane, fibroin Azelon, 1,4 butylene glycols, phosphorus ore slag, diatomite, active carbon particle, mineral wool and cementitious material are added in blender and stir 30-50min is mixed, other surplus stocks are then placed into, continues to stir 15-20min to get the mixed slurry after stirring;
(4)By step(3)The mixed slurry of preparation pours into building board with mold high temperature, and temperature when casting is controlled in 150- 180 DEG C, when casting, is smoothly put into vinyl house together along with vibration, building board and mold, covers plastic foil, rests It is demoulded after 2-3d, carries out the covering of palletizing plastic film, be put into vinyl house using solar energy curing 10-12d, then open plastic foil certainly So maintenance 20-28d.
Cementitious material is waterglass, cement or pitch, by the raw material of the construction material for the fire-proof and thermal-insulation that is gelled, so that building Material bonds stronger, improves the compression strength of the construction material entirety of fire-proof and thermal-insulation.
Retarder is sodium pyrophosphate, the time that the raw material of building materials of fire-proof and thermal-insulation can be delayed to harden, so that by stirring It mixes the more uniform of raw material stirring.
Thickener is methylcellulose, can adjust the viscosity when raw material of building materials stirring of fire-proof and thermal-insulation, so that Mixed liquor when stirring has the characteristics of stable, anti-settling and thixotroping.
Foaming agent is sodium carbonate or sodium bicarbonate, improves the construction material foaming effect of fire-proof and thermal-insulation, enhances its thermal insulation separation Thermal effect.
Water-reducing agent is naphthalene series high-efficiency water-reducing agent or lignin sulfonate water-reducing agent, can reduce water consumption, and it is former to improve mixing The workability of material.
Embodiment 4
A kind of construction material of fire-proof and thermal-insulation, the raw material including following weight:Nanometer silicon carbide 28kg, stearyl alcohol 14kg, Hai Pao Mountain flour 36kg, it asbestos 16kg, calcium silicate powder 14kg, polyurethane 19kg, fibroin fiber 3kg, 1,4 butylene glycol 9kg, discards Vinyon 26kg, phosphorus ore slag 19kg, diatomite 19kg, active carbon particle 18kg, mineral wool 18kg, cementitious material 23kg, Retarder 0.3kg, thickener 0.3kg, foaming agent 0.8kg, water-reducing agent 0.2kg and water 5kg.
Waste polyethylene plastic and phosphorus ore slag are added in raw material, these industrial wastes and construction waste are shelved on city for a long time City, does not only take up urban land, and pollutes local environment, now by these industrial wastes and construction waste cycling and reutilization, Energy-saving and environment-friendly purpose is reached.
Waste polyethylene plastic has good heat insulating effect.
Phosphorus ore slag can be improved the compression strength of the construction material of the fire-proof and thermal-insulation.
Active carbon particle can adsorb the poisonous and harmful substance of formaldehyde etc. in air.
There are many tiny holes, in heat preservation insulation, sound absorption properties, corrosion resistance and chemical stability inside mineral wool Performance is good.
Diatomite has natural micropore structure, can be realized breathing damping, adsorbs toxic and offensive gases, and it also has Have the advantages that bulk density is light, good-extensibility, impact strength are high, tensile strength is high, heat-resisting, heat-insulated and fire-retardant.
A kind of preparation method of the construction material of fire-proof and thermal-insulation, includes the following steps:
(1)Raw material is weighed according to the weight of the raw material of building materials of fire-proof and thermal-insulation;
(2)Waste polyethylene plastic is put into pulverizer and crushes 20-30min to get crushed material;
(3)By step(2)Middle crushed material, nanometer silicon carbide, stearyl alcohol, sepiolite powder, asbestos, calcium silicate powder, polyurethane, fibroin Azelon, 1,4 butylene glycols, phosphorus ore slag, diatomite, active carbon particle, mineral wool and cementitious material are added in blender and stir 30-50min is mixed, other surplus stocks are then placed into, continues to stir 15-20min to get the mixed slurry after stirring;
(4)By step(3)The mixed slurry of preparation pours into building board with mold high temperature, and temperature when casting is controlled in 150- 180 DEG C, when casting, is smoothly put into vinyl house together along with vibration, building board and mold, covers plastic foil, rests It is demoulded after 2-3d, carries out the covering of palletizing plastic film, be put into vinyl house using solar energy curing 10-12d, then open plastic foil certainly So maintenance 20-28d.
Cementitious material is waterglass, cement or pitch, by the raw material of the construction material for the fire-proof and thermal-insulation that is gelled, so that building Material bonds stronger, improves the compression strength of the construction material entirety of fire-proof and thermal-insulation.
Retarder is sodium pyrophosphate, the time that the raw material of building materials of fire-proof and thermal-insulation can be delayed to harden, so that by stirring It mixes the more uniform of raw material stirring.
Thickener is methylcellulose, can adjust the viscosity when raw material of building materials stirring of fire-proof and thermal-insulation, so that Mixed liquor when stirring has the characteristics of stable, anti-settling and thixotroping.
Foaming agent is sodium carbonate or sodium bicarbonate, improves the construction material foaming effect of fire-proof and thermal-insulation, enhances its thermal insulation separation Thermal effect.
Water-reducing agent is naphthalene series high-efficiency water-reducing agent or lignin sulfonate water-reducing agent, can reduce water consumption, and it is former to improve mixing The workability of material.
Comparative example 1
A kind of construction material of fire-proof and thermal-insulation, the raw material including following weight:Nanometer silicon carbide 19kg, stearyl alcohol 12kg, Hai Pao Mountain flour 34kg, asbestos 14kg, calcium silicate powder 8kg, polyurethane 18kg, fibroin fiber 3kg, 1,4 butylene glycol 7kg and water 5kg。
A kind of preparation method of the construction material of fire-proof and thermal-insulation, includes the following steps:
(1)Raw material is weighed according to the weight of the raw material of building materials of fire-proof and thermal-insulation;
(2)Nanometer silicon carbide, stearyl alcohol, sepiolite powder, asbestos, calcium silicate powder and polyurethane are added in blender and stir 6- Then 10min places into other surplus stocks, continue to stir 15-20min to get the mixed slurry after stirring;
(3)By step(2)The mixed slurry of preparation pours into building board with mold high temperature, and temperature when casting is controlled in 160- 170 DEG C, when casting, is smoothly put into vinyl house together along with vibration, building board and mold, covers plastic foil, rests It is demoulded after 2-3d, carries out the covering of palletizing plastic film, be put into vinyl house using solar energy curing 10-11d, then open plastic foil certainly So maintenance 20-28d.
By in embodiment 1, embodiment 2, embodiment 3, embodiment 4 and comparative example 1 be made fire-proof and thermal-insulation construction material into Row performance test, test result are as shown in table 1:
Index Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Comparative example 1
Compression strength(28d)MPa 39.9 42.1 35.6 39.5 30.3
Thermal coefficient(W/m ﹒ k) 0.023 0.021 0.027 0.028 0.034
Fire-protection rating A1 A1 A1 A1 A2
Material loss slip(%) 35 33 35 36 0
From 1 data of table compare as can be seen that it is an advantage of the invention that:
1, a kind of construction material of fire-proof and thermal-insulation and preparation method thereof, from the construction material 28d pressure resistance of the fire-proof and thermal-insulation measured The compression strength value that angle value can be seen that embodiment 1-4 is above comparative example 1, and wherein the compression strength of embodiment 1 is higher by comparison Example 1 about 33.3% illustrates that the construction material compression strength of the fire-proof and thermal-insulation is high.
2, a kind of construction material of fire-proof and thermal-insulation and preparation method thereof, from the thermally conductive of the construction material of the fire-proof and thermal-insulation measured The thermal coefficient that coefficient can be seen that embodiment 1-4 is below comparative example 1, illustrates the construction material heat preservation effect of the fire-proof and thermal-insulation Fruit is good.
3, a kind of construction material of fire-proof and thermal-insulation and preparation method thereof, from the fire prevention of the construction material of the fire-proof and thermal-insulation measured The fire-protection rating that grade can be seen that embodiment 1-4 is superior to comparative example 1, illustrates the construction material fire line of the fire-proof and thermal-insulation It is good.
4, a kind of construction material of fire-proof and thermal-insulation and preparation method thereof, from the raw material of the construction material of the fire-proof and thermal-insulation measured The material loss slip that loss slip can be seen that embodiment 1-4 is above comparative example 1, illustrates building for the fire-proof and thermal-insulation The effects of energy conservation and environmental protection for building material is good.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation Technical solution documented by example is modified or equivalent replacement of some of the technical features, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (8)

