CN108527983A - 一种高光亮、超强珠光的塑料瓶及其制备方法 - Google Patents
一种高光亮、超强珠光的塑料瓶及其制备方法 Download PDFInfo
- Publication number
- CN108527983A CN108527983A CN201810083622.3A CN201810083622A CN108527983A CN 108527983 A CN108527983 A CN 108527983A CN 201810083622 A CN201810083622 A CN 201810083622A CN 108527983 A CN108527983 A CN 108527983A
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- parts
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- pearly
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- plastic bottle
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- 239000004033 plastic Substances 0.000 title claims abstract description 40
- 229920003023 plastic Polymers 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 229920000098 polyolefin Polymers 0.000 claims abstract description 41
- 239000000463 material Substances 0.000 claims abstract description 20
- 239000000853 adhesive Substances 0.000 claims abstract description 14
- 230000001070 adhesive Effects 0.000 claims abstract description 14
- 239000004595 color masterbatch Substances 0.000 claims abstract description 14
- 210000003296 Saliva Anatomy 0.000 claims abstract description 12
- 238000000465 moulding Methods 0.000 claims abstract description 11
- 239000003086 colorant Substances 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 239000002667 nucleating agent Substances 0.000 claims abstract description 8
- 238000001125 extrusion Methods 0.000 claims description 10
- 229920001971 elastomer Polymers 0.000 claims description 8
- 239000000806 elastomer Substances 0.000 claims description 8
- 210000003128 Head Anatomy 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 210000001161 Embryo, Mammalian Anatomy 0.000 claims description 3
- 238000011030 bottleneck Methods 0.000 claims description 3
- NVKDFGCILHNHRS-UHFFFAOYSA-N C1(C=CC=C1)[Au] Chemical group 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Abstract
本发明提供一种高光亮、超强珠光的塑料瓶及其制备方法，该塑料瓶包括外层、中层和内层。按重量份计，外层5‑30份，中层5‑30份，内层40‑90份。外层包括50‑99份聚烯烃、0‑50份粘合剂、1‑5份防磨损剂、0.05‑1份成核剂；中层包括50‑99份聚烯烃、0‑50份粘合剂、1‑10份珠光色母；内层包括50‑99份聚烯烃、1‑10份有机颜料、0‑40份口水回收料。本发明使用聚烯烃塑料为主要原料，成型后的塑料瓶具有高光亮、抗冲击和表面不宜刮伤等特点。可将各种颜色的珠光色母或金属色色母放入中间层，瓶子的表面会给出立体反射发光效果，珠光和金属色效果增强。成型时形成的水口料回收添加至内层，成本降低。
