CN108661261B

CN108661261B - Impregnating coated composite anti-crack texture sandwich coating, coating and preparation method

Info

Publication number: CN108661261B
Application number: CN201710197149.7A
Authority: CN
Inventors: 吴学锋
Original assignee: Suzhou Hongni New Material Technology Co ltd
Current assignee: Suzhou Hongni New Material Technology Co ltd
Priority date: 2017-03-29
Filing date: 2017-03-29
Publication date: 2020-06-16
Anticipated expiration: 2037-03-29
Also published as: CN108661261A; CN111593854A; CN111593854B

Abstract

The invention provides an impregnation coating composite anti-crack texture sandwich coating, a coating and a method for manufacturing the coating or the coating on the surface of an object, wherein before the plasticity of a first coating is lost, a fiber texture network sandwich is adhered on the first coating, the fiber texture network sandwich contains a three-dimensional interpenetrating network structure formed by fibers, and the coating of the first coating infiltrates the fibers and infiltrates into meshes of the three-dimensional interpenetrating network structure; then coating a second coating, and applying pressure to enable the coating of the second coating to infiltrate the fibers of the three-dimensional interpenetrating network structure and into the pores of the three-dimensional interpenetrating network structure; and curing the sandwich coating, wherein in the curing process of the second coating, the coating positioned on the surfaces of the meshes of the three-dimensional interpenetrating network structure is inwards greatly collapsed, and the coating positioned on the surfaces of the fibers is blocked by the fibers and does not collapse or forms small depressions, so that the texture is formed. The invention can be used for manufacturing textures in a standardized and large-scale manner and has good crack resistance.

Description

Impregnating coated composite anti-crack texture sandwich coating, coating and preparation method

Technical Field

The invention relates to a method for decorating the surface of an object, in particular to a method for manufacturing an anti-crack texture sandwich coating and a coating on the surface of an object such as a building.

Background

The wall surface coating is used for decorating and protecting the building wall surface, so that the building wall surface is attractive and tidy, and meanwhile, the wall surface coating can also play a role in protecting the building wall surface and prolonging the service life of the building wall surface. In the specific technical field, the development of various binder film-forming technologies makes great progress on the performance of the coating, and the development of emulsion preparation technology is particularly important. The existing coating materials form a component system with binders, fillers, pigments, additives and solvents (such as water). In order to embody the environmental protection performance of the coating, inorganic binders (such as silicates) and various aqueous emulsions are commonly used as film-forming materials for the coating. In order to reduce the content of harmful substances such as VOC, benzene, formaldehyde and the like, water is generally used as a solvent.

Throughout the development process of the architectural coating technology, the development of the coating technology goes through the process from simple color decoration and functional protection to balanced development of color and functional protection, and the wall coating is developed towards the trend of rich and colorful, fashionable, healthy, environment-friendly and functional besides the decoration and protection functions of the wall coating.

The texture coating is mainly characterized in that different shapes and patterns are formed on a wall by using special tools, so that the space is more three-dimensional, real, attractive and elegant. The texture paint shows a unique space visual angle by the infinitely variable three-dimensional texture and the multi-choice individual collocation, and meets the overall decoration style by individual creation, so that the texture paint shows the own unique style in decoration, and the texture paint can also be called as artistic paint. However, the texture formed on the surface of the wall body by the texture coating is manual texture, so that a standardized and large-scale texture effect cannot be formed, and the requirement of uniform and uniform texture cannot be met when the texture coating is used in a large area.

In order to show the coating texture of the coating, the particle size of the filler in the coating component needs to be enlarged, generally the particle size range of sand, and various manual-plastering coating textures and spraying textures are formed by adopting the methods of manual plastering and spray gun spraying. In order to improve the crack resistance of the coating, a high-elasticity binder is generally used as a film-forming material to improve the ductility of the coating, or suitable short fibers are added to the components such as the binder, the filler, the pigment, the additive and the solvent (such as water) to improve the crack resistance of the coating, so as to meet the crack resistance requirement of the coating. Similar to the texture coatings described above, this texture also does not provide a standardized, scaled texture effect.

In the other technology aspect of making textures on the surface of a wall body, one is to make textures in a coating on the surface of a building by adopting a special tool. For example, chinese patents CN205577286U and CN205444747U both adopt a scraper and a spatula to scrape and coat the surface of the coating to form texture, the texture coating has high requirements on operators, the texture of the surface of the same building is easily different, and the crack resistance is poor. The other way is to form texture in a way of sticking wallpaper, wall cloth or a wallpaper imitation decorative layer, the rough surface of the wallpaper, wall cloth or decorative layer is used as the texture, and then coating is coated on the surface, the wallpaper in the texture coating is easy to peel off, and when the adjacent wallpapers are butted, gaps are very obvious, so that the texture can not be smoothly transited. For example, in chinese patent CN103758307A, the base material components are first pressed and molded in a mold with a wallpaper texture to produce a decorative surface with texture, and then an ultraviolet-resistant coating is sprayed on the texture surface, and when in use, the produced wallpaper texture-imitating layer is adhered to a wall.

Coatings with both crack resistance and texture have become a popular research direction in the coating field except for environmental protection performance, but related technologies are not yet available.

Disclosure of Invention

Aiming at the defects of no crack resistance, uncontrollable texture and the like existing in the process of manufacturing the texture on the surface of a building by using the conventional coating, the invention provides an impregnation coating composite crack-resistant texture sandwich coating, the coating and a manufacturing method.

The first aspect of the invention provides a method for manufacturing an impregnated and coated composite anti-crack texture sandwich coating on the surface of an object, and the second aspect of the invention provides a method for manufacturing texture on the surface of an object. The object is preferably a building or a part of a building (such as an inner wall, an outer wall, a column, a roof, a ground), or building decoration material such as decorative boards, tiles and the like, or a sculpture, a billboard, furniture and the like, and is more preferably a building wall, especially an inner wall.

The invention relates to a method for manufacturing an impregnation coating composite anti-crack texture sandwich coating on the surface of an object, or a method for manufacturing a texture, which comprises the following steps:

coating a first coating on the surface of an object;

before the plasticity of the first coating is lost, attaching a fiber texture network sandwich to the first coating, wherein the fiber texture network sandwich contains a three-dimensional interpenetrating network structure formed by fibers, and the coating of the first coating infiltrates the fibers and permeates into meshes of the three-dimensional interpenetrating network structure;

coating a second coating on the surface of the fibrous texture network sandwich, and applying pressure to enable the coating of the second coating to infiltrate into the fibers of the three-dimensional interpenetrating network structure and the meshes of the three-dimensional interpenetrating network structure; forming a sandwich coating;

and curing the sandwich coating, wherein in the curing process of the second coating, the coating positioned on the surfaces of the meshes of the three-dimensional interpenetrating network structure is inwards greatly collapsed, and the coating positioned on the surfaces of the fibers is blocked by the fibers and does not collapse or forms small depressions, so that the texture is formed.

