CN108726968A - A kind of fire-type rare earth heat-insulating material - Google Patents

A kind of fire-type rare earth heat-insulating material Download PDF

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Publication number
CN108726968A
CN108726968A CN201810697159.1A CN201810697159A CN108726968A CN 108726968 A CN108726968 A CN 108726968A CN 201810697159 A CN201810697159 A CN 201810697159A CN 108726968 A CN108726968 A CN 108726968A
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CN
China
Prior art keywords
parts
rare earth
fire
insulating material
type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810697159.1A
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Chinese (zh)
Inventor
刘卓栋
史邓明
肖江蓉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHAN WALLPRO TECHNOLOGY Co Ltd
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WUHAN WALLPRO TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHAN WALLPRO TECHNOLOGY Co Ltd filed Critical WUHAN WALLPRO TECHNOLOGY Co Ltd
Priority to CN201810697159.1A priority Critical patent/CN108726968A/en
Publication of CN108726968A publication Critical patent/CN108726968A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • C04B28/12Hydraulic lime
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

Abstract

The present invention provides a kind of fire-type rare earth heat-insulating material, including following component, the mass parts of each component and each component are:8~15 parts of white lime, 4~8 parts of flyash, 3~5 parts of alumina silicate fibre; 18~22 parts of rock wool; 5~8 parts of glass bead, 9~12 parts of bentonite, 10~15 parts of calcium carbonate; 9~16 parts of bleeding agent; 0.8~1.5 part of polyvinyl alcohol, 0.2~0.6 part of rare earth addition, 0.5~0.7 part of hydroxypropyl methyl cellulose ether; 2~6 parts of polyacrylamide, 0.05~0.1 part of antifoaming agent;The rare earth addition is cerium oxide.Simple production process of the present invention, product diversification (paste type, proximate matter coiled material type, dry powder-shaped type).Therefore the present invention can meet the requirement of various special-shaped equipment and pipeline (such as ball, tank, valve, elbow and reducer pipe) construction, compensate for the limitation that heat preservation plate material uses at the scene.