Description
一种高光亮、超强珠光的塑料瓶及其制备方法
技术领域
[0001]本发明涉及一种高光亮、超强珠光的塑料瓶及其制备方法，属于高分子材料技术 领域。
背景技术
[0002]目前市场上的高光泽塑料瓶一般是使用的单层或多层的PET、PETG、EVOH、PP、PE等 材料，所挤出成型生产的塑料瓶成本较高，而且一般只有有限的特性而难以满足目前市场 上对高品质、环保、成本低等的要求。本专利提供一种使用聚烯烃为主要材料的三层挤出塑 料瓶，可以同时具有多个特性以满足目前市场上越来越多的对高品质塑料平的需求。
[0003] CN102002217A公开了一种PET高光瓶，使用效果并不理想。
发明内容
[0004]本发明针对现有技术存在的不足，提供一种高光亮、超强珠光的塑料瓶，以解决目 前市场上的高光亮瓶成本高，不宜回收而且表面容易被划伤的问题。
[0005]本发明解决上述技术问题的技术方案如下:一种高光亮、超强珠光的塑料瓶，该塑 料瓶包括外层、中层和内层，按重量份计，外层5-30份，中层5-30份，内层40-90份；
[0006]按重量份计，外层包括50_99份聚烯烃、0-50份粘合剂、1-5份防磨损剂、 成核剂；
[0007]按重量份计，中层包括50-99份聚烯烃、0-50份粘合剂、1-10份珠光色母；
[0008]按重量份计，内层包括50-99份聚烯径、1-10份有机颜料、〇-4〇份口水回收料。
[0009]上述外层、中层和内层中各种组成的质量只代表重量比，不是绝对加入量，绝对加 入量为外层5-30份，中层5-30份，内层40-90份。
[0010]本发明进一步设置为，所述粘合剂为茂金属聚烯烃弹性体，如埃克森美孚化工的 EXACT〇
[0011]本发明进一步设置为，所述防磨损剂为硅氧烷聚合物，如道康宁公司的MB_5〇_ 001 〇
[0012]本发明进一步设置为，所述成核剂为11111111^11公司的即12(^、111111&1(1800或者韩 国PolyMirae的Clyrell RC5056。
[0013]本发明还提供上述高光亮、超强珠光的塑料瓶的制备方法，步骤如下：
[0014] 1)将二层机设备开启并预热2小时左右，使各个螺杆，模头，口模各个环节加热至 200-220； …、
[0015] 2)按比例配比将组成塑料瓶外层的粘合剂、防磨损剂、成核剂和聚烯烃混合充分， 并加入到外层螺杆的加料斗中；
[0016]按比例配比将组成塑料瓶中层的聚烯烃、粘合剂和珠光色母混合充分，并加入到 中层螺杆的加料斗中； 5
[0017 ]按比例配比将组成塑料瓶内层的聚稀烴、有机颜料和口水回收料混合均勻，并加 入到外层螺杆的加料斗中。
[0018] 3)开启外层螺杆，设定运转速率使外层螺杆挤出外层所需比例;然后开启中层螺 杆，设定运转速率使中层螺杆挤出中层所需比例;然后开启内层螺杆，设定运转速率使内层 螺杆挤出内层所需比例。
[0019] 4)待口模处料胚的外观光滑均匀后，开始使用预先安装好的模具成型。
[0020]本发明进一步设置为，待容器成型后瓶口和瓶底的口水料长短为30-50mm，使用天 平确认成型容器重量稳定，在所需要的重量范围内；生产完毕后，先关闭外层螺杆的运转， 依次关闭中层螺杆和外层螺杆的运转。
[0021]综上所述，本发明具有以下有益效果：
[0022] 1、使用一般的聚烯烃塑料粒子为主要原料形成表面高光泽塑料瓶，成型后的塑料 瓶具有尚光壳、抗冲击和表面不宜刮伤等特点。
[0023] 2、如果将各种颜色的珠光色母材料或金属色色母材料放入中间层，瓶子的表面会 给出立体感(3D效果)的反射发光效果，珠光和金属色效果增强。
[0024] 3、成型时形成的水口料可以回收添加至三层瓶的内层，成本会进一步的降低。
具体实施方式
[0025] 下面对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例 仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技 术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范 围。
[0026] 实施例1
[0027] —种尚光壳、超强珠光的塑料瓶，该塑料瓶包括外层、中层和内层，按重量份计，夕卜 层5份，中层5份，内层80份；
[0028]按重量份计，外层包括52份聚稀烃、1份娃氧烧聚合物、1份hpn-20E; _9]按重量份计，中层包括g9份聚烯烃、以份茂金属聚烯烃弹性体、i份珠光色母；
[0030]按重量份计，内层包括52份聚烯径、瞻有机颜料、2份口水回收料。
[0031] 实施例2
[0032] 一种高光亮、超强珠光的塑料瓶，该塑料瓶包括外层、中层和内层，按重量份计外 层30份，中层10份，内层90份； ’
