CN108688263B - Production method of fast-assembling composite top wallboard - Google Patents

Production method of fast-assembling composite top wallboard Download PDF

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Publication number
CN108688263B
CN108688263B CN201810459979.7A CN201810459979A CN108688263B CN 108688263 B CN108688263 B CN 108688263B CN 201810459979 A CN201810459979 A CN 201810459979A CN 108688263 B CN108688263 B CN 108688263B
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phenol
wallboard
composite
formaldehyde
melamine
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CN108688263A (en
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雷响
雷宇涵
戴勇
丁强
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Anhui Yangzi Meijia New Material Technology Co ltd
Anhui Yangzi Flooring Inc Co
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Anhui Yangzi Flooring Inc Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00Producing flat articles, e.g. films or sheets
    • B29D7/01Films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/02Layered products comprising a layer of paper or cardboard next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G14/00Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
    • C08G14/02Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
    • C08G14/04Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
    • C08G14/06Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
    • C08G14/10Melamines
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/34Condensation polymers of aldehydes or ketones with monomers covered by at least two of the groups C09J161/04, C09J161/18 and C09J161/20
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/028Paper layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51Elastic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536Hardness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54Yield strength; Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Laminated Bodies (AREA)
  • Phenolic Resins Or Amino Resins (AREA)

Abstract

The invention discloses a production method of a fast-assembling composite top wallboard, which comprises the following steps: s1, selecting raw materials; s2, synthesizing resin; s3, preparing a composite wallboard; and S4, testing the performance of the composite wallboard and preparing a finished product. According to the invention, melamine, phenol and formaldehyde are subjected to copolycondensation under the weak base condition to obtain melamine-phenol-formaldehyde resin, the melamine-phenol-formaldehyde resin is used as matrix resin to prepare a series of laminated boards, and the addition of the glass fiber layer greatly improves the impact strength, tensile strength, elastic modulus and Rockwell hardness of the composite top wallboard, so that the melamine-phenol-formaldehyde resin has long storage period, the formaldehyde emission of the composite top wallboard is increased, and the flame resistance is enhanced.

