CN108410399A - A kind of left and right waist patch special glue and preparation method thereof - Google Patents
A kind of left and right waist patch special glue and preparation method thereof Download PDFInfo
- Publication number
- CN108410399A CN108410399A CN201810266274.3A CN201810266274A CN108410399A CN 108410399 A CN108410399 A CN 108410399A CN 201810266274 A CN201810266274 A CN 201810266274A CN 108410399 A CN108410399 A CN 108410399A
- Authority
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- China
- Prior art keywords
- parts
- right waist
- special glue
- diene
- styrene
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J147/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Abstract
A kind of left and right waist patch special glue, in parts by weight, preparing raw material includes：100 parts of styrene ethylene based compound diene copolymer, 100 parts of tackifying resin, 50 parts of plasticising oil.The diene is conjugated diene.The tackifying resin is selected from hydrogenated petroleum resin and/or hydrogenation phenolic resin.
Description
Technical field
The present invention relates to adhesive areas more particularly to a kind of left and right waist to paste special glue and preparation method thereof.
Background technology
Hot melt adhesive is a kind of adhesive of plasticity, its physical state changes with temperature and changed in certain temperature range
Become, and chemical characteristic is constant, it is non-toxic and tasteless, belong to environmental-protecting chemical product.Because of its product itself system solid, convenient for packaging, fortune
Defeated, storage, solvent-free, pollution-free, nontoxic type；And simple production process, high added value, it is excellent that bonding strength is big, speed is fast etc.
It puts and receives favor.The adhesive property of left and right waist patch special glue on the market and ageing-resistant ability, which cannot all meet, at present wants
It asks, is easy to rub in the state of moistening, not only influences comfort level, flu is also easily caused when it is cold.
Invention content
In order to solve prior art problem, the first aspect of the present invention provides a kind of left and right waist patch special glue, prepares former
Material includes：Styrene-ethylene based compound-diene copolymer, tackifying resin, plasticising oil.
In some embodiments, in parts by weight, preparing raw material includes：Styrene-ethylene based compound-diene is total
100 parts of polymers, 100 parts of tackifying resin, 50 parts of plasticising oil.
In some embodiments, the diene is conjugated diene.
In some embodiments, the tackifying resin is selected from hydrogenated petroleum resin and/or hydrogenation phenolic resin.
In some embodiments, the plasticising oil is selected from Dioctyl Glutaricate, didecyl glutarate, two isodecyl of glutaric acid
Ester, two fourth 2-ethoxyethyl acetate of glutaric acid, two fourth oxygen ethoxy ethyl ester of glutaric acid, Di-n-butyl Adipate, diisobutyl adipate, adipic acid
Two just own esters, dioctyl adipate or adipic acid two (2- ethylhexyls), diisooctyl adipate, dinonyl adipate, oneself two
Sour dinonyl, diisodecyl adipate (DIDA), two fourth 2-ethoxyethyl acetate of adipic acid, adipic acid two (Butoxyethoxy second) ester, azelaic acid
Two fourth 2-ethoxyethyl acetates, dibenzyl azelate, dicyclohexyl azelate, dimethyl sebacate, n-butyl sebacate, decanedioic acid two are different
Propyl ester, dioctyl sebacate, Plexol 201, decanedioic acid di-sec-octyl, di-n-nonyl sebacate, two (butoxy of decanedioic acid
Second) ester, decanedioic acid two (Butoxyethoxy second) ester, dibenzyl sebacate, diethyl sebacate, in dihexyl sebacate extremely
Few one kind.
In some embodiments, the conjugated diene is selected from one kind in 1,3- octadienes, 2,4- octadienes.
In some embodiments, the vinyl compound in 1- vinyl imidazoles, 2- vinylpyridines one
Kind.
In some embodiments, styrene in the styrene-ethylene based compound-diene copolymer, vinylated
Close object, the weight ratio of diene is 1：1：8.
The second aspect of the present invention provides a kind of application of left and right waist as described above patch special glue in amenities.
The third aspect of the present invention provides a kind of preparation method of left and right waist patch special glue as described above, including walks as follows
Suddenly, in a kettle, styrene-ethylene based compound-diene copolymer, tackifying resin, plasticising oil are mixed, heating melting,
Stir 5-7h, discharge, sizing, it is cooling to get.