Wherein before the second coating is cured, the second coating can be flattened during pressing, and the texture of the second coating is formed due to different mesh holes and fiber subsidence after curing.

Wherein, the first coating can also be retracted or not retracted during the curing process.

In a preferred embodiment, after the fibrous texture network is applied to the first coating layer, pressure is applied to at least partially immerse the fibrous texture network into the first coating layer.

In a preferred embodiment, the coating material of the second coating layer is immersed in the pores of the three-dimensional interpenetrating network structure and is contacted with the coating material of the first coating layer immersed in the pores of the three-dimensional interpenetrating network structure, and more preferably, after the first coating layer and the second coating layer are contacted, the pressure is continuously applied to further combine the first coating layer and the second coating layer tightly.

In a preferred embodiment of the invention, the first coating, and/or the second coating is one or more coatings, each of which may independently be the same or different.

For example, the first coating layer may be one or more adhesive layers, and/or organic coating layers, and/or inorganic coating layers. Also, the first coating layer may contain a putty layer, a base coat layer, a sealing primer layer, an interfacial agent, and the like.

For example, the second coating may be one or more adhesive layers, and/or organic coating layers, and/or inorganic coating layers. Also, the second coating layer may contain a top coat layer, an abrasion resistant layer, and the like.

The first coating and the second coating can be independently and preferably one or more of an opaque coating, a semitransparent coating and a transparent coating; or the first coating and the second coating can independently contain one or more of a transparent coating and a semitransparent coating, and particularly the second coating can be preferably one or more of a semitransparent coating and a transparent coating; or the second coating layer can preferably contain one or more of a transparent coating layer and a semitransparent coating layer.

In a preferred embodiment of the present invention, the adhesive may be an inorganic adhesive and/or an organic adhesive, and preferably, the film-forming material thereof may be any one or more of adhesives at least including cement, lime, epoxy resin, organic silica gel, silicone adhesive, polyamide adhesive, polyurethane resin, acrylic resin, melamine-formaldehyde resin, polyester, polyacrylate, and polyvinyl acetate.

In a preferred embodiment of the present invention, the organic coating film-forming material may be any one or more materials at least including tung oil, nitrocellulose, alkyd resin, epoxy resin, polyacrylate, polyurethane, polyvinyl acetate, latex paint, and the like.

In the preferred embodiment of the present invention, the inorganic coating film-forming material may include at least one or more of alkali metal silicate, colloidal silica, phosphate, and polysiloxane. The inorganic coating is more preferably an inorganic dry powder coating.

More preferably, both the first coating and the second coating most preferably comprise at least one inorganic dry powder coating.

In a more preferred embodiment of the present invention, the method comprises:

coating a first adhesive on the surface of an object;

before the first adhesive loses viscosity, attaching the fiber texture network sandwich to the first adhesive, and infiltrating the fiber with the first adhesive or infiltrating the fiber with the adhesive by applying pressure and infiltrating into meshes of the three-dimensional interpenetrating network structure;

coating a second adhesive on the surface of the fibrous texture network sandwich, and applying pressure to enable the second adhesive to infiltrate the fibers of the three-dimensional interpenetrating network structure and to be immersed into the meshes of the three-dimensional interpenetrating network structure; forming a sandwich coating;

and curing the sandwich coating, wherein in the curing process of the second adhesive, the adhesive on the surfaces of the meshes of the three-dimensional interpenetrating network structure forms larger collapse inwards, and the adhesive on the surfaces of the fibers is blocked by the fibers and does not collapse or forms smaller collapse, so that the texture is formed.

In another more preferred embodiment of the present invention, the method comprises:

coating an adhesive on the surface of an object;

before the adhesive loses viscosity, attaching the fiber texture network sandwich to the adhesive, and infiltrating the fiber with the adhesive or infiltrating the fiber with the adhesive by applying pressure and infiltrating into meshes of the three-dimensional interpenetrating network structure;

coating inorganic dry powder coating on the surface of the fibrous texture network sandwich, and applying pressure to enable the inorganic dry powder coating to soak the fibers of the three-dimensional interpenetrating network structure and to soak into the meshes of the three-dimensional interpenetrating network structure; forming a sandwich coating;

and curing the sandwich coating, wherein in the curing process of the inorganic dry powder coating, the coating positioned on the surfaces of the meshes of the three-dimensional interpenetrating network structure is inwards greatly collapsed, and the coating positioned on the surfaces of the fibers is blocked by the fibers and does not collapse or forms small depressions, so that the convex-concave three-dimensional texture is formed.

coating a first inorganic dry powder coating on the surface of an object;

before the plasticity of the first inorganic dry powder coating is lost, attaching the fiber texture network sandwich to the first inorganic dry powder coating, and infiltrating the fiber by the first inorganic dry powder coating or infiltrating the fiber by applying pressure by the first inorganic dry powder coating into the mesh of the three-dimensional interpenetrating network structure;

coating a second inorganic dry powder coating on the surface of the fibrous texture network sandwich, and applying pressure to enable the second inorganic dry powder coating to infiltrate into the fibers of the three-dimensional interpenetrating network structure and into the meshes of the three-dimensional interpenetrating network structure; forming a sandwich coating;

and curing the sandwich coating, wherein in the curing process of the second inorganic dry powder coating, the coating positioned on the surfaces of the meshes of the three-dimensional interpenetrating network structure inwards forms large collapse, and the coating positioned on the surfaces of the fibers is blocked by the fibers and does not collapse or forms small collapse, so that the texture is formed.

The third aspect of the invention provides an impregnated and coated composite anti-crack texture sandwich coating, which comprises a first coating, a second coating and a fiber texture network sandwich sandwiched between the first coating and the second coating, wherein the fiber texture network sandwich contains a three-dimensional interpenetrating network structure formed by fibers, and the first coating and the second coating are infiltrated into meshes of the three-dimensional interpenetrating network structure; the second coating is sunk in the partial surface of the three-dimensional interpenetrating network structure meshes, and the convex-concave three-dimensional texture is formed on the part of the three-dimensional interpenetrating network structure fiber surface without or with smaller sunk parts.

The fourth aspect of the invention provides an infiltration coating composite anti-crack texture sandwich coating, which comprises a first coating, a second coating and a fiber texture network sandwich sandwiched between the first coating and the second coating, wherein the fiber texture network sandwich contains a three-dimensional interpenetrating network structure formed by fibers, and the first coating and the second coating infiltrate the fiber surface of the fiber texture network sandwich and infiltrate into meshes of the three-dimensional interpenetrating network structure; the second coating is sunk in the partial surface of the three-dimensional interpenetrating network structure meshes, and the convex-concave three-dimensional texture is formed on the part of the three-dimensional interpenetrating network structure fiber surface without or with smaller sunk parts.

