CN108611693A - A kind of 6 yarn of mosquito proof polyamide fibre - Google Patents
A kind of 6 yarn of mosquito proof polyamide fibre Download PDFInfo
- Publication number
- CN108611693A CN108611693A CN201810532816.7A CN201810532816A CN108611693A CN 108611693 A CN108611693 A CN 108611693A CN 201810532816 A CN201810532816 A CN 201810532816A CN 108611693 A CN108611693 A CN 108611693A
- Authority
- CN
- China
- Prior art keywords
- polyamide fibre
- weight
- parts
- mosquito
- mosquito proof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
Abstract
The present invention provides a kind of 6 yarn of mosquito proof polyamide fibre, first weighs 76~80 parts by weight chinlon 6 sections, the polycyclic aromatic ester of 18~22 parts by weight, 2 parts by weight stabilizers；Each raw material component is sufficiently mixed later and is put into reaction kettle, 2h is mixed at 230 DEG C and obtains polymer melt；Polymer melt can be obtained to 6 master batch of polyamide fibre of tool mosquito proof effect by serial process successively, for use；Weigh 6 master batch of polyamide fibre obtained by 95~97 parts by weight chinlon 6 sections, 3~5 parts by weight, and the two is sent into screw extruder and is tentatively mixed, it waits being warming up to 230~280 DEG C and melting, then impurity is removed into obtain spinning solution via fondant filter, subsequent spinning melt is emitted into silk from spinneret orifice extruding, then filament tow after air-flow cools down drawing-off up to 6 yarn of mosquito proof polyamide fibre.The present invention not only have excellent mosquito proof effect, but also have the characteristics that the longer mosquito-proof effect service life, mosquito proof functional agglomerate consuming less, use occasion it is multifarious.
Description
【Technical field】
The invention belongs to extrusion spinning fields, and in particular to a kind of 6 yarn of mosquito proof polyamide fibre.
【Background technology】
Summer is mosquito multiple season, and people will produce the senses of discomfort such as pain tickling, or even production after by bite by mosquitos
The further disease such as hair tonic heat, thus in order to solve the problems, such as that bite by mosquitos in summer, various mosquito-proof insects products are answered
It transports and gives birth to.And in daily life, widely used mosquito proof method main time directly drives mosquito using medicament
It keeps away or kills, but this method easily generates injury to human body and environment, therefore, later frequently with the textile pair with human contact
It is handled, to realize the effect of insect prevention mosquito proof.
Currently, having a degree of research to the product with anti-mosquito functions both at home and abroad, certain effect is also achieved.
For example, the patent of invention that number of patent application is CN201410426407.0 discloses " a kind of mosquito-repellent fabric ", using will wrap up
Anti-mosquito agent mosquito proof interlayer it is neat be arranged in the mode between base fabric and top fabric to prepare anti-mosquito fabric, from
And realize the function of slow release mosquito proof smell, and then protect persons from biting for mosquito；Number of patent application is
The patent of invention of CN201510589379.9, entitled " a kind of mosquito repellent quilt ", by will be directly introduced to by needle by body
The mode dried after being impregnated in mosquito proof liquid made of cherry extract, purple perilla juice, pyridine etc., to reach mosquito proof effect
The lasting effect of fruit；Number of patent application is that the patent of invention of CN201210356407.7 discloses " a kind of mosquito dispelling mat ", this kind
Mat is set to the mosquito proof layer and skid resistant course composition of mat ontology lower surface, wherein mosquito proof layer is by weight with mat ontology
Amount is than being 100:The Chinese herbal medicine of 5-40 flattens after mixing with natural rubber glue, this kind of mosquito proof mat can not only have
Effect ground mosquito expelling, also has and promotes blood circulation, treats the health-care effects such as sleep.
Mosquito proof product prepared by the physical methods such as above-mentioned complex method or final finishing, although can be to a certain extent
Play the role of mosquito proof, but its anti-mosquito agent is attached to fabric or fiber surface mostly, therefore product is all in the presence of as follows
Defect：Mosquito-proof effect short life, anti-mosquito agent additive amount is big, and mosquito proof effect is limited, and use occasion is more single.
【Invention content】
Technical problem to be solved by the present invention lies in a kind of 6 yarn of mosquito proof polyamide fibre is provided, not only prevent with excellent
Mosquito effect, and the functional agglomerate with longer mosquito-proof effect service life, mosquito proof expends less, the multifarious spy of use occasion
Point.
