CN108598051A - 一种高导热的石墨烯碳纳米浆料及其制备方法 - Google Patents
一种高导热的石墨烯碳纳米浆料及其制备方法 Download PDFInfo
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- CN108598051A CN108598051A CN201810526832.5A CN201810526832A CN108598051A CN 108598051 A CN108598051 A CN 108598051A CN 201810526832 A CN201810526832 A CN 201810526832A CN 108598051 A CN108598051 A CN 108598051A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 108
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 79
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 40
- 238000007306 functionalization reaction Methods 0.000 claims abstract description 30
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 29
- 239000002245 particle Substances 0.000 claims abstract description 28
- 239000006185 dispersion Substances 0.000 claims abstract description 26
- 239000007788 liquid Substances 0.000 claims abstract description 20
- 239000007822 coupling agent Substances 0.000 claims abstract description 19
- 238000003756 stirring Methods 0.000 claims abstract description 19
- 239000003960 organic solvent Substances 0.000 claims abstract description 12
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 8
- 239000010439 graphite Substances 0.000 claims abstract description 8
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 230000008878 coupling Effects 0.000 claims description 7
- 238000010168 coupling process Methods 0.000 claims description 7
- 238000005859 coupling reaction Methods 0.000 claims description 7
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 6
- 230000004523 agglutinating effect Effects 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 6
- 238000010008 shearing Methods 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 14
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 238000003980 solgel method Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 206010037660 Pyrexia Diseases 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
- H01L23/3738—Semiconductor materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/194—After-treatment
Abstract
Description
Claims (8)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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CN2018103200224 | 2018-04-11 | ||
CN201810320022 | 2018-04-11 |
Publications (2)
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CN108598051A true CN108598051A (zh) | 2018-09-28 |
CN108598051B CN108598051B (zh) | 2019-12-10 |
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CN201810526832.5A Active CN108598051B (zh) | 2018-04-11 | 2018-05-29 | 一种高导热的石墨烯碳纳米浆料及其制备方法 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111423855A (zh) * | 2020-04-24 | 2020-07-17 | 牛墨石墨烯应用科技有限公司 | 一种硼化石墨烯高导热浆料及其制备方法 |
CN113056045A (zh) * | 2019-12-27 | 2021-06-29 | 陈建波 | 一种石墨烯发热混合料、发热元件、发热管及制备工艺 |
CN113056043A (zh) * | 2019-12-27 | 2021-06-29 | 陈建波 | 一种石墨烯高温发热管及其加工方法 |
CN113337956A (zh) * | 2021-05-18 | 2021-09-03 | 南方科技大学 | 三维高导热聚合物基复合材料及其制备方法 |
CN115093228A (zh) * | 2022-06-24 | 2022-09-23 | 南京中蓝智能科技有限公司 | 一种改性的远红外纳米陶瓷粉及其在散热涂料制备中的应用 |
Citations (6)
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CN103500597A (zh) * | 2013-09-30 | 2014-01-08 | 广州市尤特新材料有限公司 | 一种基于功能化石墨烯的太阳能背铝浆料及其制备方法 |
CN103848428A (zh) * | 2012-12-07 | 2014-06-11 | 深圳富泰宏精密工业有限公司 | 二氧化硅溶胶,应用该二氧化硅溶胶对金属基体进行表面处理的方法及其制品 |
CN106479232A (zh) * | 2015-08-25 | 2017-03-08 | 现代自动车株式会社 | 含有石墨烯的涂层膜及其制备方法 |
CN107236150A (zh) * | 2017-07-07 | 2017-10-10 | 青岛科技大学 | 一种新型石墨烯负载二氧化硅杂化填料及其制备方法、应用 |
CN107880484A (zh) * | 2017-12-05 | 2018-04-06 | 中北大学 | 一种纳米粒子/氧化石墨烯复合改性高分子材料及其制备 |
KR20180036261A (ko) * | 2016-09-30 | 2018-04-09 | 포항공과대학교 산학협력단 | 나노복합체 및 그의 제조방법 |
-
2018
- 2018-05-29 CN CN201810526832.5A patent/CN108598051B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103848428A (zh) * | 2012-12-07 | 2014-06-11 | 深圳富泰宏精密工业有限公司 | 二氧化硅溶胶,应用该二氧化硅溶胶对金属基体进行表面处理的方法及其制品 |
CN103500597A (zh) * | 2013-09-30 | 2014-01-08 | 广州市尤特新材料有限公司 | 一种基于功能化石墨烯的太阳能背铝浆料及其制备方法 |
CN106479232A (zh) * | 2015-08-25 | 2017-03-08 | 现代自动车株式会社 | 含有石墨烯的涂层膜及其制备方法 |
KR20180036261A (ko) * | 2016-09-30 | 2018-04-09 | 포항공과대학교 산학협력단 | 나노복합체 및 그의 제조방법 |
CN107236150A (zh) * | 2017-07-07 | 2017-10-10 | 青岛科技大学 | 一种新型石墨烯负载二氧化硅杂化填料及其制备方法、应用 |
CN107880484A (zh) * | 2017-12-05 | 2018-04-06 | 中北大学 | 一种纳米粒子/氧化石墨烯复合改性高分子材料及其制备 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113056045A (zh) * | 2019-12-27 | 2021-06-29 | 陈建波 | 一种石墨烯发热混合料、发热元件、发热管及制备工艺 |
CN113056043A (zh) * | 2019-12-27 | 2021-06-29 | 陈建波 | 一种石墨烯高温发热管及其加工方法 |
CN113056045B (zh) * | 2019-12-27 | 2023-04-07 | 陈建波 | 一种石墨烯发热混合料、发热元件、发热管及制备工艺 |
CN113056043B (zh) * | 2019-12-27 | 2023-04-18 | 陈建波 | 一种石墨烯高温发热管及其加工方法 |
CN111423855A (zh) * | 2020-04-24 | 2020-07-17 | 牛墨石墨烯应用科技有限公司 | 一种硼化石墨烯高导热浆料及其制备方法 |
CN113337956A (zh) * | 2021-05-18 | 2021-09-03 | 南方科技大学 | 三维高导热聚合物基复合材料及其制备方法 |
CN113337956B (zh) * | 2021-05-18 | 2022-08-12 | 南方科技大学 | 三维高导热聚合物基复合材料及其制备方法 |
CN115093228A (zh) * | 2022-06-24 | 2022-09-23 | 南京中蓝智能科技有限公司 | 一种改性的远红外纳米陶瓷粉及其在散热涂料制备中的应用 |
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Effective date of registration: 20200511 Address after: 321015 Graphene Science and Technology Industrial Park No. 1 Niume Road, Xiaoshun Town, Jindong District, Jinhua City, Zhejiang Province Patentee after: NEW MORE GRAPHENE APPLICATION TECHNOLOGY Co.,Ltd. Address before: 310016 444, 4 / F, 4 building, 9 Ring Road, Jianggan District nine, Hangzhou, Zhejiang. Patentee before: HANGZHOU NEW MORE TECHNOLOGY Co.,Ltd. |
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Denomination of invention: A High Thermal Conductive Graphene Carbon Nanoslurry and Its Preparation Method Effective date of registration: 20231205 Granted publication date: 20191210 Pledgee: Yiwu Branch of Industrial Bank Co.,Ltd. Pledgor: NEW MORE GRAPHENE APPLICATION TECHNOLOGY Co.,Ltd. Registration number: Y2023980069398 |
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