The invention provides an object with textures on the surface, in particular to a wall with textures on the surface, which comprises a body, wherein an impregnating coating composite anti-crack texture sandwich coating is formed on the surface of the body, the impregnating coating composite anti-crack texture sandwich coating comprises a first coating, a second coating and a fiber texture network sandwich sandwiched between the first coating and the second coating, the fiber texture network sandwich contains a three-dimensional interconnected network structure formed by fibers, and the first coating and the second coating infiltrate the fiber surface of the fiber texture network sandwich and permeate into meshes of the three-dimensional interconnected network structure; the first coating is adhered to the surface of the body; the second coating is sunk in the partial surface of the three-dimensional interpenetrating network structure meshes, and the convex-concave three-dimensional texture is formed on the part of the three-dimensional interpenetrating network structure fiber surface without or with smaller sunk parts.

In a preferred embodiment of the present invention, the first coating layer and the second coating layer are connected in the pores of the three-dimensional interpenetrating network structure, and are preferably connected into a whole. In another preferred embodiment of the present invention, the first coating layer and the second coating layer are not in contact with each other in part of the mesh openings or all of the mesh openings of the three-dimensional interpenetrating network structure, that is, voids are formed between the first coating layer and the second coating layer in the mesh openings of the three-dimensional interpenetrating network structure.

In a preferred embodiment of the present invention, the first coating layer and the second coating layer may be respectively and independently a multi-layer coating layer, and each layer of the multi-layer coating layer may be independently the same or different.

The first coating and the second coating can be one or more of opaque coating, semitransparent coating and transparent coating independently; or the first coating and the second coating can be independently and preferably selected from one or more transparent coatings and semitransparent coatings, and especially the second coating can be preferably selected from one or more semitransparent coatings or transparent coatings; or the second coating layer can preferably contain one or more of a transparent coating layer and a semitransparent coating layer.

In the above aspect of the invention, the fibrous texture network sandwich comprises fibers and three-dimensional crossed meshes formed by the gaps among the fibers, and more preferably, the fibers are arranged in a three-dimensional distribution.

In a more preferred embodiment, the fibers comprise at least horizontal, vertical, and obliquely oriented fibers, and more preferably, at least two or three of the horizontal portion, the vertical portion, and the obliquely oriented portion are present for each of at least some of the fibers.

More preferably, any one or more of the horizontal part, the vertical part and the inclined part of the fiber are mutually crossed, and/or any one or more of the horizontal part, the vertical part and the inclined part of the fiber are mutually crossed with any one or more of the horizontal part, the vertical part and the inclined part of the fiber.

In a more preferred embodiment, the meshes at least comprise meshes in horizontal, vertical and inclined directions, wherein one or more of the meshes in the horizontal, vertical and inclined directions are communicated with one or more of the meshes in the other horizontal, vertical and inclined directions.

The term "inclined" as used in the above description of the present invention means that the included angle is not 0 degrees with respect to both the horizontal and vertical directions. The "horizontal" is in the horizontal plane and the "vertical" is in the vertical plane. That is, the "horizontal", "vertical" and "inclined" do not belong to the same plane.

The "horizontal parts" in the above-mentioned contents of the present invention may be in the same horizontal plane, or in different horizontal planes; the vertical parts can be in the same vertical plane or different vertical planes; the "inclined direction portions" may be in the same inclined plane, or in different inclined planes.

In a more preferred embodiment of the present invention, the fibers are arranged in multiple layers, the fibers in the same layer define a first mesh, the fibers in each layer at least partially intersect with each other to define a second mesh, and at least a portion of the first mesh and the second mesh are communicated with each other to form a three-dimensional interpenetrating network structure.

In a more preferred embodiment of the present invention, each layer of fibers may be a two-dimensional network structure formed by interweaving warp and weft threads, and/or a two-dimensional network structure formed by arranging fibers in a curved manner.

More preferably, at least some of the fibers are interspersed between at least two of the fibrous layers.

More preferably, the fibers of each layer are arranged in a staggered manner to form meshes in different directions. For example, the fiber intersections of each layer or at least some of the layers are located at the meshes of the other layers, and/or the fibers of each layer or at least some of the layers have a different fiber direction than the other layers.

In the above aspect of the present invention, the connection points between the fibers of the fibrous texture network sandwich may be one or more of connection methods such as welding, chemical bonding, and the like, and are preferably welded.

In the above aspect of the present invention, the number of the fiber connection points of the fiber texture network sandwich is preferably 1% to 100%.

In the above aspect of the present invention, the number of the connection points refers to the percentage of the number of the connection points of the fibers to the number of the fiber intersections.

In the above content of the present invention, the fibrous texture network sandwich may be made of materials such as metal, plastic, rubber, fiber, and the like, and is preferably made of fiber materials, and the fiber may be any one or more of inorganic fiber and organic fiber, and may be any one or more of synthetic fiber, natural fiber (including natural fiber modification), regenerated fiber obtained after natural fiber processing, metal fiber, and alloy fiber.

In a more preferred embodiment, the fibers may be selected from: polyamide (nylon 6, nylon 66, etc.), polyimide (such as P84 fiber), polypropylene, polytetrafluoroethylene, polyester (such as PET, PBT, etc.), aramid (such as aramid 1414, aramid 1313, etc., specifically Kevlar, Nomex, Twaron, Technora, Taparan, etc., of dupont), polyphenylene sulfide, etc. But may be glass fiber or the like.

The fiber can also improve rigidity and anti-deformation capability through modification processes such as gum dipping and the like.

The fiber section shape of the fiber texture network sandwich can be one or more regular and/or irregular shapes, such as at least one or more of the shapes of circle, ellipse, semicircle, polygon (such as triangle, quadrangle, pentagon and hexagon), pentagram, cashew nut, ripple, dumbbell and the like, and preferably one or more of the shapes of circle and ellipse.

In the above-mentioned aspect of the present invention, the fibrous texture network sandwich is preferably obtained by one or more methods of weaving (including non-woven materials and non-woven fabric technology), casting, die pressing, 3D printing, and the like. Particularly preferably by non-woven fabric technology, and/or non-woven textile material technology, such as electrospinning technology and the like. In a more preferred embodiment, the method for manufacturing the fiber texture network sandwich comprises the following steps: and performing melt spinning, namely, spinning and laminating fiber yarns, and then, performing hot pressing to respectively connect fibers in layers and between layers.

In the above aspect of the present invention, the fiber diameter of the fibromuscular network core is preferably 1 μm to 5000 μm, more preferably 1 μm to 1000 μm, more preferably 1 μm to 100 μm, more preferably 1 μm to 50 μm, more preferably 5 μm to 50 μm, and more preferably 5 μm to 40 μm.

In the above aspect of the present invention, the thickness of the fibrous texture network sandwich is preferably 0.1mm to 10mm, more preferably 0.1mm to 5mm, more preferably 0.1mm to 1mm, more preferably 0.1mm to 0.5mm, more preferably 0.2 mm to 0.4mm, such as 0.25mm, 0.28mm, 0.3mm, 0.33mm, 0.35mm, 0.37mm, etc.

In the above aspect of the invention, the mesh shape of the fiber texture network sandwich is not particularly required, and can be set according to the texture requirement. Wherein, the meshes can be uniformly distributed, or the distribution density of the meshes in different areas is different.

