CN108505329A - A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles - Google Patents

A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles Download PDF

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Publication number
CN108505329A
CN108505329A CN201810417438.8A CN201810417438A CN108505329A CN 108505329 A CN108505329 A CN 108505329A CN 201810417438 A CN201810417438 A CN 201810417438A CN 108505329 A CN108505329 A CN 108505329A
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CN
China
Prior art keywords
dressing liquid
flame
water
disposable sanitary
sanitary articles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810417438.8A
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Chinese (zh)
Inventor
余刚
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SHANGHAI GAOJU BIOTECHNOLOGY CO Ltd
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SHANGHAI GAOJU BIOTECHNOLOGY CO Ltd
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Priority to CN201810417438.8A priority Critical patent/CN108505329A/en
Publication of CN108505329A publication Critical patent/CN108505329A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192Polycarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/72Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties

Abstract

The invention discloses a kind of flame-proof antibiotic deodorization dressing liquids for disposable sanitary articles, it is related to antiseptic technical field, solving dressing liquid in the prior art does not have deodouring effect, it is difficult to meet the technical issues of people are to antibacterial, fire-retardant, deodorization a variety of demands.Dressing liquid includes following components in percentage by weight:Saturated straight chain dicarboxylic acids 1 ~ 10%;Polymer guanidine salt 0.1 ~ 5%;Water-soluble flame retardant 2 ~ 15%;Pure water complements to 100%.The carboxyl of saturated straight chain dicarboxylic acids can be reacted with ammonia, generate the amido bond and water of odorless, to eliminate stink, after being used in compounding with polymer guanidine salt, can be mutually reinforcing respective sterilization and deodorizing effect, and reduce respective dosage;Water-soluble flame retardant is added, so that dressing liquid is had the effect of fire-retardant;When handling disposable sanitary articles, only dressing liquid need to be sprayed, impregnated or be padded on pending material, it is simple for process.

