CN108341640A - A kind of early-strength gypsum base thick-layer leveling mortar - Google Patents

A kind of early-strength gypsum base thick-layer leveling mortar Download PDF

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Publication number
CN108341640A
CN108341640A CN201810323517.2A CN201810323517A CN108341640A CN 108341640 A CN108341640 A CN 108341640A CN 201810323517 A CN201810323517 A CN 201810323517A CN 108341640 A CN108341640 A CN 108341640A
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agent
early
leveling mortar
water
base thick
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Inventor
张超
王辉
钱建男
蔡文龙
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JIANGSU ZHAOJIA BUILDING MATERIALS TECHNOLOGY CO LTD
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JIANGSU ZHAOJIA BUILDING MATERIALS TECHNOLOGY CO LTD
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Priority to CN201810323517.2A priority Critical patent/CN108341640A/en
Publication of CN108341640A publication Critical patent/CN108341640A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/60Flooring materials
    • C04B2111/62Self-levelling compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of early-strength gypsum base thick-layer leveling mortar, the mass percent of leveling mortar component is as follows:Gypsum, 10 40%;Hydraulic cementing materials, 0 10%;Exciting agent, 0 5%;Filler, 40 80.75%;Additive, 0.25 5%;The additive is redispersable latex powder, super plasticizer, water-retaining agent, retarder, segregation reducing agent, antifoaming agent, and the mass percent of component is respectively:Redispersable latex powder 0 3%;Super plasticizer 0.05 0.5%;Water-retaining agent 0 0.2%;Retarder 0.05 0.2%;Segregation reducing agent 0 0.1%;Antifoaming agent 0.01 0.2%.It is uniformly mixed by the mass percent of said components and is packaged into bag.This product has the advantages that early strong, ungauged regions, wear-resisting, water-fast, application property is good, anti-isolation bleeding, low cost and without harmful chemical.

Description

A kind of early-strength gypsum base thick-layer leveling mortar
Technical field
The present invention relates to a kind of leveling mortar, specifically a kind of early-strength gypsum base thick-layer leveling mortar.
Background technology
Gypsum base thick-layer leveling mortar is by gypsum, hydraulic cementing materials, exciting agent, priority with gathering materials and additive A kind of pulverulent material made of factory's premixing in appropriate proportions.Used time need to only add water stirring can become uniformly, consistency it is suitable, The early-strength gypsum base thick-layer leveling mortar with self-leveling of construction requirement can be met.
At present in engineering common leveling mortar with cement base facing sand slurry based on, and cement base facing sand slurry there are intensity The problems such as development is slow, and fluidity is poor, surface powder, hollowing easy to crack, it is unstable to directly result in construction quality, and building is not achieved and sets Meter standard;In addition, although gypsum base leveling mortar contraction is relatively low, due to its water resistance, wearability, the shortcomings of bleeding is easily isolated not It is used widely.
Invention content
The purpose of the present invention is to provide a kind of early-strength gypsum base thick-layer leveling mortar, water resistance, resistance to is significantly improved Mill property, mechanical strength and construction mobility.
To achieve the goals above, a kind of early-strength gypsum base thick-layer leveling mortar is provided in the embodiment of the present invention, The mass percent of component is as follows:
Gypsum 10-40%
Hydraulic cementing materials 0-10%
Exciting agent 0-5%
Filler 40-80.75%
Additive 0.25-5%
The additive is redispersable latex powder, super plasticizer, water-retaining agent, retarder, segregation reducing agent, antifoaming agent, group Point mass percent be respectively:Redispersable latex powder 0-4%;Super plasticizer 0.05-0.5%;Water-retaining agent 0-0.2%;Slow setting Agent 0.05-0.2%;Segregation reducing agent 0-0.1%;Antifoaming agent 0.01-0.2%;
Further, gypsum is one or more mixing in β-semi-hydrated gypsum, alpha-semi water plaster stone and anhydrite, and volume is in above-mentioned gypsum model Enclose it is interior arbitrarily assemble, the gypsum can be prepared by the industrial by-products such as desulfurated plaster, ardealite, fluorgypsum and the natural gypsum.