In the above aspect of the present invention, the mesh opening of the fibrous texture network sandwich preferably has a pore size of 0.1mm to 10mm, more preferably 0.1mm to 5mm, more preferably 0.1mm to 3mm, and more preferably 0.1mm to 1 mm.

In the above aspect of the invention, the density of the fiber texture network sandwich is preferably 10-300g/m²More preferably 15 to 200g/m²More preferably 20 to 150g/m²More preferably 20 to 100g/m²More preferably 20 to 50g/m²。

In the above aspect of the present invention, the fiber texture network sandwich further comprises at least one pattern, the pattern is formed by a structural structure which is the same as or different from the fiber texture network sandwich, and the pattern can be protruded or recessed in the fiber texture network sandwich, or the fiber texture network sandwich is die-cut to form a pattern penetrating through the fiber texture network sandwich.

In a more preferred embodiment, the pattern is formed by a more dense or loose mesh arrangement than the rest of the pattern. Alternatively, the pattern of the fibrous texture network core may be formed of a mesh. Alternatively, the pattern of the fibrillar texture network core may be prepared by an embossing process.

The pattern can be realized by one or more of the technologies of weaving (including non-woven fabric technology), casting, mould pressing, hot bonding stamping, blocking partial meshes and the like, and preferably, the pattern can be realized by one or more of the methods of non-woven fabric technology, plastic spraying, film pasting, hot bonding stamping, blocking partial meshes, die cutting and the like. More preferably, the method is realized by a non-woven fabric technology, and the pattern can be formed in the process of forming the three-dimensional interpenetrating network structure of the fiber texture network sandwich by spinning, or the pattern can be formed by hot pressing after the fiber texture network sandwich is formed.

In the above aspect of the invention, the fibrous texture network sandwich may be or have been subjected to surface finishing. But may also be without surface finishing. The surface finish may be a single-sided surface finish or a double-sided surface finish.

Wherein, the surface finishing is preferably any one or more of the following a) to g):

a) flattening the surface, but leaving surface openings in communication with the internal mesh; can be single-sided flattening or double-sided flattening;

b) the surface is coated with a material that alters the properties of the fibers, preferably with a material that has a different water absorption, more preferably the properties (e.g., water absorption) are graded from one end of the surface finish portion to the other end, more preferably the properties (e.g., water absorption) are graded from one end of the fibrous texture network core to the other end;

c) dyeing, namely enabling the surface of the fiber texture network sandwich to have colors, wherein the colors are preferably single colors and multiple colors, and the multiple colors are preferably gradient colors;

d) sticking the film, but keeping the surface opening communicated with the internal mesh;

e) molding to make the sandwich surface of the fiber texture network have indentation patterns; more preferably, embossing, rolling point and hole finishing are carried out;

f) die cutting to make the fibrous texture network sandwich have through patterns;

g) and the processes of dipping and the like are modified to improve the rigidity of the fiber and improve the deformation resistance.

In the above aspect of the present invention, the thickness of the fibrous texture network core is preferably greater than or equal to the sum of the thicknesses of the first coating layer and the second coating layer, and is particularly preferably greater than the sum of the thicknesses of the first coating layer and the second coating layer.

In the above aspect of the present invention, the thickness of the second coating layer is preferably 1/2 which is less than or equal to the thickness of the fibrous texture network core, and more preferably 1/2 which is less than the thickness of the fibrous texture network core.

In the content of the invention, the material or the coating of the coating can be any available coating, and the particle size of the coating can meet the functions of infiltrating, permeating and filling the coating into the mesh in the three-dimensional interpenetrating network structure of the fiber texture network sandwich.

In the above aspect of the present invention, the maximum particle diameters of the first coating layer and the second coating layer are preferably 50 μm or less, more preferably 30 μm or less, more preferably 20 μm or less, and more preferably 10 μm or less, respectively.

In the above aspect of the invention, the maximum particle diameters of the first coating and the second coating are preferably not more than 1/5, more preferably not more than 1/10, and more preferably not more than 1/100 of the average pore diameter of the meshes of the fibrous texture network sandwich; but more preferably is not less than 1/1000.

In the above-mentioned disclosure, the first coating layer and the second coating layer each independently preferably include an inorganic gel material and/or an organic gel material, more preferably at least an inorganic gel material, and more preferably, may further include any one or more of a filler, an additive, a pigment, and a solvent.

The inorganic gel material can at least comprise any one or more of cement, lime, alkali metal silicate, phosphate, silica sol and polysiloxane, and preferably at least comprises any one or more of cement, lime and alkali metal silicate.

Wherein, the organic gel material can be any one or more of tung oil, linseed oil, shellac, epoxy resin, alkyd resin, amino alkyd resin, polyurethane, chlorinated rubber, perchloroethylene paint, polyvinyl acetate emulsion, styrene-acrylic emulsion, ethylene-propylene emulsion, pure acrylic emulsion and the like.

Wherein, the filler can be one or more of stone powder, fiber and metal powder, such as any one or more of graphite, talcum powder, glass powder, diatomite, kaolin, carbon black, alumina, mica, wood powder, asbestos powder, pottery clay, calcium carbonate and fly ash.

The additive can be any available additive capable of improving the form and/or appearance (such as color) of the coating, such as one or more of a drier, an anti-settling agent, an anti-aging agent, a mildew preventive, a plasticizer, polymer rubber powder, cellulose ether, a defoaming agent, a thickening agent, a waterproof agent, a leveling agent and the like.

The solvent may contain any one or more of water and organic solvents (such as toluene, xylene, cyclohexanone, formaldehyde, etc.), and the solvent is preferably water.

In the above content of the present invention, the curing time (plasticity loss) of the first coating and the second coating is preferably not limited independently, and the first coating and the second coating can be infiltrated, permeated and filled into the meshes of the fiber texture network sandwich after being pasted with the fiber texture network sandwich. It is generally preferred to cure within 24 hours after painting, more preferably within 12 hours after painting, and still more preferably within 2 hours after painting.

The curing time of the first coating and the second coating is more preferably 1 minute after painting, more preferably 2 minutes after painting, more preferably 5 minutes after painting, more preferably 10 minutes after painting, more preferably 15 minutes after painting, more preferably 20 minutes after painting, and more preferably 30 minutes after painting.

In the above-mentioned disclosure, the curing manners of the first coating layer and the second coating layer may be, independently, preferably any one or more of solvent evaporation curing (such as water loss curing), photo-curing, air curing, and reaction curing, and particularly preferably water loss curing and/or air curing.

In the above-mentioned aspect of the present invention, the pressing may be performed by any available method, such as any one or more of rolling and scraping. More preferably, the rolling, scraping process does not itself form texture.

In the above-mentioned aspect of the present invention, the first coating layer and the second coating layer may be coated independently by any one or more known coating methods, such as spraying, knife coating, roller coating, and brush coating.