The present invention is to solve above-mentioned technical problem by the following technical programs：It is prepared by a kind of 6 yarn of mosquito proof polyamide fibre
Method includes following concrete operation step：
(1), 76~80 parts by weight chinlon 6 sections, the polycyclic aromatic ester of 18~22 parts by weight nano-scales, 2 weight are weighed
Part stabilizer；The each raw material component weighed is sufficiently mixed later and is put into reaction kettle, and is mixed at 230 DEG C
2h is stirred, polymer melt is obtained；Resulting polymers melt is filtered successively, cutter pelletizing, extraction, nitrogen drying
It can be obtained 6 master batch of polyamide fibre of tool mosquito proof effect after pelletizing, for use；
(2), 6 master batch of polyamide fibre obtained by 95~97 parts by weight chinlon 6 sections, 3~5 parts by weight steps (1) is weighed, and will
The two is sent into screw extruder and is tentatively mixed, and waits being warming up to 230~280 DEG C and melting so that fully mixed between material
It closing, impurity is then removed into obtain spinning solution via fondant filter, subsequent spinning melt is emitted into silk from spinneret orifice extruding, and
Afterwards filament tow after air-flow cools down drawing-off up to 6 yarn of mosquito proof polyamide fibre.
Further, in the step (1), the size of polycyclic aromatic ester is 100~300nm.
Further, in the step (2), 6 Yarn homogeneous of gained mosquito proof polyamide fibre is wound on the winder.
The beneficial effects of the present invention are：
By the way that functional agglomerate, that is, polycyclic aromatic ester of mosquito proof is added in 6 spinning solution preparation process of polyamide fibre, to make
6 yarn of mosquito proof polyamide fibre of the present invention not only has excellent mosquito proof effect, but also with longer mosquito-proof effect service life, mosquito-proof
The functional agglomerate of worm expends few feature, in addition, can be used using its anti-mosquito fabric obtained of 6 yarn of mosquito proof polyamide fibre of the present invention
In civilian, military or certain special role occasions, i.e. use occasion has diversity.
【Specific implementation mode】
A kind of 6 yarn of mosquito proof polyamide fibre of the present invention, preparation method includes following concrete operation step：
(1), 76~80 parts by weight chinlon 6 sections, the polycyclic aromatic ester of 18~22 parts by weight nano-scales, 2 weight are weighed
Part stabilizer；The each raw material component weighed is sufficiently mixed later and is put into reaction kettle, and is mixed at 230 DEG C
2h is stirred, polymer melt is obtained；Resulting polymers melt is filtered successively, cutter pelletizing, extraction, nitrogen drying
It can be obtained tool mosquito proof after pelletizing and act on excellent 6 master batch of polyamide fibre, for use；
(2), 6 master batch of polyamide fibre obtained by 95~97 parts by weight chinlon 6 sections, 3~5 parts by weight steps (1) is weighed, and will
The two is sent into screw extruder and is tentatively mixed, and waits being warming up to 230~280 DEG C and melting so that fully mixed between material
It closing, impurity is then removed into obtain spinning solution via fondant filter, subsequent spinning melt is emitted into silk from spinneret orifice extruding, and
Afterwards filament tow after air-flow cools down drawing-off up to 6 yarn of mosquito proof polyamide fibre.
Wherein, in the present embodiment, in step (1), the size of polycyclic aromatic ester preferably selects 100~300nm；Step
Suddenly in (2), 6 Yarn homogeneous of mosquito proof polyamide fibre of the present invention winding on the winder, cylinder is wound into facilitate, be readily transported carrying or
It uses.
And it should be noted that the polycyclic aromatic ester of nano-scale is functional agglomerate in the present invention, size is nanometer
Grade has larger specific surface area, increases the compatibility between chinlon 6 section melt, and it is promoted after melting can
It is evenly distributed in chinlon 6 section melt, it is ensured that polycyclic aromatic ester can be uniformly distributed in final products so that its is mosquito-proof
Worm excellent effect；In addition, the size due to functional agglomerate is small, dispersion effect is good so that during melt spinning, to main body brocade
The influence of the processes such as the hot gas spring of synthetic fibre 6 and cooling is relatively small, to ensure that the mechanical property of 6 yarn of polyamide fibre.