Further, hydraulic cementing materials is portland cement, aluminate cement, one kind in sulphate aluminium cement or more Kind mixing, volume arbitrarily assemble within the above range.
Any one in portland cement, Portland cement and white portland cement is selected under normal conditions, Volume arbitrarily assembles within the above range, and strength grade must not be less than P.O42.5, P.II42.5 or P.W42.5, in order to reach Early strong purpose, can select any one compounding in Portland cement and aluminate cement or sulphate aluminium cement to make With aluminate cement or sulphate aluminium cement can also be used alone.
Further, exciting agent is sodium metasilicate, potassium silicate, sodium hydroxide, potassium hydroxide, calcium hydroxide, miberal powder, silicon ash, powder One or more mixing in coal ash, volume arbitrarily assemble within the above range.
Wherein sodium metasilicate, potassium silicate, sodium hydroxide and other matter can provide alkaline environment, and miberal powder, silicon ash, flyash are in alkali Property under the conditions of reacted with gypsum produce hydraulic cementing materials, significantly improve materials water-resistant and surface strength.
Further, filler is made of fleut and granulated filler, and fleut and granulated filler ratio exist(0:1) ~(1:0), fleut is the powdered whitings of 200 mesh or more, kaolin, one or more in talcum powder, and granulated filler is One or more kinds of mixing in quartz sand, Machine-made Sand, washed-out sand and river sand that fineness modulus is 1.6 ~ 3.7, volume is in above-mentioned model It encloses and interior arbitrarily assembles.
Further, redispersable latex powder is ethene-vinyl acetate class, acrylic compounds, butadiene-styrene class can divide again One or more mixing in latex powder are dissipated, volume arbitrarily assembles within the above range.Redispersable latex powder is as polyphosphazene polymer Object is closed, can effectively be formed a film in leveling mortar, elasticity modulus is reduced, improves the flexibility and cohesive force of mortar, increase simultaneously The seal and water proofing property of mortar, and effectively improve application property.
Further, super plasticizer is one or more mixing in polycarboxylic acid salt, melamine class, naphthalene water reducer, is mixed Amount arbitrarily assembles within the above range.Super plasticiser can substantially reduce the water consumption of mortar as surfactant, reduce The ratio of mud improves the compactness and intensity of mortar, improves the fluidity of mortar, improves the application property of mortar.
Further, water-retaining agent is one kind in water soluble ethoxyl methyl cellulose ether or hydroxypropyl methyl cellulose ether Or several mixtures, volume arbitrarily assemble within the above range.The viscosity of water-retaining admixture is 400 mPa.s.Water-retaining agent is in sand Water conservation, thickening, air-entraining effect are primarily served in slurry, can effectively prevent mortar segregation layering, and can keep moisture, gelling is provided Water needed for material aquation, while application property can be significantly improved.
Further, segregation reducing agent be aluminium-magnesium silicate, starch ether, montmorillonite, attapulgite, bentonite, aerosil, In attapulgite clay, organic thixotrope of rilanit special, hydrophobically modified polyurethane rheological agent, hydrophobically modified polyethers rheological agent One or more mixtures, volume arbitrarily assemble within the above range.Segregation reducing agent mainly plays thickening in mortar, anti-isolation is made With, and the mobile performance of material is not influenced.
Further, retarder is sodium citrate, citric acid, tartaric acid, sodium metaphosphate, borax and protide calcium sulphate retarder One or more of mixture, volume arbitrarily assemble within the above range.Retarder can effectively extend mortar in mortar Open hour, good application property is provided.
Further, the antifoaming agent is polysiloxane defoaming agent, polyethers antifoaming agent, tributyl phosphate, mineral oil disappear One or more of infusion and alkynes alcohol defoaming agent mixture, volume arbitrarily assemble within the above range.Antifoaming agent is in mortar In can quickly defoam, continue foam control, improve mortar compactness and mechanical strength, and ensure the good flatness of mortar surface.
