CN108709839A - Smog detection in real time and multiple sensing system - Google Patents

Smog detection in real time and multiple sensing system Download PDF

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Publication number
CN108709839A
CN108709839A CN201810736102.8A CN201810736102A CN108709839A CN 108709839 A CN108709839 A CN 108709839A CN 201810736102 A CN201810736102 A CN 201810736102A CN 108709839 A CN108709839 A CN 108709839A
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time
unit
real
smog
liquid crystal
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杨晨宇
王细娥
王旭
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Wuxi Zhong Chuang Future Technology Application Co Ltd
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Wuxi Zhong Chuang Future Technology Application Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
    • G01N15/06Investigating concentration of particle suspensions
    • GPHYSICS
    • G08SIGNALLING
    • G08BSIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
    • G08B21/00Alarms responsive to a single specified undesired or abnormal condition and not otherwise provided for
    • G08B21/02Alarms for ensuring the safety of persons
    • G08B21/12Alarms for ensuring the safety of persons responsive to undesired emission of substances, e.g. pollution alarms
    • GPHYSICS
    • G08SIGNALLING
    • G08BSIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
    • G08B5/00Visible signalling systems, e.g. personal calling systems, remote indication of seats occupied
    • G08B5/22Visible signalling systems, e.g. personal calling systems, remote indication of seats occupied using electric transmission; using electromagnetic transmission
    • G08B5/36Visible signalling systems, e.g. personal calling systems, remote indication of seats occupied using electric transmission; using electromagnetic transmission using visible light sources
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
    • G01N15/06Investigating concentration of particle suspensions
    • G01N15/075Investigating concentration of particle suspensions by optical means

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  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Electromagnetism (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Toxicology (AREA)
  • Business, Economics & Management (AREA)
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Abstract

A kind of smog detection in real time and multiple sensing device further, include mainly arm processor unit, smoke sensor device unit, electronic clock unit, liquid crystal display display unit, voice real-time broadcasting unit, external event trigger element, air quality rank LED light warning unit, realizes the methods of seeing, listen, guarding against triple sensing smokescopes;Device is measured in real time smog, PM10 concentration, real-time time synchronization is carried out using real time clock unit, smog, PM10 concentration values and real-time time carry out real-time display by liquid crystal display, triggering voice real-time broadcasting current environment smog, PM10 concentration values and real-time time can also be carried out by the button of external trigger unit, when smokescope is more than 200mg/ cubic metres, system red LED lamp carries out smog warning.

