CN108773129A - 一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法和应用 - Google Patents

一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法和应用 Download PDF

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CN108773129A
CN108773129A CN201810678811.5A CN201810678811A CN108773129A CN 108773129 A CN108773129 A CN 108773129A CN 201810678811 A CN201810678811 A CN 201810678811A CN 108773129 A CN108773129 A CN 108773129A
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parts
glass
silver
codope
doubling
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CN108773129B (zh
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方桂华
方贵龙
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Guangzhou Yi Yi Industrial Co Ltd
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Abstract

本发明公开了一种纳米铂‑银共掺杂夹胶热伏玻璃的制备方法，其特征在于，包括以下步骤：S1、在反应釜中加入以下重量份数的纳米铂‑银共掺杂粉(5～25份)、纳米铈‑铝共掺杂氧化锌粉(5～25份)、丙烯酸树脂(10～25份)、硅丙树脂(10～25份)、水(10～30份)和助剂(5～25份)，搅拌后得到液体状的合成物；S2、将S1得到的合成物淋涂到玻璃表面自干或烘干；S3、将步骤S2自干或烘干后的玻璃在压力反应釜中进行夹胶。本发明制备工艺简单，纳米铂‑银共掺杂夹胶热伏玻璃储能传热效率高，抗老化能力强。

Description

一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法和应用
技术领域
本发明涉及功能性涂料领域，尤其涉及一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法和应用。
背景技术
目前太阳能的利用主要是利用太阳能辐射通过层压入太阳能电池，通过光线透过率产生电能。热伏玻璃是一种透光率高的新材料科技产品，通过把太阳光辐射阻隔在玻璃上面，这样太阳能辐射形成的能量转化为热能，热能传导到特种金属线上，通过逆变的形式进入蓄电池中形成电能。
本发明旨在提供一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法。
发明内容
有鉴于此，本发明旨在提供一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法。
一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法，包括以下步骤：
S1、在反应釜中加入以下重量份数的纳米铂-银共掺杂粉(5～25份)、纳米铈-铝共掺杂氧化锌粉(5～25份)、丙烯酸树脂(10～25份)、硅丙树脂(10～25份)、水(10～30份)和助剂(5～25份)，搅拌后得到液体状的合成物；
S2、将S1得到的合成物淋涂到玻璃表面自干或烘干；
S3、将步骤S2自干或烘干后的玻璃在压力反应釜中进行夹胶。
通过铈-铝共掺杂氧化锌将太阳光阻隔在玻璃上面，太阳光辐射产生的能量转化为热能积攒在合成物中，热能通过铂-银共掺杂粉传导到特种金属线上，通过逆变的形式进入蓄电池中形成电能。
本发明合成物对玻璃具有良好的附着力，铈-铝共掺杂氧化锌对太阳光有较强的阻挡能力，使玻璃积攒较多太阳光辐射产生的热能，热能经传热性能良好的铂-银共掺杂粉传递，传递效率高；另外，本发明合成物由于本身具有较强的储能传热能力，长期在太阳光照射下性质稳定，抗老化能力强。
优选的，步骤S3夹胶材料采用PVB或EVA。
PVB与EVB对玻璃以及本发明合成物具有较强的粘合能力，制得的热伏玻璃结构稳定。
优选的，步骤S3夹胶时压力反应釜中进行。
自干或烘干后的合成物与玻璃的附着力最强。
优选的，步骤S2中玻璃进行自干或烘干。
优选的，所述助剂包括分散剂、附着力促进剂、消泡剂中的至少一种。
分散剂有助于合成物中各组分的分散，尤其是纳米铂-银共掺杂粉和纳米铈-铝共掺杂氧化锌粉的分散，从而加强热伏玻璃整体的储能传热性能。
附着力促进剂有助于提高合成物与玻璃、胶层的附着力，提高热伏玻璃的结构稳定性。
消泡剂消除合成物中的气泡，防止合成物自干或烘干之后存在气泡，避免热伏玻璃的储能传热性能受影响。
本发明纳米铂-银共掺杂夹胶热伏玻璃应用于建筑物窗户。
本发明与现有技术相比，具有如下优点与有益效果：
本发明制备工艺简单，纳米铂-银共掺杂夹胶热伏玻璃储能传热效率高，抗老化能力强。
具体实施方式
实施例1
本实施例提供一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法，包括以下步骤：
S1、在反应釜中加入以下重量份数的纳米铂-银共掺杂粉5份、纳米铈-铝共掺杂氧化锌粉5份、丙烯酸树脂10份、硅丙树脂10份、水10和分散剂5份，搅拌后得到液体状的合成物；
S2、将S1得到的合成物淋涂到玻璃表面自干或烘干；
S3、将步骤S2自干或烘干后的玻璃在压力反应釜中进行夹胶。
步骤S3夹胶材料采用PVB。
步骤S3夹胶时压力反应釜进行。
步骤S2中玻璃进行自干或烘干。
实施例2
本实施例提供一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法，包括以下步骤：
S1、在反应釜中加入以下重量份数的纳米铂-银共掺杂粉25份、纳米铈-铝共掺杂氧化锌粉25份、丙烯酸树脂25份、硅丙树脂25份、水30份和附着力促进剂25份，搅拌后得到液体状的合成物；
S2、将S1得到的合成物淋涂到玻璃表面自干或烘干；
S3、将步骤S2自干或烘干后的玻璃在压力反应釜中进行夹胶。
步骤S3夹胶材料采用EVA。
步骤S3夹胶时压力反应釜进行。
步骤S2中玻璃进行自干或烘干。
实施例3
本实施例提供一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法，包括以下步骤：
S1、在反应釜中加入以下重量份数的纳米铂-银共掺杂粉15份、纳米铈-铝共掺杂氧化锌粉15份、丙烯酸树脂17份、硅丙树脂18份、水20份和消泡剂15份，搅拌后得到液体状的合成物；
S2、将S1得到的合成物淋涂到玻璃进行自干或烘干；
S3、将步骤S2自干或烘干后的玻璃在压力反应釜中进行夹胶。
步骤S3夹胶材料采用EVA。
步骤S3夹胶时压力反应釜中进行。
步骤S2中玻璃进行自干或烘干。
实施例4
本实施例提供一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法，包括以下步骤：
S1、在反应釜中加入以下重量份数的纳米铂-银共掺杂粉15份、纳米铈-铝共掺杂氧化锌粉15份、丙烯酸树脂17份、硅丙树脂18份、水20份、消泡剂15份、分散剂5份和附着力促进剂5份，搅拌后得到液体状的合成物；
S2、将S1得到的合成物淋涂到玻璃表面自干或烘干；
S3、将步骤S2自干或烘干后的玻璃在压力反应釜中进行夹胶。
步骤S3夹胶材料采用EVA。
步骤S3夹胶时压力反应釜温中进行。
步骤S2中玻璃进行自干或烘干。
以上为本发明的其中具体实现方式，其描述较为具体和详细，但并不能因此而理解为对本发明专利范围的限制。对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些显而易见的替换形式均属于本发明的保护范围。