The specific application method of the present invention is uniformly mixed by the mass percent of said components, is then packaged into bag, through inspection Construction site can be transported to by testing qualification.The present invention is shown using hydraulic cementing materials, exciting agent and the additive of addition rational proportion Work improves water resistance, wearability, mechanical strength and construction mobility, various aspects of performance and is better than existing mortar;In addition water consumption Wide cut degree significantly improves, and worker is facilitated to construct, and isolation bleeding, surface will not be caused to play powder phenomenon.Early-strength prepared by the present invention Gypsum base thick-layer leveling mortar has early strong, ungauged regions, high fluidity, excellent abrasive resistance and water resistance, low cost and without harmful Chemical substance can be widely applied to the indoor levelling engineering such as civil engineering tooling or house ornamentation decoration.
Specific implementation mode
The invention will be further described below.
Embodiment 1
A kind of early-strength gypsum base thick-layer leveling mortar, the mass percent of component are as follows:
Gypsum 30%
Hydraulic cementing materials 0%
Exciting agent 1%
Filler 67%
Additive 2%
Wherein additive is redisperse latex powder, super plasticizer, water-retaining agent, retarder, segregation reducing agent and antifoaming agent, and each component exists Mass percent in leveling mortar is:Redispersable latex powder 1.3%;Super plasticizer 0.35%;Water-retaining agent 0.1%;Retarder 0.1%;Segregation reducing agent 0.05%;Antifoaming agent 0.1%.
Further, gypsum is one or more in β-semi-hydrated gypsum, alpha-semi water plaster stone and anhydrite, can arbitrarily be assembled, institute Stating gypsum can be prepared by the industrial by-products such as desulfurated plaster, ardealite, fluorgypsum and the natural gypsum.
Further, exciting agent is calcium hydroxide.
Further, filler is made of fleut and granulated filler, and fleut and granulated filler ratio are(0: 1)~(1:0), the fleut is one or more arbitrary in the powdered whiting, kaolin, talcum powder of 200 mesh or more Assemble, it is a kind of in quartz sand, Machine-made Sand, washed-out sand and river sand that the granulated filler fineness modulus is 1.6 ~ 3.7 or Person is a variety of arbitrarily to be assembled.
Further, redispersable latex powder is vinyl acetate-ethylene copolymer.
Further, super plasticizer be polycarboxylic acid salt, melamine class mixture.
Further, water-retaining agent is hydroxypropylcelluloether ether;The viscosity of water-retaining agent is 400mPas.
Further, retarder be protide calcium sulphate retarder, citric acid, borax mixture.
Further, segregation reducing agent, which is aluminium-magnesium silicate, starch ether, montmorillonite, aerosil, rilanit special, has The mixture of machine thixotrope.
Further, antifoaming agent is the mixture of polysiloxane defoaming agent, polyethers antifoaming agent, mineral oil antifoam agent.
Embodiment 2
A kind of early-strength gypsum base thick-layer leveling mortar, the mass percent of component are as follows:
Gypsum 40%
Hydraulic cementing materials 5%
Exciting agent 0%
Filler 51%
Additive 4%
The additive is redispersable latex powder, super plasticizer, water-retaining agent, retarder, segregation reducing agent, antifoaming agent, is mixed Amount is respectively:Redispersable latex powder 3%;Super plasticizer 0.4%;Water-retaining agent 0.2%;Retarder 0.15%;Segregation reducing agent 0.05%;Antifoaming agent 0.2%.
Further, hydraulic cementing materials is the mixture of white portland cement, sulphate aluminium cement.
Further, gypsum is one or more mixing in β-semi-hydrated gypsum, alpha-semi water plaster stone and anhydrite, can be arbitrary group Match, the gypsum can be prepared by the industrial by-products such as desulfurated plaster, ardealite, fluorgypsum and the natural gypsum.