Description

Production method of fast-assembling composite top wallboard
Technical Field
The invention belongs to the field of architecture, and particularly relates to a production method of a fast-assembly composite top wallboard.
Background
High molecular polymer materials are widely used in various aspects of production and life, but meanwhile, fire caused by flammability of the high molecular polymer materials also brings about serious casualties and economic losses, and the fireproof plate is a fireproof building material for surface decoration and is widely used in the fields of interior decoration, furniture, kitchen cabinets, laboratory tables, outer walls and the like. The fireproof plate has a plurality of varieties, wherein the phenolic fireproof plate is one of varieties which are considered to have satisfactory performance and competitive cost, so that the phenolic fireproof plate has wide application prospect.
However, the flame resistance of the composite top wall panel in the prior art is not good enough, and therefore a production method of the fast-assembly composite top wall panel with good flame resistance is provided to solve the problems.
Disclosure of Invention
The invention aims to provide a production method of a fast-assembling composite top wallboard, which aims to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: a production method of a fast-assembling composite roof wallboard comprises the following steps:
s1, selecting raw materials: selecting melamine, formaldehyde, phenol, kraft paper, sodium hydroxide solution and glass fiber as raw materials;
s2, synthesis of resin: weighing a certain amount of formaldehyde and phenol, melting the phenol, adding the melted phenol and the formaldehyde into a stirring tank, uniformly stirring, simultaneously adding a certain amount of sodium hydroxide solution to adjust the pH value to 8.0-9.5, heating to 40-45 ℃, adding melamine, continuously heating to 90-95 ℃, preserving heat for 30-45min, and preserving heat for 45-60min when the reaction is finished;
s3, preparation of the composite wallboard: preparing a fireproof plate on a flat vulcanizing machine, adopting a direct method gum dipping process to glue two surfaces of kraft paper, respectively adding three layers, six layers and nine layers of glass fibers in the middle of the kraft paper for reinforcement in the stacking process of the kraft paper, then putting the kraft paper into a drying box for oxidation drying and curing, heating the kraft paper by steam in the drying box, circulating hot air to uniformly dry the kraft paper, and taking down the composite wallboard after drying and cooling;
s4, performance test and finished product preparation of the composite wallboard: and (4) detecting the impact, the tension and the hardness of the extracted composite wallboard, and shearing and polishing the prepared composite wallboard to obtain a finished product.
Preferably, the molar ratio of the formaldehyde to the phenol in the step S2 is 1:1.0-1.5, and the addition amount of the melamine is 40% of the mass of the phenol.
Preferably, the operation speed of the impregnated paper base in the step S3 is 10-15 m/min, the temperature of the oven is 90-100 ℃, and the final impregnation amount is 30 g/m.
Preferably, the hot pressing process of the drying oven in the step S3 includes preheating, heating, heat preservation and cooling, wherein the preheating temperature is 40 ℃, the heating temperature is increased to 120 ℃, the heat preservation time is 45-60min, and the cooling is performed to the room temperature.
The invention has the technical effects and advantages that: according to the production method of the fast-assembly composite top wallboard, melamine, phenol and formaldehyde are subjected to copolycondensation under the condition of weak alkali to obtain melamine-phenol-formaldehyde resin, the melamine-phenol-formaldehyde resin is used as matrix resin to prepare a series of laminated boards, and a glass fiber layer is added, so that the impact strength, the tensile strength, the elastic modulus and the Rockwell hardness of the composite top wallboard are greatly improved, the melamine-phenol-formaldehyde resin is long in storage period, the formaldehyde emission of the composite top wallboard is increased, and the flame resistance is enhanced.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
A production method of a fast-assembling composite roof wallboard comprises the following steps:
s1, selecting raw materials: selecting melamine, formaldehyde, phenol, kraft paper, sodium hydroxide solution and glass fiber as raw materials;
s2, synthesis of resin: weighing a certain amount of formaldehyde and phenol, melting the phenol, adding the melted phenol and the formaldehyde into a stirring tank, uniformly stirring, simultaneously adding a certain amount of sodium hydroxide solution to adjust the pH value to 8.0-9.5, heating to 40-45 ℃, adding melamine, continuously heating to 90-95 ℃, preserving heat for 30-45min, and preserving heat for 45-60min when the reaction is finished;
