CN108689537A - A kind of processing system and technique of wheel hub production waste water - Google Patents

A kind of processing system and technique of wheel hub production waste water Download PDF

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Publication number
CN108689537A
CN108689537A CN201810872913.0A CN201810872913A CN108689537A CN 108689537 A CN108689537 A CN 108689537A CN 201810872913 A CN201810872913 A CN 201810872913A CN 108689537 A CN108689537 A CN 108689537A
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China
Prior art keywords
waste water
water
washing
effluent
tank liquor
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CN201810872913.0A
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Chinese (zh)
Inventor
范涛
刘鹏
丁恒祯
姚翰威
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Dongguan Dao Hui Environmental Protection Polytron Technologies Inc
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Dongguan Dao Hui Environmental Protection Polytron Technologies Inc
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Priority to CN201810872913.0A priority Critical patent/CN108689537A/en
Publication of CN108689537A publication Critical patent/CN108689537A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/40Devices for separating or removing fatty or oily substances or similar floating material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/16Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/14Maintenance of water treatment installations
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/16Regeneration of sorbents, filters

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses processing systems and technique that a kind of wheel hub produces waste water, and processing system includes the washing waste water processing subsystem for handling washing waste water and the high load wastewater treatment subsystem for handling hc effluent;Washing waste water processing subsystem includes sequentially connected washing pH regulating reservoirs, washing coagulative precipitation tank, washing filtering unit and washing film separation unit;The water outlet of washing film separation unit includes that concentrated water outlet and water outlet, water outlet are connected with reuse unit;High load wastewater treatment subsystem includes sequentially connected highly concentrated homogeneous pond, highly concentrated pH regulating reservoirs and highly concentrated coagulative precipitation tank, and concentrated water outlet connects the water inlet in highly concentrated homogeneous pond.The present invention separately handles hc effluent and washing waste water, and washing waste water fresh water part reuse that treated to production line, washing waste water concentrated water part is handled as hc effluent.

Description

A kind of processing system and technique of wheel hub production waste water
Technical field
The present invention relates to processing systems and technique that technical field of waste water processing more particularly to a kind of wheel hub produce waste water.
Background technology
Wheel hub is important security personnel's part in running car system.With steel wheel hub and than aluminium alloy wheel hub has more accurate Go to action and enter curved performance, reduces the thermal inertia of the rotating parts such as wheel, thermal diffusivity is good, improves acceleration and braking Property.Have that concentricity is high, longitudinal end multiplies to low, car of beating and sails steady, reasonable stress, corrosion-resistant, handsome in appearance, easy to assembly concurrently With the manufacturing cycle it is short the advantages that.Therefore, the use of aluminium alloy wheel hub is very universal, and occupation rate of market is about 70~75%, attracts More and more manufacturers enter in the production of the auto parts and components.In order to keep wheel hub more aesthetically pleasing, need to aluminium alloy Wheel hub carries out surface treatments, the surface treatment process such as application and will produce the production waste water of complicated component.The electroplating technology one of wheel hub As include following process:The wheel hub of casting and forming → CNC machinings → degreasing degreasing → pickling → passivation → wheel products.Often walk Multiple tracks washing step is provided with after process.
It is useless that wheel hub production waste water generally will produce the useless tank liquor of a small amount of cutting, the useless tank liquor of degreasing, the useless tank liquor of pickling and passivation The washing waste water of the hc effluents such as tank liquor and a large amount of low concentration, hc effluent also contain in addition to containing a large amount of inorganic salts Organic matter and mass fraction are not less than 5% total dissolved solid object (TDS).Currently, hc effluent is blended by most enterprises It is handled into washing waste water, then with coagulating sedimentation and biochemistry combination process.But the pollutant kind of hc effluent is complicated And concentration is higher, conventional treatment process coagulating sedimentation has limitation with biochemistry combination process to the removal of its pollutant, it is difficult to Stably reach higher removal rate.And hc effluent is mixed into washing waste water and is handled, wastewater treatment difficulty is increased, The difficulty for increasing washing waste water treatment for reuse simultaneously, fails to achieve the effect that energy-saving and emission-reduction.Therefore, there is an urgent need for a kind of stabilization and economy Effective wheel hub production wastewater treatment system and technique.
Invention content
The purpose of the present invention is to provide processing systems and technique that a kind of wheel hub produces waste water, by hc effluent and washing Waste water is handled to emission request, and makes washing waste water after treatment being capable of reuse.
For this purpose, the present invention uses following technical scheme:
A kind of processing system of wheel hub production waste water, include for handle the washing waste water processing subsystem of washing waste water and High load wastewater treatment subsystem for handling hc effluent;
The washing waste water processing subsystem includes sequentially connected washing pH regulating reservoirs, washing coagulative precipitation tank, washing Filter element and washing film separation unit;The water outlet of the washing film separation unit includes concentrated water outlet and water outlet, institute It states water outlet and is connected with reuse unit;
The high load wastewater treatment subsystem includes sequentially connected highly concentrated homogeneous pond, highly concentrated pH regulating reservoirs and highly concentrated coagulation Sedimentation basin, the concentrated water outlet connect the water inlet in the highly concentrated homogeneous pond.