Further, filler is made of fleut and granulated filler, and fleut and granulated filler ratio are(0: 1)~(1:0), the fleut is one or more arbitrary in the powdered whiting, kaolin, talcum powder of 200 mesh or more Assemble, it is a kind of in quartz sand, Machine-made Sand, washed-out sand and river sand that the granulated filler fineness modulus is 1.6 ~ 3.7 or Person is a variety of arbitrarily to be assembled.
Further, redispersable latex powder be acrylic compounds, butadiene-styrene class mixture.
Further, super plasticizer be polycarboxylic acid salt, melamine class mixture.
Further, water-retaining agent is hydroxyethyl ether cellulose;The viscosity of water-retaining agent is 400mPas.
Further, retarder be protide calcium sulphate retarder, tartaric acid mixture.
Further, segregation reducing agent is organic thixotrope, hydrophobic of attapulgite, aerosil, rilanit special Mixture in modified polyether rheological agent.
Further, antifoaming agent is the mixture of polysiloxane defoaming agent, polyethers antifoaming agent, mineral oil antifoam agent.
Embodiment 3
A kind of early-strength gypsum base thick-layer leveling mortar, the mass percent of component are as follows:
Gypsum 40%
Hydraulic cementing materials 10%
Exciting agent 5%
Filler 40%
Additive 5%
The additive is redispersable latex powder, super plasticizer, water-retaining agent, retarder, segregation reducing agent, antifoaming agent, is mixed Amount is respectively:Redispersable latex powder 4%;Super plasticizer 0.5%;Water-retaining agent 0.1%;Retarder 0.2%;Segregation reducing agent 0%;Defoaming Agent 0.2%.
Further, hydraulic cementing materials is the mixture of Portland cement, sulphate aluminium cement.
Further, gypsum is one or more in β-semi-hydrated gypsum, alpha-semi water plaster stone and anhydrite, can arbitrarily be assembled, institute Stating gypsum can be prepared by the industrial by-products such as desulfurated plaster, ardealite, fluorgypsum and the natural gypsum.
Further, exciting agent is the mixture of sodium metasilicate, potassium hydroxide, calcium hydroxide, miberal powder, silicon ash, flyash.
Further, filler is made of fleut and granulated filler, and fleut and granulated filler ratio are(0: 1)~(1:0), the fleut is one or more arbitrary in the powdered whiting, kaolin, talcum powder of 200 mesh or more Assemble, it is a kind of in quartz sand, Machine-made Sand, washed-out sand and river sand that the granulated filler fineness modulus is 1.6 ~ 3.7 or Person is a variety of arbitrarily to be assembled.
Further, redispersable latex powder is vinyl acetate-ethylene copolymer.
Further, super plasticizer is polycarboxylic acid salt.
Further, water-retaining agent is hydroxypropylcelluloether ether;The viscosity of water-retaining agent is 400mPas.
Further, retarder be protide calcium sulphate retarder, sodium citrate, tartaric acid mixture.
Further, segregation reducing agent is bentonite, attapulgite clay, aerosil, hydrophobically modified polyurethane stream Become agent composition.
Further, antifoaming agent is the mixture of polysiloxane defoaming agent, polyethers antifoaming agent, mineral oil antifoam agent.
Embodiment 4
A kind of early-strength gypsum base thick-layer leveling mortar, the mass percent of component are as follows:
Gypsum 10%
Hydraulic cementing materials 5%
Exciting agent 4%
Filler 80.75%
Additive 0.25%
The additive is redispersable latex powder, super plasticizer, water-retaining agent, retarder, segregation reducing agent, antifoaming agent, is mixed Amount is respectively:Redispersable latex powder 0%;Super plasticizer 0.05%;Water-retaining agent 0%;Retarder 0.05%;Segregation reducing agent 0.1%; Antifoaming agent 0.05%.
Further, hydraulic cementing materials is the mixture of portland cement, aluminate cement.
