CN108373950A - A kind of cleaning agent and cleaning for PCB dry film developing troughs - Google Patents

A kind of cleaning agent and cleaning for PCB dry film developing troughs Download PDF

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Publication number
CN108373950A
CN108373950A CN201711011574.9A CN201711011574A CN108373950A CN 108373950 A CN108373950 A CN 108373950A CN 201711011574 A CN201711011574 A CN 201711011574A CN 108373950 A CN108373950 A CN 108373950A
Authority
CN
China
Prior art keywords
dry film
cleaning
cleaning agent
water
groove body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711011574.9A
Other languages
Chinese (zh)
Inventor
张本汉
张元正
许永章
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xinfeng Zhengtianwei Electronic Technologies Co Ltd
Original Assignee
Xinfeng Zhengtianwei Electronic Technologies Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xinfeng Zhengtianwei Electronic Technologies Co Ltd filed Critical Xinfeng Zhengtianwei Electronic Technologies Co Ltd
Priority to CN201711011574.9A priority Critical patent/CN108373950A/en
Publication of CN108373950A publication Critical patent/CN108373950A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/042Acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • C11D2111/22
    • C11D2111/44

Abstract

The present invention relates to cleaning agent, detergent fields, provide a kind of cleaning agent and its cleaning for PCB dry film developing troughs.It is grouped as by the group that content is following mass percent:Sulfuric acid:10~20%;Acetic acid:10~30%;Solubilizer:1~5%;Surfactant:0.5~3%;Water:Surplus.The present invention can efficiently emulsify its dry film residue, to make acid system faster with remain on calcium ions and magnesium ions crystal in dry film residue carry out reacting so temperature decline, scavenging period shorten, improve dry film residue dissolution rate;Its cleaning performance is substantially better than the cleaning way of conventional cleaning agent, and can efficiently remove groove body residue, ensures that PCB processing procedures normally produce, and can save certain energy consumption and improve production capacity, has certain economy and environment protection significance.

