CN108567182A - A kind of antistatic clothes - Google Patents
A kind of antistatic clothes Download PDFInfo
- Publication number
- CN108567182A CN108567182A CN201810423439.3A CN201810423439A CN108567182A CN 108567182 A CN108567182 A CN 108567182A CN 201810423439 A CN201810423439 A CN 201810423439A CN 108567182 A CN108567182 A CN 108567182A
- Authority
- CN
- China
- Prior art keywords
- antistatic
- fabric
- retardant
- waterproof ventilated
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 claims abstract description 42
- 239000003063 flame retardant Substances 0.000 claims abstract description 19
- 229920000728 polyester Polymers 0.000 claims abstract description 17
- 239000012528 membrane Substances 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 14
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 11
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000003115 biocidal effect Effects 0.000 claims abstract description 7
- 235000019355 sepiolite Nutrition 0.000 claims description 23
- 229910021556 Chromium(III) chloride Inorganic materials 0.000 claims description 22
- 239000011636 chromium(III) chloride Substances 0.000 claims description 22
- 239000002131 composite material Substances 0.000 claims description 22
- 238000012986 modification Methods 0.000 claims description 18
- 230000004048 modification Effects 0.000 claims description 18
- 238000002360 preparation method Methods 0.000 claims description 17
- 239000004113 Sepiolite Substances 0.000 claims description 13
- 229910052624 sepiolite Inorganic materials 0.000 claims description 13
- 229910002771 BaFe12O19 Inorganic materials 0.000 claims description 11
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 claims description 10
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 6
- 238000013329 compounding Methods 0.000 claims description 6
- 235000007831 chromium(III) chloride Nutrition 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 2
- 150000004676 glycans Chemical class 0.000 claims 1
- 238000009738 saturating Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 18
- 239000007788 liquid Substances 0.000 description 18
- 239000000835 fiber Substances 0.000 description 15
- 239000000843 powder Substances 0.000 description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 11
- 229910019142 PO4 Inorganic materials 0.000 description 11
- 239000000706 filtrate Substances 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 11
- 239000010452 phosphate Substances 0.000 description 11
- 229920001661 Chitosan Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000002994 raw material Substances 0.000 description 4
- 229920004934 Dacron® Polymers 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000007835 Cyamopsis tetragonoloba Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000792 Monel Inorganic materials 0.000 description 1
- 206010028813 Nausea Diseases 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- DZGCGKFAPXFTNM-UHFFFAOYSA-N ethanol;hydron;chloride Chemical compound Cl.CCO DZGCGKFAPXFTNM-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 206010022437 insomnia Diseases 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000008693 nausea Effects 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229940045916 polymetaphosphate Drugs 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/008—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting against electric shocks or static electricity
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/26—Electrically protective, e.g. preventing static electricity or electric shock
- A41D31/265—Electrically protective, e.g. preventing static electricity or electric shock using layered materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/24—Halides of elements of Groups 6 or 16 of the Periodic Table, e.g. chromyl chloride
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of antistatic clothes, include from outer to inner anti-electrostatic polyester fabric successively, flame-retardant layer, waterproof ventilated membrane, antibiotic layer, the waterproof ventilated membrane is using TPU waterproof ventilated membranes.The fire-retardant layer material is fire retardant；The antibacterial layer material antibacterial fabric is prepared.The present invention has good antistatic effect, its surface has excellent strength and toughness using anti-electrostatic polyester fabric, its antistatic property is greatly enhanced after modified compound, the antistatic internal layer that takes also has flame-retardant layer, waterproof ventilated membrane, antibiotic layer, collect fire-retardant, air permeable waterproof and antibacterial are integrated.
Description
Technical field
The present invention relates to a kind of antistatic clothes.
Background technology
The antistatic problem of cloth especially chemical fibre emulating fabric is an old project, but is not still obtained so far
Obtain breakthrough progress.
Currently, carried out corresponding research for the antistatic problem of cloth, such as added in cloth conductive wire with
Antistatic problem to be solved.
Currently, the synthetic fibers such as terylene, polyamide fibre are due to wider by market with more excellent strength and toughness than natural fiber
General application but its fabric has been easy electrostatic, causes to wear uncomfortable, and electrostatic has certain damaging effect to human body,
The nervous centralis that can influence people makes one to feel fatigue, irritated, insomnia, headache；Lasting electrostatic can influence the acid-base value in human body
Balance can also allow people to feel nausea, malaise etc..
Invention content
The purpose of the present invention is to provide a kind of antistatic clothes, improve the antistatic property of clothes.