Further, gypsum is one or more in β-semi-hydrated gypsum, alpha-semi water plaster stone and anhydrite, can arbitrarily be assembled, institute Stating gypsum can be prepared by the industrial by-products such as desulfurated plaster, ardealite, fluorgypsum and the natural gypsum.
Further, exciting agent is the mixture of potassium silicate, sodium hydroxide, calcium hydroxide, miberal powder, silicon ash, flyash.
Further, filler is made of fleut and granulated filler, and fleut and granulated filler ratio are(0: 1)~(1:0), the fleut is one or more arbitrary in the powdered whiting, kaolin, talcum powder of 200 mesh or more Assemble, it is a kind of in quartz sand, Machine-made Sand, washed-out sand and river sand that the granulated filler fineness modulus is 1.6 ~ 3.7 or Person is a variety of arbitrarily to be assembled.
Further, redispersable latex powder is vinyl acetate-ethylene copolymer.
Further, super plasticizer be polycarboxylic acid salt, naphthalene water reducer mixture.
Further, water-retaining agent is hydroxypropylcelluloether ether;The viscosity of water-retaining agent is 400mPas.
Further, retarder is the mixture of sodium citrate, citric acid, tartaric acid, sodium metaphosphate.
Further, segregation reducing agent is aluminium-magnesium silicate, starch ether, attapulgite, attapulgite clay, the poly- ammonia of hydrophobically modified Mixture in ester rheological agent.
Further, antifoaming agent is the mixture of polysiloxane defoaming agent, polyethers antifoaming agent, mineral oil antifoam agent.
Above example 1-4 production methods are according to following technique productions gypsum base thick-layer leveling mortar:(1)According to embodiment In the mass percents of each raw material put into double-screw type dry powder and mortar batch mixer and stir, temperature is 20~30 DEG C, stirring 15min, packaging obtain the product.
The leveling mortar that above-mentioned production is obtained carries out properties of product detection, and with conventional gypsum base thick-layer leveling mortar pair Than the results are shown in table below:
Project Initial flow degree/mm 30min fluidities/mm Compression strength/MPa for 24 hours 28d compression strength/MPa Size changing rate/‰ Water-fast adhesion strength/MPa Wearing valve/g
Embodiment 1 320 315 8.2 21.5 0.2 0.57 0.9
Embodiment 2 330 320 12.1 26.6 0.5 0.63 0.4
Embodiment 3 330 315 14.6 29.8 0.6 0.72 0.3
Embodiment 4 290 270 6.6 17.8 0.8 0.53 1.2
Comparative example 250 240 4.2 13.6 0.4 0.22 3.8
In conclusion can be obtained according to above-described embodiment and detection data table, with traditional gypsum base leveling mortar(Comparison Example)Comparison, the gypsum base thick-layer leveling mortar have good construction mobility, dimensional stability, water resistance, wearability and surface Hardness.
The low in raw material price that the gypsum base thick-layer leveling mortar that the present invention is announced is selected, can not only fully meet levelling Requirement, good heat preservation, heat insulation can be provided, further, since gypsum base have good water resistance, wearability and size Stability, can improve the durability of floor heating leveling mortar, effectively avoid hollowing cracking, play powder phenomenon.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, any made by repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of early-strength gypsum base thick-layer leveling mortar, it is characterised in that:The mass percent of its component is as follows:
Gypsum 10-40%
Hydraulic cementing materials 0-10%
Exciting agent 0-5%
Filler 40-80.75%
Additive 0.25-5%
The additive is redispersable latex powder, super plasticizer, water-retaining agent, retarder, segregation reducing agent, antifoaming agent, group Point mass percent be respectively:Redispersable latex powder 0-4%;Super plasticizer 0.05-0.5%;Water-retaining agent 0-0.2%;Slow setting Agent 0.05-0.2%;Segregation reducing agent 0-0.1%;Antifoaming agent 0.01-0.2%.