Optionally, the washing waste water includes cutting fluid cleaning waste water, cleaning by degreasing waste water, pickling waste water and passivation Clean at least one of waste water;The hc effluent includes washing waste water concentrated water part, cuts give up tank liquor and the useless tank liquor of degreasing, The hc effluent further includes at least one of the useless tank liquor of pickling and the useless tank liquor of passivation.
The processing system further includes the useless tank liquor pretreatment unit of cutting and the useless tank liquor pretreatment unit of degreasing, the cutting The water outlet of useless tank liquor pretreatment unit and the useless tank liquor pretreatment unit of the degreasing is all connected with the water inlet in the highly concentrated homogeneous pond Mouthful.
Optionally, the water inlet of the washing pH regulating reservoirs is also associated with washing homogeneous pond;
The washing filtering unit includes sequentially connected sand filter and cartridge filter, the water outlet of the cartridge filter The water inlet of the mouth connection washing film separation unit;
The water outlet of the washing coagulative precipitation tank is also associated with intermediate pool, and the water outlet of the intermediate pool connects institute State the water inlet of sand filter.
Optionally, the washing film separation unit includes sequentially connected ultrafiltration buffer pool, ultrafiltration membrane group, reverse osmosis buffering Pond and reverse osmosis membrane group;The water outlet of the cartridge filter connects the water inlet of the ultrafiltration buffer pool;The reverse osmosis membrane The water outlet of group includes the water outlet and concentrated water outlet.
Optionally, the highly concentrated oxidation unit includes sequentially connected Fenton's reaction pond, UV reactive device and ultraviolet water outlet Scratch pool;The water outlet of the highly concentrated pH regulating reservoirs connects the water inlet in the Fenton's reaction pond, the ultraviolet water outlet scratch pool Water outlet connect the water inlet of the highly concentrated coagulative precipitation tank;The water outlet of the highly concentrated coagulative precipitation tank is also associated with carbon filter Device.
Optionally, it is described cutting give up tank liquor pretreatment unit include sequentially connected cutting homogeneous pond, be demulsified reactor and Oil water separator, the water outlet of the oil water separator connect the water inlet in the highly concentrated homogeneous pond;
The degreasing tank liquor pretreatment unit that gives up includes sequentially connected degreasing homogeneous pond and degreasing coagulative precipitation tank, described The water outlet of degreasing coagulative precipitation tank connects the water inlet in the highly concentrated homogeneous pond.
A kind for the treatment of process of wheel hub production waste water, includes the washing waste water treatment process and use for handling washing waste water In the high load wastewater treatment technique of processing hc effluent;
The washing waste water treatment process includes the following steps:
Washing waste water homogeneous:Homogenization is carried out to washing waste water;
Washing waste water pH is adjusted:The pH of washing waste water after homogeneous is adjusted to washing waste water pH preset values;
Washing waste water precipitates:Flocculant is added in washing waste water after being adjusted to pH and carries out coagulating sedimentation;
Washing waste water filters:Washing waste water after coagulating sedimentation is filtered by filter;
Washing waste water UF membrane:Filtered washing waste water is detached by seperation film, obtains washing waste water fresh water Part and washing waste water concentrated water part;Washing waste water fresh water part is as washing water reuse, washing waste water concentrated water portion Divide and is handled into the high load wastewater treatment technique;
The high load wastewater treatment technique includes the following steps:
Hc effluent homogeneous:Homogenization is carried out to hc effluent;The hc effluent includes the washing waste water concentrated water Part;
Hc effluent pH is adjusted:The pH of hc effluent after homogeneous is adjusted to hc effluent pH preset values;
Hc effluent aoxidizes:The organic pollution in hc effluent after pH is adjusted is degraded by oxidation reaction;
Hc effluent precipitates:Flocculant is added into the hc effluent after oxidation and carries out coagulating sedimentation.
Optionally, the washing waste water includes cutting fluid cleaning waste water, cleaning by degreasing waste water, pickling waste water and passivation Clean at least one of waste water;The hc effluent includes the useless tank liquor of cutting, the useless tank liquor of degreasing and the washing waste water concentrated water Part, the hc effluent further include at least one of the useless tank liquor of pickling and the useless tank liquor of passivation;
The cutting gives up the tank liquor progress hc effluent homogenizing step before also by cutting the tank liquor pretreating process that gives up Processing, the useless tank liquor pretreating process of cutting include the following steps:
The useless tank liquor homogeneous of cutting:Homogenization is carried out to cutting the tank liquor that gives up;
Demulsification reaction:So that the tank liquor that gives up of the cutting after homogeneous is detached from stable emulsion state, formed mutual exclusive water phase and Oil phase;
Water-oil separating:By the oil phase and aqueous phase separation of the useless tank liquor of cutting after demulsification;The water phase of the useless tank liquor of cutting is as institute It states hc effluent and carries out homogeneous into the hc effluent homogenizing step;
The degreasing gives up before tank liquor carries out the hc effluent homogenizing step and is also given up tank liquor pretreating process by degreasing Processing, the useless tank liquor pretreating process of the degreasing include the following steps:
The useless tank liquor homogeneous of degreasing:To degreasing give up tank liquor carry out homogenization;
The useless tank liquor precipitation of degreasing:Flocculant is added in giving up tank liquor to the degreasing after homogeneous and carries out coagulating sedimentation;Coagulating sedimentation The useless tank liquor of degreasing afterwards enters the hc effluent homogenizing step as the hc effluent and carries out homogeneous.