Illustrate 6 yarn of mosquito proof polyamide fibre of the present invention to be expanded on further, applicant illustrates following several embodiments.
Embodiment 1
Weigh 78 parts by weight chinlon 6 sections, polycyclic aromatic ester, the 2 parts by weight stabilizers that 20 parts by weight sizes are 100nm；
The each raw material component weighed is sufficiently mixed later and is put into reaction kettle, and 2h is mixed at 230 DEG C, is obtained
To polymer melt；Resulting polymers melt is filtered successively, cutter pelletizing, extraction, nitrogen drying pelletizing after i.e.
6 master batch of polyamide fibre of tool mosquito proof effect is can get, for use；
6 master batch of polyamide fibre obtained by 95 parts by weight chinlon 6 sections, 5 parts by weight is weighed, and the two is sent into screw extruder
It is tentatively mixed, waits being warming up to 230~280 DEG C and melting so that be sufficiently mixed between material, then via fondant filter
Impurity is removed into obtain spinning solution, subsequent spinning melt is emitted into silk from spinneret orifice extruding, and then filament tow is cooled down through air-flow
Up to 6 yarn of mosquito proof polyamide fibre after drawing-off.
6 yarn of mosquito proof polyamide fibre obtained by the present embodiment is subjected to relevant parameter test, test result is：Mosquito proof brocade
6 yarn tensile strength of synthetic fibre is 4.5cN/dtex, to walk quickly and keep away rate to mosquito be 75.3% for elongation at break 53%, anophelifuge fabrics.
Embodiment 2
Weigh 78 parts by weight chinlon 6 sections, polycyclic aromatic ester, the 2 parts by weight stabilizers that 20 parts by weight sizes are 100nm；
The each raw material component weighed is sufficiently mixed later and is put into reaction kettle, and 2h is mixed at 230 DEG C, is obtained
To polymer melt；Resulting polymers melt is filtered successively, cutter pelletizing, extraction, nitrogen drying pelletizing after i.e.
6 master batch of polyamide fibre of tool mosquito proof effect is can get, for use；
6 master batch of polyamide fibre obtained by 97 parts by weight chinlon 6 sections, 3 parts by weight is weighed, and the two is sent into screw extruder
It is tentatively mixed, waits being warming up to 230~280 DEG C and melting so that be sufficiently mixed between material, then via fondant filter
Impurity is removed into obtain spinning solution, subsequent spinning melt is emitted into silk from spinneret orifice extruding, and then filament tow is cooled down through air-flow
Up to 6 yarn of mosquito proof polyamide fibre after drawing-off.
6 yarn of mosquito proof polyamide fibre obtained by the present embodiment is subjected to relevant parameter test, test result is：Mosquito proof brocade
6 yarn tensile strength of synthetic fibre is 4.7cN/dtex, to walk quickly and keep away rate to mosquito be 70.3% for elongation at break 60%, anophelifuge fabrics.
Embodiment 3
Weigh 78 parts by weight chinlon 6 sections, polycyclic aromatic ester, the 2 parts by weight stabilizers that 20 parts by weight sizes are 300nm；
The each raw material component weighed is sufficiently mixed later and is put into reaction kettle, and 2h is mixed at 230 DEG C, is obtained
To polymer melt；Resulting polymers melt is filtered successively, cutter pelletizing, extraction, nitrogen drying pelletizing after i.e.
6 master batch of polyamide fibre of tool mosquito proof effect is can get, for use；
6 master batch of polyamide fibre obtained by 95 parts by weight chinlon 6 sections, 5 parts by weight is weighed, and the two is sent into screw extruder
It is tentatively mixed, waits being warming up to 230~280 DEG C and melting so that be sufficiently mixed between material, then via fondant filter
Impurity is removed into obtain spinning solution, subsequent spinning melt is emitted into silk from spinneret orifice extruding, and then filament tow is cooled down through air-flow
Up to 6 yarn of mosquito proof polyamide fibre after drawing-off.
6 yarn of mosquito proof polyamide fibre obtained by the present embodiment is subjected to relevant parameter test, test result is：Mosquito proof brocade
6 yarn tensile strength of synthetic fibre is 4.4cN/dtex, to walk quickly and keep away rate to mosquito be 72.9% for elongation at break 49%, anophelifuge fabrics.