Description

Smog detection in real time and multiple sensing system
Technical field
The present invention relates to smog to detect in real time and multiple sensing system.
Invention content
Cigarette fog real-time monitoring provided by the invention and multiple sensing system, can detect smog, the PM10 of environment in real time Concentration value, real-time clock is accurate, and union liquid crystal display is shown, a key voice broadcast, air quality rank LED light guard against triple sensings Function is suitable for different groups in one.The smoke detection system have smog, PM10 accuracy of detection it is high, it is cost-effective, work The advantages that reliable and stable, has very high practical value and promotional value.
The present invention provides a kind of smog detection in real time and multiple sensing device further, includes mainly:One smoke sensor device unit, It is used to detect Real-time Smoke concentration, PM10 concentration;One electronic clock unit, is used to record real-time time;One external event Trigger element;It includes a triggering button, is used for real-time broadcasting current environment smog, PM10 concentration values and real-time time;One liquid Crystalline substance screen display unit, for showing Real-time Smoke concentration, PM10 concentration and real-time time;One voice real-time broadcasting unit, is used for Voice coding, decoding function can support user to record and play;One air quality rank LED light guards against unit comprising Three LED light of red, yellow, and green;And a microprocessor, when the microprocessor is with the smoke sensor device unit, the electronics Clock unit, the external event trigger element, the liquid crystal display display unit, the voice real-time broadcasting unit and the air Quality scale LED light guards against unit electrical connection, for receiving the smoke sensor device unit, the electronic clock unit, described Real-time Smoke concentration signal that external event trigger element transmits respectively, real-time time signal, control signal, and realize described micro- Processor is warned with the liquid crystal display display unit, the voice real-time broadcasting unit and the air quality rank LED light Guard against unit communication.
Preferably, described to use arm processor unit for processor comprising a processor chips, a power circuit, one Clock circuit, a reset circuit, a JTAG emulation interface and a SDRAM unit.
Preferably, the smoke sensor device senses it using laser light scattering smog, which can detect cigarette simultaneously Mistiness degree and PM10 concentration;Smoke sensor device carries out hardware with the serial ports of a chip and connect, and realizes that the chip is sensed with smog Data communication between device;The operating voltage of smoke sensor device is+5V.Even being produced on the aerial suspended particulate substance of laser irradiation Raw scattering, while scattering light is collected in a certain special angle, obtain the curve that scattered light intensity changes over time, and then microprocessor Using algorithm, the particulate matter quantity of different-grain diameter in the equivalent grain size and unit volume of particulate matter is obtained.
Preferably, the real time clock unit includes electronic clock (RTC) chip and comparator electricity that a precision is I2C Road, electronic clock (RTC) chip that the precision is I2C carry 236 byte battery back SRAM, and electronic clock chip provides Second, point, when, week, the date, Month And Year information, carry the leap year debugging functions;And the comparison circuit and pass through high-precision, warp The voltage reference of excess temperature compensation monitors VCC states.Power failure is detected, provides reset output, and cut automatically if necessary Change to backup battery.
Preferably, the voice real-time broadcasting unit uses the chipspeech of high integration, it can be achieved that Chinese, English Phonetic synthesis;It is integrated with voice coding, decoding function, user can be supported to record and play.
Preferably, the liquid crystal display display unit is set using TFT liquid crystal displays display unit as the display of fume monitor It is standby, presentation of information is carried out in real time;This element uses one 3.5 cun, 320 × 240 pixels, 260,000 colors, supports touch function TFT liquid Crystalline substance screen.
During a kind of smog detection in real time provided by the invention and multiple sensing device further use, the external event touches Bill member includes a button, and external key is pressed, and generates low level, and external event triggers voice broadcast unit and carries out smokescope With the report of real-time clock.Air quality rank LED light guard against unit mainly include red, yellow, and green LED light, when air without LED green lights are lighted when smog, and when air has slight smog, LED amber lights are lighted, and when air has a large amount of smog, LED is red Colored lights is lighted.