Specific implementation mode
The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this hair can be more easily understood
Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with fields of the present invention
The normally understood identical meaning of technical staff.When there is a conflict, the definition in this specification shall prevail.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ",
" having ", " containing " or its any other deformation, it is intended that cover non-exclusionism includes.For example, the combination comprising listed elements
Object, step, method, product or device are not necessarily limited to those elements, but may include not expressly listed other elements or
Such composition, step, method, product or the intrinsic element of device.
Conjunction " Consists of " excludes any element that do not point out, step or component.If in claim, this
Phrase will make claim be closed, so that it is not included the material in addition to the material of those descriptions, but relative normal
Except rule impurity.When being rather than immediately following after theme in the clause that phrase " Consists of " appears in claim main body,
It is only limited to the element described in the clause；Other elements are not excluded except the claim as a whole.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit
When the Range Representation that choosing value limits, this, which should be understood as, specifically discloses by any range limit or preferred value and any range
Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open
When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to
5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise range intention includes its end
Value and all integers and score in the range.
Singulative includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " arbitrary
It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and
The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, and it is specific to indicate that the present invention is not limited to this
Quantity further includes the modified part of the acceptable change without lead to related basic function close to the quantity.Phase
It answers, modifies a numerical value with " about ", " about " etc., mean that the present invention is not limited to the exact numericals.In some examples, approximate
Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, range limits can be with
Combination and/or exchange, these ranges include all subranges contained therebetween if not stated otherwise.
The first aspect of the present invention provides a kind of left and right waist patch special glue, and preparing raw material includes：Styrene-ethylene base
Close object-diene copolymer, tackifying resin, plasticising oil.
In some embodiments, in parts by weight, preparing raw material includes：Styrene-ethylene based compound-diene is total
100 parts of polymers, 100 parts of tackifying resin, 50 parts of plasticising oil.
In some embodiments, the diene is conjugated diene.
In some embodiments, the tackifying resin is selected from hydrogenated petroleum resin and/or hydrogenation phenolic resin.
Plasticising oil is added in polymer, can increase its plasticity, improve processability, assigns product flexibility.Thermoplasticity
There is interaction force between linear macromolecule, this physical force comes from Van der Waals force (electrostatic force, induction force and color
Dissipate power) and hydrogen bond, its size it is related with polymer architecture.Generally, the force ratio nonpolar molecule of polar molecule is big.Molecule
Between active force not only make polymer that there is certain mechanical strength, but also many performances such as also affect its processing and forming.Heat
The essence of plastic resin processing is exactly to increase the activity of polymer molecule by heating, weaken active force therebetween, to make
Have plasticity.But, intermolecular force strong for certain polarity is greatly and for the polymer of thermally labile, often
It meets difficulty.The effect of plasticising oil is that the active force weakened between polymer molecule, to reduce softening temperature, melting temperature
And glass transition temperature, reduce the viscosity of melt, increase its mobility, improves the processability and product and flexibility of polymer.
In some embodiments, the plasticising oil is selected from Dioctyl Glutaricate, didecyl glutarate, two isodecyl of glutaric acid
Ester, two fourth 2-ethoxyethyl acetate of glutaric acid, two fourth oxygen ethoxy ethyl ester of glutaric acid, Di-n-butyl Adipate, diisobutyl adipate, adipic acid
Two just own esters, dioctyl adipate or adipic acid two (2- ethylhexyls), diisooctyl adipate, dinonyl adipate, oneself two
Sour dinonyl, diisodecyl adipate (DIDA), two fourth 2-ethoxyethyl acetate of adipic acid, adipic acid two (Butoxyethoxy second) ester, azelaic acid
Two fourth 2-ethoxyethyl acetates, dibenzyl azelate, dicyclohexyl azelate, dimethyl sebacate, n-butyl sebacate, decanedioic acid two are different
Propyl ester, dioctyl sebacate, Plexol 201, decanedioic acid di-sec-octyl, di-n-nonyl sebacate, two (butoxy of decanedioic acid
Second) ester, decanedioic acid two (Butoxyethoxy second) ester, dibenzyl sebacate, diethyl sebacate, in dihexyl sebacate extremely
Few one kind.
In some embodiments, the conjugated diene is selected from one kind in 1,3- octadienes, 2,4- octadienes.
No. CAS of 1,3- octadiene is 1002-33-1, and No. CAS of 2,4- octadienes is 13643-08-8.
In some embodiments, the vinyl compound in 1- vinyl imidazoles, 2- vinylpyridines one
Kind.
No. CAS of 1- vinyl imidazoles is 1072-63-5, and No. CAS of 2- vinylpyridines is 100-69-6.
In some embodiments, styrene in the styrene-ethylene based compound-diene copolymer, vinylated
Close object, the weight ratio of diene is 1：1：8.