Description

A kind of cleaning agent and cleaning for PCB dry film developing troughs
Technical field
The present invention relates to cleaning agent, detergent field more particularly to a kind of cleaning agents for PCB dry film developing troughs.
Background technology
Currently, substrates of the PCB as electronic device device, quality directly decide the performance of entire circuit.And in PCB Manufacturing process in, dry film processing procedure is particularly important, constantly has dry film using duration passage with developing trough in dry film processing procedure Or the residue of wet film is adhered on idler wheel or groove body, it is therefore desirable to dry film developing trough is cleaned, conventional detergent, It is usually directly handled, is found in actual use, this kind of alkaline cleaner using Strong oxdiative sodium, not only needed in cleaning Heat treatment is carried out to enhance the solubility to dry film residue, and scavenging period is longer, cleaning performance is not good enough.
Invention content
In view of the above-mentioned problems, technical problem to be solved by the invention is to provide a kind of for the clear of PCB dry film developing troughs Lotion, cleaning temperature requirement is relatively low, scavenging period is short while cleaning performance is good.
It is as follows using technical solution:
A kind of cleaning agent for PCB dry film developing troughs is grouped as by the group that content is following mass percent:
Sulfuric acid:10~20%;
Acetic acid:10~30%;
Solubilizer:1~5%;
Surfactant:0.5~3%;
Water:Surplus.
The sum of mass percent of the above component is 100%;
The substance is all with the Mass Calculation of pure material.
Preferably, it is grouped as by the group that content is following mass percent:
Sulfuric acid:13~17%;
Acetic acid:15~25%;
Solubilizer:2~4%;
Surfactant:1.5~2%;
Water:Surplus.
The sum of mass percent of the above component is 100%.
Specifically,
One or more in the preferred ethylene glycol monobutyl ether of the solubilizer or ethylene glycol ethyl ether, for removing dry film Organic residue during ginseng slag is residual;Ethylene glycol monobutyl ether or ethylene glycol ethyl ether are water-soluble, and to organic in dry film residue Residue has certain dissolubility.
The preferred water soluble polyether of surfactant, can completely mix with sulfuric acid, acetic acid, since it has the spy of inverse dissolubility Point has synergistic effect for surface reactive material, effectively reduces medical liquid surface tension and cleaning action.
A kind of cleaning of cleaning agent for PCB dry film developing troughs, step are:
(1) at normal temperatures, developing trough is cleaned three times with clear water;
(2) cleaning agent is allocated in water filling in groove body, sulfuric acid, acetic acid is sequentially added after being stirred and being uniformly dissolved in water, Solubilizer, surfactant are added, is stirred evenly;
(3) according to the groove body residue of developing trough again water filling allocate detergent concentration, generally 21%~50%;
(4) it is cleaned using lasting stirring or circulated sprinkling mode, scavenging period is 1~1.5h;
(5) sewage in groove body is discharged, then is rinsed three times with clear water, is i.e. cleaning is completed.
Beneficial effects of the present invention:Its dry film residue can efficiently be emulsified, to make acid system faster with remain on Calcium ions and magnesium ions crystal carries out reaction so temperature declines, and scavenging period shortens in dry film residue, improves the dissolving of dry film residue Rate;Its cleaning performance is substantially better than the cleaning way of conventional cleaning agent, and can efficiently remove groove body residue, ensures PCB processing procedures Normal production, and certain energy consumption can be saved and improve production capacity, there is certain economy and environment protection significance.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme of the present invention is clearly and completely described, it is clear that institute The embodiment of description is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, Every other embodiment obtained by those of ordinary skill in the art without making creative efforts, belongs to this hair The range of bright protection.
Clear, complete description, certainly, described embodiment are carried out to the technical solution in patent of invention example below The only a part of embodiment of the present invention, instead of all the embodiments.Based on embodiment in the present invention, ordinary skill Personnel do not make the every other embodiment obtained under the premise of creative work, belong to the scope of the present invention.
Embodiment 1
A kind of cleaning agent for PCB dry film developing troughs is grouped as by the group that content is following mass percent:
Sulfuric acid:15kg;
Acetic acid:20kg;
Solubilizer:3kg;
Surfactant:1.25kg;
Water:60.75kg.
Clear water cleans developing trough three times, at normal temperatures, in groove body water filling allocate cleaning agent, by above-mentioned formula by sulfuric acid, Acetic acid sequentially adds be stirred and be uniformly dissolved in water after, add solubilizer, surfactant, stir evenly.
Detergent concentration, generally 21%~50% are allocated again according to the groove body residue of developing trough.It can be used and continue Stirring or circulated sprinkling mode are cleaned, and scavenging period is 1~1.5h.Sewage in groove body is discharged after cleaning, then three are rinsed with clear water Time, that is, complete cleaning.The dissolution rate of groove body residue is up to 95% or more.After the completion of cleaning after testing, only slight for groove body Corrosion.
The present invention can efficiently emulsify its dry film residue, to make acid system faster with remain on calcium in dry film residue Magnesium ion crystal carries out reaction so temperature can decline, and scavenging period shortens, and improves dry film residue dissolution rate;It is clear The cleaning way with obvious effects better than conventional cleaning agent is washed, and can efficiently remove groove body residue, ensures that PCB processing procedures are normally given birth to Production, and certain energy consumption can be saved and improve production capacity.
Embodiment 2
A kind of cleaning agent for PCB dry film developing troughs is grouped as by the group that content is following mass percent:
Sulfuric acid:10kg;
Acetic acid:30kg;
Solubilizer:5kg;
Surfactant:0.5kg;
Water:54.5kg.
By above-mentioned formula sulfuric acid, acetic acid are sequentially added after mixed dissolution is uniform in water using preceding in cleaning agent, is added and increases Solvent, surfactant are stirred evenly and be can be used.
It is i.e. capable of washing at normal temperatures, detergent concentration is determined according to the groove body residue of developing trough, using 21%.When cleaning Between be 1.5h.The dissolution rate of groove body residue is up to 95% or more.After the completion of cleaning after testing, it is corrosion-free to visually observe groove body.
Embodiment 3
A kind of cleaning agent for PCB dry film developing troughs is grouped as by the group that content is following mass percent:
Sulfuric acid:20kg;
Acetic acid:10kg;
Solubilizer:1kg;
Surfactant:3kg;
Water:66kg.
By above-mentioned formula sulfuric acid, acetic acid are sequentially added after mixed dissolution is uniform in water using preceding in cleaning agent, is added and increases Solvent, surfactant are stirred evenly and be can be used.
It is i.e. capable of washing at normal temperatures, detergent concentration is determined according to the groove body residue of developing trough, using 25%.When cleaning Between be 1.5h.The dissolution rate of groove body residue is up to 95% or more.After the completion of cleaning after testing, only has slight erosion for groove body.
The present invention can efficiently emulsify its dry film residue, to make acid system faster with remain on calcium in dry film residue Magnesium ion crystal carries out reaction so temperature can decline, and scavenging period shortens, and improves dry film residue dissolution rate;It is clear The cleaning way with obvious effects better than conventional cleaning agent is washed, and can efficiently remove groove body residue, ensures that PCB processing procedures are normally given birth to Production, and certain energy consumption can be saved and improve production capacity.
Embodiment 4
A kind of cleaning agent for PCB dry film developing troughs is grouped as by the group that content is following mass percent:
Sulfuric acid:13kg;
Acetic acid:15kg;
Solubilizer:2kg;
Surfactant:1.5kg;
Water:68.5kg.
By above-mentioned formula sulfuric acid, acetic acid are sequentially added after mixed dissolution is uniform in water using preceding in cleaning agent, is added and increases Solvent, surfactant are stirred evenly and be can be used.
It is i.e. capable of washing at normal temperatures, detergent concentration is determined according to the groove body residue of developing trough, using 30%.When cleaning Between be 1.5h.The dissolution rate of groove body residue is up to 95% or more.After the completion of cleaning after testing, only has slight erosion for groove body.
The present invention can efficiently emulsify its dry film residue, to make acid system faster with remain on calcium in dry film residue Magnesium ion crystal carries out reaction so temperature can decline, and scavenging period shortens, and improves dry film residue dissolution rate;It is clear The cleaning way with obvious effects better than conventional cleaning agent is washed, and can efficiently remove groove body residue, ensures that PCB processing procedures are normally given birth to Production, and certain energy consumption can be saved and improve production capacity.
Embodiment 5
A kind of cleaning agent for PCB dry film developing troughs is grouped as by the group that content is following mass percent:
Sulfuric acid:17kg;
Acetic acid:25kg;
Solubilizer:4kg;
Surfactant:2kg;
Water:52kg.
By above-mentioned formula sulfuric acid, acetic acid are sequentially added after mixed dissolution is uniform in water using preceding in cleaning agent, is added and increases Solvent, surfactant are stirred evenly and be can be used.
It is i.e. capable of washing at normal temperatures, detergent concentration is determined according to the groove body residue of developing trough, using 50%.When cleaning Between be 1h.The dissolution rate of groove body residue is up to 95% or more.After the completion of cleaning after testing, there is slight erosion for groove body.
The present invention can efficiently emulsify its dry film residue, to make acid system faster with remain on calcium in dry film residue Magnesium ion crystal carries out reaction so temperature can decline, and scavenging period shortens, and improves dry film residue dissolution rate;It is clear The cleaning way with obvious effects better than conventional cleaning agent is washed, and can efficiently remove groove body residue, ensures that PCB processing procedures are normally given birth to Production, and certain energy consumption can be saved and improve production capacity.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (5)