Claims (6)

1.一种纳米铂-银共掺杂夹胶热伏玻璃的制备方法，其特征在于，包括以下步骤：
S1、在反应釜中加入以下重量份数的纳米铂-银共掺杂粉(5～25份)、纳米铈-铝共掺杂氧化锌粉(5～25份)、丙烯酸树脂(10～25份)、硅丙树脂(10～25份)、水(10～30份)和助剂(5～25份)，搅拌后得到液体状的合成物；
S2、将S1得到的合成物淋涂到玻璃表面自干或烘干；
S3、将步骤S2自干或烘干后的玻璃在压力反应釜中进行夹胶。
2.根据权利要求1所述的纳米铂-银共掺杂夹胶热伏玻璃的制备方法，其特征在于，步骤S3夹胶材料采用PVB或EVA。
3.根据权利要求2所述的纳米铂-银共掺杂夹胶热伏玻璃的制备方法，其特征在于，步骤S3夹胶时压力反应釜中进行。
4.根据权利要求1所述的纳米铂-银共掺杂夹胶热伏玻璃的制备方法，其特征在于，步骤S2中玻璃进行自干或烘干。
5.根据权利要求1所述的纳米铂-银共掺杂夹胶热伏玻璃的制备方法，其特征在于，所述助剂包括分散剂、附着力促进剂、消泡剂中的至少一种。
6.一种如权利要求1-5任意一项权利要求所述制备方法制成的纳米铂-银共掺杂夹胶热伏玻璃的应用，其特征在于，所述纳米铂-银共掺杂夹胶热伏玻璃应用于建筑物窗户。
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