2. early-strength gypsum base thick-layer leveling mortar according to claim 1, it is characterised in that:The gypsum is β-half One or more mixing in water gypsum, alpha-semi water plaster stone and anhydrite, the gypsum pass through desulfurated plaster, ardealite, fluorite The industrial by-products such as cream and the natural gypsum are prepared.
3. early-strength gypsum base thick-layer leveling mortar according to claim 1, it is characterised in that:The hydraulic cement Material is one or more mixing in portland cement, aluminate cement, sulphate aluminium cement.
4. early-strength gypsum base thick-layer leveling mortar according to claim 1, it is characterised in that:The exciting agent is silicon One or more mixing in sour sodium, potassium silicate, sodium hydroxide, potassium hydroxide, calcium hydroxide, miberal powder, silicon ash, flyash.
5. early-strength gypsum base thick-layer leveling mortar according to claim 1, it is characterised in that:The filler is filled out by powdery Material and granulated filler composition, fleut and granulated filler ratio are(0:1)~(1:0), the fleut is 200 mesh One or more mixing in above powdered whiting, kaolin, talcum powder, the granulated filler fineness modulus is 1.6 ~ One or more kinds of mixing in 3.7 quartz sand, Machine-made Sand, washed-out sand and river sand.
6. early-strength gypsum base thick-layer leveling mortar according to claim 1, it is characterised in that:The redispersible breast Rubber powder is one or more mixing in ethene-vinyl acetate class, acrylic compounds, butadiene-styrene class redispersable latex powder; The super plasticizer is one or more mixing in polycarboxylic acid salt, melamine class, naphthalene system diminishing.
7. early-strength gypsum base thick-layer leveling mortar according to claim 1, it is characterised in that:The water-retaining agent is water One or more of dissolubility ethoxyl methyl cellulose ether or hydroxypropyl methyl cellulose ether mixture.
8. early-strength gypsum base thick-layer leveling mortar according to claim 1, it is characterised in that:The segregation reducing agent is Aluminium-magnesium silicate, starch ether, montmorillonite, attapulgite, bentonite, aerosil, attapulgite clay, rilanit special One or more mixtures in organic thixotrope, hydrophobically modified polyurethane rheological agent, hydrophobically modified polyethers rheological agent.
9. early-strength gypsum base thick-layer leveling mortar according to claim 1, it is characterised in that:The retarder is lemon One or more of lemon acid sodium, citric acid, tartaric acid, sodium metaphosphate, borax and protide calcium sulphate retarder mixture.
10. early-strength gypsum base thick-layer leveling mortar according to claim 1, it is characterised in that:The antifoaming agent is Polysiloxane defoaming agent, polyethers antifoaming agent, tributyl phosphate, mineral oil antifoam agent and one kind or several in alkynes alcohol defoaming agent Kind mixture.
CN201810323517.2A 2018-04-12 2018-04-12 A kind of early-strength gypsum base thick-layer leveling mortar Pending CN108341640A (en)

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CN113187114A (en) * 2021-04-06 2021-07-30 华南理工大学 Light composite heat-insulation sound-insulation board and preparation method thereof
CN113265171A (en) * 2021-04-09 2021-08-17 龙牌粉料(太仓)有限公司 Cold-resistant heat-insulating building troweling gypsum and preparation process thereof
CN113387670A (en) * 2021-05-24 2021-09-14 苏州金世晟建筑装饰工程有限公司 Novel gypsum-based leveling material
CN113667344A (en) * 2021-08-25 2021-11-19 亚士漆(上海)有限公司 Desulfurized gypsum composition, preparation method thereof, gypsum-based interior wall putty and application