Description

A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles
Technical field
The present invention relates to antiseptic technical fields, more specifically, it relates to a kind of resistance for disposable sanitary articles Fire antibacterial and deodouring dressing liquid.
Background technology
Disposable sanitary articles include mainly gynecologic menstrual amenities (sanitary napkin, panty liner, tampon), diaper etc. Excreta amenities (urine pants, diaper pad, urine pad);Skin, mucous membrane amenities (hygenic towelette, sanitary wet paper towel, anti-/ suppression Bacterium lotion).As the improvement of people's living standards, the added values such as packaging, smell, color, the shape of people in addition to being concerned about commodity In addition, the health of oneself and household is become more concerned with, also increasingly worries that disposable sanitary articles are easy to grow in daily life The potential danger of endophytic bacteria.
There are some materials with antibiotic effect or flame retardant efficiency or deodouring effect on Vehicles Collected from Market, but first, these All it is that can only assign one or both of three kinds of fire-retardant, antibacterial, deodorization effects;Secondly, it is related to anti-flammability, current main-stream Fire retardant is divided into the additive flame retardant of physical mixed and two class of reactive flame retardant of chemical bonding, and additive flame retardant is logical It crosses mechanical mix techniques to be added in polymer, makes polymer that there is anti-flammability;Reactive flame retardant is as a kind of monomer It participates in polymerisation and makes polymer itself containing flame-retardant composition, both are all in the production process of solid material in fact It is added as auxiliary material, processing is all material and non-product, thus it is complex process, with high costs, and applicability is not wide.
It is disclosed in the Chinese invention patent of Publication No. CN102619086A a kind of for the fire-retardant, anti-of fiber art Bacterium composite modifier and preparation method thereof, active constituent are alkyl phosphate, alkyl guanidine, and finished product is solid, belongs to addition Pending object can only be added in type fire retardant under special process, inconvenient for use, and specific processing method is that PP is added as master batch, And complex process, it is with high costs.
A kind of water-soluble thermal-reactive polyurethane is disclosed in the Chinese invention patent of Publication No. CN106498749A Hydrophilic, fire-retardant, antibacterial finishing agent, including following components in percentage by weight:Water-soluble thermal-reactive polyurethane, 15-20 parts;Second Acyl glutamine, 0.1-10 parts;Glycerine, 2-12 parts.Although the patent is liquid, may be used and the methods of pad, spray processing one Secondary sex hygiene articles for use, but there is no addition antimicrobial component and flame-retardant compositions in the patent, effect is actually closer in anti- Wrinkle, shrink-resistant finish and enhancing richness and elasticity, therefore, antibacterial effect is difficult to meet the needs of disposable sanitary articles, and And it does not have deodouring effect, it is difficult to meet people to antibacterial, fire-retardant, deodorization a variety of demands.
Invention content
In view of the deficiencies of the prior art, the present invention intends to provide a kind of resistance for disposable sanitary articles Antibacterial and deodouring dressing liquid is fired, the growth and breeding of bacterium, germ, mould, virus etc. is hindered by using polymer guanidine salt, using full With straight-chain dicarboxylic acid's deodorization, flame retardant effect is reached using water-soluble flame retardant, to solve the above technical problems, has and kills Bacterium, good deodorization effect integrate fire-retardant, antibacterial, the advantage of deodouring effect.
To achieve the above object, the present invention provides following technical solutions:
A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, including following components in percentage by weight:
Saturated straight chain dicarboxylic acids 1~10%;
Polymer guanidine salt 0.1~5%;
Water-soluble flame retardant 2~15%;
Pure water complements to 100%.
By using above-mentioned technical proposal, polymer guanidine salt can effectively hinder the growth of bacterium, germ, mould, virus etc. Breeding, antibacterial action mainly by solubilizing lipids, change the permeability of bacterial cell membrane, and endobacillary metabolism is made to hinder Hinder and antibacterial.Antimicrobial spectrum is wider, to Gram-positive and negative bacterium and mould effective force, has colourless, odorless, stingless to skin Swash property, nontoxicity, non-corrosive feature.And enable some to generate the strain of stink can not to breed, so also can be to deodorization Effect has certain help, and can reduce the dosage of saturated straight chain dicarboxylic acids.
Saturated straight chain dicarboxylic acids is as deodorant, and different from usually used absorption, capture or sterilization smelly eliminating, human body is smelly The main source of taste is ammonia, and the carboxyl of saturated straight chain dicarboxylic acids is reacted with ammonia, generates amido bond (odorless) and water.Make Saturated straight chain dicarboxylic acids itself for deodorant has certain antibacterial effect, and can reduce the dosage of polymer guanidine salt. Therefore, after saturated straight chain dicarboxylic acids and polymer guanidine salt are used in compounding, it can be mutually reinforcing respective sterilization and deodorizing effect, And reduce respective dosage.