The second aspect of the present invention provides a kind of application of left and right waist as described above patch special glue in amenities.
The third aspect of the present invention provides a kind of preparation method of left and right waist patch special glue as described above, including walks as follows
Suddenly, in a kettle, styrene-ethylene based compound-diene copolymer, tackifying resin, plasticising oil are mixed, heating melting,
Stir 5-7h, discharge, sizing, it is cooling to get.
Left and right waist provided by the invention pastes special glue, has higher peel strength, styrene-ethylene based compound-bis-
Main body of the alkene copolymer as adhesive improves the water resistance of adhesive, the especially performance of salt tolerant aqueous corrosion, for
It is not easily to fall off when in amenities.Left and right waist patch special glue provided by the invention has good cryogenic property simultaneously, in temperature
The case where degumming and cracking will not occur in storage and use under the conditions of lower.
With reference to specific embodiment, the present invention is further explained.
Embodiment 1
Left and right waist pastes special glue, and in parts by weight, preparing raw material includes：Styrene-ethylene based compound-diene copolymerization
100 parts of object, 100 parts of hydrogenated petroleum resin, 30 parts of diisodecyl glutarate, 20 parts of Plexol 201.
The preparation method of the styrene-ethylene based compound-diene copolymer is, by styrene, 1- vinyl imidazoles,
1,3- octadiene mixes, and is heated to 150 DEG C, cumyl peroxide is then added, and persistently stirs 15h, discharging to get.It is described
Styrene, 1- vinyl imidazoles, 1,3- octadienes, cumyl peroxide weight ratio be 1：1：8：0.04.
Preparation method includes the following steps, in a kettle, by styrene-ethylene based compound-diene copolymer 100
20 parts of part, 100 parts of hydrogenated petroleum resin, 30 parts of diisodecyl glutarate, Plexol 201 mixing, heating melting, stirring
6h discharges, sizing, it is cooling to get.
Embodiment 2
Left and right waist pastes special glue, and in parts by weight, preparing raw material includes：Styrene-ethylene based compound-diene copolymerization
100 parts of object, 100 parts of hydrogenated petroleum resin, 30 parts of diisodecyl glutarate, 20 parts of Plexol 201.
The preparation method of the styrene-ethylene based compound-diene copolymer is, by styrene, 1- vinyl imidazoles,
2,4- octadienes mix, and are heated to 150 DEG C, cumyl peroxide is then added, and persistently stir 15h, discharging to get.It is described
Styrene, 1- vinyl imidazoles, 2,4- octadienes, cumyl peroxide weight ratio be 1：1：8：0.04.
Preparation method includes the following steps, in a kettle, by styrene-ethylene based compound-diene copolymer 100
20 parts of part, 100 parts of hydrogenated petroleum resin, 30 parts of diisodecyl glutarate, Plexol 201 mixing, heating melting, stirring
6h discharges, sizing, it is cooling to get.
Embodiment 3
Left and right waist pastes special glue, and in parts by weight, preparing raw material includes：Styrene-ethylene based compound-diene copolymerization
100 parts of object, 100 parts of hydrogenated petroleum resin, 30 parts of diisodecyl glutarate, 20 parts of Plexol 201.
The preparation method of the styrene-ethylene based compound-diene copolymer is, by styrene, 2- vinylpyridines,
1,3- octadiene mixes, and is heated to 150 DEG C, cumyl peroxide is then added, and persistently stirs 15h, discharging to get.It is described
Styrene, 2- vinylpyridines, 1,3- octadienes, cumyl peroxide weight ratio be 1：1：8：0.04.
Preparation method includes the following steps, in a kettle, by styrene-ethylene based compound-diene copolymer 100
20 parts of part, 100 parts of hydrogenated petroleum resin, 30 parts of diisodecyl glutarate, Plexol 201 mixing, heating melting, stirring
6h discharges, sizing, it is cooling to get.
Embodiment 4
Adhesive, in parts by weight, preparing raw material includes：Styrene-ethylene based compound -00 part of monoene copolymer 1,
100 parts of hydrogenated petroleum resin, 30 parts of diisodecyl glutarate, 20 parts of Plexol 201.
The preparation method of the styrene-ethylene based compound-monoene copolymer is, by styrene, 1- vinyl imidazoles,
2- octenes mix, and are heated to 150 DEG C, cumyl peroxide is then added, and persistently stir 15h, discharging to get.The benzene second
Alkene, 1- vinyl imidazoles, 2- octenes, cumyl peroxide weight ratio be 1：1：8：0.04.