1. a kind of construction material of fire-proof and thermal-insulation, which is characterized in that the raw material including following parts by weight:Nanometer silicon carbide 20-32 Part, 14-22 parts of stearyl alcohol, 35-41 parts of sepiolite powder, 14-23 parts of asbestos, 8-14 parts of calcium silicate powder, 18-22 parts of polyurethane, silk 3-5 parts of fibroin fiber, 7-11 parts of 1,4 butylene glycol, 22-30 parts of waste polyethylene plastic, 17-21 parts of phosphorus ore slag, diatomite 17-31 parts, 17-25 parts of active carbon particle, 13-21 parts of mineral wool, 19-25 parts of cementitious material, 0.2-0.4 parts of retarder, thickening 0.3-0.5 parts of agent, 0.5-1.1 parts of foaming agent, 0.1-0.5 parts of water-reducing agent and 5-9 parts of water.
2. the construction material of fire-proof and thermal-insulation according to claim 1, which is characterized in that the raw material including following parts by weight: 26 parts of nanometer silicon carbide, 18 parts of stearyl alcohol, 38 parts of sepiolite powder, 18.5 parts of asbestos, 11 parts of calcium silicate powder, polyurethane 20 part, thread 4 parts of fibroin fiber, 9 parts of 1,4 butylene glycol, 26 parts of waste polyethylene plastic, 19 parts of phosphorus ore slag, 24 parts of diatomite, active carbon 21 parts of particle, 17 parts of mineral wool, 22 parts of cementitious material, 0.3 part of retarder, 0.4 part of thickener, 0.8 part of foaming agent, water-reducing agent 0.3 part and 7 parts of water.
3. the construction material of fire-proof and thermal-insulation according to claim 1, it is characterised in that:The cementitious material be waterglass, Cement or pitch.
4. the construction material of fire-proof and thermal-insulation according to claim 1, it is characterised in that:The retarder is sodium pyrophosphate.
5. the construction material of fire-proof and thermal-insulation according to claim 1, it is characterised in that:The thickener is Methyl cellulose Element.
6. the construction material of fire-proof and thermal-insulation according to claim 1, it is characterised in that:The foaming agent is sodium carbonate or carbon Sour hydrogen sodium.
7. the construction material of fire-proof and thermal-insulation according to claim 1, it is characterised in that:The water-reducing agent subtracts for naphthalene series high-efficiency Aqua or lignin sulfonate water-reducing agent.
8. a kind of preparation method of the construction material of the fire-proof and thermal-insulation as described in claim 1-7 any one, feature exist In including the following steps:
(1)Raw material is weighed according to the parts by weight of the raw material of building materials of fire-proof and thermal-insulation;
(2)Waste polyethylene plastic is put into pulverizer and crushes 20-30min to get crushed material;
(3)By step(2)Middle crushed material, nanometer silicon carbide, stearyl alcohol, sepiolite powder, asbestos, calcium silicate powder, polyurethane, fibroin Azelon, 1,4 butylene glycols, phosphorus ore slag, diatomite, active carbon particle, mineral wool and cementitious material are added in blender and stir 30-50min is mixed, other surplus stocks are then placed into, continues to stir 15-20min to get the mixed slurry after stirring;
(4)By step(3)The mixed slurry of preparation pours into building board with mold high temperature, and temperature when casting is controlled in 150- 180 DEG C, when casting, is smoothly put into vinyl house together along with vibration, building board and mold, covers plastic foil, rests It is demoulded after 2-3d, carries out the covering of palletizing plastic film, be put into vinyl house using solar energy curing 10-12d, then open plastic foil certainly So maintenance 20-28d.
CN201810797340.XA 2018-07-19 2018-07-19 A kind of construction material of fire-proof and thermal-insulation and preparation method thereof Withdrawn CN108821648A (en)