Water-soluble flame retardant is soluble easily in water, is dissolved in for colourless transparent liquid after water, and non-toxic and tasteless, performance is stablized.Saturation is straight After chain dicarboxylic acids, polymer guanidine salt and water-soluble flame retardant are used in compounding, integrate fire-retardant, antibacterial, deodouring effect.
Further preferably, the saturated straight chain dicarboxylic acids is in glutaric acid, pimelic acid, suberic acid, azelaic acid Any one.
By using above-mentioned technical proposal, it is found through experiment that, glutaric acid, pimelic acid, suberic acid, azelaic acid have certain Antibacterial effect, and the dosage of polymer guanidine salt can be reduced.There are two carboxyls in one molecule, can be with the ammonia of two molecules It reacts, dosage is small, good deodorization effect.
Further preferably, the polymer guanidine salt be selected from poly (hexamethylene) hydrochloride, polyhexamethylene guanide phosphate, Any one in polyhexamethylene guanide propionate, poly hexamethylene biguanide.
By using above-mentioned technical proposal, above-mentioned antiseptic wide sterilization spectrum, sterilization intensity is high, is used to disposable hygienic It only needs to spray, impregnate or pad when product are handled, it is simple for process, it is corrosion-free to processed material and its discoloration will not be made, and nothing It is color, tasteless, to light, thermostabilization, can permanently effective antibacterial, it is mild without the nuisances such as heavy metal, safety.
Further preferably, the water-soluble flame retardant is water-soluble poly ammonium phosphate.
By using above-mentioned technical proposal, water-soluble poly ammonium phosphate is soluble easily in water, non-toxic and tasteless, acute oral toxicity LD50 >5000mg/kg, toxicity very little, and etchant gas is not generated, thermal stability is high, is a kind of non-halogen fire retardant of function admirable;Together When, water-soluble poly ammonium phosphate is soluble in water, and dressing liquid is made to have fire-retardant performance after addition, and is infusion method, spray The method for sorting such as method provide possibility.
Further preferably comprising following components in percentage by weight:
Saturated straight chain dicarboxylic acids 4%;
Polymer guanidine salt 2%;
Water-soluble flame retardant 8%;
Pure water 86%.
By using above-mentioned technical proposal, under said ratio, dressing liquid has certain flame retardant effect, and sterilizes and remove Smelly effect is preferable.
Further preferably comprising following components in percentage by weight:
Saturated straight chain dicarboxylic acids 7%;
Polymer guanidine salt 3%;
Water-soluble flame retardant 10%;
Pure water 80%.
By using above-mentioned technical proposal, under said ratio, the sterilization of dressing liquid and deodorizing effect are better than current commercial Product.
In conclusion compared with prior art, the invention has the advantages that:
(1) polymer guanidine salt can effectively hinder the growth and breeding of bacterium, germ, mould, virus etc., and antimicrobial spectrum is wider, and makes Some strains that can generate stink can not be bred, so can also there is certain help to deodouring effect;Saturated straight chain dicarboxylic acids Carboxyl reacted with ammonia, amido bond (odorless) and water is generated, to eliminate stink.Saturated straight chain binary as deodorant Carboxylic acid itself has certain antibacterial effect, and can reduce the dosage of polymer guanidine salt.Therefore, saturated straight chain dicarboxylic acids and After polymer guanidine salt is used in compounding, it can be mutually reinforcing respective sterilization and deodorizing effect, and reduce respective dosage.
(2) after saturated straight chain dicarboxylic acids, polymer guanidine salt and water-soluble flame retardant are used in compounding, collection is fire-retardant, antibacterial, removes Smelly effect is in one, when handling disposable sanitary articles, only need to spray dressing liquid on pending material, soaks It steeps or pads, it is simple for process.
(3) safety of saturated straight chain dicarboxylic acids, polymer guanidine salt and water-soluble poly ammonium phosphate is all very high, nontoxic stingless Swash property, and free from extraneous odour, the processing particularly suitable for disposable sanitary articles.
Specific implementation mode
With reference to embodiment, the present invention will be described in detail.
Embodiment 1:A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, each component and its corresponding weight It is as shown in table 1 to measure percentage, and acquisition is made by the steps:
Step 1 weighs saturated straight chain dicarboxylic acids, polymer guanidine salt, water-soluble flame retardant and pure water in proportion;
Saturated straight chain dicarboxylic acids is added in pure water, adds polymer guanidine salt, water-soluble flame retardant by step 2, stirs It is uniformly mixed, obtains flame-proof antibiotic deodorization dressing liquid.
Embodiment 2-7:A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, the difference with embodiment 1 Place is that each component and its corresponding weight percent are as shown in table 1.
Each component and its weight percent in 1 embodiment 1-7 of table
Saturated straight chain dicarboxylic acids in table 1 uses glutaric acid, and polymer guanidine salt uses poly (hexamethylene) hydrochloride, water-soluble Fire retardant uses water-soluble poly ammonium phosphate.
Embodiment 8:A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, it is different from embodiment 7 it It is in saturated straight chain dicarboxylic acids uses pimelic acid.
Embodiment 9:A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, it is different from embodiment 7 it It is in saturated straight chain dicarboxylic acids uses suberic acid.