CN113943141A (en) * 2021-11-30 2022-01-18 客诺环保科技(青岛)有限公司 Surface-modified reinforced gypsum powder and preparation method and application thereof
CN115124315A (en) * 2022-07-18 2022-09-30 贵州磷化绿色环保产业有限公司 Pouring type sand-free self-leveling mortar taking phosphogypsum as main raw material and preparation method and application thereof

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CN108676415A (en) * 2018-08-13 2018-10-19 岑英 A kind of water-fast indoor wall alignment material thick with quick-drying heap, neutral
CN109516755A (en) * 2018-12-27 2019-03-26 河南强耐新材股份有限公司 A kind of dedicated gypsum based self-leveling mortar of floor heating backfill
CN110330302A (en) * 2019-06-18 2019-10-15 李山 A kind of dedicated gypsum based self-leveling mortar of floor heating backfill
CN110526658A (en) * 2019-06-24 2019-12-03 中建材料技术研究成都有限公司 A kind of spray phosphogypsum light plastering mortar preparation of machine and construction method
CN110436848A (en) * 2019-08-12 2019-11-12 河南城建学院 A kind of cement composition, foamed cement slurry, foam concrete pour material and preparation method thereof
CN110482987A (en) * 2019-09-18 2019-11-22 贵州中能高新材料有限公司 A kind of building mortar and preparation method thereof based on gypsum
US10954162B1 (en) * 2019-09-24 2021-03-23 Geopolymer Solutions, LLC Protective coating
CN110655377B (en) * 2019-11-20 2021-11-12 亚士漆(上海)有限公司 Bi-component ground renovation filling material, bi-component ground renovation filling material slurry and preparation method and application thereof
CN110655377A (en) * 2019-11-20 2020-01-07 亚士漆(上海)有限公司 Bi-component ground renovation filling material, bi-component ground renovation filling material slurry and preparation method and application thereof
CN111393122A (en) * 2020-02-25 2020-07-10 苏州市兴邦化学建材有限公司 Phosphogypsum mortar for load-bearing structure and preparation method thereof
CN111393122B (en) * 2020-02-25 2022-02-08 苏州市兴邦化学建材有限公司 Phosphogypsum mortar for load-bearing structure and preparation method thereof
CN111423758A (en) * 2020-04-21 2020-07-17 陈晨 Waterproof high-stability putty powder
CN111908879A (en) * 2020-06-29 2020-11-10 河南恒发建筑材料有限公司 Heavy gypsum mortar and preparation method thereof
CN111732400A (en) * 2020-07-09 2020-10-02 西卡(上海)管理有限公司 Foamed cement and production method thereof
CN112159145A (en) * 2020-09-30 2021-01-01 苏州市兴邦化学建材有限公司 Gypsum primary and final setting time regulator and preparation method thereof
CN112250408A (en) * 2020-10-22 2021-01-22 浙江古思建筑科技有限公司 Gypsum-based self-leveling mortar and application and construction method thereof
CN112552001A (en) * 2020-12-07 2021-03-26 绵竹市铸诚混凝土有限公司 Phosphogypsum mortar for load-bearing structure and preparation method thereof
CN113187114A (en) * 2021-04-06 2021-07-30 华南理工大学 Light composite heat-insulation sound-insulation board and preparation method thereof
CN113265171A (en) * 2021-04-09 2021-08-17 龙牌粉料(太仓)有限公司 Cold-resistant heat-insulating building troweling gypsum and preparation process thereof
CN113387670A (en) * 2021-05-24 2021-09-14 苏州金世晟建筑装饰工程有限公司 Novel gypsum-based leveling material
CN113667344A (en) * 2021-08-25 2021-11-19 亚士漆(上海)有限公司 Desulfurized gypsum composition, preparation method thereof, gypsum-based interior wall putty and application
CN113943141A (en) * 2021-11-30 2022-01-18 客诺环保科技(青岛)有限公司 Surface-modified reinforced gypsum powder and preparation method and application thereof
CN113943141B (en) * 2021-11-30 2022-12-06 客诺环保科技(青岛)有限公司 Surface modification enhanced gypsum powder and preparation method and application thereof
CN115124315A (en) * 2022-07-18 2022-09-30 贵州磷化绿色环保产业有限公司 Pouring type sand-free self-leveling mortar taking phosphogypsum as main raw material and preparation method and application thereof

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