To achieve the above object, the present invention provides the following technical solutions：A kind of antistatic clothes include successively from outer to inner
Anti-electrostatic polyester fabric, flame-retardant layer, waterproof ventilated membrane, antibiotic layer.
The waterproof ventilated membrane uses TPU waterproof ventilated membranes.
The fire-retardant layer material is fire retardant.
Anti-electrostatic polyester fabric using modification liquid to polyester modified, then in preparation process introduce sepiolite/
BaFe12O19/CrCl3 composite materials are prepared with materials compoundings such as acetyl chitosans.
The antibacterial layer material antibacterial fabric is prepared.
Compared with prior art, the beneficial effects of the invention are as follows：
There is the present invention good antistatic effect, surface to have excellent strength and toughness, warp using anti-electrostatic polyester fabric
Its antistatic property is greatly enhanced after crossing modified compounding, and the antistatic internal layer that takes also has flame-retardant layer, waterproof ventilated membrane,
Antibiotic layer, collection is fire-retardant, and air permeable waterproof and antibacterial are integrated.
Description of the drawings
Fig. 1 is the sectional view of the antistatic clothes of the present invention；
In figure：1, anti-electrostatic polyester fabric, 2, flame-retardant layer, 3, waterproof ventilated membrane, 4, antibiotic layer.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
A kind of antistatic clothes include anti-electrostatic polyester fabric 1, flame-retardant layer 2, waterproof ventilated membrane 3, antibacterial successively from outer to inner
Layer 4.It is fire retardant that the waterproof ventilated membrane, which uses TPU waterproof ventilated membranes, the fire-retardant layer material, and the antibacterial layer material is anti-
Bacterium fabric is prepared.Each shell fabric is bonded using adhesive,
There is the present invention good antistatic effect, surface to have excellent strength and toughness, warp using anti-electrostatic polyester fabric
Its antistatic property is greatly enhanced after crossing modified compounding, and the antistatic internal layer that takes also has flame-retardant layer, waterproof ventilated membrane,
Antibiotic layer, collection is fire-retardant, and air permeable waterproof and antibacterial are integrated.
Anti-electrostatic polyester fabric using modification liquid to polyester modified, then in preparation process introduce sepiolite/
BaFe12O19/CrCl3 composite materials are prepared with materials compoundings such as acetyl chitosans.
By modification liquid to polyester modified, sepiolite/BaFe is then introduced in preparation process12O19/CrCl3Composite wood
Material, the electric conductivity that fabric can be improved is used in compounding with materials such as acetyl chitosans, and the electronics for the generation that rubs on fabric is fast
Speed is transferred out, and for the fabric compared with existing fabric, antistatic property is more preferable, and preparation process is simple, and process is environmentally protective.
Specific preparation method is as follows：
Embodiment 1
（1）Dacron dipping modification liquid is initially modified, 10 h are impregnated, then dries 2h at 40 drying DEG C,
Modified dacron fabric is obtained,
（2）38 parts by weight polyethylene terephthalate, 17 parts by weight acetyl chitosans, 9 parts by weight guar gums are weighed in beaker
In, 80 parts by weight hydrochloric acid ethanol solutions are added, magnetic agitation 2h places it in ultrasonic wave under 300W power, nitrogen atmosphere
30min is handled, is filtered with vacuum pump, takes its filtrate, it is spare；
（3）Take 50 ~ 90 parts by weight above-mentioned steps（2）In obtained filtrate, 10 ~ 50 parts by weight sepiolites/BaFe is added12O19/
CrCl3Composite material, 20 parts by weight of deionized water obtain antistatic treatment liquid after magnetic agitation 2h, modified dacron fabric are soaked
Stain is in above-mentioned treatment fluid, bath raio 1:25,60 DEG C of sonic oscillation 2h take out be placed in baking oven after reaction, dried at 65 DEG C
2h, washing and drying obtain novel antistatic polyester fabric.
The modification liquid and preparation method thereof is as follows：By ZnAl-LDH powders under the conditions of 70 DEG C drying 6h, according to 1:
Ionized water is added in 50 weight ratios, and stirring forms nanometer Zn Al-LDH particle water dispersion liquids；And methacrylic acid ether phosphoric acid is added
Ester, methacrylic acid ether phosphate are 10 with ZnAl-LDH powder quality ratios:1, it is formed by the way of ultrasonic disperse after mixing
Solution containing reactive emulsifier, i.e. modification liquid.