Preparation method includes the following steps, in a kettle, by styrene-ethylene based compound-monoene copolymer 1 00
20 parts of part, 100 parts of hydrogenated petroleum resin, 30 parts of diisodecyl glutarate, Plexol 201 mixing, heating melting, stirring
6h discharges, sizing, it is cooling to get.
Embodiment 5
Adhesive, in parts by weight, preparing raw material includes：Styrene-ethylene based compound -100 parts of diene copolymer,
100 parts of hydrogenated petroleum resin, 30 parts of diisodecyl glutarate, 20 parts of Plexol 201.
The preparation method of the styrene-ethylene based compound-diene copolymer is, by styrene, 1- vinyl imidazoles,
1,3- octadiene mixes, and is heated to 150 DEG C, cumyl peroxide is then added, and persistently stirs 15h, discharging to get.It is described
Styrene, 1- vinyl imidazoles, 1,3- octadienes, cumyl peroxide weight ratio be 1：0.1：8：0.04.
Preparation method includes the following steps, in a kettle, by styrene-ethylene based compound-diene copolymer 100
20 parts of part, 100 parts of hydrogenated petroleum resin, 30 parts of diisodecyl glutarate, Plexol 201 mixing, heating melting, stirring
6h discharges, sizing, it is cooling to get.
Embodiment 6
Adhesive, in parts by weight, preparing raw material includes：100 parts of styrene-diene copolymer, hydrogenated petroleum resin
100 parts, 30 parts of diisodecyl glutarate, 20 parts of Plexol 201.
The preparation method of the styrene-diene copolymer is to mix styrene, 1,3- octadienes, be heated to 150
DEG C, cumyl peroxide is then added, persistently stirs 15h, discharging to get.The styrene, 1,3- octadienes, peroxidating
The weight ratio of diisopropylbenzene (DIPB) is 1：4：0.02.
Preparation method includes the following steps, in a kettle, by 100 parts of styrene-diene copolymer, non-hydrogenated petroleum tree
20 parts of 100 parts of fat, 30 parts of diisodecyl glutarate, Plexol 201 mixing, heating melting stir 6h, discharge, sizing,
It is cooling to get.
Test method
1. water resistance test
By embodiment 1-6 in nonwoven cloth proofing, gluing layer thickness is 2mm, and peel strength is measured according to GB/T 2791,
It is denoted as A0, unit N/cm.Then the non-woven fabrics for being pasted with embodiment 1-6 is washed, washing times are 90 times, then measure stripping
From intensity, it is denoted as A1, unit N/cm.
2. cryogenic property is tested
By embodiment 1-6 in nonwoven cloth proofing, gluing layer thickness is 2mm, then stores 90 days in -18 DEG C, then
Peel strength is measured, A is denoted as2, unit N/cm.
Test result is listed in the table below.
Example above-mentioned is merely illustrative, some features for explaining this patent.The attached claims are intended to
The range as wide as possible being contemplated that is sought, and embodiments as presented herein is only the combination according to all possible embodiment
Selection embodiment explanation.Therefore, the purpose of applicant is the feature that the attached claims are not illustrated the present invention
Exemplary selectional restriction.And the progress in science and technology will be formed language express inaccuracy due to and it is not current
The possible equivalent or son considered is replaced, and these variations should also be interpreted to be wanted by appended right in the conceived case
Ask covering.
Claims (10)
1. a kind of left and right waist pastes special glue, which is characterized in that it prepares raw material and includes：Styrene-ethylene based compound-diene is total
Polymers, tackifying resin, plasticising oil.
2. left and right waist as described in claim 1 pastes special glue, which is characterized in that in parts by weight, preparing raw material includes：Benzene
100 parts of ethylene-vinyl compound-diene copolymer, 100 parts of tackifying resin, 50 parts of plasticising oil.
3. left and right waist as described in claim 1 pastes special glue, which is characterized in that the diene is conjugated diene.
4. left and right waist as described in claim 1 pastes special glue, which is characterized in that the tackifying resin is selected from hydrogenated petroleum resin
And/or hydrogenation phenolic resin.
