CN108752140A - A kind of charcoal base manure material and preparation method thereof - Google Patents
A kind of charcoal base manure material and preparation method thereof Download PDFInfo
- Publication number
- CN108752140A CN108752140A CN201810930008.6A CN201810930008A CN108752140A CN 108752140 A CN108752140 A CN 108752140A CN 201810930008 A CN201810930008 A CN 201810930008A CN 108752140 A CN108752140 A CN 108752140A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- mixture
- powder
- charcoal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Plant Pathology (AREA)
- Fertilizers (AREA)
Abstract
A kind of preparation method of charcoal base manure material, includes the following steps:5-25 parts by weight charcoals are taken to dry, it is broken to sieve with 100 mesh sieve;Take 5-15 parts by weight of binder, crushing sieves with 100 mesh sieve, 25-50 parts by weight of urea, 5-20 parts by weight ammonium chloride, 5-20 parts by weight potassium chloride, one hydrogen ammonium of 5-20 parts by weight of phosphoric acid, 2-10 parts by weight ammonium hydrogen carbonate are taken, is mixed with broken charcoal, stirring 5min obtains the first mixture;It takes 5-15 parts by weight of binder and the first mixture that 10min is mixed and obtains the second mixture, it is granulated at 60-85 DEG C after the biomass pyrolysis liquid stirring 10min for accounting for the second total weight of the mixture 4%-10% is added in the second mixture, grain size 3-5mm, quality 0.1-0.5g.The charcoal base manure material energy antibacterial desinsection of this method preparation improves environment and soil quality, improves crop yield.
Description
Technical field
The present invention relates to a kind of methods that biomass pyrolysis liquid prepares charcoal base manure material.
Background technology
China is large agricultural country, is most abundant one of the country of stalk resource.Nearly 20 years, the grain-production in China increased year after year
It receives, but is the substantial increase of stalk resource in the behind of the big volume increase of this grain, but so many stalk resource, only less than
One third realizes straw-returning, remaining is all burned off or wastes, if by the crops returning to the field such as these stalks,
Whether to soil environment, improving soil quality all has enormous benefits.
Agricultural crop straw will produce many byproducts, including three kinds of liquid, gaseous state and solid-state during preparing charcoal
The substance of form, the flue gas natural cooling liquefaction emerged during firing, the liquid of formation is exactly biomass pyrolysis liquid.Mesh
Preceding more and more enterprises start to prepare charcoal, these by-products of generation are also more and more, if cannot be timely and effectively
Processing, it will more serious secondary pollution is generated to environment.
Invention content
It is prepared as raw material using charcoal and biomass pyrolysis liquid technical problem to be solved by the invention is to provide a kind of
Charcoal base manure material, can antibacterial desinsection, improvement environment and soil quality, raising crop yield.
Another technical problem to be solved by this invention is to provide a kind of preparation method of charcoal base manure material, this method step
Simply, easy to operate, raw material is easy to get, and is suitble to promote the use of in industry.
In order to solve the above technical problems, the present invention provides a kind of charcoal base manure material, which is made by following methods:
(1) charcoal of 5-25 parts by weight is taken to dry in an oven, oven temperature is 105 DEG C, time 2h, then by it
It is broken, it sieves with 100 mesh sieve;
(2) adhesive for taking 5-15 parts by weight smashes it through 100 mesh sieve, then takes the urea powder of 25-50 parts by weight, 5-
The ammonium chloride powder of 20 parts by weight, the potassium chloride powder of 5-20 parts by weight, the monoammonium phosphate powder of 5-20 parts by weight, 2-10 weights
The ammonium hydrogen carbonate powder for measuring part, then mixes with step (1) broken charcoal, and stirring 5min obtains the first mixture;
(3) continue stirring 10min after taking the adhesive of 5-15 parts by weight to mix with the first mixture obtained by step (2) to obtain
To the second mixture, the mass ratio of the mixture that wherein adhesive is made of corn flour and white sugar, corn flour and white sugar is:1:
3-5:3;
(4) biology for accounting for the second total weight of the mixture 4%-10% is added in through the second mixture obtained by step (3)
10min is mixed in matter pyrolytic behavior, is then added in fertilizer granulator and is granulated at 60-85 DEG C, the diameter of individual particle
For 3-5mm, quality 0.1-0.5g.