Embodiment 4
Weigh 76 parts by weight chinlon 6 sections, polycyclic aromatic ester, the 2 parts by weight stabilizers that 22 parts by weight sizes are 100nm；
The each raw material component weighed is sufficiently mixed later and is put into reaction kettle, and 2h is mixed at 230 DEG C, is obtained
To polymer melt；Resulting polymers melt is filtered successively, cutter pelletizing, extraction, nitrogen drying pelletizing after i.e.
6 master batch of polyamide fibre of tool mosquito proof effect is can get, for use；
6 master batch of polyamide fibre obtained by 95 parts by weight chinlon 6 sections, 5 parts by weight is weighed, and the two is sent into screw extruder
It is tentatively mixed, waits being warming up to 230~280 DEG C and melting so that be sufficiently mixed between material, then via fondant filter
Impurity is removed into obtain spinning solution, subsequent spinning melt is emitted into silk from spinneret orifice extruding, and then filament tow is cooled down through air-flow
Up to 6 yarn of mosquito proof polyamide fibre after drawing-off.
6 yarn of mosquito proof polyamide fibre obtained by the present embodiment is subjected to relevant parameter test, test result is：Mosquito proof brocade
6 yarn tensile strength of synthetic fibre is 4.3cN/dtex, to walk quickly and keep away rate to mosquito be 76.5% for elongation at break 43%, anophelifuge fabrics.
To sum up, functional agglomerate, that is, polycyclic virtue that the present invention passes through the addition mosquito proof in 6 spinning solution preparation process of polyamide fibre
Fragrant ester to make 6 yarn of mosquito proof polyamide fibre of the present invention not only have excellent mosquito proof effect, but also has longer mosquito-proof effect
The fruit service life, mosquito proof functional agglomerate expend few feature, in addition, because 6 yarn of mosquito proof polyamide fibre of the present invention have it is better
Tensile strength, therefore elongation at break can be used in civilian, military or certain special using its anti-mosquito fabric obtained
Occasion is acted on, i.e. use occasion is no longer single, has diversity.
The above, be only record the present invention for present solve the problems, such as used by technological means better embodiment and
, not it is used for limiting the scope of implementation of the present invention.I.e. all equivalent changes and modifications done in interest field of the present invention, all
Scope of the present invention should be belonged to.
Claims (3)
1. a kind of 6 yarn of mosquito proof polyamide fibre, it is characterised in that：Preparation method includes following concrete operation step：
(1), it is steady that 76~80 parts by weight chinlon 6 sections, the polycyclic aromatic ester of 18~22 parts by weight nano-scales, 2 parts by weight are weighed
Determine agent；The each raw material component weighed is sufficiently mixed later and is put into reaction kettle, and is mixed at 230 DEG C
2h obtains polymer melt；Resulting polymers melt is filtered successively, cutter pelletizing, extraction, nitrogen drying pelletizing
It can be obtained 6 master batch of polyamide fibre of tool mosquito proof effect afterwards, for use；
(2), 6 master batch of polyamide fibre obtained by 95~97 parts by weight chinlon 6 sections, 3~5 parts by weight steps (1) is weighed, and the two is sent
Enter in screw extruder and tentatively mixed, waits being warming up to 230~280 DEG C and melting so that be sufficiently mixed between material, then
Impurity is removed into obtain spinning solution via fondant filter, subsequent spinning melt is emitted into silk from spinneret orifice extruding, then long filament
Tow is after air-flow cools down drawing-off up to 6 yarn of mosquito proof polyamide fibre.
2. a kind of 6 yarn of mosquito proof polyamide fibre according to claim 1, it is characterised in that：In the step (1), polycyclic virtue
The size of fragrant ester is 100~300nm.
