CN108796220A - 一种铋铁混合溶液中萃取-硫化转相分离铋和铁的方法 - Google Patents
一种铋铁混合溶液中萃取-硫化转相分离铋和铁的方法 Download PDFInfo
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- CN108796220A CN108796220A CN201810723321.2A CN201810723321A CN108796220A CN 108796220 A CN108796220 A CN 108796220A CN 201810723321 A CN201810723321 A CN 201810723321A CN 108796220 A CN108796220 A CN 108796220A
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- CN
- China
- Prior art keywords
- bismuth
- iron
- mixed solution
- separation
- purity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052797 bismuth Inorganic materials 0.000 title claims abstract description 82
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 title claims abstract description 82
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 67
- RDQSSKKUSGYZQB-UHFFFAOYSA-N bismuthanylidyneiron Chemical compound [Fe].[Bi] RDQSSKKUSGYZQB-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 238000000926 separation method Methods 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 37
- 239000011259 mixed solution Substances 0.000 title claims abstract description 36
- 238000004073 vulcanization Methods 0.000 title claims abstract description 15
- 229910052742 iron Inorganic materials 0.000 title abstract description 21
- 238000000605 extraction Methods 0.000 claims abstract description 56
- NNLOHLDVJGPUFR-UHFFFAOYSA-L calcium;3,4,5,6-tetrahydroxy-2-oxohexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(=O)C([O-])=O.OCC(O)C(O)C(O)C(=O)C([O-])=O NNLOHLDVJGPUFR-UHFFFAOYSA-L 0.000 claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 claims abstract description 21
- 239000012074 organic phase Substances 0.000 claims abstract description 19
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 10
- 230000001172 regenerating effect Effects 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 28
- 239000012071 phase Substances 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 14
- 239000000284 extract Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 7
- 239000011707 mineral Substances 0.000 claims description 7
- 230000002195 synergetic effect Effects 0.000 claims description 7
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 5
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 claims description 5
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical group CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims description 4
- 229910001447 ferric ion Inorganic materials 0.000 claims description 4
- 239000003085 diluting agent Substances 0.000 claims description 3
- 229910001448 ferrous ion Inorganic materials 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000003350 kerosene Substances 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims 2
- 230000005611 electricity Effects 0.000 claims 1
- 229910001451 bismuth ion Inorganic materials 0.000 abstract description 4
- 238000001556 precipitation Methods 0.000 abstract description 3
- 238000009856 non-ferrous metallurgy Methods 0.000 abstract description 2
- 238000007670 refining Methods 0.000 abstract description 2
- 150000002500 ions Chemical class 0.000 abstract 2
- 230000008569 process Effects 0.000 description 16
- 239000000843 powder Substances 0.000 description 10
- 238000002386 leaching Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000004070 electrodeposition Methods 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- 230000008929 regeneration Effects 0.000 description 7
- 238000011069 regeneration method Methods 0.000 description 7
- 239000013049 sediment Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 239000006228 supernatant Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 238000003723 Smelting Methods 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- -1 iron ion Chemical class 0.000 description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical group Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- IEVWNXLJUKRPPX-UHFFFAOYSA-N bismuth azane Chemical compound N.[Bi+3] IEVWNXLJUKRPPX-UHFFFAOYSA-N 0.000 description 2