A kind of preparation method of charcoal base manure material, includes the following steps:
(1) charcoal of 5-25 parts by weight is taken to dry in an oven, oven temperature is 105 DEG C, time 2h, then by it
It is broken, it sieves with 100 mesh sieve;
(2) adhesive for taking 5-15 parts by weight smashes it through 100 mesh sieve, then takes the urea powder of 25-50 parts by weight, 5-
The ammonium chloride powder of 20 parts by weight, the potassium chloride powder of 5-20 parts by weight, the monoammonium phosphate powder of 5-20 parts by weight, 2-10 weights
The ammonium hydrogen carbonate powder for measuring part, then mixes with step (1) broken charcoal, and stirring 5min obtains the first mixture;
(3) continue stirring 10min after taking the adhesive of 5-15 parts by weight to mix with the first mixture obtained by step (2) to obtain
To the second mixture, the mass ratio of the mixture that wherein adhesive is made of corn flour and white sugar, corn flour and white sugar is:1:
3-5:3;
(4) biology for accounting for the second total weight of the mixture 4%-10% is added in through the second mixture obtained by step (3)
10min is mixed in matter pyrolytic behavior, is then added in fertilizer granulator and is granulated at 60-85 DEG C, the diameter of individual particle
For 3-5mm, quality 0.1-0.5g.
Preferably, using 12.5 parts by weight charcoals in the step (1), 7.5 are used in the step (2)
The potassium chloride powder of the attapulgite of parts by weight, the urea powder of 40 parts by weight, the ammonium chloride powder of 15 parts by weight, 12.5 parts by weight
Last, the monoammonium phosphate powder of 10 parts by weight, 4 parts by weight ammonium hydrogen carbonate powder, the step (3) is middle to use 4 parts by weight
Adhesive, the mass ratio of corn flour and white sugar is 2:3.In the step (4) plus the amount of biomass pyrolysis liquid accounts for second and mixes
The 4% of object total weight is closed, prilling temperature is 65.5 DEG C, a diameter of 4.3mm, the quality 0.3g of individual particle.
Biomass pyrolysis liquid can inhibit the breeding of miscellaneous bacteria, have the effect of fungi-proofing, insect prevention, while can also promote plant
Growth.Furthermore it is also possible to improve soil, biomass pyrolysis liquid sprinkling can be prevented to the damping-off of seed in the soil,
It can be used as the disinfectant of soil.Bamboo vinegar liquid energy is applied in soil effectively inhibits the breeding for hindering the microbiology class of plant growth, and
The pests such as knot nematodes can be killed.
Charcoal can increase the soil organism and content of mineral substances (potassium element, element silicon etc.), and chesson improves soil
Character improves the soil moisture, adjusts soil acidity or alkalinity.
Urea is a kind of high concentration nitrogenous fertilizer, belongs to neutral quick-acting fertilizer.Not residual harmful substance in the soil.
Ammonium chloride is a kind of quick-acting nitrogen chemical fertilizer, it is suitable for the crops such as wheat, rice, corn, rape.
Potassium chloride is one of primary raw material of potash fertilizer, and fertilizer efficiency is fast, is directly applied to farmland, on Neng Shi soil lower layer moisture
It rises, there is drought resisting.
Monoammonium phosphate is mainly used as high concentration N phosphorus composite fertilizer, is a kind of high efficiency fertilizer being widely used in crops
Material.
Ammonium hydrogen carbonate is used as nitrogenous fertilizer, is suitable for various soil, can provide the ammonium nitrogen and dioxy needed for plant growth simultaneously
Change carbon.
Advantages of the present invention:
A kind of charcoal base manure material provided by the present invention, energy antibacterial desinsection, improvement environment and soil quality, raising make produce
Amount.In addition, its raw material uses charcoal and biomass pyrolysis liquid, biomass pyrolysis liquid be generated in charcoal preparation process it is useless
Material, its value can be promoted by using it for making charcoal base manure material, avoided the wasting of resources, reached resource reutilization, environmental protection
Purpose.
A kind of preparation method of charcoal base manure material provided by the present invention, this method step is simple, easy to operate, and raw material is easy
, it is suitble to promote the use of in industry.