Optionally, the washing waste water pH preset values are 7.5-8.5;
The washing waste water settling step, specially:Polyacrylamide is added in washing waste water after being adjusted to pH and gathers It closes aluminium chloride and carries out coagulating sedimentation;
The washing waste water filtration step, specially:Washing waste water after coagulating sedimentation is passed sequentially through into sand filter and guarantor Peace filter is filtered;
The washing waste water UF membrane step, specially:Filtered washing waste water is passed sequentially through into ultrafiltration membrane group and anti- Permeable membrane group carries out UF membrane, obtains washing waste water fresh water part and washing waste water concentrated water part.
Optionally, the hc effluent pH preset values are 3.0-3.5;
The hc effluent oxidation step, specially:Hydrogen peroxide and divalent is added into the hc effluent after adjusting pH Iron ion carries out Fenton's reaction, degradable organic pollution in hc effluent of degrading;Hc effluent is sent into UV reactive again Hydrogen peroxide is added into hc effluent for device, organic dirt difficult to degrade of being degraded using the synergy of ultraviolet light and hydrogen peroxide Contaminate object;
The hc effluent settling step, specially:Into the hc effluent after oxidative degradation be added polyacrylamide and Aluminium polychloride carries out coagulating sedimentation;
Further include a step after the hc effluent settling step:
Hc effluent filters:Hc effluent after coagulating sedimentation is filtered by carbon filter.
Compared with prior art, the embodiment of the present invention has the advantages that:
The processing system and technique of wheel hub production waste water provided by the invention, hc effluent and washing waste water are separately located Reason, washing waste water is after the processing of washing waste water processing subsystem, washing waste water fresh water part reuse to production line, washing waste water Concentrated water part enters high load wastewater treatment subsystem and other useless tank liquors are handled as hc effluent together, and it is high that treated The water quality index of density wastewater reaches discharge standard.The processing system and technique of wheel hub production waste water provided by the invention, Neng Goujian It is easily linked in existing production technology, reduces processing cost, while improving treatment effect stability.
Description of the drawings
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention without having to pay creative labor, may be used also for those of ordinary skill in the art To obtain other attached drawings according to these attached drawings.
Fig. 1 is the schematic diagram for the processing system that the wheel hub that the embodiment of the present invention one provides produces waste water.
It illustrates:10, washing homogeneous pond;11, pH regulating reservoirs are washed;12, coagulative precipitation tank is washed;13, intermediate pool; 14, sand filter;15, cartridge filter;16, ultrafiltration buffer pool;17, ultrafiltration membrane group;18, reverse osmosis buffer pool;19, reverse osmosis membrane Group;20, reuse unit;30, highly concentrated homogeneous pond;31, highly concentrated pH regulating reservoirs;32, Fenton's reaction pond;33, UV reactive device;34, Ultraviolet water outlet scratch pool;35, highly concentrated coagulative precipitation tank;36, carbon filter;37, exhaust unit;40, cutting homogeneous pond;41, it is demulsified Reactor;42, oil water separator;50, degreasing homogeneous pond;51, degreasing coagulative precipitation tank;60, sludge treating block;70, waste oil Processing unit.
Specific implementation mode
In order to make the invention's purpose, features and advantages of the invention more obvious and easy to understand, below in conjunction with the present invention Attached drawing in embodiment, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that disclosed below Embodiment be only a part of the embodiment of the present invention, and not all embodiment.Based on the embodiments of the present invention, this field All other embodiment that those of ordinary skill is obtained without making creative work, belongs to protection of the present invention Range.
In the description of the present invention, it is to be understood that, the instructions such as term "upper", "lower", "top", "bottom", "inner", "outside" Orientation or positional relationship be based on the orientation or positional relationship shown in the drawings, be merely for convenience of description the present invention and simplification retouch It states, does not indicate or imply the indicated device or element must have a particular orientation, with specific azimuth configuration and operation, Therefore it is not considered as limiting the invention.It should be noted that when a component is considered as " connection " another component, It can be directly to another component or may be simultaneously present the component being centrally located.
Technical solution to further illustrate the present invention below with reference to the accompanying drawings and specific embodiments.
The present invention provides processing systems and technique that a kind of wheel hub produces waste water, and wheel hub can be produced to the wash water in waste water Treatment for reuse, and by the part of the non-reuse of wash water and high concentration tank liquor mixed processing.
Embodiment one
Referring to FIG. 1, the processing system of wheel hub production waste water provided in this embodiment, includes for handling washing waste water Washing waste water processing subsystem and high load wastewater treatment subsystem for handling hc effluent.
Washing waste water processing subsystem includes sequentially connected washing pH regulating reservoirs 11, washing coagulative precipitation tank 12, washing Filter element and washing film separation unit.The water outlet of washing film separation unit includes that concentrated water outlet and water outlet, fresh water go out Mouth connection reuse unit 20.
High load wastewater treatment subsystem includes sequentially connected highly concentrated homogeneous pond 30, highly concentrated pH regulating reservoirs 31, highly concentrated oxidation Unit and highly concentrated coagulative precipitation tank 35.The concentrated water outlet for washing film separation unit connects the water inlet in highly concentrated homogeneous pond 30.