A kind of smog provided by the invention detection in real time and multiple sensing device further, when smoke sensor device unit and an electronics Clock unit detects Real-time Smoke concentration respectively, real-time PM10 concentration values and real-time time value, external event trigger element can be real Existing real-time broadcasting current environment smog, PM10 concentration values and real-time time;One liquid crystal display display unit, for showing real-time cigarette Mistiness degree, PM10 concentration and real-time time;Its air quality rank LED light warning unit can provide visual alarm.Collect liquid crystal display It has been shown that, a key voice broadcast, air quality rank LED light guard against triple sensing functions in one, are suitable for different groups.The cigarette Fog detecting system has many advantages, such as that smog, PM10 accuracy of detection are high, cost-effective, stable and reliable in work, has very high practicality Value and promotional value.
Description of the drawings
Fig. 1 is the smog detection in real time and multiple sensing device further principle framework figure that first embodiment of the invention provides.
Fig. 2 is the processor unit hardware for the smog detection and multiple sensing device further in real time that first embodiment of the invention provides Functional block diagram;
Fig. 3 is the real time clock unit hardware circuit diagram that first embodiment of the invention provides.
Specific implementation mode
The embodiments described below are only a part of the embodiment of the present invention, instead of all the embodiments.Based on this Embodiment in invention, the every other reality that those of ordinary skill in the art are obtained without creative efforts Example is applied, shall fall within the protection scope of the present invention.
1 system integrally realizes framework
The smog designed herein detection in real time includes mainly arm processor unit, smoke sensor device with multiple sensing system Unit, electronic clock unit, liquid crystal display display unit, voice real-time broadcasting unit, external event trigger element, air quality grade Other LED light guards against unit.It realizes the method for seeing, listen, guarding against triple sensing smokescopes, meets auditorily handicapped, dysopia etc. The needs of different disadvantaged group.System allomeric function block diagram is as shown in Figure 1.
System is measured in real time smog, PM10 concentration, and real-time time synchronization, cigarette are carried out using real time clock unit Mist, PM10 concentration values and real-time time carry out real-time display by liquid crystal display, can also pressing by external trigger unit Key carries out triggering voice real-time broadcasting current environment smog, PM10 concentration values and real-time time, when smokescope is more than 200mg/ When cubic meter, system red LED lamp carries out smog warning.
2 the Hardware Designs
2.1 arm processor unit hardwares design
ARM main control units are using the LM3S9B96 chips of compatible Cortex-M3 and Thumb-2 instruction set, Thumb-2 technologies With 16 and 32 bit instructions and the advantage deposited, reach the optimum balance of code density and performance, the insertion for low cost declines Controller application brings 32 high-performance calculation abilities, and kernel has high-performance, low-power consumption, three aspect of low cost significantly Feature also has outstanding calculated performance and superior system break responding ability.The main body of high-performance of LM3S9B96 chips Present following characteristic:
1) at high speed:The CPU speeds of service are up to 80-MHz;
2) on piece memory:256KB monocycle flash storages, speed are up to 50MHz;96KB monocycle SRAM;
3) abundant peripheral resources:With piece external equipment interface (EPI), the integrated MAC and PHY of IEEE 1588PTP are supported 10/100 Ethernet, CAN 2.0A/B controller two-way, USB 2.0OTG/Host/Device, support IrDA and ISO 7816 Tri- tunnels UART, I2C module two-way, synchronous serial interface module (SSI) two-way, internal integrated circuit audio (I2S) interface mould Block, 10 analog-digital converters (ADC) 2 of 1000k times/second of sample rate, analog input channel 16, analog comparator 3, number Word comparator 16, on piece Voltagre regulator export 8 tunnels, for the tight of low delay for motor and the advanced PWM of energy source use The fault of emergency stop machine inputs 4, orthogonal coding input (QEI) 2 etc.;Abundant peripheral hardware carries for embedded product hardware design Convenient hardware interface has been supplied, the system integration is convenient for;
4) system integration:Direct memory access controller (DMA), the on piece precision oscillator of 16-MHz have real-time The 32 bit timing device 4 (can be used as 8 16) of clock capability, captures/compares/PWM pins (CCP) 8, WatchDog Timer 2, GPIO mouthfuls up to 65.
Arm processor unit hardware design mainly by power circuit, clock circuit, reset circuit, JTAG emulation interface and SDRAM unit forms, and LM3S9B96 processor unit hardware block diagrams are as shown in Figure 2.
2.2 smoke sensor device unit hardwares design