s3, preparation of the composite wallboard: preparing a fireproof plate on a flat vulcanizing machine, adopting a direct method gum dipping process to glue two surfaces of kraft paper, respectively adding three layers, six layers and nine layers of glass fibers in the middle of the kraft paper for reinforcement in the stacking process of the kraft paper, then putting the kraft paper into a drying box for oxidation drying and curing, heating the kraft paper by steam in the drying box, circulating hot air to uniformly dry the kraft paper, and taking down the composite wallboard after drying and cooling;
s4, performance test and finished product preparation of the composite wallboard: and (4) detecting the impact, the tension and the hardness of the extracted composite wallboard, and shearing and polishing the prepared composite wallboard to obtain a finished product.
Specifically, in the step S2, the molar ratio of formaldehyde to phenol is 1:1.0-1.5, and the addition amount of melamine is 40% of the mass of phenol.
Specifically, in the step S3, the operation speed of the impregnated paper base is 10-15 m/min, the temperature of the oven is 90-100 ℃, and the final impregnation amount is 30 g/m.
Specifically, the hot-pressing process of the drying box in the step S3 includes preheating, heating, heat preservation and cooling, wherein the preheating temperature is 40 ℃, the heating is carried out to 120 ℃, the heat preservation time is 45-60min, and the cooling is carried out to the room temperature.
According to the production method of the fast-assembly composite top wallboard, melamine, phenol and formaldehyde are subjected to copolycondensation under the condition of weak alkali to obtain melamine-phenol-formaldehyde resin, the melamine-phenol-formaldehyde resin is used as matrix resin to prepare a series of laminated boards, and a glass fiber layer is added, so that the impact strength, the tensile strength, the elastic modulus and the Rockwell hardness of the composite top wallboard are greatly improved, the melamine-phenol-formaldehyde resin is long in storage period, the formaldehyde emission of the composite top wallboard is increased, and the flame resistance is enhanced.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments or portions thereof without departing from the spirit and scope of the invention.
A production method of a fast-assembling composite roof wallboard comprises the following steps:
s1, selecting raw materials: selecting melamine, formaldehyde, phenol, kraft paper, sodium hydroxide solution and glass fiber as raw materials;
s2, synthesis of resin: weighing a certain amount of formaldehyde and phenol, melting the phenol, adding the melted phenol and the formaldehyde into a stirring tank, uniformly stirring, simultaneously adding a certain amount of sodium hydroxide solution to adjust the pH value to 8.0-9.5, heating to 40-45 ℃, adding melamine, continuously heating to 90-95 ℃, preserving heat for 30-45min, and preserving heat for 45-60min when the reaction is finished;
s3, preparation of the composite wallboard: preparing a fireproof plate on a flat vulcanizing machine, adopting a direct method gum dipping process to glue two surfaces of kraft paper, respectively adding three layers, six layers and nine layers of glass fibers in the middle of the kraft paper for reinforcement in the stacking process of the kraft paper, then putting the kraft paper into a drying box for oxidation drying and curing, heating the kraft paper by steam in the drying box, circulating hot air to uniformly dry the kraft paper, and taking down the composite wallboard after drying and cooling;
s4, performance test and finished product preparation of the composite wallboard: and (4) detecting the impact, the tension and the hardness of the extracted composite wallboard, and shearing and polishing the prepared composite wallboard to obtain a finished product.
Specifically, in the step S2, the molar ratio of formaldehyde to phenol is 1:1.0-1.5, and the addition amount of melamine is 40% of the mass of phenol.
Specifically, in the step S3, the operation speed of the impregnated paper base is 10-15 m/min, the temperature of the oven is 90-100 ℃, and the final impregnation amount is 30 g/m.
Specifically, the hot-pressing process of the drying box in the step S3 includes preheating, heating, heat preservation and cooling, wherein the preheating temperature is 40 ℃, the heating is carried out to 120 ℃, the heat preservation time is 45-60min, and the cooling is carried out to the room temperature.
According to the production method of the fast-assembly composite top wallboard, melamine, phenol and formaldehyde are subjected to copolycondensation under the condition of weak alkali to obtain melamine-phenol-formaldehyde resin, the melamine-phenol-formaldehyde resin is used as matrix resin to prepare a series of laminated boards, and a glass fiber layer is added, so that the impact strength, the tensile strength, the elastic modulus and the Rockwell hardness of the composite top wallboard are greatly improved, the melamine-phenol-formaldehyde resin is long in storage period, the formaldehyde emission of the composite top wallboard is increased, and the flame resistance is enhanced.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments or portions thereof without departing from the spirit and scope of the invention.