Specifically, washing waste water includes cutting fluid cleaning waste water, cleaning by degreasing waste water, pickling waste water and passivation cleaning Waste water.Washing waste water processing subsystem further includes washing homogeneous pond 10, and the various cleaning waste water for workshop to be discharged carry out equal Matter processing.
Wash the water inlet of the water outlet connection washing pH regulating reservoirs 11 in homogeneous pond 10.PH regulating reservoirs 11 are washed to be used for water The pH for washing waste water is adjusted to 7.5-8.5, is convenient for subsequent reactions.Washing waste water originally is generally acidity, and pH adjustment processes use The mode that piece alkali is added carries out.
Wash the water inlet of the water outlet connection washing coagulative precipitation tank 12 of pH regulating reservoirs 11.To washing coagulative precipitation tank 12 In washing waste water be added flocculant, make the solid suspension in washing waste water polymerize to form floccule body and precipitate.Flocculant selects With polyacrylamide and aluminium polychloride.
The water inlet of the water outlet connection intermediate pool 13 of coagulative precipitation tank 12 is washed, washing waste water is by coagulating sedimentation Production water enters intermediate pool 13 from water outlet, and intermediate pool 13 is for buffering.The sludge mouth connection for washing coagulative precipitation tank 12 is dirty Mud processing unit 60, the sludge that washing waste water is formed through coagulating sedimentation enter sludge treating block 60 from sludge mouth.Treatment of Sludge Unit 60 includes filter press.
Washing filtering unit includes sequentially connected sand filter 14 and cartridge filter 15.The water outlet of intermediate pool 13 connects Connect the water inlet of sand filter 14, the water inlet of the water outlet connection washing film separation unit of cartridge filter 15.Sand filter 14 is used In removing the solid suspension not eliminated in coagulation-settlement process, microorganism and other subparticles, washing waste water is reduced Turbidity is convenient for the operation of subsequent technique.Cartridge filter 15 is for removing small suspended matter, the bacterium that sand filter 14 can not remove And other impurities, so that the water quality of washing waste water is reached the inflow requirement of ultrafiltration membrane.
It includes sequentially connected ultrafiltration buffer pool 16 and ultrafiltration membrane group 17 to wash film separation unit, and cartridge filter 15 goes out The mouth of a river connects the water inlet of ultrafiltration buffer pool 16.Ultrafiltration membrane group 17 is used to remove bacterium, iron rust and the colloid etc. in washing waste water Harmful substance.Ultrafiltration membrane group 17 further reduced the turbidity and pollution index of washing waste water so that the water quality of washing waste water reaches To the inflow requirement of reverse osmosis membrane, shield to the normal work of reverse osmosis membrane as reverse osmosis pre-treatment step.
It further includes sequentially connected reverse osmosis buffer pool 18 and reverse osmosis membrane group 19 to wash film separation unit.Ultrafiltration membrane group 17 Water outlet connect the water inlet of reverse osmosis buffer pool 18.The water outlet of reverse osmosis membrane group 19 includes that water outlet and concentrated water go out Mouthful, water outlet connects reuse unit 20, and concentrated water outlet connects the water inlet in highly concentrated homogeneous pond 30.
Factory is entered by reuse unit 20 through the washing waste water fresh water part of reverse osmosis membrane group 19, is made as washing water With.The part that washing waste water does not penetrate reverse osmosis membrane group 19 loses fresh water and is condensed to as concentrated water, into high load wastewater treatment System carries out subsequent processing.
Hc effluent further includes the useless tank liquor of cutting, the useless tank liquor of degreasing, the useless tank liquor of pickling other than washing waste water concentrated water part With the useless tank liquor of passivation.
Highly concentrated homogeneous pond 30 be used for washing waste water concentrated water part, cutting give up tank liquor, degreasing give up tank liquor, pickling give up tank liquor and The useless tank liquor of passivation carries out homogenization.
The water outlet in highly concentrated homogeneous pond 30 connects the water inlet of highly concentrated pH regulating reservoirs 31.Into the height of highly concentrated pH regulating reservoirs 31 Density wastewater pH is less than 1, and by the way that piece alkali (technical grade, 96%) is added, the water outlet pH for controlling highly concentrated pH regulating reservoirs 31 is 3.0-3.5, The pH is suitble to subsequent oxidation reaction.
Highly concentrated oxidation unit includes Fenton's reaction pond 32, the water outlet connection Fenton's reaction pond 32 of highly concentrated pH regulating reservoirs 31 Water inlet.In Fenton's reaction pond 32, hydrogen peroxide is added to hc effluent and ferrous ion carries out Fenton's reaction, makes organic Contaminant degradation, to remove removal organic polluter.Specifically, to hc effluent be added 4000ppm hydrogen peroxide (technical grade, 27.5%) and the ferrous sulfate heptahydrate of 3000ppm carries out Fenton's reaction, and the Fenton's reaction residence time is 120-150min.
The water inlet of the water outlet connection UV reactive device 33 in Fenton's reaction pond 32, the water outlet connection of UV reactive device 33 The water inlet of ultraviolet water outlet scratch pool 34.UV reactive device 33 carries out sterilizing to hc effluent, in UV reactive device 33, Hydrogen peroxide is added into hc effluent, is further degraded by the photochemical oxidation effect of the hydrogen peroxide of ultraviolet light sum organic Pollutant, further to remove organic pollution difficult to degrade.Specifically, be added 3500ppm hydrogen peroxide (technical grade, 27.5%).