Embodiment 10:A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, it is different from embodiment 7 it It is in saturated straight chain dicarboxylic acids uses azelaic acid.
Embodiment 11:A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, it is different from embodiment 7 it It is in polymer guanidine salt uses polyhexamethylene guanide phosphate.
Embodiment 12:A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, it is different from embodiment 7 it It is in polymer guanidine salt uses polyhexamethylene guanide propionate.
Embodiment 13:A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, it is different from embodiment 7 it It is in polymer guanidine salt uses poly hexamethylene biguanide.
Comparative example 1:A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, it is different from embodiment 1 it It is in glutaric acid is replaced with pure water.
Comparative example 2:A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, it is different from embodiment 1 it It is in poly (hexamethylene) hydrochloride is replaced with pure water.
Comparative example 3:Antibiotic finish is prepared using the embodiment 1 in the Chinese invention patent of Publication No. CN106498749A Agent.
Test specimen:Using the flame-proof antibiotic deodorization dressing liquid obtained in embodiment 1-13 as test specimen 1-13, adopt With the flame-proof antibiotic deodorization dressing liquid and antibacterial finishing agent obtained in comparative example 1-3 sample 1-3 as a contrast.
Test deodoriging properties test
Test method:It is 1#-17# to take 17 pieces of paper handkerchief cloth numbers, and 1#-16# is arranged using test specimen 1-13 and control sample 1-3 The dosage of paper handkerchief cloth, dressing liquid is that every piece of paper handkerchief 10g, 17# paper handkerchief cloth is without any processing, as a contrast;
By treated, 1#-17# paper handkerchief cloth is put into 17 conical flasks, and ammonia is passed through into conical flask, seals conical flask, is stood After 30min, the judgement of the stink in Shi Jinhang conical flasks is identified by 1 stink.The judgement for indicating stink is evaluated with 5 grades, it will most Weak stink is set as 0, and strongest stink is set as 5, and ammonia detector detection ammonia residual quantity is used in combination and calculates ammonia Except rate.
Test result:Test specimen 1-13 and control sample 1-3 deodorization test results are as shown in table 2.As shown in Table 2, only Ammonia removal rate is 50.9% only with ammonia removal rate when glutaric acid for 29.8% when using poly (hexamethylene) hydrochloride, And the ammonia removal rate of test specimen 1-13 is above the sum of the ammonia removal rate of control sample 1 and control sample 2, illustrates After saturated straight chain dicarboxylic acids and polymer guanidine salt are used in compounding, it can be mutually reinforcing respective deodorizing effect, and reaching Respective dosage can be reduced when identical deodorizing effect.
The deodorization test result of table 2 test specimen 1-13 and control sample 1-3
Test two anti-microbial property tests
Test method:With reference to standard GB/T 15979-2002《Disposable Sanitary Accessory sanitary standard》Product anti-microbial property Test method (appendix C), test strain is bacterium:Staphylococcus aureus (ATCC6538), Escherichia coli (ATCC25922), fungi:Candida albicans (ATCC10231), the antibiotic property of testing experiment sample 1-13 and control sample 1-3 Energy.
Test result:Test specimen 1-13 and control sample 1-3 test results are as shown in table 3.As shown in Table 3, test sample The antibiotic rate of product 1-13 is significantly larger than control sample 1-3, and the antibiotic rate of test specimen 1-13 is above control sample 1 and right The sum of the antibiotic rate of product 2 in the same old way after illustrating that saturated straight chain dicarboxylic acids and polymer guanidine salt are used in compounding, can be mutually reinforcing each From bactericidal effect, and respective dosage is reduced when reaching identical antibacterial effect.
3 test specimen 1-13 of table and control sample 1-3 anti-bacteria test results
Test the test of three flame retardant properties
Test method:Using test specimen 1-13 and control sample 1-3 dressed nonwoven fabrics, the dosage of dressing liquid is 2 grams/square Rice, dries non-woven fabrics after immersion, using GB/T5455-2014《Textile combustion performance vertical direction char length glow and The measurement of after flame time》In method test flame retardant property.
Test result:Test specimen 1-13 and control sample 1-3 flame test results are as shown in table 4, can by table 4 Know, the flame retardant property of test specimen 1-13 can reach B grades, illustrate saturated straight chain dicarboxylic acids, polymer guanidine in the present invention After salt and water-soluble flame retardant are used in compounding, integrate fire-retardant, antibacterial, deodouring effect, a variety of demands of people can be met.
4 test specimen 1-13 of table and control sample 1-3 flame test results
Sample number into spectrum Flame retardant rating
Test specimen 1 B grades
Test specimen 2 B grades
Test specimen 3 B grades
Test specimen 4 B grades
Test specimen 5 B grades
Test specimen 6 B grades
Test specimen 7 B grades
Test specimen 8 B grades
Test specimen 9 B grades
Test specimen 10 B grades
Test specimen 11 B grades
Test specimen 12 B grades
Test specimen 13 B grades
Control sample 1 B grades
Control sample 2 B grades
Control sample 3 C grades
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-described embodiment, All technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art For those of ordinary skill, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (6)