The method for manufacturing the impregnation coating composite anti-crack texture sandwich coating on the surface of the object or the method for manufacturing the texture has the following beneficial effects that:

1) the impregnating coating paint is coated on the surface of an object, has enough adhesive force with the surface of the object, and the whole coating finish surface is firm and reliable.

2) The coating infiltrates, permeates and fills into the meshes of the three-dimensional interpenetrating network structure of the fiber texture network sandwich, so that the fibers of the fiber texture network sandwich and the infiltrated coating have occlusion and bonding effects, and meanwhile, because the meshes of the three-dimensional interpenetrating network structure are three-dimensionally distributed and are communicated with each other, and the infiltration, permeation and filling of the coating in the meshes are also in a three-dimensional form, the coating and the fiber texture network sandwich can be more tightly combined, so that compared with the texture manufacturing of wallpaper, the coating has obviously higher stripping resistance.

3) The sandwich structure is formed, the fiber texture network sandwich is positioned between the impregnating coating materials, the thickness of the fiber texture network sandwich is more than or equal to the sum of the thicknesses of the first coating and the second coating, after the second coating is coated on the surface of the fiber texture network sandwich, the thickness of the surface of the fiber is increased, and the second coating on the surface of the mesh is sunken in the curing process, so that the texture of the fiber texture network sandwich is presented, therefore, the sandwich structure has the advantage of controllable texture, the fiber texture network sandwich can be manufactured in a standardized and large-scale production manner, and the consistency of the texture is ensured; meanwhile, the texture modeling can be diversified, so that the texture modeling of the coating is rich and diverse.

4) Compared with the texture coating made of wallpaper and wall cloth in a layered mode, the sandwich structure has obviously better anti-stripping capability, and compared with the coating made of glass fiber cloth in the prior art, the sandwich structure is obviously smaller in coating weight and has no loss of pit cracking capability.

5) The method of the invention can produce texture on the surface of the object, no obvious gap can be generated at the butt joint, and the texture consistency is good;

6) the method can produce abundant textures similar to wallpaper on the surface of an object.

Drawings

FIG. 1A is a schematic structural diagram of an impregnated and coated composite anti-crack texture sandwich coating and paint prepared on the surface of a wall body, and FIG. 1B is a schematic structural diagram of the texture of the surface of the wall body in FIG. 1A;

FIGS. 2A-2C are schematic views of different point-like connection points of the fibrous texture network core;

FIG. 3 is a schematic view of a local cross-sectional structure of a three-dimensional interpenetrating network structure of a fibrous texture network sandwich;

FIGS. 4A-4B are perspective photographs of the fibrous texture network core of the present invention;

FIGS. 5A-5B are photographs of the fibrous texture network core of the present invention after being impregnated and filled with a coating;

FIGS. 6A-6C are schematic diagrams of a process for preparing an impregnated coated composite anti-crack texture sandwich coating according to the present invention; wherein: FIG. 6A: coating a first inorganic dry powder coating on the surface of a wall to form a first coating; FIG. 6B: before the plasticity of the first inorganic dry powder coating is lost, attaching the fiber texture network sandwich to the first inorganic dry powder coating; FIG. 6C: a second coating is applied.

Detailed Description

Example 1

Referring to fig. 1A, the structure of the impregnation-coated composite anti-crack texture sandwich coating or paint of the present invention is as follows:

the surface impregnated coated composite crack resistant texture sandwich coating or paint for the wall 10 comprises a first coating 20, a second coating 40, and a fibrous texture network sandwich 30 sandwiched between the first coating 20 and the second coating 40.

The fiber texture network sandwich 30 is internally provided with a three-dimensional interpenetrating network structure formed by fibers, the fibers comprise horizontal fibers, vertical fibers and fibers in an inclined direction, the overlooking structures of the fiber texture network sandwich 30 are shown in figures 2A-2C, referring to figures 2A-2C, in the same plane, transverse fibers 5, longitudinal fibers 4 and inclined fibers 3 are mutually crossed, and the crossed fibers form meshes 2 in a surrounding mode. The intersections between the fibers are at least partially connected together to form the connection points 1, for example, the connection points may be one or more of welding, chemical bonding, and the like, and in this embodiment, welding is preferred.

The number of fibre junctions may be 1-100% of the number of fibre junctions, i.e. junctions may all form junctions, but also only some junctions may form junctions. As shown in fig. 2A, the intersection between the transverse fiber indicated by the mark 5 and the longitudinal fiber indicated by the mark 4 does not form a connection point, but the intersection between the transverse fiber indicated by the mark 5 and the bias fiber indicated by the mark 3, and the intersection between the longitudinal fiber indicated by the mark 4 and the bias fiber indicated by the mark 3 form a connection point 1.

It should be understood that the fibrous texture network core 30 of the present invention is a three-dimensional structure, i.e., the fibers are not all arranged in the same plane, and there are actually horizontal, vertical, and oblique fibers, which cross each other and form at least some of the connection points. In addition, because of the large length of the fibers, each fiber may have a plurality of horizontal portions, vertical portions, and inclined portions, and the plurality of horizontal portions, the plurality of vertical portions, or the plurality of inclined portions may or may not exist in the same horizontal plane, vertical plane, or inclined plane.

As shown in FIG. 3, transverse meshes 22 are formed between the transverse fibers 31 in the upper horizontal plane and the transverse fibers 32 in the lower horizontal plane, and longitudinal meshes 21 are formed between the transverse fibers and the vertical fibers 33 in the vertical plane, and the transverse meshes 22 are communicated with the longitudinal meshes 21. Similarly, the oblique direction meshes 23 are formed between the transverse fibers 31 and the oblique direction fibers and between the vertical fibers 33 and the oblique direction fibers in the upper horizontal plane, respectively, and fig. 3 shows the case where the two oblique direction meshes 23 communicate, but the oblique direction meshes 23 may communicate with the transverse direction meshes 22 and/or the longitudinal direction meshes 21.

The transverse fibers 31 in the upper horizontal plane and the transverse fibers 32 in the lower horizontal plane may be derived from two horizontal portions of the same fiber, or may be derived from two fibers.