Smoke sensor device uses laser light scattering principle, is dissipated even being generated on the aerial suspended particulate substance of laser irradiation It penetrates, while scattering light is collected in a certain special angle, obtain the curve that scattered light intensity changes over time.And then microprocessor utilizes Based on the algorithm of Michaelis (MIE) theory, the particulate matter quantity of different-grain diameter in the equivalent grain size and unit volume of particulate matter is obtained. This smoke sensor device model PMS70XX series, for obtaining in unit volume suspended particulate substance number, i.e. particulate matter in air Concentration, and exported in the form of digital interface.The smoke sensor device can detect smokescope and PM10 concentration simultaneously.Smoke sensor device Hardware is carried out with the serial ports UART0 of LM3S9B96 chips to connect, and realizes that the data between LM3S9B96 chips and smoke sensor device are logical Letter.The operating voltage of smoke sensor device is+5V.
2.3 real time clock unit hardware designs
Using superhigh precision I2C electronic clocks (RTC) chip DS3232M, 236 byte battery back SRAM are carried. The battery input of DS3232M integrated chips, when DS3232M chip main power sources power off can keep exact timing.The RTC offer seconds, Point, when, week, the date, Month And Year information, carry the leap year debugging functions;And pass through high-precision, the voltage base by temperature-compensating Accurate and comparator circuit monitors VCC states, detects power failure, provides reset output, and automatically switch to if necessary standby Part power supply.It is realized using the I2C universal serial bus 1 of LM3S9B96 chips and the serial data interface of DS3232M real-time timepiece chips Hardware connects, and using power monitoring chip MAX708, monitors the power supply power supply of DS3232M real-time timepiece chips, and realize system The circuit of power supply and internal battery powers switches, and ensures DS3232M real-time timepiece chips not power down operations.Its hardware circuit As shown in Figure 3.
2.4 voice real-time broadcasting unit hardwares design
Voice real-time broadcasting unit uses XFS5152CE chips.XFS5152CE is a height of HKUST News company production The chipspeech of integrated level is, it can be achieved that Chinese, English phonetic synthesis;It is integrated with voice coding, decoding function, can support to use It is recorded and is played in family;It is innovatively integrated with the speech identifying function of lightweight, supports the identification of 30 order words, and Support the order word customized demand of user.Hardware development is carried out for the convenience of the user, and XFS5152CE chips provide SPI, I2C, UART 3 kinds of hardware interface modes.LM3S9B96 chips control speech chip by serial ports UART1.
2.5 liquid crystal display display unit hardware designs
Display equipment of the TFT liquid crystal displays unit as fume monitor, carries out presentation of information in real time.This element uses one 3.5 cun, 320 × 240 pixels, 260,000 colors, support touch function TFT liquid crystal displays, using the GPIO pin of LM3S9B96 to TFT liquid Crystalline substance screen carries out hardware controls.
2.6 external event trigger element hardware designs
External event trigger element realizes that external key is pressed using external key, generates low level, external event triggering Voice broadcast unit carries out the report of smokescope and real-time clock, and the GPIO pin PJ7 of LM3S9B96 carries out keys interrupt Detection.
2.7 air quality rank LED light guard against unit hardware design
Air quality rank LED light is mainly wrapped for guarding against current air mass, air quality rank LED light warning unit Red, yellow, and green LED light is included, when air non smoke, LED green lights are lighted, when air has slight smog, LED amber lights It lights, when air has a large amount of smog, LED red colored lamps are lighted.By LM3S9B96 GPIO mouths PF3, PF2 and PF1 respectively to it is red, The state of yellow, green three-color LED light is controlled.
3 system softwares are realized
Software program development carries out on the basis of the hardware of each hardware cell is debugged successfully, the composing software ring of program development Border selects KEIL4, software program to write language and select C language, to shorten the period of program development, is utilized when software program is write The API function libraries of CortexM3 family chips, provides fast for programming.After the completion of system software program is write, into Row system hardware and software joint debugging, until system function is realized.
The above for those of ordinary skill in the art can according to the technique and scheme of the present invention and technology Other various corresponding change and deformations are made in design, and all these change and distortions should all belong to the appended right of the present invention It is required that protection domain.