Description

A kind of fire-type rare earth heat-insulating material
Technical field
The present invention relates to a kind of thermal insulation material and its developments, more particularly to a kind of to be protected for equipment, duct fire type rare earth Adiabator and its method of production, belong to building material field.
Background technology
Although the building energy conservation and insulation of equipment material in China have prodigious development in recent years, from material performance itself and All there is undesirable place in use scope.
The thermal insulation material for being currently used for building mainly has two major classes:Organic heat-insulating and inorganic heat preservation.In organic insulation material Using being more widely EPS sheet and XPS plate, but its combustion rating is low, poor fire, non-refractory, to wall boundary layer and Binding material is more demanding, is susceptible to hollowing, large area obscission, there is some potential safety problems during one's term of military service;As The kervit microbead insulated sand slurry that inorganic heat insulation material uses, its shortcoming is that construction technology is cumbersome, pole big by such environmental effects Easily there is hollowing cracking phenomena, surface need to do anti-cracking waterproof processing, and the integral heat insulation of material is by production and site operation shadow Sound is larger, and heat insulation effect needs to improve, and particularly thorny between lightweight and intensity, thermal technology's property is poor.
Current building thermal insulation material in the construction process, in order to protect thermal insulation material, is required for being plastered, crack-resistant layer Construction, increase cost and difficulty of construction, and engineering special-shaped for some, under particular surroundings is difficult to reach thermal requirements.
Invention content
It is an object of the invention to be directed to defect existing for above-mentioned thermal insulation material, and develop a kind of containing rare earth catalyst The high-efficiency insulated fire-type material of agent, be used in the various equipment such as electric power, chemical industry, metallurgy, mechanical processing, pharmacy, boiler, heat supply network and Pipeline is difficult to competent special-shaped equipment and pipeline such as ball, tank, valve, elbow and reducer pipe especially suitable for Conventional insulation Deng heat insulation effect is excellent, and construction is simple is convenient.
Technical solution is used by realizing above-mentioned purpose of the present invention:
The mass parts of a kind of fire-type rare earth heat-insulating material, including following component, each component and each component are:White lime 8~15 parts, 4~8 parts of flyash, 3~5 parts of alumina silicate fibre, 18~22 parts of rock wool, 5~8 parts of glass bead, bentonite 9~12 Part, 10~15 parts of calcium carbonate, 9~16 parts of bleeding agent, 0.8~1.5 part of polyvinyl alcohol, 0.2~0.6 part of rare earth addition, hydroxypropyl 0.5~0.7 part of ylmethyl cellulose ether, 2~6 parts of polyacrylamide, 0.05~0.1 part of antifoaming agent;The rare earth addition For cerium oxide.
The white lime is calcium hydroxide, and CaO+MgO contents are not more than not less than the rate that tails over of 65%, 0.9mm sieves 0.2%.
The alumina silicate fibre is containing white type, fibre length 5mm, 1350 DEG C of operating temperature.
The bulk density of the glass bead is 120g/L, rate of closed hole >=80%.
The calcium carbonate is calcite in powder, the mesh of fineness >=200.
The bleeding agent is succinic acid alkyl ester sulfonate sodium.
Compared with prior art, the present invention has the following advantages:Simple production process of the present invention, product diversification (paste Type, proximate matter coiled material type, dry powder-shaped type).Therefore the present invention can meet various special-shaped equipment and pipeline (such as ball, tank, valve, elbow And reducer pipe) construction requirement, compensate for the limitation that heat preservation plate material uses at the scene.It is also possible to be made Paste mixture, scene are not required to again dispensing stirring, ensure that the stabilization of product workability and heat-insulating property, site operation work Skill is simple and convenient, and required equipment is few, can prepare suitable product according to different engineering-environments, efficiently solve heat insulating work In various problems, such as thermal coefficient height, fire-protection rating is low, and construction is complicated, of high cost etc..
Specific implementation mode
Invention specific in detail done to the present invention with reference to specific embodiment, but protection scope of the present invention not office It is limited to following embodiment.
Embodiment 1:
Paste rare earth heat-insulating material of the present invention, is developed by weight by following raw material:
8 parts of white lime,
8 parts of flyash,
5 parts of alumina silicate fibre,
18 parts of rock wool,
5 parts of glass bead,
9 parts of bentonite,
15 parts of calcium carbonate,
15 parts of bleeding agent
5 parts of polyacrylamide
0.8 part of polyvinyl alcohol,
0.4 part of rare earth cerium oxide,
0.7 part of hydroxypropyl methyl cellulose ether,
0.1 part of antifoaming agent,
10 parts of water
The technological process of paste rare earth heat-insulating material of the present invention is:
1), first mixing dispersion is slightly carried out by load weighted alumina silicate fibre, rock wool input reaction kettle;
2) reaction kettle, sealed soak 24 hours is added in the bleeding agent after, being diluted with water;
3), the mixture in reaction kettle is transferred in blender, bentonite is added, calcium carbonate stirs 5~8 minutes;
4) white lime, is added, flyash continues stirring 5 minutes;
5) polyvinyl alcohol, rare earth addition, hydroxypropyl methyl cellulose, polyacrylamide, 10 points of stirring, are slowly added to Clock is added water appropriate and carries out consistency adjusting according to mixture state, makes the control of mixture fluidity in 350mm or so;
6) glass bead aggregate, is added, stirs evenly, paste is made;
7) it, is eventually adding antifoaming agent, is stirred 1 minute, half an hour is stood, waits for without apparent bubble.
Embodiment 2:
Coiled material, proximate matter rare earth heat-insulating material prepared by the present embodiment, are developed by weight by following raw material:
15 parts of white lime,
4 parts of flyash,
3 parts of alumina silicate fibre,
22 parts of rock wool,
8 parts of glass bead,
9 parts of bentonite,
10 parts of calcium carbonate,
9 parts of bleeding agent
6 parts of polyacrylamide
1.5 parts of polyvinyl alcohol,
0.6 part of rare earth cerium oxide,
0.5 part of hydroxypropyl methyl cellulose ether,
0.1 part of antifoaming agent,
11.3 parts of water.
The technological process of coiled material, proximate matter rare earth heat-insulating material of the present invention is:
1), first mixing dispersion is slightly carried out by load weighted alumina silicate fibre, rock wool input reaction kettle;
2) reaction kettle, sealed soak 24 hours is added in the bleeding agent after, being diluted with water;
3), the mixture in reaction kettle is transferred in blender, bentonite is added, calcium carbonate stirs 5~8 minutes;
4) white lime, is added, flyash continues stirring 5 minutes;
5) polyvinyl alcohol, rare earth addition, hydroxypropyl methyl cellulose, polyacrylamide, 10 points of stirring, are slowly added to Clock is added water appropriate and carries out consistency adjusting according to mixture state, makes the control of mixture fluidity in 350mm or so;
6) glass bead aggregate, is added, stirs evenly, paste is made;
7) it, is eventually adding antifoaming agent, is stirred 1 minute, half an hour is stood;
8) it, by the paste of production number, is applied on non-woven fabrics according to certain specification (thickness, size), is put into baker In, oven drying temperature is controlled at 100 DEG C or so, is dried 12 hours, after taking out cooling, removes non-woven fabrics.
Embodiment 3:
Coiled material, proximate matter rare earth heat-insulating material described in the present embodiment, are developed by weight by following raw material:
14 parts of white lime,
6 parts of flyash,
4 parts of alumina silicate fibre,
20 parts of rock wool,
6 parts of glass bead,
12 parts of bentonite,
12 parts of calcium carbonate,
16 parts of bleeding agent
2 parts of polyacrylamide
1.3 parts of polyvinyl alcohol,
0.2 part of rare earth cerium oxide,
0.5 part of hydroxypropyl methyl cellulose ether,
0.05 part of antifoaming agent,
5.95 parts of water.
The technological process of coiled material, proximate matter rare earth heat-insulating material of the present invention is:
1), first mixing dispersion is slightly carried out by load weighted alumina silicate fibre, rock wool input reaction kettle;
2) reaction kettle, sealed soak 24 hours is added in the bleeding agent after, being diluted with water;
3), the mixture in reaction kettle is transferred in blender, bentonite is added, calcium carbonate stirs 5~8 minutes;
4) white lime, is added, flyash continues stirring 5 minutes;
5) polyvinyl alcohol, rare earth addition, hydroxypropyl methyl cellulose, polyacrylamide, 10 points of stirring, are slowly added to Clock is added water appropriate and carries out consistency adjusting according to mixture state, makes the control of mixture fluidity in 350mm or so;
6) glass bead aggregate, is added, stirs evenly, paste is made;
7) it, is eventually adding antifoaming agent, is stirred 1 minute, half an hour is stood;
8) it, by the paste of production number, is applied on non-woven fabrics according to certain specification (thickness, size), is put into baker In, oven drying temperature is controlled at 100 DEG C or so, is dried 12 hours, after taking out cooling, removes non-woven fabrics.
The fire-type rare earth heat-insulating material of the present invention by detection, 1, heat insulation effect it is ideal, high temperature resistant, maximum operation (service) temperature Up to 1200 DEG C, picking is not fallen off, is not carbonized, reachable -40 DEG C of minimum temperature in use does not generate deformation;2, low-density, paste Density≤800Kg/m3, coiled material, proximate matter dry density≤250Kg/m3;3, thermal coefficient is low, thermal coefficient≤0.06W/ under room temperature m·k;4, acidproof, alkaline-resisting, anti-corrosion.