Specific implementation mode
Embodiment one:
A kind of method that biomass pyrolysis liquid prepares charcoal base manure material, includes the following steps:
(1) charcoal of 5 parts by weight is taken to dry in an oven, oven temperature is 105 DEG C, then time 2h is broken
It is broken, it sieves with 100 mesh sieve;
(2) attapulgite for taking 5 parts by weight smashes it through 100 mesh sieve, then takes the urea powder of 30 parts by weight, 10 weight
The ammonium chloride powder of part, the ammonium hydrogen carbonate of the potassium chloride powder of 5 parts by weight, the monoammonium phosphate powder of 5 parts by weight, 2 parts by weight
Then powder is mixed with step (1) broken charcoal, stirring 5min obtains the first mixture;
(3) continue stirring 10min after taking the adhesive of 4 parts by weight to mix with the first mixture obtained by step (2) to obtain
The mass ratio of the mixture that second mixture, wherein adhesive are made of corn flour and white sugar, corn flour and white sugar is 1:3;
(4) biomass pyrolytic for accounting for the second total weight of the mixture 2% is added in through the second mixture obtained by step (3)
10min is mixed in liquid, is then added in fertilizer granulator and is granulated at 60 DEG C, a diameter of 3mm of individual particle, quality
For 0.1g.
Embodiment two:
A kind of preparation method of charcoal base manure material, includes the following steps:
(1) charcoal of 12.5 parts by weight is taken to dry in an oven, oven temperature is 105 DEG C, time 2h, then by it
It is broken, it sieves with 100 mesh sieve;
(2) attapulgite for taking 5-10 parts by weight smashes it through 100 mesh sieve, then takes the urea powder of 40 parts by weight, 15 weights
Measure the carbon of the ammonium chloride powder of part, the potassium chloride powder of 12.5 parts by weight, the monoammonium phosphate powder of 10 parts by weight, 4 parts by weight
Then sour hydrogen ammonium powder is mixed with step (1) broken charcoal, stirring 5min obtains the first mixture;
(3) continue stirring 10min after taking the adhesive of 4 parts by weight to mix with the first mixture obtained by step (2) to obtain
The mass ratio of the mixture that second mixture, wherein adhesive are made of corn flour and white sugar, corn flour and white sugar is 2:3;
(4) biomass pyrolytic for accounting for the second total weight of the mixture 4% is added in through the second mixture obtained by step (3)
10min is mixed in liquid, and prilling temperature is 65.5 DEG C, a diameter of 4.3mm, the quality 0.3g of individual particle.
More preferably to embody the effect of the present invention, first a kind of preparation method of charcoal base manure material according to embodiment two is made
A kind of standby charcoal base manure material carries out one group of manure trial.
Preparatory work of experiment:In experimental plot, three groups of setting are tested respectively, and the variety of crops of experiment is little Bai
Dish.
Grouping and experiment:Experiment is divided into experimental group, control group one, control group two, and every group sets 10 plants of samples, and experimental group is by root
A kind of charcoal base manure material prepared by preparation method according to a kind of charcoal base manure material described in embodiment two disposably does base manure application, applies
Fertilizer amount is 200kgha-1, the existing chemical fertilizer of the application equivalent of control group one, control group two is that blank control group does not apply chemical fertilizer, three
A group is all made of identical and conventional field management and plants 25 days.
Experiment measures:After 25 days, the average plant height of every group of sample is measured and calculated, the dry weight of all samples in every group is weighed
Summation (is put into baking oven 105 DEG C of water-removing 15min and then dries to constant weight at 80 DEG C and weigh dry weight with a ten thousandth assay balance), will
As a result it is recorded in table one.
Table one
Group | Average plant height (cm) | Gross dry weight (g) |
Experimental group | 20.4 | 53.5 |
Control group one | 16.5 | 47.1 |
Control group two | 12.3 | 44.2 |
The control group two for not applying chemical fertilizer, strain are compared using the control group one of existing chemical fertilizer it can be seen from upper table data
Height improves 25.4%, and the control group two for not applying chemical fertilizer, plant height are compared using the experimental group of charcoal base manure material of the present invention
Improve 39.7%.The control group two for not applying chemical fertilizer is compared using the control group one of existing chemical fertilizer, gross dry weight improves
12.5%, the control group two for not applying chemical fertilizer is compared using the experimental group of charcoal base manure material of the present invention, gross dry weight plant height carries
Rise 17.9%, it can be seen that charcoal base manure material provided by the present invention can promote plant growth, improve crop yield.