Above-mentioned sepiolite/BaFe12O19/CrCl3Composite material and preparation method thereof is as follows：
Weigh 30 parts by weight sepiolites, 5 parts by weight nano barium ferrites, 8 parts by weight chromium chlorides, 12 parts by weight polymetaphosphate sodium
It is placed in three-necked flask, 120 DEG C is warming up to after 95 parts by weight of deionized water magnetic agitation 4h are added, heat preservation is anti-under nitrogen atmosphere
6h, natural cooling, centrifugation is answered to be centrifuged after taking lower sediment thing to wash 2 ~ 3 times with absolute ethyl alcohol and deionized water respectively, it will
Product is packed into internal diameter as 1/2 inch, the Monel material tubular reactor of long 30cm, is passed through carbon dioxide gas, 320 ~ 350
2h is roasted at DEG C, is cooled down at room temperature, is ground into 160 ~ 200 mesh powder, is obtained sepiolite/BaFe12O19/CrCl3Composite material.
Embodiment 2
Identical with embodiment 1, difference is：105 parts by weight filtrates, 15 parts by weight sepiolites/BaFe are added12O19/
CrCl3Composite material.
Embodiment 3
Identical with embodiment 1, difference is：100 parts by weight filtrates, 20 parts by weight sepiolites/BaFe are added12O19/
CrCl3Composite material.
Embodiment 4
Identical with embodiment 1, difference is：95 parts by weight filtrates, 25 parts by weight sepiolites/BaFe are added12O19/CrCl3
Composite material.
Embodiment 5
Identical with embodiment 1, difference is：85 parts by weight filtrates, 35 parts by weight sepiolites/BaFe are added12O19/CrCl3
Composite material.
Embodiment 6
Identical with embodiment 1, difference is：80 parts by weight filtrates, 40 parts by weight sepiolites/BaFe are added12O19/CrCl3
Composite material.
Embodiment 7
Identical with embodiment 1, difference is：75 parts by weight filtrates, 45 parts by weight sepiolites/BaFe are added12O19/CrCl3
Composite material.
Embodiment 8
Identical with embodiment 1, difference is：70 parts by weight filtrates, 50 parts by weight sepiolites/BaFe are added12O19/CrCl3
Composite material.
Embodiment 9
Identical with embodiment 1, difference is：65 parts by weight filtrates, 55 parts by weight sepiolites/BaFe are added12O19/CrCl3
Composite material.
Comparative example 1
Identical with embodiment 1, difference is：Sepiolite/BaFe is added without when preparing antistatic fibre fabric12O19/
CrCl3Composite material.
Comparative example 2
Identical with embodiment 1, difference is：When preparing antistatic fibre fabric Hai Pao is replaced with untreated sepiolite
Stone/BaFe12O19/CrCl3Composite material.
Comparative example 3
Identical with embodiment 1, difference is：Prepare sepiolite/BaFe12O19/CrCl3Poly is added without when composite material
Sodium metaphosphate.
Comparative example 4
Identical with embodiment 1, difference is：Prepare sepiolite/BaFe12O19/CrCl3Without roasting when composite material
Processing.
Comparative example 5
Identical with embodiment 1, difference is：Prepare sepiolite/BaFe12O19/CrCl3Dioxy is not passed through when composite material
Change carbon.
Comparative example 6
Identical with embodiment 1, difference is：It is added without acetyl chitosan when preparing the antistatic fibre fabric.
Comparative example 7
Identical with embodiment 1, difference is：It is added without modification liquid when preparing the antistatic fibre fabric.
Comparative example 8
Identical with embodiment 1, difference is：In modification liquid preparation process, methacrylic acid ether phosphate and ZnAl-
LDH powder quality ratios are 1:1.
Comparative example 9
Identical with embodiment 1, difference is：In modification liquid preparation process, methacrylic acid ether phosphate and ZnAl-
LDH powder quality ratios are 1:2.
Comparative example 10
Identical with embodiment 1, difference is：In modification liquid preparation process, methacrylic acid ether phosphate and ZnAl-
LDH powder quality ratios are 1:5.
Comparative example 11
Identical with embodiment 1, difference is：In modification liquid preparation process, methacrylic acid ether phosphate and ZnAl-
LDH powder quality ratios are 1:8.
Comparative example 12
Identical with embodiment 1, difference is：In modification liquid preparation process, methacrylic acid ether phosphate and ZnAl-
LDH powder quality ratios are 1:20.
Comparative example 13
Identical with embodiment 1, difference is：In modification liquid preparation process, methacrylic acid ether phosphate and ZnAl-
LDH powder quality ratios are 2:1.
Comparative example 14
Identical with embodiment 1, difference is：In modification liquid preparation process, methacrylic acid ether phosphate and ZnAl-
LDH powder quality ratios are 5:1.
Comparative example 15
Identical with embodiment 1, difference is：In modification liquid preparation process, methacrylic acid ether phosphate and ZnAl-
LDH powder quality ratios are 10:1.