5. left and right waist as described in claim 1 pastes special glue, which is characterized in that the plasticising oil be selected from Dioctyl Glutaricate,
Didecyl glutarate, diisodecyl glutarate, two fourth 2-ethoxyethyl acetate of glutaric acid, two fourth oxygen ethoxy ethyl ester of glutaric acid, adipic acid-di-n
Butyl ester, diisobutyl adipate, di-n-hexyl adipate, dioctyl adipate or adipic acid two (2- ethylhexyls), adipic acid
Di-isooctyl, dinonyl adipate, diisononyl adipate, diisodecyl adipate (DIDA), two fourth 2-ethoxyethyl acetate of adipic acid, adipic acid two
(Butoxyethoxy second) ester, two fourth 2-ethoxyethyl acetate of azelaic acid, dibenzyl azelate, dicyclohexyl azelate, dimethyl sebacate,
N-butyl sebacate, diisopropyl sebacate, dioctyl sebacate, Plexol 201, decanedioic acid di-sec-octyl, the last of the ten Heavenly stems two
Sour two nonyl esters, decanedioic acid two (butoxy second) ester, decanedioic acid two (Butoxyethoxy second) ester, dibenzyl sebacate, decanedioic acid
At least one of diethylester, dihexyl sebacate.
6. left and right waist as claimed in claim 3 pastes special glue, which is characterized in that the conjugated diene be selected from 1,3- octadienes,
One kind in 2,4- octadienes.
7. left and right waist as described in claim 1 pastes special glue, which is characterized in that the vinyl compound is selected from 1- vinyl
One kind in imidazoles, 2- vinylpyridines.
8. left and right waist as described in claim 1 pastes special glue, which is characterized in that the styrene-ethylene based compound-diene
Styrene in copolymer, vinyl compound, diene weight ratio be 1：1：8.
9. a kind of left and right waist as claimed in any one of claims 1-8 pastes special glue answering in amenities
With.
10. a kind of preparation method of left and right waist patch special glue as claimed in any one of claims 1-8, including such as
Lower step mixes styrene-ethylene based compound-diene copolymer, tackifying resin, plasticising oil, heating is molten in a kettle
Melt, stir 5-7h, discharge, sizing, it is cooling to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810266274.3A CN108410399B (en) | 2018-03-28 | 2018-03-28 | A kind of left and right waist patch special glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810266274.3A CN108410399B (en) | 2018-03-28 | 2018-03-28 | A kind of left and right waist patch special glue and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN108410399A true CN108410399A (en) | 2018-08-17 |
| CN108410399B CN108410399B (en) | 2019-10-11 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001059024A1 (en) * | 2000-02-08 | 2001-08-16 | 3M Innovative Properties Company | Compatibilized pressure-sensitive adhesives |
| CN1664043A (en) * | 2005-02-25 | 2005-09-07 | 苏州市丛岭胶粘剂有限公司 | Sealing adhesive |
| CN102702990A (en) * | 2012-05-31 | 2012-10-03 | 苏州联科合成材料有限公司 | Removable hot-melt pressure-sensitive adhesive tape for temporary fixation |
| CN103540281A (en) * | 2013-10-21 | 2014-01-29 | 广东东方树脂有限公司 | Quickly-cured rubber-type hot melt adhesive |
| CN107603538A (en) * | 2017-09-25 | 2018-01-19 | 常州中翔科技有限公司 | A kind of epoxidized block copolymer adhesive and preparation method thereof |
-
2018
- 2018-03-28 CN CN201810266274.3A patent/CN108410399B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001059024A1 (en) * | 2000-02-08 | 2001-08-16 | 3M Innovative Properties Company | Compatibilized pressure-sensitive adhesives |
| CN1664043A (en) * | 2005-02-25 | 2005-09-07 | 苏州市丛岭胶粘剂有限公司 | Sealing adhesive |
| CN102702990A (en) * | 2012-05-31 | 2012-10-03 | 苏州联科合成材料有限公司 | Removable hot-melt pressure-sensitive adhesive tape for temporary fixation |
| CN103540281A (en) * | 2013-10-21 | 2014-01-29 | 广东东方树脂有限公司 | Quickly-cured rubber-type hot melt adhesive |
| CN107603538A (en) * | 2017-09-25 | 2018-01-19 | 常州中翔科技有限公司 | A kind of epoxidized block copolymer adhesive and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN108410399B (en) | 2019-10-11 |
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Address after: 226553 Rugao, Nantong, Jiangsu. 12 and 13 groups of Deng yuan community, such as town Applicant after: Jiangsu Jia Hao hot melt adhesive Limited by Share Ltd Address before: 226553 Rugao, Nantong, Jiangsu. 12 and 13 groups of Deng yuan community, such as town Applicant before: RUGAO JIAHAO HOT MELT ADHESIVE CO., LTD. |
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