1. a kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles, which is characterized in that including following weight percent The component of ratio:
Saturated straight chain dicarboxylic acids 1 ~ 10%;
Polymer guanidine salt 0.1 ~ 5%;
Water-soluble flame retardant 2 ~ 15%;
Pure water complements to 100%.
2. the flame-proof antibiotic deodorization dressing liquid according to claim 1 for disposable sanitary articles, which is characterized in that institute State any one of saturated straight chain dicarboxylic acids in glutaric acid, pimelic acid, suberic acid, azelaic acid.
3. the flame-proof antibiotic deodorization dressing liquid according to claim 1 for disposable sanitary articles, which is characterized in that institute It states polymer guanidine salt and is selected from poly (hexamethylene) hydrochloride, polyhexamethylene guanide phosphate, polyhexamethylene guanide propionate, poly- six Any one in methylene biguanides.
4. the flame-proof antibiotic deodorization dressing liquid according to claim 1 for disposable sanitary articles, which is characterized in that institute It is water-soluble poly ammonium phosphate to state water-soluble flame retardant.
5. the flame-proof antibiotic deodorization dressing liquid according to claim 1 for disposable sanitary articles, which is characterized in that its Including following components in percentage by weight:
Saturated straight chain dicarboxylic acids 4%;
Polymer guanidine salt 2%;
Water-soluble flame retardant 8%;
Pure water 86%.
6. the flame-proof antibiotic deodorization dressing liquid according to claim 1 for disposable sanitary articles, which is characterized in that its Including following components in percentage by weight:
Saturated straight chain dicarboxylic acids 7%;
Polymer guanidine salt 3%;
Water-soluble flame retardant 10%;
Pure water 80%.
CN201810417438.8A 2018-05-03 2018-05-03 A kind of flame-proof antibiotic deodorization dressing liquid for disposable sanitary articles Pending CN108505329A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1036498A (en) * 1989-03-08 1989-10-25 何复光 Stink-eliminating bactericidal film for telephone
JP2000169316A (en) * 1998-12-02 2000-06-20 Tsumoru Shimada Deodorizing processed sand, antimicrobial processed sand, deodorizing/antimicrobial processed sand, deodorizing material, antimicrobial material, deodorizing/ antimicrobial material, and their production
CN101173041A (en) * 2007-10-19 2008-05-07 华南理工大学 High molecular weight guanidine salt and polyamine antimicrobial polymeric compounds, producing method and application of the same
CN101253235A (en) * 2005-08-31 2008-08-27 金伯利-克拉克环球有限公司 Antimicrobial composition
CN102246794A (en) * 2011-06-08 2011-11-23 江中药业股份有限公司 Composition for killing microbes
CN104846647A (en) * 2015-04-28 2015-08-19 中国科学院合肥物质科学研究院 Fabric with flame-retardant function and anti-bacterial function and manufacturing method of fabric
CN104884044A (en) * 2012-12-21 2015-09-02 利拉伐控股有限公司 Germicidal compositions comprising carboxylic acid mixture and use as topical disinfectants

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1036498A (en) * 1989-03-08 1989-10-25 何复光 Stink-eliminating bactericidal film for telephone
JP2000169316A (en) * 1998-12-02 2000-06-20 Tsumoru Shimada Deodorizing processed sand, antimicrobial processed sand, deodorizing/antimicrobial processed sand, deodorizing material, antimicrobial material, deodorizing/ antimicrobial material, and their production
CN101253235A (en) * 2005-08-31 2008-08-27 金伯利-克拉克环球有限公司 Antimicrobial composition
CN101173041A (en) * 2007-10-19 2008-05-07 华南理工大学 High molecular weight guanidine salt and polyamine antimicrobial polymeric compounds, producing method and application of the same
CN102246794A (en) * 2011-06-08 2011-11-23 江中药业股份有限公司 Composition for killing microbes
CN104884044A (en) * 2012-12-21 2015-09-02 利拉伐控股有限公司 Germicidal compositions comprising carboxylic acid mixture and use as topical disinfectants
CN104846647A (en) * 2015-04-28 2015-08-19 中国科学院合肥物质科学研究院 Fabric with flame-retardant function and anti-bacterial function and manufacturing method of fabric

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