The method for preparing the impregnating and coating composite anti-crack texture sandwich coating or coating in the embodiment comprises the following steps:

referring to fig. 6A, a first inorganic dry powder paint is applied to the surface of the wall 10 to form a first coating layer 20, which only needs to cover the surface of the wall 10, but does not need to be smoothed;

referring to fig. 6B, before the first inorganic dry powder coating loses plasticity, the fibrous texture network sandwich 30 is attached to the first inorganic dry powder coating, and the first inorganic dry powder coating infiltrates the fibers, or the first inorganic dry powder coating infiltrates the fibers by applying pressure, and the fibers infiltrate into the pores of the three-dimensional interpenetrating network structure; in the process, the fibrous texture network sandwich 30 can be pressed to contact the surface of the wall body 10 or not, and the first inorganic dry powder coating can also penetrate through the meshes of the fibrous texture network sandwich 30 and seep out of the meshes, but is not necessary;

referring to fig. 6C, a second inorganic dry powder coating, i.e., a second coating 40, is applied, and pressure is applied to make the second inorganic dry powder coating infiltrate into the three-dimensional interpenetrating network structure fibers and into the pores of the three-dimensional interpenetrating network structure; forming a sandwich coating; in the process, the total thickness of the second coating layer and the first coating layer is preferably not more than 50% of the thickness of the fibrous texture network sandwich 30, more preferably not more than 30%, and more preferably not more than 30% of the thickness of the fibrous texture network sandwich 30;

after the pressure is applied, the first inorganic dry powder coating and the second inorganic dry powder coating are contacted in the mesh and are tightly combined under the action of the pressure; as shown in fig. 6C;

curing the sandwich coating, wherein in the curing process of the second inorganic dry powder coating, the coating positioned on the surface of the holes of the three-dimensional interpenetrating network structure forms large collapse inwards, and the coating positioned on the surface of the fiber is blocked by the fiber and does not collapse or forms small collapse, so that the texture is formed; as shown in fig. 1A. And in the curing process of the first inorganic dry powder coating and the second inorganic dry powder coating, the tightly combined parts are connected into a whole.

Referring to fig. 1B, the surface fibers of the fibrous texture network sandwich 30 may be uneven, such as the first portion of fibers 301 is lower than the second portion of fibers 302 in fig. 1B, but the surface of the fibrous texture network sandwich 30 may also be flattened by a flattening process; during the curing of the second coating layer 40, the coating layer on the surface of the fiber is blocked by the fiber to stay on the surface of the fiber, for example, the surface of the first portion of the fiber 301 forms a lower texture 501, the surface of the second portion of the fiber 302 forms an upper texture 502, and the second coating layer 40 is depressed at the mesh openings 2 to form a depressed texture portion 503, thereby forming the rugged texture 50, and the shape of the texture 50 is identical to or very close to the rugged structure of the surface of the fibrous texture network core 30.

Referring to fig. 5A-5B, the coating material is impregnated into the fibers and penetrates into the openings, wherein the dark portions are the coating material or coating material filling the openings and the light portions are the fibers. Because the coating infiltrates, permeates and fills the mesh of the three-dimensional interpenetrating network structure of the fiber texture network sandwich 30, the fiber of the fiber texture network sandwich and the infiltration coating have the effects of occlusion and bonding, and simultaneously, because the pores of the three-dimensional interpenetrating network structure are three-dimensionally distributed and are communicated with each other, and the infiltration, permeation and filling of the coating in the pores are also in a three-dimensional form, the invention can provide tighter combination between the coating and the fiber texture network sandwich 30 and has good stripping resistance.

Referring to fig. 2B, using polyethylene fiber as an example, in the process of welding the fibers of the three-dimensional arrangement of the fiber texture network sandwich 30 by hot pressing, a part of the fibers are melted to form a block structure 100, so that when the first inorganic dry powder coating and the second inorganic dry powder coating are infiltrated and penetrated and filled into the meshes, the biting force on the fibers can be further increased.

Referring to fig. 2C, if the hot pressing is excessive or the bonding is excessive, the molten and cast fibers or bonding agent is filled in the fiber-enclosed mesh 2, but a new mesh 200 is formed in the cast fibers or bonding agent, the new mesh 200 is communicated with the fiber-enclosed mesh 2, and the filling of the coating in the mesh of the fiber texture network sandwich 30 is more complicated, so that the tear resistance (peeling resistance) can be further increased.

Referring to FIGS. 4A-4B, the fiber diameter of the fibromuscular network core of the present invention is preferably 1 μm to 5000 μm, more preferably 1 μm to 1000 μm, more preferably 1 μm to 100 μm, more preferably 1 μm to 50 μm, more preferably 5 μm to 40 μm. The aperture of the mesh of the fibrous texture network sandwich is preferably 0.1mm-5mm, more preferably 0.1mm-3mm, and more preferably 0.1mm-1 mm. The density of the fibrous texture network sandwich 30 is preferably 10-300g/m²More preferably 15 to 200g/m²More preferably 20 to 150g/m²More preferably 20 to 100g/m²More preferably 20 to 50g/m²。

The thickness of the fibrous texture network core 30 is preferably 0.1mm to 10mm, more preferably 0.1mm to 5mm, more preferably 0.1 to 1mm, more preferably 0.1 to 0.5mm, more preferably 0.2 to 0.4mm, such as 0.25mm, 0.28mm, 0.3mm, 0.33mm, 0.35mm, 0.37mm, and the like. The thickness of the fibrous texture network core 30 of the present invention is preferably greater than or equal to the sum of the thicknesses of the first coating and the second coating, and more preferably greater than the sum of the thicknesses of the first coating and the second coating. The second coating thickness is preferably equal to or less than 1/2 a of the thickness of the fibrous texture network core 30.

The first inorganic dry powder coating and the second inorganic dry powder coating are both preferably alkali metal silicate as a film forming material, and can contain components such as fillers, pigments, additives and the like. Of all the components, the largest particles (generally fillers) preferably have a particle size of 50 μm or less, more preferably 30 μm or less, more preferably 20 μm or less, more preferably 10 μm or less. And preferably 1/5 which is less than or equal to the average pore diameter of the meshes of the fibrous texture network sandwich, more preferably 1/10, and more preferably 1/100; but more preferably is not less than 1/1000.

Example 2

coating organic adhesive, such as epoxy resin adhesive, on the surface of the wall 10, or coating the organic adhesive on the surface of the fiber texture network sandwich 30 as a first coating layer, wherein the fiber texture network sandwich 30 is adhered to the surface of the wall 10 by the organic adhesive,

enabling the organic adhesive to infiltrate into the fibers and penetrate into the holes of the three-dimensional interpenetrating network structure by applying pressure;

coating organic paint to form a second coating, and applying pressure to enable the organic paint to soak the fibers of the three-dimensional interpenetrating network structure and to be soaked into the meshes of the three-dimensional interpenetrating network structure; forming a sandwich coating;

and curing the sandwich coating, wherein the organic coating on the surface of the mesh is inwards largely collapsed, and the organic coating on the surface of the fiber is blocked by the fiber and does not collapse or forms small depressions, so that the texture is formed.

Wherein the fiber diameter of the fiber texture network sandwich is 20 μm. The aperture of the mesh of the fibrous texture network sandwich is 0.5 mm. The density of the fibrous texture network sandwich 30 is preferably 50g/m²。

The thickness of the fibrous texture network core 30 is preferably 0.25 mm. The thickness of the first coating was 0.1mm and the thickness of the second coating was 0.13 mm.

Solid particles may not generally be present in the organic binder or organic coating, but may also be present, in which case the largest particles (generally fillers) have a particle size of 20 μm.