Claims (3)

1. A production method of a fast-assembling composite roof wallboard is characterized by comprising the following steps:
s1, selecting raw materials: selecting melamine, formaldehyde, phenol, kraft paper, sodium hydroxide solution and glass fiber as raw materials;
s2, synthesis of resin: weighing a certain amount of formaldehyde and phenol, melting the phenol, adding the phenol and the formaldehyde into a stirring tank, uniformly stirring, adding a certain amount of sodium hydroxide solution, adjusting the p H value to be 8.0-9.5, heating to 40-45 ℃, adding melamine, continuously heating to 90-95 ℃, keeping the temperature for 30-45min, and keeping the temperature of the solution for 45-60min when the reaction is finished, wherein the molar ratio of the formaldehyde to the phenol is 1:1.0-1.5, and the addition amount of the melamine is 40% of the mass of the phenol;
s3, preparation of the composite wallboard: preparing a fireproof plate on a flat vulcanizing machine, adopting a direct method gum dipping process to glue two surfaces of kraft paper, respectively adding three layers, six layers and nine layers of glass fibers in the middle of the kraft paper for reinforcement in the stacking process of the kraft paper, then putting the kraft paper into a drying box for oxidation drying and curing, heating the kraft paper by steam in the drying box, circulating hot air to uniformly dry the kraft paper, and taking down the composite wallboard after drying and cooling;
s4, performance test and finished product preparation of the composite wallboard: and (4) detecting the impact, the tension and the hardness of the extracted composite wallboard, and shearing and polishing the prepared composite wallboard to obtain a finished product.
2. The method of claim 1 for producing a quick-install composite ceiling panel, wherein: in the step S3, the operation speed of the gumming paper machine is 10-15 m/min, the temperature of the oven is 90-100 ℃, and the final gum dipping amount is 30 g/m.
3. The method of claim 1 for producing a quick-install composite ceiling panel, wherein: and the hot pressing process of the drying box in the step S3 comprises preheating, heating, heat preservation and cooling, wherein the preheating temperature is 40 ℃, the heating is carried out to 120 ℃, the heat preservation time is 45-60min, and the cooling is carried out to the room temperature.
CN201810459979.7A 2018-05-15 2018-05-15 Production method of fast-assembling composite top wallboard Active CN108688263B (en)

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Publication number Priority date Publication date Assignee Title
CN112715386B (en) * 2021-01-15 2023-01-24 上海奇偌新材料科技有限公司 Environment-friendly agglomerated cat litter and production process thereof
CN113619245B (en) * 2021-07-21 2023-06-09 今创集团股份有限公司 High-strength composite decoration panel

Citations (4)

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Publication number Priority date Publication date Assignee Title
CN201179674Y (en) * 2008-03-18 2009-01-14 金月华 Wooden composite decoration sheet
CN103571409A (en) * 2012-07-31 2014-02-12 苏州维艾普新材料有限公司 High-temperature resistant and fire-retardant adhesive and preparation method thereof
CN104942966A (en) * 2014-03-24 2015-09-30 周国贞 Machining process of fireproof board
CN105500873A (en) * 2015-12-22 2016-04-20 苏州市强森木业有限公司 Manufacturing method of synergistic flame-retardant composite laminated fireproof plate

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9133374B2 (en) * 2012-05-03 2015-09-15 Georgia-Pacific Chemicals Llc Resin systems for making composite products

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201179674Y (en) * 2008-03-18 2009-01-14 金月华 Wooden composite decoration sheet
CN103571409A (en) * 2012-07-31 2014-02-12 苏州维艾普新材料有限公司 High-temperature resistant and fire-retardant adhesive and preparation method thereof
CN104942966A (en) * 2014-03-24 2015-09-30 周国贞 Machining process of fireproof board
CN105500873A (en) * 2015-12-22 2016-04-20 苏州市强森木业有限公司 Manufacturing method of synergistic flame-retardant composite laminated fireproof plate

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Patentee before: ANHUI YANGZI FLOORING Inc.,Co.

OL01 Intention to license declared
OL01 Intention to license declared
EE01 Entry into force of recordation of patent licensing contract
EE01 Entry into force of recordation of patent licensing contract

Application publication date: 20181023

Assignee: Laian Yangtze Floor Co.,Ltd.

Assignor: ANHUI YANGZI FLOORING Inc.,Co.|Anhui Yangzi Meijia New Material Technology Co.,Ltd.

Contract record no.: X2025980024922

Denomination of invention: A production method for a quick-assembly composite ceiling and wall panel

Granted publication date: 20210202

License type: Open License

Record date: 20250930