3. a kind of 6 yarn of mosquito proof polyamide fibre according to claim 1, it is characterised in that：In the step (2), gained is anti-
6 Yarn homogeneous of mosquito polyamide fibre is wound on the winder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810532816.7A CN108611693A (en) | 2018-05-29 | 2018-05-29 | A kind of 6 yarn of mosquito proof polyamide fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810532816.7A CN108611693A (en) | 2018-05-29 | 2018-05-29 | A kind of 6 yarn of mosquito proof polyamide fibre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108611693A true CN108611693A (en) | 2018-10-02 |
Family
ID=63664466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810532816.7A Pending CN108611693A (en) | 2018-05-29 | 2018-05-29 | A kind of 6 yarn of mosquito proof polyamide fibre |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108611693A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111074409A (en) * | 2019-12-09 | 2020-04-28 | 浙江正辉纺织有限公司 | Mosquito-proof spandex blended knitted fabric and production method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0332397A2 (en) * | 1988-03-08 | 1989-09-13 | BASF Corporation | Fiber-containing yarn possessing antimicrobial activity |
| KR20060069997A (en) * | 2004-12-20 | 2006-06-23 | 주식회사 효성 | A process for preparing self-crimping nylon filament yarn having antimicrobial |
| CN102618959A (en) * | 2012-03-20 | 2012-08-01 | 杭州鑫福纺织有限公司 | Mosquito-dispelling polyamide 6 fiber and preparation method thereof |
-
2018
- 2018-05-29 CN CN201810532816.7A patent/CN108611693A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0332397A2 (en) * | 1988-03-08 | 1989-09-13 | BASF Corporation | Fiber-containing yarn possessing antimicrobial activity |
| KR20060069997A (en) * | 2004-12-20 | 2006-06-23 | 주식회사 효성 | A process for preparing self-crimping nylon filament yarn having antimicrobial |
| CN102618959A (en) * | 2012-03-20 | 2012-08-01 | 杭州鑫福纺织有限公司 | Mosquito-dispelling polyamide 6 fiber and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111074409A (en) * | 2019-12-09 | 2020-04-28 | 浙江正辉纺织有限公司 | Mosquito-proof spandex blended knitted fabric and production method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103215751B (en) | Preparation method of long-acting insect prevention and mosquito repelling PP (Polypropylene) non-woven fabric | |
| CN103882543B (en) | A kind of mite-proofing and antimicrobial thermal plasticity high polymer melt spins fiber and its preparation method | |
| KR100910241B1 (en) | Nanofibers comprising naturalplant extract or naturalplant essential oil and method for producing the same | |
| US8105688B2 (en) | Inorganic solid-phase combined powder, master batch and method for manufacturing the same, fiber and method for manufacturing the same | |
| CN103649409B (en) | Composition for impregnation of textiles such as nettings | |
| CN102618030B (en) | Fragrant chinlon masterbatch, fragrant chinlon fiber and preparation methods thereof | |
| CN104878607A (en) | Method for tidying fabrics by mosquito repelling microcapsules | |
| WO2021042716A1 (en) | Plant functional pp spunbond nonwoven fabric and preparation method therefor | |
| CN102851765A (en) | Far-infrared fiber and its manufacturing method | |
| CN112323171A (en) | Lavender-containing nylon fiber and preparation method thereof | |
| CN109267163A (en) | A kind of lavender cellulose fibre and preparation method thereof | |
| CN101792939B (en) | Functional fiber | |
| CN108611693A (en) | A kind of 6 yarn of mosquito proof polyamide fibre | |
| CN104831384B (en) | Apply the method and melt-spinning apparatus of the melt spinning in pulse regulatable magnetic field | |
| CN103668548A (en) | Lukens fiber and functional fiber prepared therefrom | |
| CN109620553A (en) | A kind of preparation method of Graphene antibiosis amenities chip | |
| CN109355729A (en) | A kind of manufacturing method of Tai Ji stone and polyester fiber composite material | |
| CN113322577B (en) | Wadding with antibacterial flame-retardant warm-keeping function and preparation method thereof | |
| CN115386108A (en) | Preparation method and application of anti-mite antibacterial master batch | |
| CN112501708B (en) | Cool fiber and preparation method thereof | |
| CN106435819A (en) | Novel high-performance composite porous nanometer antibacterial fiber material adopting functionalized graphene and preparation method of novel high-performance composite porous nanometer antibacterial fiber material | |
| CN106120150A (en) | A kind of can continuously releasing negative oxygen ion containing bamboo filament fibre non-woven fabrics and preparation method thereof | |
| JP5849378B2 (en) | Functional rayon fiber and method for producing the same | |
| CN103627126A (en) | Antibiosis master batch and application of antibiosis master batch in blended yarn, blended fabric and woven fabric | |
| CN111253720A (en) | Plant-derived PET master batch and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181002 |