Embodiment three:
A kind of preparation method of charcoal base manure material, includes the following steps:
(1) charcoal of 20 parts by weight is taken to dry in an oven, oven temperature is 105 DEG C, then time 2h is broken
It is broken, it sieves with 100 mesh sieve;
(2) attapulgite for taking 10 parts by weight smashes it through 100 mesh sieve, then takes the urea powder of 50 parts by weight, 20 weight
The ammonium chloride powder of part, the bicarbonate of the potassium chloride powder of 20 parts by weight, the monoammonium phosphate powder of 15 parts by weight, 6 parts by weight
Then ammonium powder is mixed with step (1) broken charcoal, stirring 5min obtains the first mixture;
(3) continue stirring 10min after taking the adhesive of 5 parts by weight to mix with the first mixture obtained by step (2) to obtain
The mass ratio of the mixture that second mixture, wherein adhesive are made of corn flour and white sugar, corn flour and white sugar is 5:3;
(4) biomass pyrolytic for accounting for the second total weight of the mixture 4% is added in through the second mixture obtained by step (3)
10min is mixed in liquid, is then added in fertilizer granulator and is granulated at 85 DEG C, a diameter of 5mm of individual particle, quality
For 0.5g.
In above-described embodiment:
Charcoal and biomass pyrolysis liquid are purchased from Anhui Xinquan Rice Co., Ltd., address:Anhui Province Fuyang City Ying
Upper county industrial park, phone:4566399.
Attapulgite is purchased from Anhui Bo Shuo Science and Technology Ltd.s, address:The Anhui Province Mingguang City industrial parks Jian Xi are experienced
500 meters of class north, phone:8032646.
It is all according to the claims in the present invention the foregoing is merely the preferred embodiment of the present invention rather than limitation of the present invention
The simple modification made and equivalence replacement, should all belong to protection scope of the present invention.
Claims (3)
1. a kind of preparation method of charcoal base manure material, which is characterized in that include the following steps:
(1) charcoal of 5-25 parts by weight is taken to dry in an oven, oven temperature is 105 DEG C, then time 2h is broken
It is broken, it sieves with 100 mesh sieve;
(2) adhesive for taking 5-15 parts by weight smashes it through 100 mesh sieve, then takes the urea powder of 25-50 parts by weight, 5-20 weights
Measure the ammonium chloride powder of part, the potassium chloride powder of 5-20 parts by weight, the monoammonium phosphate powder of 5-20 parts by weight, 2-10 parts by weight
Ammonium hydrogen carbonate powder, then mixed with step (1) broken charcoal, stirring 5min obtain the first mixture;
(3) continue to stir 10min after taking the adhesive of 5-15 parts by weight to mix with the first mixture obtained by step (2) and obtain the
The mass ratio of the mixture that two mixtures, wherein adhesive are made of corn flour and white sugar, corn flour and white sugar is:1:3-5:
3;
(4) biomass thermal for accounting for the second total weight of the mixture 4%-10% is added in through the second mixture obtained by step (3)
It solves liquid and 10min is mixed, be then added in fertilizer granulator and be granulated at 60-85 DEG C, a diameter of 3- of individual particle
5mm, quality 0.1-0.5g.
2. a kind of preparation method of charcoal base manure material according to claim 1, it is characterised in that:It is adopted in the step (1)
With 12.5 parts by weight charcoals, in the step (2) using the attapulgite of 7.5 parts by weight, 40 parts by weight urea powder,
The ammonium chloride powder of 15 parts by weight, the potassium chloride powder of 12.5 parts by weight, the monoammonium phosphate powder of 10 parts by weight, 4 parts by weight
Ammonium hydrogen carbonate powder, using the adhesive of 4 parts by weight in the step (3), the mass ratio of corn flour and white sugar is 2:3.
In the step (4) plus the amount of biomass pyrolysis liquid accounts for the 4% of the second total weight of the mixture, and prilling temperature is 65.5 DEG C, single
A diameter of 4.3mm, the quality 0.3g of a particle.