The water outlet of ultraviolet water outlet scratch pool 34 connects the water inlet of highly concentrated coagulative precipitation tank 35.Highly concentrated coagulative precipitation tank 35 For removing fixed suspended matter, flocculant selects polyacrylamide and aluminium polychloride.The water outlet of highly concentrated coagulative precipitation tank 35 Carbon filter 36 is connected, the sludge mouth of highly concentrated coagulative precipitation tank 35 connects sludge treating block 60.
The water inlet of the water outlet connection carbon filter 36 of highly concentrated coagulative precipitation tank 35, carbon filter 36 is for removing above-mentioned waste water During treatment process, possible interference causes some organic pollutants for failing removal, ensures that stable water outlet reaches discharge mark It is accurate.The water outlet of carbon filter 36 connects exhaust unit 37, and exhaust unit 37 is up to the hc effluent discharge of discharge standard.
Processing system further includes that cutting is given up tank liquor pretreatment unit, and it is more to cut contained grease in giving up tank liquor, with other First the grease in the useless tank liquor of cutting is removed before hc effluent homogeneous.The useless tank liquor pretreatment unit of cutting includes sequentially connected cuts It cuts homogeneous pond 40, demulsification reactor 41 and oil water separator 42, the water outlet of oil water separator 42 and connects highly concentrated homogeneous pond 30 Water inlet, the oil outlet connection waste oil disposal unit 70 of oil water separator 42.Demulsification reactor 41 makes cutting give up tank liquor disengaging surely Fixed emulsion state forms incompatible water phase and oil phase, is convenient for subsequent water-oil separation.
Processing system further includes the useless tank liquor pretreatment unit of degreasing, and the useless tank liquor pretreatment unit of degreasing includes sequentially connected Degreasing homogeneous pond 50 and degreasing coagulative precipitation tank 51, the water outlet of degreasing coagulative precipitation tank 51 connect the water inlet in highly concentrated homogeneous pond 30 Mouthful.Since the degreasing tank liquor that gives up belongs to high-concentration waste liquid, pollutant kind is complicated and very high concentrations, independent coagulating sedimentation pretreatment There can be 30% or so removal rate.If degreasing is given up, tank liquor is not preprocessed is directly mixed in highly concentrated homogeneous pond 30, and degreasing is given up slot Pollutant in liquid is possible to react with other pollutants in highly concentrated homogeneous pond 30, leads to the pollution in hc effluent Species are increasingly complex, are unfavorable for subsequent processing.
The present embodiment provides the treatment process that wheel hub produces waste water, including:At washing waste water treatment process and hc effluent Science and engineering skill, washing waste water are converted into washing waste water fresh water part and washing waste water concentrated water part by washing waste water treatment process, Washing waste water fresh water part enters high load wastewater treatment process as washing water reuse, washing waste water concentrated water part.
Washing waste water treatment process includes the following steps:
Washing waste water homogeneous:To cutting fluid cleaning waste water, cleaning by degreasing waste water, pickling waste water and passivation cleaning waste water Carry out homogenization.
Washing waste water pH is adjusted:Washing waste water after homogeneous piece alkali is adjusted into pH to 7.5-8.5.
Washing waste water precipitates:Polyacrylamide is added in washing waste water after being adjusted to pH and aluminium polychloride carries out coagulation Precipitation obtains production water and production mud, and production water carries out next step, and production sludge is handled by sludge treatment technique.
Washing waste water filters:Washing waste water after coagulating sedimentation is passed sequentially through into sand filter 14 and cartridge filter 15 carries out Filtering.
Washing waste water UF membrane:Filtered washing waste water is passed sequentially through into ultrafiltration membrane group 17 and reverse osmosis membrane group 19 carries out UF membrane, the washing waste water fresh water part that reverse osmosis membrane group 19 detaches enter as washing water reuse, washing waste water concentrated water part High load wastewater treatment technique.
High load wastewater treatment technique includes the following steps:
Hc effluent homogeneous:It gives up tank liquor and blunt to washing waste water concentrated water part, cutting give up tank liquor, pickling of tank liquor, degreasing of giving up Change the tank liquor that gives up and carries out homogenization.
Hc effluent pH is adjusted:Hc effluent after homogeneous piece alkali is adjusted into pH to 3.0-3.5.
Hc effluent aoxidizes:Hydrogen peroxide is added into the hc effluent after adjusting pH and ferrous ion progress Fenton is anti- It answers, degradable organic pollution in hc effluent of degrading;Hc effluent is sent into UV reactive device 33 again, into hc effluent Hydrogen peroxide, organic pollution difficult to degrade of degrading using the synergy of ultraviolet light and hydrogen peroxide is added.
Hc effluent precipitates:Polyacrylamide is added into the hc effluent after oxidative degradation and aluminium polychloride is mixed Retrogradation is formed sediment, and the production water of coagulating sedimentation carries out next step, and the sludge of coagulating sedimentation output is handled by sludge treatment technique.
Hc effluent filters:Hc effluent after coagulating sedimentation is filtered by carbon filter 36, the production of carbon filter 36 Water reaches standard of drainage, is discharged.