[0033]按重量份计，外层包括80份聚烯烃、15份茂金属聚烯烃弹性体、K 8份硅氧烷聚合 物、0.6份mi 1 lard800;
[0034]按重量份计，中层包括50份聚烯烃、10份珠光色母；
[0035]按重量份计，内层包括61份聚烯烃、3份有机颜料、2〇份口水回收料。
[0036] 实施例3
[0037] —种筒光亮、超强珠光的塑料瓶，该塑料瓶包括外层、中层和内层，按重量份计 层15份，中层20份，内层40份； ’71
[0038]顏量侃，外层傭95份聚驗、赠茂金属聚錄雜体、3 2紐氧八 物、0.3份Clyrell RC5056; n
[0039]顏量份计，中层包括7〇份聚燦烃、讀茂金属聚稀烃弹性体、7份珠光色母；
[0(M0]顏量册，p(g层傭79份聚驗、6份前^辦、铺D水回 [0041] 实施例4 。 珠光的塑料瓶，麵料瓶包括外层、中层和内层，按重量份计外 层22份，中层30份，内层60份；
[OO43]顏遽计，外层傭69份聚駿、讀齡属聚觀弹雖、5份 0.05份Clyrell RC5056;
[0044]顏量份计，中层包括6〇份聚烯烃、5〇份茂金属聚驗弹性体、4份珠 [0045]按重量份计，内层包括98份聚烯烃、10份有机颜料。 ’
[0046]本发明还提供上述高光亮、超强珠光的塑料瓶的制备方法，步骤如下： _7] 1)将三层机设备开启并预热2小时左右，使各个螺杆，模头，口模各个环节至 200-220； …、
[0048] 2)按比例配比将组成塑料瓶外层的粘合剂、防磨损剂、成核剂和聚烯烃混合充分， 并加入到外层螺杆的加料斗中；
[0049]按比例配比将组成塑料瓶中层的聚烯烃、粘合剂和珠光色母混合充分，并加入到 中层螺杆的加料斗中；
[0050]按比例配比将组成塑料瓶内层的聚烯烃、有机颜料和口水回收料混合均匀，并加 入到外层螺杆的加料斗中。
[0051] 3)开启外层螺杆，设定运转速率(表数为5-50%)使外层螺杆挤出外层所需比例； 然后开启中层螺杆，设定运转速率(表数为5-50%)使中层螺杆挤出中层所需比例;然后开 启内层螺杆，设定运转速率使内层螺杆挤出内层所需比例。
[0052] 4)待口模处料胚的外观光滑均匀后，开始使用预先安装好的模具成型；
[0053] 5)待容器成型后瓶口和瓶底的口水料长短为3〇-50mm，使用天平确认成型容器重 量稳定，在所需要的重量范围内；
[0054] ©保持成型条件不变的情况下，生产所需要的容器个数；
[0055] 7)生产完毕后，先关闭外层螺杆的运转，依次关闭中层螺杆和外层螺杆的运转，确 保生产设备中的模头以及口模内部的有色的中层和内层材料不会粘接在内壁，以便清洗和 设备待用。
[0056]以上所述仅为本发明的较佳实施例，并不用以限制本发明，凡在本发明的精神和 原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (6)
1.一种高光亮、超强珠光的塑料瓶，其特征在于:该塑料瓶包括外层、中层和内层，按重 量份计，外层5-30份，中层5-30份，内层40-90份； 按重量份计，外层包括5〇_99份聚烯烃、0-50份粘合剂、丨—5份防磨损剂、0.054份成核 剂； 按重量份计，中层包括50_99份聚稀烃、〇_5〇份粘合剂、卜川份珠光色母； 按重量份计，内层包括50-99份聚烯烃、；1-10份有机颜料、〇_4〇份口水回收料。
2.根据权利要求1所述的高光亮、超强珠光的塑料瓶，其特征在于:所述粘合剂为茂金 属聚烯烃弹性体。
3.根据权利要求1所述的高光亮、超强珠光的塑料瓶，其特征在于:所述防磨损剂为硅 氧烷聚合物。
4.根据权利要求1所述的高光亮、超强珠光的塑料瓶，其特征在于:所述成核剂为HpN_ 20已、111；111&『(1800或013^6111^5056。
5.根据权利要求1-4任一所述的高光亮、超强珠光的塑料瓶的制备方法，其特征在于： 1) 将三层机设备开启并预热2小时左右，使各个螺杆，模头，口模各个环节加热至2〇〇_ 220； 2) 按比例配比将组成塑料瓶外层的粘合剂、防磨损剂、成核剂和聚烯烃混合充分，并加 入到外层螺杆的加料斗中； 按比例配比将组成塑料瓶中层的聚烯烃、粘合剂和珠光色母混合充分，并加入到中层 螺杆的加料斗中； 按比例配比将组成塑料瓶内层的聚烯烃、有机颜料和口水回收料混合均匀，并加入到 外层螺杆的加料斗中； 3) 开启外层螺杆，使外层螺杆挤出外层所需比例;然后开启中层螺杆，使中层螺杆挤出 中层所需比例;接着开启内层螺杆，设定运转速率使内层螺杆挤出内层所需比例； 4) 待口模处料胚的外观光滑均匀后，开始使用预先安装好的模具成型。
6.根据权利要求5所述的高光亮、超强珠光的塑料瓶的制备方法，其特征在于:待容器 成型后瓶口和瓶底的口水料长短为30-50mm，使用天平确认成型容器重量稳定，在所需要的 重量范围内；生产完毕后，先关闭外层螺杆的运转，依次关闭中层螺杆和外层螺杆的运转。
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