Example 3

applying a first organic coating, such as latex paint, to the surface of the wall 10 to form a first coating 20;

applying the fibrous texture network sandwich 30 to the surface of the first coating layer 20, and applying pressure to the fibrous texture network sandwich 30 to enable the first organic coating to soak the fibers and permeate into the holes of the three-dimensional interpenetrating network structure;

coating a second organic coating, which can also be emulsion paint, as a second coating, and applying pressure to enable the second organic coating to soak the fibers of the three-dimensional interpenetrating network structure and to be soaked into the meshes of the three-dimensional interpenetrating network structure; forming a sandwich coating; and curing the sandwich coating, wherein the organic coating on the surface of the mesh is inwards largely collapsed, and the organic coating on the surface of the fiber is blocked by the fiber and does not collapse or forms small depressions, so that the texture is formed.

Wherein the fiber diameter of the fiber texture network sandwich is 30 μm. The aperture of the mesh of the fibrous texture network sandwich is 1 mm. The density of the fibrous texture network sandwich 30 is preferably 100g/m²。

The thickness of the fibrous texture network core 30 is preferably 0.3 mm. The first coating thickness was 0.15mm and the second coating thickness was 0.15 mm.

The organic coating material may be an acrylic emulsion as the film-forming material, and solid particles may not be present in the organic coating material, but may also be present, and in the case of the presence of solid particles, the particle size of the largest particles (typically fillers) is 40 μm.

Example 4

coating a first inorganic dry powder coating on the surface of the wall 10 to form a first coating 20;

applying the fibrous texture network sandwich 30 to the surface of the first coating 20, and applying pressure to the fibrous texture network sandwich 30 to enable the first inorganic dry powder coating to soak the fibers and permeate into the holes of the three-dimensional interpenetrating network structure;

coating a second inorganic dry powder coating (which can also be coated with an organic coating such as latex paint), and applying pressure to enable the second inorganic dry powder coating to infiltrate the fibers of the three-dimensional interpenetrating network structure and to be immersed into the meshes of the three-dimensional interpenetrating network structure; forming a sandwich coating; unlike example 1, the second inorganic dry powder coating is a clear or translucent coating; curing the sandwich coating, the coating on the surface of the mesh is inwards formed into larger collapse, and the coating on the surface of the fiber is blocked by the fiber and is not collapsed or is formed into smaller collapse, so that the texture is formed.

Example 5

the fiber texture network sandwich 30 is pasted on the surface of the first coating 20, different from the embodiment 1, the fiber texture network sandwich 30 of the embodiment contains a pattern composed of dense meshes;

pressing the fibrous texture network sandwich 30 to enable the first inorganic dry powder coating to soak the fibers and to permeate into the holes of the three-dimensional interpenetrating network structure;

Example 6

the fiber texture network sandwich 30 is pasted on the surface of the first coating 20, different from the embodiment 1, the fiber texture network sandwich 30 of the embodiment contains the pattern formed after the embossing arrangement;

coating a second inorganic dry powder coating, which can also be emulsion paint, and applying pressure to enable the second inorganic dry powder coating to soak the fibers of the three-dimensional interpenetrating network structure and to be soaked into the meshes of the three-dimensional interpenetrating network structure; forming a sandwich coating; unlike example 1, the second inorganic dry powder coating is a clear or translucent coating;

curing the sandwich coating, wherein the coating on the surface of the mesh is inwards formed into larger subsidence, and the coating on the surface of the fiber is blocked by the fiber and does not subside or forms smaller subsidence, so that the texture is formed; however, unlike example 1, at least a part of the first inorganic dry powder coating and the second inorganic dry powder coating may not contact each other in the mesh, thereby forming a partially hollow structure in the mesh.

Comparative example 1

Wallpaper is applied to the surface of a wall by using an organic adhesive.

And coating emulsion paint on the surface of the wallpaper.

Curing organic adhesive and emulsion paint.

Comparative example 2

And (3) applying the wallpaper to the surface of the wall by using inorganic dry powder paint.

And coating inorganic dry powder paint on the surface of the wallpaper.

And curing the inorganic dry powder coating.

Comparative example 3

And (3) applying the glass fiber cloth to the surface of the wall by using inorganic dry powder coating.

And coating inorganic dry powder paint on the surface of the glass fiber cloth.

And curing the inorganic dry powder coating.

Comparative example 4

And (3) applying the two-dimensional mesh cloth woven by the warps and the wefts to the surface of the wall by using inorganic dry powder coating.

And coating inorganic dry powder coating on the surface of the two-dimensional mesh cloth.

And curing the inorganic dry powder coating.

In comparative examples 1 to 4 described above, the same coating thickness as in inventive example 5 was used.

The coatings of the above examples and comparative examples of the invention were compared for tear resistance and surface texture with the following results:

TABLE 1 comparison of tear resistance and surface texture of the coatings of the examples and comparative examples

In general, the method can produce rich texture similar to wallpaper, and simultaneously enables the texture and the coating to have good tear resistance and peeling resistance; especially, no seam is visible to naked eyes at the sandwich of the fiber network, and the obtained texture has good continuity.

The coating made of the wallpaper has obvious gaps at the splicing positions of the wallpaper and is easy to peel. The coating made of the glass fiber cloth or the two-dimensional mesh cloth has an unobvious texture or an excessively monotonous texture, so that the texture effect of the wallpaper cannot be formed, and in addition, the texture difference between the splicing part (or overlapping or gap spacing) of the mesh cloth and the texture of other parts is too large.

The embodiments of the present invention have been described in detail, but the embodiments are merely examples, and the present invention is not limited to the embodiments described above. Any equivalent modifications and substitutions to those skilled in the art are also within the scope of the present invention. Accordingly, equivalent changes and modifications made without departing from the spirit and scope of the present invention should be covered by the present invention.

Claims

1. A method for manufacturing an impregnation coating composite anti-crack texture sandwich coating on the surface of an object is characterized by comprising the following steps:

coating a first coating on the surface of an object;

coating a second coating, and applying pressure to enable the coating of the second coating to infiltrate the fibers of the three-dimensional interpenetrating network structure and into the pores of the three-dimensional interpenetrating network structure; forming a sandwich coating;

curing the sandwich coating, wherein in the curing process of the second coating, the coating positioned on the surfaces of the meshes of the three-dimensional interpenetrating network structure forms large collapse inwards, and the coating positioned on the surfaces of the fibers is prevented by the fibers and does not collapse or forms small collapse, so that the texture is formed; wherein

The maximum particle diameters of the first coating and the second coating are respectively and independently less than or equal to 50 mu m; the density of the fiber texture network sandwich is 10-300g/m²(ii) a The maximum particle size of the first coating and the second coating is 1/5 which is not more than the average pore size of meshes of the fibrous texture network sandwich independently; the fiber intersections all form junctions, or some of the intersections form junctions.

2. The method of claim 1, wherein after the application of the fibromuscular network core to the first coating, the application of pressure causes the fibromuscular network core to at least partially sink into the first coating.

3. The method of claim 1, wherein the second coating of coating material is immersed in the pores of the three-dimensional interpenetrating network structure and is in contact with the first coating of coating material immersed in the pores of the three-dimensional interpenetrating network structure.