The useless tank liquor of cutting, also by the useless tank liquor pretreating process processing of cutting, is cut before entering high load wastewater treatment technique Useless tank liquor pretreating process is cut to include the following steps:
The useless tank liquor homogeneous of cutting:Homogenization is carried out to cutting the tank liquor that gives up.
Demulsification reaction:So that the tank liquor that gives up of the cutting after homogeneous is detached from stable emulsion state, formed mutual exclusive water phase and Oil phase.
Water-oil separating:By the oil phase and aqueous phase separation of the useless tank liquor of cutting after demulsification, water phase enters high load wastewater treatment work Skill is handled, and oil phase enters waste oil disposal technique and handled.
Degreasing give up tank liquor enter high load wastewater treatment technique before also by degreasing give up tank liquor pretreating process processing, take off The useless tank liquor pretreating process of fat includes the following steps:
The useless tank liquor homogeneous of degreasing:To degreasing give up tank liquor carry out homogenization.
The useless tank liquor precipitation of degreasing:Flocculant is added in giving up tank liquor to the degreasing after homogeneous and carries out coagulating sedimentation, coagulating sedimentation Production water enter hc effluent homogenizing step as hc effluent and carry out homogeneous, the sludge of coagulating sedimentation output passes through Treatment of Sludge Process.
The processing system and technique of wheel hub production waste water provided in this embodiment, high-concentration waste tank liquor and low concentration are washed Waste water is separately handled, and washing waste water is after the processing of washing waste water processing subsystem, washing waste water fresh water part reuse to production Line, washing waste water concentrated water part enter high load wastewater treatment subsystem and other high-concentration waste tank liquors and are used as hc effluent together It is handled, the water quality index of treated hc effluent reaches"Integrated wastewater discharge standard"(GB8978-1996) three-level mark It is accurate.The processing system and technique of wheel hub production waste water provided in this embodiment, can simply be linked in existing production technology, drop Low processing cost, while improving treatment effect stability.
Embodiment two
Embodiment two is used as subjects by choosing Shandong Binzhou wheel hub production waste water, to wheel hub provided by the invention The effect of the processing system and technique that produce waste water illustrates.
The water quality of washing waste water and hc effluent such as following table:
Cutting fluid cleans waste water, cleaning by degreasing waste water, pickling waste water and passivation cleaning waste water by washing homogeneous pond After 10 homogeneous, it is pumped to washing pH regulating reservoirs 11.The COD of washing waste water is 300-400mg/L before pH is adjusted, and PH is in 3.0- Between 4.0, conductivity 2000-2500us/cm.Piece alkali (technical grade, 96%) is added into washing waste water, controls washing waste water PH be 7.5-8.5.Later by washing waste water be sent into washing coagulative precipitation tank 12, into washing waste water be added polyacrylamide and Aluminium polychloride, reaction time 40min.The production water of coagulating sedimentation passes sequentially through sand filter 14, cartridge filter 15, ultrafiltration Buffer pool 16, ultrafiltration membrane group 17, reverse osmosis buffer pool 18 and reverse osmosis membrane group 19, the washing waste water that reverse osmosis membrane group 19 detaches are light Water section is sent into reuse unit 20 and washing water reuse, the washing waste water concentrated water part that reverse osmosis membrane group 19 detaches is used as to be sent into highly concentrated Homogeneous pond 30.
The useless tank liquor of cutting passes sequentially through cutting homogeneous pond 40, demulsification reactor 41 and oil water separator 42, oil water separator The water phase of the useless tank liquor of cutting of 42 separation is sent into highly concentrated homogeneous pond 30.The COD of the useless tank liquor water phase of the cutting is 15600mg/L, pH Between 2.0-3.0, conductivity 20000-25000us/cm.
The useless tank liquor of degreasing passes sequentially through degreasing homogeneous pond 50 and degreasing coagulative precipitation tank 51, the production of degreasing coagulative precipitation tank 51 Water is sent into highly concentrated homogeneous pond 30, and the COD of the production water is 14000mg/L, pH between 8.0-8.5, conductivity 15000- 20000us/cm。
Highly concentrated pH regulating reservoirs 31 are pumped to by the hc effluent after highly concentrated 30 homogeneous of homogeneous pond, it is highly concentrated useless before pH adjustings The COD of water is that 5000-8000mg/L is not waited, PH is less than 1, conductivity 15000-22000us/cm;To highly concentrated pH regulating reservoirs 31 In hc effluent be added piece alkali (technical grade, 96%), control hc effluent pH be 3.0-3.5.It is adjusted by pH highly concentrated Waste water enters Fenton's reaction pond 32, and the hydrogen peroxide (technical grade, 27.5%) and 3000ppm of 4000ppm are added to hc effluent Ferrous sulfate heptahydrate, reaction time 120-150min.It is pumped to by the hc effluent in Fenton's reaction pond 32 ultraviolet The hydrogen peroxide (technical grade, 27.5%) of 3500ppm is added to hc effluent for reactor 33.By Fenton's reaction oxidation and purple The hc effluent that photochemical oxidation is combined in outside line, hydrogen peroxide is sent into highly concentrated coagulative precipitation tank 35, and hc effluent is in highly concentrated coagulation Residence time in sedimentation basin 35 is 2.0h.The production water COD of the water outlet of highly concentrated coagulative precipitation tank 35 is 300mg/L, highly concentrated mixed The sludge pumping of the sludge mouth output of solidifying sedimentation basin 35 is to sludge treating system, every liter of wastewater sludge production after handling in this example Amount is 18.1-18.6g (moisture content about 80%).The water of the water outlet outflow of highly concentrated coagulative precipitation tank 35 is discharged.