Antistatic fibre fabric prepared by embodiment 1 ~ 9 and comparative example 1 ~ 9 is clean according to GB/T24249-2009 antistatics
Net fabric antistatic property is detected, as a result as follows：
Antistatic fibre fabric performance test result
By embodiment 1 ~ 9 it can be found that when in the present proportioning environment of embodiment 1, antistatic fibre fabric obtained resists quiet
Electric effect is best, and triboelectrification voltage is only 23V, but antistatic fibre fabric antistatic property prepared by embodiment 2 ~ 9 is not
It is especially desirable, triboelectrification voltage is in 300V or more, it is seen that the proportioning of its raw material is to the anti-quiet of antistatic fibre fabric
Electrical property has tremendous influence, the proportioning of embodiment 1 to produce unexpected antistatic effect, it is seen that in 1 institute of embodiment
What is prepared under the raw material proportioning stated resists quiet polyester fabric, changes by initial acrylic acid ether phosphate and ZnAl-LDH modification liquids
Property on the basis of, the filtrate of extraction and sepiolite/BaFe12O19/CrCl3Concertedness is best between several substances such as composite material, this
When antistatic effect it is best, the antistatic fibre fabric antistatic property because obtained from is most excellent.In addition 1 ~ 5 explanation of comparative example
Sepiolite/BaFe12O19/CrCl3The addition of composite material is affected to antistatic fibre fabric performance, 8 ~ 14 explanation of comparative example
Prepare antistatic fibre raw material of fabric, the proportioning selection of initial modification liquid and raw material has its antistatic property prodigious
It influences, especially methacrylic acid ether phosphate and ZnAl-LDH powder quality ratios are 10:It can finally be increased substantially when 1 anti-quiet
Electrically.
Claims (5)
1. a kind of antistatic clothes include anti-electrostatic polyester fabric, flame-retardant layer, waterproof ventilated membrane and antibiotic layer successively from outer to inner.
2. a kind of antistatic clothes according to claim 1, it is characterised in that：The waterproof ventilated membrane is saturating using TPU waterproofs
Air film.
3. a kind of antistatic clothes according to claim 1, it is characterised in that：The fire-retardant layer material is fire retardant.
4. a kind of antistatic clothes according to claim 1, it is characterised in that：The anti-electrostatic polyester fabric is using modification
Then treatment fluid introduces sepiolite/BaFe12O19/CrCl3 composite materials, with acetyl shell to polyester modified in preparation process
The materials such as glycan compounding is prepared.
5. a kind of antistatic clothes according to claim 1, it is characterised in that：It is prepared by the antibacterial layer material antibacterial fabric
It forms.
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| CN201810423439.3A CN108567182A (en) | 2018-05-06 | 2018-05-06 | A kind of antistatic clothes |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810423439.3A CN108567182A (en) | 2018-05-06 | 2018-05-06 | A kind of antistatic clothes |
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| CN108567182A true CN108567182A (en) | 2018-09-25 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN204298558U (en) * | 2014-09-25 | 2015-04-29 | 常熟市乐德维织造有限公司 | A kind of outer ventilative interior moisture absorption type waterproof anti-static fabric |
| CN105801748A (en) * | 2016-03-24 | 2016-07-27 | 陕西科技大学 | Preparation method of layered doubled hydroxide modified polyacrylate composite emulsion |
| CN106690585A (en) * | 2017-01-19 | 2017-05-24 | 江苏广达医材集团有限公司 | Surgical degradable disposable surgical gown material |
| CN207274033U (en) * | 2017-09-11 | 2018-04-27 | 嘉兴市天之华喷织有限公司 | A kind of environment-friendly antibacterial, Anti-static flame-retardant fabric |
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2018
- 2018-05-06 CN CN201810423439.3A patent/CN108567182A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN204298558U (en) * | 2014-09-25 | 2015-04-29 | 常熟市乐德维织造有限公司 | A kind of outer ventilative interior moisture absorption type waterproof anti-static fabric |
| CN105801748A (en) * | 2016-03-24 | 2016-07-27 | 陕西科技大学 | Preparation method of layered doubled hydroxide modified polyacrylate composite emulsion |
| CN106690585A (en) * | 2017-01-19 | 2017-05-24 | 江苏广达医材集团有限公司 | Surgical degradable disposable surgical gown material |
| CN207274033U (en) * | 2017-09-11 | 2018-04-27 | 嘉兴市天之华喷织有限公司 | A kind of environment-friendly antibacterial, Anti-static flame-retardant fabric |
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Application publication date: 20180925 |