3. a kind of charcoal base manure material prepared by a kind of preparation method of charcoal base manure material according to claim 1 or 2.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810930008.6A CN108752140A (en) | 2018-08-15 | 2018-08-15 | A kind of charcoal base manure material and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810930008.6A CN108752140A (en) | 2018-08-15 | 2018-08-15 | A kind of charcoal base manure material and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN108752140A true CN108752140A (en) | 2018-11-06 |
Family
ID=63970104
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810930008.6A Pending CN108752140A (en) | 2018-08-15 | 2018-08-15 | A kind of charcoal base manure material and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108752140A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112142512A (en) * | 2020-09-23 | 2020-12-29 | 山东奥淼科技发展有限公司 | Method for preparing organic controlled-release biochar-based fertilizer by using biological semicoke |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102173944A (en) * | 2011-02-17 | 2011-09-07 | 陈温福 | Carbon-based controlled-release fertilizer special for potato and preparation method thereof |
CN104250171A (en) * | 2014-03-05 | 2014-12-31 | 安徽拜尔福生物科技有限公司 | Preparation method for charcoal base fertilizer |
CN105294324A (en) * | 2015-12-04 | 2016-02-03 | 内蒙古民族大学 | Novel carbon-based compound fertilizer and preparation method thereof |
CN106916020A (en) * | 2017-04-11 | 2017-07-04 | 安徽科技学院 | A kind of charcoal base manure material and preparation method thereof |
-
2018
- 2018-08-15 CN CN201810930008.6A patent/CN108752140A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102173944A (en) * | 2011-02-17 | 2011-09-07 | 陈温福 | Carbon-based controlled-release fertilizer special for potato and preparation method thereof |
CN104250171A (en) * | 2014-03-05 | 2014-12-31 | 安徽拜尔福生物科技有限公司 | Preparation method for charcoal base fertilizer |
CN105294324A (en) * | 2015-12-04 | 2016-02-03 | 内蒙古民族大学 | Novel carbon-based compound fertilizer and preparation method thereof |
CN106916020A (en) * | 2017-04-11 | 2017-07-04 | 安徽科技学院 | A kind of charcoal base manure material and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
中国可持续发展研究会: "《生物技术与未来农业》", 31 January 2016, 中国科学技术出版社 * |
李子东等: "《现代胶粘技术手册》", 31 January 2001, 新时代出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112142512A (en) * | 2020-09-23 | 2020-12-29 | 山东奥淼科技发展有限公司 | Method for preparing organic controlled-release biochar-based fertilizer by using biological semicoke |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105706882B (en) | tomato seedling substrate | |
CN101691317B (en) | Efficient snail-killing type organic fertilizer produced from tea seed cakes and preparation method thereof | |
CN102503642B (en) | Preparation method of organic and inorganic compound fertilizer special for tobaccos | |
CN102503611B (en) | Organic fertilizer or bio-mixed organic fertilizer special for rice and preparing method thereof | |
CN102976812B (en) | Method for producing biomass fertilizer by using straw | |
CN101759476B (en) | Organic fertilizer prepared from wood sugar residua and preparation method thereof | |
CN102358714A (en) | Multi-functional biomass carbon fertilizer produced by using biomass carbon from straws and kitchen waste | |
CN106083453A (en) | A kind of biomass organic fertilizer and preparation method thereof | |
CN105175174A (en) | Biochar slow release base fertilizer special for wheat and preparation method thereof | |
CN104961579B (en) | A kind of Chinese medicine slag biological fertilizer and preparation method | |
CN102417419B (en) | Special bio-organic fertilizer for liquorice and preparation method thereof | |
CN108276231A (en) | A kind of Soil organic phosphorus fractions modifying agent, preparation method and applications | |
CN105000968A (en) | Special biochar slow release base fertilizer for potatoes and preparation method thereof | |
CN101768023A (en) | Organic silicon fertilizer and preparation method thereof | |
CN106916020A (en) | A kind of charcoal base manure material and preparation method thereof | |
CN108752140A (en) | A kind of charcoal base manure material and preparation method thereof | |
CN101717314B (en) | Organic-inorganic compound fertilizer special for expelling parasite from potato and preparation method thereof | |
CN110204402A (en) | A kind of soil organism cultivates functional fertilizer and preparation method thereof | |
CN102633546A (en) | Method for producing organic fertilizer by utilizing jatropha curcas slag oil waste | |
CN109503259A (en) | A kind of chili special-purpose fertilizer and preparation method thereof | |
CN105036902A (en) | Biocarbon sustain-released potassium fertilizer and preparation method thereof | |
CN105315021B (en) | A method of organic fertilizer is produced using the gumbo dregs of rice and sour suede | |
CN104291887A (en) | Method for producing organic fertilizer special for tobacco by taking pig manure and cake fertilizer as raw materials and organic fertilizer special for tobacco | |
CN108299119A (en) | A kind of charcoal organic fertilizer and preparation method thereof | |
CN106278723A (en) | Manganese modification biological charcoal is fertile and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181106 |
|
RJ01 | Rejection of invention patent application after publication |