Wheel hub produces the following table of quality inspection measured data of waste water water after processing system is handled:
Wheel hub is can be seen that by the data of upper table and produces waste water after processing system is handled, and water quality index reaches"Sewage Comprehensive discharge standard"(GB8978-1996) grade III Standard.
Embodiment two further illustrates processing system and technique provided by the invention to wheel by specific test data Hub produces the good treatment effect of waste water.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments Invention is explained in detail, it will be understood by those of ordinary skill in the art that:It still can be to aforementioned each implementation Technical solution recorded in example is modified or equivalent replacement of some of the technical features;And these modification or It replaces, the spirit and scope for various embodiments of the present invention technical solution that it does not separate the essence of the corresponding technical solution.

Claims (10)

1. a kind of processing system of wheel hub production waste water, which is characterized in that include for handling at the washing waste water of washing waste water Manage subsystem and the high load wastewater treatment subsystem for handling hc effluent;
The washing waste water processing subsystem includes sequentially connected washing pH regulating reservoirs, washing coagulative precipitation tank, washing filtering Unit and washing film separation unit;It is described washing film separation unit water outlet include concentrated water outlet and water outlet, it is described light Water out is connected with reuse unit;
The high load wastewater treatment subsystem includes sequentially connected highly concentrated homogeneous pond, highly concentrated pH regulating reservoirs and highly concentrated coagulating sedimentation Pond, the concentrated water outlet connect the water inlet in the highly concentrated homogeneous pond.
2. the processing system of wheel hub production waste water according to claim 1, which is characterized in that the washing waste water includes cutting Cut at least one of liquid cleaning waste water, cleaning by degreasing waste water, pickling waste water and passivation cleaning waste water;The hc effluent It gives up tank liquor including give up tank liquor and degreasing of washing waste water concentrated water part, cutting, the hc effluent further includes that pickling is given up tank liquor and blunt Change at least one of the tank liquor that gives up.
The processing system further includes the useless tank liquor pretreatment unit of cutting and the useless tank liquor pretreatment unit of degreasing, the useless slot of cutting The water outlet of liquid pretreatment unit and the useless tank liquor pretreatment unit of the degreasing is all connected with the water inlet in the highly concentrated homogeneous pond.
3. the processing system of wheel hub production waste water according to claim 1, which is characterized in that the washing pH regulating reservoirs Water inlet is also associated with washing homogeneous pond;
The washing filtering unit includes sequentially connected sand filter and cartridge filter, and the water outlet of the cartridge filter connects Connect the water inlet of the washing film separation unit;
The water outlet of the washing coagulative precipitation tank is also associated with intermediate pool, and the water outlet of the intermediate pool connects the sand The water inlet of filter.
4. the processing system of wheel hub production waste water according to claim 3, which is characterized in that the washing film separation unit Including sequentially connected ultrafiltration buffer pool, ultrafiltration membrane group, reverse osmosis buffer pool and reverse osmosis membrane group;The cartridge filter goes out The mouth of a river connects the water inlet of the ultrafiltration buffer pool;The water outlet of the reverse osmosis membrane group includes the water outlet and described dense Water out.
5. the processing system of wheel hub production waste water according to claim 1, which is characterized in that the highly concentrated oxidation unit packet Include sequentially connected Fenton's reaction pond, UV reactive device and ultraviolet water outlet scratch pool;The water outlet of the highly concentrated pH regulating reservoirs connects Connect the water inlet in the Fenton's reaction pond, the water outlet of the ultraviolet water outlet scratch pool connect the highly concentrated coagulative precipitation tank into The mouth of a river;The water outlet of the highly concentrated coagulative precipitation tank is also associated with carbon filter.
6. the processing system of wheel hub production waste water according to claim 2, which is characterized in that the useless tank liquor of cutting is located in advance Reason unit includes sequentially connected cutting homogeneous pond, demulsification reactor and oil water separator, the water outlet of the oil water separator Connect the water inlet in the highly concentrated homogeneous pond;
The useless tank liquor pretreatment unit of the degreasing includes sequentially connected degreasing homogeneous pond and degreasing coagulative precipitation tank, the degreasing The water outlet of coagulative precipitation tank connects the water inlet in the highly concentrated homogeneous pond.
7. a kind for the treatment of process of wheel hub production waste water, which is characterized in that include for handling at the washing waste water of washing waste water Science and engineering skill and high load wastewater treatment technique for handling hc effluent;
The washing waste water treatment process includes the following steps:
Washing waste water homogeneous:Homogenization is carried out to washing waste water;
Washing waste water pH is adjusted:The pH of washing waste water after homogeneous is adjusted to washing waste water pH preset values;
Washing waste water precipitates:Flocculant is added in washing waste water after being adjusted to pH and carries out coagulating sedimentation;
Washing waste water filters:Washing waste water after coagulating sedimentation is filtered by filter;
Washing waste water UF membrane:Filtered washing waste water is detached by seperation film, obtains washing waste water fresh water part With washing waste water concentrated water part;Washing waste water fresh water part as washing water reuse, washing waste water concentrated water part into Enter the high load wastewater treatment technique to be handled;
The high load wastewater treatment technique includes the following steps:
Hc effluent homogeneous:Homogenization is carried out to hc effluent;The hc effluent includes washing waste water concentrated water part;
Hc effluent pH is adjusted:The pH of hc effluent after homogeneous is adjusted to hc effluent pH preset values;
Hc effluent aoxidizes:The organic pollution in hc effluent after pH is adjusted is degraded by oxidation reaction;
Hc effluent precipitates:Flocculant is added into the hc effluent after oxidation and carries out coagulating sedimentation.