1. a kind of cleaning agent for PCB dry film developing troughs, which is characterized in that it is by the component that content is following mass percent Composition:
Sulfuric acid:10~20%;
Acetic acid:10~30%;
Solubilizer:1~5%;
Surfactant:0.5~3%;
Water:Surplus.
The sum of mass percent of the above component is 100%.
2. the cleaning agent according to claim 1 for PCB dry film developing troughs, it is characterised in that:It is following by content The group of mass percent is grouped as:
Sulfuric acid:13~17%;
Acetic acid:15~25%;
Solubilizer:2~4%;
Surfactant:1.5~2%;
Water:Surplus.
3. the cleaning agent according to claim 1 or 2 for PCB dry film developing troughs, it is characterised in that:The solubilizer is One or more in ethylene glycol monobutyl ether or ethylene glycol ethyl ether.
4. the cleaning agent according to claim 1 or 2 for PCB dry film developing troughs, it is characterised in that:The surface-active Agent is water soluble polyether.
5. a kind of cleaning agent and cleaning for PCB dry film developing troughs according to claim 1 or 2, feature exist In step is:
(1) at normal temperatures, developing trough is cleaned three times with clear water;
(2) cleaning agent is allocated in water filling in groove body, sulfuric acid, acetic acid is sequentially added after being stirred and being uniformly dissolved in water, then is added Enter solubilizer, surfactant, stirs evenly;
(3) according to the groove body residue of developing trough again water filling allocate detergent concentration, generally 21%~50%;
(4) it is cleaned using lasting stirring or circulated sprinkling mode, scavenging period is 1~1.5h;
(5) sewage in groove body is discharged, then is rinsed three times with clear water, is i.e. cleaning is completed.
CN201711011574.9A 2017-10-26 2017-10-26 A kind of cleaning agent and cleaning for PCB dry film developing troughs Pending CN108373950A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711011574.9A CN108373950A (en) 2017-10-26 2017-10-26 A kind of cleaning agent and cleaning for PCB dry film developing troughs