Claims (6)

1. a kind of fire-type rare earth heat-insulating material, it is characterised in that including following component, the mass parts of each component and each component For:8~15 parts of white lime, 4~8 parts of flyash, 3~5 parts of alumina silicate fibre, 18~22 parts of rock wool, 5~8 parts of glass bead are swollen 9~12 parts of profit soil, 10~15 parts of calcium carbonate, 9~16 parts of bleeding agent, 0.8~1.5 part of polyvinyl alcohol, rare earth addition 0.2~ 0.6 part, 0.5~0.7 part of hydroxypropyl methyl cellulose ether, 2~6 parts of polyacrylamide, 0.05~0.1 part of antifoaming agent;Described Rare earth addition is cerium oxide.
2. fire-type rare earth heat-insulating material according to claim 1, it is characterised in that:The white lime is hydroxide Calcium, CaO+MgO contents are not more than 0.2% not less than the rate that tails over of 65%, 0.9mm sieves.
3. fire-type rare earth heat-insulating material according to claim 1, it is characterised in that:The alumina silicate fibre is containing white Type, fibre length 5mm, 1350 DEG C of operating temperature.
4. fire-type rare earth heat-insulating material according to claim 1, it is characterised in that:The bulk density of the glass bead For 120g/L, rate of closed hole >=80%.
5. fire-type rare earth heat-insulating material according to claim 1, it is characterised in that:The calcium carbonate is calcite in powder, The mesh of fineness >=200.
6. fire-type rare earth heat-insulating material according to claim 1, it is characterised in that:The bleeding agent is succinic acid alkane Base ester sodium sulfonate.
CN201810697159.1A 2018-06-29 2018-06-29 A kind of fire-type rare earth heat-insulating material Pending CN108726968A (en)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110498636A (en) * 2019-08-30 2019-11-26 中海润达新材料科技有限公司 A kind of insulation combination object
CN110510930A (en) * 2019-08-30 2019-11-29 中海润达新材料科技有限公司 A kind of thermal insulation material
CN110510904A (en) * 2019-08-30 2019-11-29 中海润达新材料科技有限公司 A kind of additive and its application
CN111777368A (en) * 2020-07-22 2020-10-16 青岛启明环保节能技术有限公司 Aerogel type rare earth composite thermal insulation material and preparation method thereof
CN112457048A (en) * 2020-11-19 2021-03-09 中猫科技有限公司 Additive for thermal insulation material and application thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110498636A (en) * 2019-08-30 2019-11-26 中海润达新材料科技有限公司 A kind of insulation combination object
CN110510930A (en) * 2019-08-30 2019-11-29 中海润达新材料科技有限公司 A kind of thermal insulation material
CN110510904A (en) * 2019-08-30 2019-11-29 中海润达新材料科技有限公司 A kind of additive and its application
CN111777368A (en) * 2020-07-22 2020-10-16 青岛启明环保节能技术有限公司 Aerogel type rare earth composite thermal insulation material and preparation method thereof
CN111777368B (en) * 2020-07-22 2022-02-15 青岛启明环保节能技术有限公司 Aerogel type rare earth composite thermal insulation material and preparation method thereof
CN112457048A (en) * 2020-11-19 2021-03-09 中猫科技有限公司 Additive for thermal insulation material and application thereof

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Application publication date: 20181102

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