8. the treatment process of wheel hub production waste water according to claim 7, it is characterised in that
The washing waste water includes in cutting fluid cleaning waste water, cleaning by degreasing waste water, pickling waste water and passivation cleaning waste water At least one;The hc effluent includes the useless tank liquor of cutting, the useless tank liquor of degreasing and washing waste water concentrated water part, the height Density wastewater further includes at least one of the useless tank liquor of pickling and the useless tank liquor of passivation;
The useless tank liquor of cutting is also handled by cutting the tank liquor pretreating process that gives up before carrying out the hc effluent homogenizing step, The useless tank liquor pretreating process of cutting includes the following steps:
The useless tank liquor homogeneous of cutting:Homogenization is carried out to cutting the tank liquor that gives up;
Demulsification reaction:So that the useless tank liquor of the cutting after homogeneous is detached from stable emulsion state, forms mutual exclusive water phase and oil phase;
Water-oil separating:By the oil phase and aqueous phase separation of the useless tank liquor of cutting after demulsification;The water phase of the useless tank liquor of cutting is as the height Density wastewater enters the hc effluent homogenizing step and carries out homogeneous;
The degreasing gives up before tank liquor carries out the hc effluent homogenizing step and is also given up the processing of tank liquor pretreating process by degreasing, The useless tank liquor pretreating process of the degreasing includes the following steps:
The useless tank liquor homogeneous of degreasing:To degreasing give up tank liquor carry out homogenization;
The useless tank liquor precipitation of degreasing:Flocculant is added in giving up tank liquor to the degreasing after homogeneous and carries out coagulating sedimentation;After coagulating sedimentation The useless tank liquor of degreasing enters the hc effluent homogenizing step as the hc effluent and carries out homogeneous.
9. the treatment process of wheel hub production waste water according to claim 7, which is characterized in that the washing waste water pH is default Value is 7.5-8.5;
The washing waste water settling step, specially:Polyacrylamide and polymerization chlorine are added in washing waste water after being adjusted to pH Change aluminium and carries out coagulating sedimentation;
The washing waste water filtration step, specially:Washing waste water after coagulating sedimentation is passed sequentially through into sand filter and was ensured public security Filter is filtered;
The washing waste water UF membrane step, specially:Filtered washing waste water is passed sequentially through into ultrafiltration membrane group and reverse osmosis Film group carries out UF membrane, obtains washing waste water fresh water part and washing waste water concentrated water part.
10. the treatment process of wheel hub production waste water according to claim 7, which is characterized in that the hc effluent pH is pre- If value is 3.0-3.5;
The hc effluent oxidation step, specially:To adjust be added in the hc effluent after pH hydrogen peroxide and ferrous iron from Son carries out Fenton's reaction, degradable organic pollution in hc effluent of degrading;Hc effluent is sent into UV reactive device again, to Hydrogen peroxide is added in hc effluent, organic pollution difficult to degrade of degrading using the synergy of ultraviolet light and hydrogen peroxide;
The hc effluent settling step, specially:Polyacrylamide and polymerization are added into the hc effluent after oxidative degradation Aluminium chloride carries out coagulating sedimentation;
Further include a step after the hc effluent settling step:
Hc effluent filters:Hc effluent after coagulating sedimentation is filtered by carbon filter.
CN201810872913.0A 2018-08-02 2018-08-02 A kind of processing system and technique of wheel hub production waste water Pending CN108689537A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101734815A (en) * 2009-12-23 2010-06-16 苏州市环境工程有限责任公司 Electronic electroplating wastewater recycling advanced treatment technology
CN105776670A (en) * 2016-05-10 2016-07-20 路林茫 Wastewater split-flow separation and quality-based treatment utilization process method
CN107098518A (en) * 2017-04-21 2017-08-29 深圳市深投环保科技有限公司 The processing method and processing system of chemical nickle-plating wastewater
CN208717062U (en) * 2018-08-02 2019-04-09 东莞道汇环保科技股份有限公司 A treatment system for waste water from wheel hub production

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101734815A (en) * 2009-12-23 2010-06-16 苏州市环境工程有限责任公司 Electronic electroplating wastewater recycling advanced treatment technology
CN105776670A (en) * 2016-05-10 2016-07-20 路林茫 Wastewater split-flow separation and quality-based treatment utilization process method
CN107098518A (en) * 2017-04-21 2017-08-29 深圳市深投环保科技有限公司 The processing method and processing system of chemical nickle-plating wastewater
CN208717062U (en) * 2018-08-02 2019-04-09 东莞道汇环保科技股份有限公司 A treatment system for waste water from wheel hub production

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