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Publication number Priority date Publication date Assignee Title
CN111822080A (en) * 2020-07-16 2020-10-27 卫凤仪 Processing method of high-strength environment-friendly concrete
CN113527866A (en) * 2021-08-04 2021-10-22 安徽省宁合建筑工程有限公司 Environment-friendly material for building decoration engineering and preparation method thereof
CN114180928A (en) * 2021-11-01 2022-03-15 宁波侨兴新材料科技发展有限公司 Zero-carbon building material reinforced fiber material and application thereof
CN114276063A (en) * 2022-01-05 2022-04-05 绍兴文理学院元培学院 Light building material and preparation method thereof

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WO1982001544A1 (en) * 1980-10-30 1982-05-13 Motoki Hideo Composition for producing inorganic foam
CN107032738A (en) * 2017-06-06 2017-08-11 合肥月煌新型装饰材料有限公司 A kind of construction material of environmental protection and energy saving and preparation method thereof
CN107188514A (en) * 2017-06-08 2017-09-22 合肥华盖光伏科技有限公司 A kind of construction material of fire-proof and thermal-insulation and preparation method thereof

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CN107032738A (en) * 2017-06-06 2017-08-11 合肥月煌新型装饰材料有限公司 A kind of construction material of environmental protection and energy saving and preparation method thereof
CN107188514A (en) * 2017-06-08 2017-09-22 合肥华盖光伏科技有限公司 A kind of construction material of fire-proof and thermal-insulation and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111822080A (en) * 2020-07-16 2020-10-27 卫凤仪 Processing method of high-strength environment-friendly concrete
CN111822080B (en) * 2020-07-16 2021-10-08 舟山恒尊预拌混凝土有限公司 Processing method of high-strength environment-friendly concrete
CN113527866A (en) * 2021-08-04 2021-10-22 安徽省宁合建筑工程有限公司 Environment-friendly material for building decoration engineering and preparation method thereof
CN114180928A (en) * 2021-11-01 2022-03-15 宁波侨兴新材料科技发展有限公司 Zero-carbon building material reinforced fiber material and application thereof
CN114276063A (en) * 2022-01-05 2022-04-05 绍兴文理学院元培学院 Light building material and preparation method thereof

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