4. The method of claim 3, wherein the pressing is continued after the first coating material and the second coating material are contacted to further bond the first coating material and the second coating material together.

5. The method of claim 1, wherein the first coating or the second coating is independently an opaque coating, a clear coating, or a translucent coating, respectively; or the first coating and the second coating are opaque coating, transparent coating or semitransparent coating simultaneously; or

The first coating or the second coating independently comprises a clear coating or a translucent coating, respectively; or the first coating and the second coating comprise both a clear coating or a translucent coating.

6. The method of claim 1, wherein the first coating or second coating is an inorganic coating layer; or

The first coating and the second coating are both inorganic coating layers.

7. The method of claim 1, wherein the fibromuscular network core comprises fibers and interstices between the fibers forming a mesh of intersecting spaces.

8. The method of claim 7, wherein the arrangement of fibers is a three-dimensional volumetric distribution.

9. The method of claim 7, wherein the fibers comprise at least horizontal, vertical, and diagonal fibers.

10. The method of claim 9, wherein at least some of the fibers each have at least two or three of a horizontal portion, a vertical portion, and an obliquely oriented portion; wherein

Any one or more of the horizontal part, the vertical part and the inclined part of the fiber are mutually crossed, and/or any one or more of the horizontal part, the vertical part and the inclined part of the fiber are mutually crossed with any one or more of the horizontal part, the vertical part and the inclined part of the fiber.

11. The method of claim 10, wherein the mesh openings comprise at least horizontal, vertical, and diagonal mesh openings, wherein one or more of the horizontal, vertical, and diagonal mesh openings are in communication with one or more other of the one or more horizontal, vertical, and diagonal mesh openings.

12. The method of claim 1, wherein the fibrous texture network core has a fiber diameter of 1 μ ι η to 5000 μ ι η.

13. The method of claim 12, wherein the fibrous texture network core has a fiber diameter of 1 μ ι η to 1000 μ ι η.

14. The method of claim 12, wherein the fibrous texture network core has a fiber diameter of 1 μ ι η to 100 μ ι η.

15. The method of claim 12, wherein the fibrous texture network core has a fiber diameter of 1 μ ι η to 50 μ ι η.

16. The method of claim 12, wherein the fibrous texture network core has a fiber diameter of 5 μ ι η to 50 μ ι η.

17. The method of claim 12, wherein the fibrous texture network core has a fiber diameter of 5 μ ι η to 40 μ ι η.

18. The method of claim 1, wherein the thickness of the fibromuscular network core is 0.1mm to 10 mm.

19. The method of claim 18, wherein the thickness of the fibromuscular network core is 0.1mm to 5 mm.

20. The method of claim 18, wherein the thickness of the fibromuscular network core is 0.1mm to 1 mm.

21. The method of claim 18, wherein the thickness of the fibromuscular network core is 0.1mm to 0.5 mm.

22. The method of claim 18, wherein the thickness of the fibromuscular network core is 0.2-0.4 mm.

23. The method of claim 18, wherein the thickness of the fibromuscular network core is selected from the group consisting of 0.25mm, 0.28mm, 0.3mm, 0.33mm, 0.35mm, and 0.37 mm.

24. The method of claim 1 or 18, wherein the thickness of the fibromuscular network core is greater than or equal to the sum of the thickness of the first coating and the second coating.

25. The method of claim 1, wherein the mesh of the fibromuscular network core has a pore size of 0.1mm to 10 mm.

26. The method of claim 25, wherein the mesh of the fibromuscular network sandwich has a pore size of 0.1mm to 5 mm.

27. The method of claim 25, wherein the mesh of the fibromuscular network sandwich has a pore size of 0.1mm to 3 mm.

28. The method of claim 27, wherein the mesh of the fibromuscular network core has a pore size of 0.1mm to 1 mm.

29. The method of claim 1 or 25, wherein the first coating layer and the second coating layer each independently have a maximum particle size of 30 μm or less.

30. The method of claim 29, wherein the first coating layer and the second coating layer each independently have a maximum particle size of 20 μm or less.

31. The method of claim 29, wherein the first coating layer and the second coating layer each independently have a maximum particle size of 10 μm or less.

32. The method of claim 1, wherein the first coating layer and the second coating layer each independently have a maximum particle size of 1/10 that is equal to or less than the average pore size of the mesh of the fibrous texture network core.

33. The method of claim 32, wherein the first coating layer and the second coating layer each independently have a maximum particle size of 1/100 that is equal to or less than the average pore size of the mesh of the fibrous texture network core.

34. The method of claim 32, wherein the maximum particle size of each of the first coating layer and the second coating layer is 1/1000 being equal to or larger than the average pore size of the mesh of the fibrous texture network core.

35. The method of claim 1, wherein the density of the fibromuscular network core is 15-200g/m²。

36. The method of claim 35, wherein the density of the fibromuscular network core is 20-150g/m²。

37. The method of claim 35, wherein the density of the fibromuscular network core is 20-100g/m²。

38. The method of claim 35, wherein the density of the fibromuscular network core is 20-50g/m²。

39. The method of claim 1, wherein the fibromuscular network core further comprises at least one pattern formed from a structural organization that is the same or different from the fibromuscular network core, wherein the pattern may be raised or lowered in the fibromuscular network core or die cut into the fibromuscular network core to form a pattern through the fibromuscular network core.

40. The method according to claim 1 or 39, wherein the fibrous texture network sandwich is or has been subjected to a one-sided or two-sided surface finishing comprising any one or several of the following a) -g):

a) flattening the surface, but leaving surface openings in communication with the internal mesh;

b) the surface is coated with a material for changing the fiber property;

c) dyeing, namely enabling the surface of the fibrous texture network sandwich to have colors, wherein the colors are single colors or multiple colors;

e) molding to make the sandwich surface of the fiber texture network have patterns;

g) the dipping process is modified to improve the rigidity of the fiber and the anti-deformation capability.

41. The method of claim 40, wherein the surfaces are coated with a material that has a different water absorption.

42. The method of claim 40, wherein the property in b) is graded from one end of the surface finish portion to the other end.

43. The method of claim 40, wherein the properties in b) are graded from one end of the fibromuscular network core to the other.

44. The method of claim 40, wherein said plurality of colors in c) are gradient colors.

45. The method of claim 40, wherein said embossing is selected from the group consisting of embossing, and hole finishing.

46. An impregnated coated composite crack-resistant texture sandwich coating obtained by the method of claim 1, which comprises a first coating layer, a second coating layer and a fiber texture network sandwich sandwiched between the first coating layer and the second coating layer, wherein the fiber texture network sandwich contains a three-dimensional interpenetrating network structure formed by fibers, and the first coating layer and the second coating layer are infiltrated into the meshes of the three-dimensional interpenetrating network structure; the second coating is sunk in the partial surface of the three-dimensional interpenetrating network structure meshes, and the convex-concave three-dimensional texture is formed on the part of the three-dimensional interpenetrating network structure fiber surface without or with smaller sunk parts.