Claims (6)

1. a kind of detection in real time of smog and multiple sensing device further, which is characterized in that it includes mainly:
One smoke sensor device unit is used to detect Real-time Smoke concentration and PM10 concentration;
One electronic clock unit, is used to record real-time time;
One external event trigger element;It includes a triggering button;
One liquid crystal display display unit, for showing Real-time Smoke concentration, PM10 concentration and real-time time;
One voice real-time broadcasting unit can support user to record and play for voice coding, decoding function;
One air quality rank LED light guards against unit comprising three LED light of red, yellow, and green in parallel;
And
One processor, the processor are triggered with the smoke sensor device unit, the electronic clock unit, the external event Unit, the liquid crystal display display unit, the voice real-time broadcasting unit and air quality rank LED light warning unit electricity Connection, is transmitted respectively for receiving the smoke sensor device unit, the electronic clock unit, the external event trigger element Real-time Smoke concentration signal, real-time time signal and control signal, and realize the processor and the liquid crystal screen display Show unit, the voice real-time broadcasting unit and air quality rank LED light warning unit communication.
2. a kind of smog detection in real time as described in claim 1 and multiple sensing device further, which is characterized in that the processor is adopted With arm processor unit comprising a processor chips, a power circuit, a clock circuit, a reset circuit, a JTAG are imitative True interface and a SDRAM unit.
3. smog as claimed in claim 1 or 2 detection in real time and multiple sensing device further, which is characterized in that the smog sensing Device uses laser light scattering smoke sensor device, the smoke sensor device to detect smokescope and PM10 concentration simultaneously;The smog sensing Device carries out hardware with the serial ports of a chip and connect, and realizes that chip is communicated with the data between smoke sensor device, the smoke sensor device Operating voltage be+5V.
4. the smog detection in real time as described in claim 1-3 any one and multiple sensing device further, which is characterized in that the reality When clock unit include a precision be I2C electronic clock (RTC) chip and a comparator circuit, the precision be I2C electricity Sub-clock (RTC) chip carry 236 byte battery back SRAM, electronic clock chip provide the second, point, when, week, the date, the moon With year information;And the comparator circuit and VCC states are monitored by high-precision, the voltage reference by temperature-compensating.
5. the smog detection in real time as described in claim 1-4 any one and multiple sensing device further, which is characterized in that voice is real When report unit use high integration chipspeech.
6. the smog detection in real time as described in claim 1-5 any one and multiple sensing device further, which is characterized in that liquid crystal display Display unit uses display equipment of the TFT liquid crystal displays display unit as fume monitor, carries out presentation of information, this element in real time Using one 3.5 cun, 320 × 240 pixels, 260,000 colors, support touch function TFT liquid crystal displays.
CN201810736102.8A 2018-07-06 2018-07-06 Smog detection in real time and multiple sensing system Pending CN108709839A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203657837U (en) * 2014-01-03 2014-06-18 马慧 Environment monitoring device
CN205252523U (en) * 2015-12-09 2016-05-25 江西英博科技实业有限公司 Teddy bear with fire alarm function
CN105608844A (en) * 2014-11-22 2016-05-25 西安嘉昱知识产权运营管理有限公司 Multifunctional indoor wall-hanging apparatus
CN205692310U (en) * 2016-06-06 2016-11-16 武汉网信机电工程股份有限公司 A kind of intelligent building fire automatization alarm device
CN205785300U (en) * 2016-05-23 2016-12-07 三明学院 Portable intelligent environment monitoring device
CN205786220U (en) * 2016-06-06 2016-12-07 北京农业职业学院 A kind of PM2.5 detector
CN206292940U (en) * 2016-12-06 2017-06-30 重庆工程学院 A kind of anti-theft fireproof warning device
CN206804620U (en) * 2017-05-17 2017-12-26 上海清煜环保科技有限公司 Air quality monitor

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203657837U (en) * 2014-01-03 2014-06-18 马慧 Environment monitoring device
CN105608844A (en) * 2014-11-22 2016-05-25 西安嘉昱知识产权运营管理有限公司 Multifunctional indoor wall-hanging apparatus
CN205252523U (en) * 2015-12-09 2016-05-25 江西英博科技实业有限公司 Teddy bear with fire alarm function
CN205785300U (en) * 2016-05-23 2016-12-07 三明学院 Portable intelligent environment monitoring device
CN205692310U (en) * 2016-06-06 2016-11-16 武汉网信机电工程股份有限公司 A kind of intelligent building fire automatization alarm device
CN205786220U (en) * 2016-06-06 2016-12-07 北京农业职业学院 A kind of PM2.5 detector
CN206292940U (en) * 2016-12-06 2017-06-30 重庆工程学院 A kind of anti-theft fireproof warning device
CN206804620U (en) * 2017-05-17 2017-12-26 上海清煜环保科技有限公司 Air quality monitor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
曲爱玲等: "PM2.5实时检测与多重感知系统设计", 《电子设计工程》 *

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