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 description 2
- 229910000416 bismuth oxide Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 208000003351 Melanosis Diseases 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- PEEDYJQEMCKDDX-UHFFFAOYSA-N antimony bismuth Chemical compound [Sb].[Bi] PEEDYJQEMCKDDX-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- FIMTUWGINXDGCK-UHFFFAOYSA-H dibismuth;oxalate Chemical compound [Bi+3].[Bi+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O FIMTUWGINXDGCK-UHFFFAOYSA-H 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 206010020718 hyperplasia Diseases 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- ZVFDEWVVVBNBHW-UHFFFAOYSA-N nitrous acid hydrochloride Chemical compound Cl.ON=O ZVFDEWVVVBNBHW-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
- C22B3/46—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes by substitution, e.g. by cementation
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/28—Amines
- C22B3/288—Quaternary ammonium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B30/00—Obtaining antimony, arsenic or bismuth
- C22B30/06—Obtaining bismuth
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
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CN201810723321.2A CN108796220B (zh) | 2018-07-04 | 2018-07-04 | 一种铋铁混合溶液中萃取-硫化转相分离铋和铁的方法 |
Applications Claiming Priority (1)
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CN201810723321.2A CN108796220B (zh) | 2018-07-04 | 2018-07-04 | 一种铋铁混合溶液中萃取-硫化转相分离铋和铁的方法 |
Publications (2)
Publication Number | Publication Date |
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CN108796220A true CN108796220A (zh) | 2018-11-13 |
CN108796220B CN108796220B (zh) | 2020-03-24 |
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CN201810723321.2A Active CN108796220B (zh) | 2018-07-04 | 2018-07-04 | 一种铋铁混合溶液中萃取-硫化转相分离铋和铁的方法 |
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CN (1) | CN108796220B (zh) |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1990004654A1 (de) * | 1988-10-28 | 1990-05-03 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur abtrennung von störelementen aus wertmetall-elektrolytlösungen |
CN1134989A (zh) * | 1995-01-12 | 1996-11-06 | 住友金属矿山株式会社 | 从铜电解液中回收锑和铋的方法 |
CN1297067A (zh) * | 1999-11-23 | 2001-05-30 | 北京矿冶研究总院 | 一种采用溶剂萃取净化铜电解液的方法 |
CN101376929A (zh) * | 2008-09-27 | 2009-03-04 | 中南大学 | 一种从铋精矿或含铋物料中提取铋的方法 |
CN103484694A (zh) * | 2013-08-25 | 2014-01-01 | 云南锡业集团有限责任公司研究设计院 | 一种从铜铋精矿中提取铋的方法 |
CN103849902A (zh) * | 2014-03-25 | 2014-06-11 | 金隆铜业有限公司 | 铜电解液中锑和铋的回收工艺 |
CN104060106A (zh) * | 2014-06-09 | 2014-09-24 | 中南大学 | 从含铋溶液中用溶剂萃取法提取铋及制备氧化铋的方法 |
CN107715860A (zh) * | 2017-08-21 | 2018-02-23 | 中南大学 | 一种三氧化二铋光催化剂的制备及其应用 |
-
2018
- 2018-07-04 CN CN201810723321.2A patent/CN108796220B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1990004654A1 (de) * | 1988-10-28 | 1990-05-03 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur abtrennung von störelementen aus wertmetall-elektrolytlösungen |
CN1134989A (zh) * | 1995-01-12 | 1996-11-06 | 住友金属矿山株式会社 | 从铜电解液中回收锑和铋的方法 |
CN1297067A (zh) * | 1999-11-23 | 2001-05-30 | 北京矿冶研究总院 | 一种采用溶剂萃取净化铜电解液的方法 |
CN101376929A (zh) * | 2008-09-27 | 2009-03-04 | 中南大学 | 一种从铋精矿或含铋物料中提取铋的方法 |
CN103484694A (zh) * | 2013-08-25 | 2014-01-01 | 云南锡业集团有限责任公司研究设计院 | 一种从铜铋精矿中提取铋的方法 |
CN103849902A (zh) * | 2014-03-25 | 2014-06-11 | 金隆铜业有限公司 | 铜电解液中锑和铋的回收工艺 |
CN104060106A (zh) * | 2014-06-09 | 2014-09-24 | 中南大学 | 从含铋溶液中用溶剂萃取法提取铋及制备氧化铋的方法 |
CN107715860A (zh) * | 2017-08-21 | 2018-02-23 | 中南大学 | 一种三氧化二铋光催化剂的制备及其应用 |
Also Published As
Publication number | Publication date |
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CN108796220B (zh) | 2020-03-24 |
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