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Application Number Priority Date Filing Date Title
CN201711011574.9A CN108373950A (en) 2017-10-26 2017-10-26 A kind of cleaning agent and cleaning for PCB dry film developing troughs

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Publication Number Publication Date
CN108373950A true CN108373950A (en) 2018-08-07

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108103557A (en) * 2017-12-26 2018-06-01 廊坊京磁精密材料有限公司 For the electrophoresis tub cleaning method of neodymium iron boron magnetic body ability cathode electrophoresis
CN109097204A (en) * 2018-08-23 2018-12-28 中山市博锐电子材料有限公司 A kind of clear tank liquor and production technology
CN109234036A (en) * 2018-09-19 2019-01-18 珠海特普力高精细化工有限公司 A kind of environment-friendly type developing trough dirt removal agent and preparation method thereof and application method
CN110684606A (en) * 2019-10-28 2020-01-14 江苏本川智能电路科技股份有限公司 Liquid medicine for cleaning PCB green oil and preparation method thereof
CN111607463A (en) * 2020-05-06 2020-09-01 南昌欧菲显示科技有限公司 Tank washing agent and preparation method and application thereof
CN113134498A (en) * 2021-04-16 2021-07-20 新余市木林森线路板有限公司 Cleaning process of dry film developing machine for circuit board

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757871A (en) * 2012-06-19 2012-10-31 瀚宇博德科技(江阴)有限公司 Cleaning agent for dry-film developing tank of printed circuit board (PCB) and preparation method of cleaning agent
CN106434011A (en) * 2016-08-31 2017-02-22 珠海顺泽科技股份有限公司 Developing bath cleaning agent used for manufacture procedure of PCB

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757871A (en) * 2012-06-19 2012-10-31 瀚宇博德科技(江阴)有限公司 Cleaning agent for dry-film developing tank of printed circuit board (PCB) and preparation method of cleaning agent
CN106434011A (en) * 2016-08-31 2017-02-22 珠海顺泽科技股份有限公司 Developing bath cleaning agent used for manufacture procedure of PCB

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108103557A (en) * 2017-12-26 2018-06-01 廊坊京磁精密材料有限公司 For the electrophoresis tub cleaning method of neodymium iron boron magnetic body ability cathode electrophoresis
CN109097204A (en) * 2018-08-23 2018-12-28 中山市博锐电子材料有限公司 A kind of clear tank liquor and production technology
CN109234036A (en) * 2018-09-19 2019-01-18 珠海特普力高精细化工有限公司 A kind of environment-friendly type developing trough dirt removal agent and preparation method thereof and application method
CN110684606A (en) * 2019-10-28 2020-01-14 江苏本川智能电路科技股份有限公司 Liquid medicine for cleaning PCB green oil and preparation method thereof
CN110684606B (en) * 2019-10-28 2021-05-11 江苏本川智能电路科技股份有限公司 Liquid medicine for cleaning PCB green oil and preparation method thereof
CN111607463A (en) * 2020-05-06 2020-09-01 南昌欧菲显示科技有限公司 Tank washing agent and preparation method and application thereof
CN113134498A (en) * 2021-04-16 2021-07-20 新余市木林森线路板有限公司 Cleaning process of dry film developing machine for circuit board

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Application publication date: 20180807