CN108341440A - The method of water treatment agent, preparation method and water treatment agent processing fire demand water - Google Patents

The method of water treatment agent, preparation method and water treatment agent processing fire demand water Download PDF

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Publication number
CN108341440A
CN108341440A CN201810176059.4A CN201810176059A CN108341440A CN 108341440 A CN108341440 A CN 108341440A CN 201810176059 A CN201810176059 A CN 201810176059A CN 108341440 A CN108341440 A CN 108341440A
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China
Prior art keywords
treatment agent
water treatment
parts
water
high temperature
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CN201810176059.4A
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Chinese (zh)
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CN108341440B (en
Inventor
黄琦
卞磊
常立明
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Beijing Lihua Fire Engineering Co Ltd
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Beijing Lihua Fire Engineering Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06Aluminium; Calcium; Magnesium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • A01N59/20Copper
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents

Abstract

The present invention relates to a kind of methods that water treatment agent, preparation method and the water treatment agent handle fire demand water, and wherein water treatment agent includes that the raw material of following weight fraction expression is made:30 40 parts of high temperature active aluminium oxide;45 60 parts of bactericidal composition;40 50 parts of slow releasing composition;Bactericidal composition, slow releasing composition are coated on high temperature active aluminium oxide periphery successively, wherein bactericidal composition includes the following component indicated with weight fraction:25 parts of copper sulphate;38 parts of aluminum sulfate;58 parts of iron chloride;25 parts of polymeric aluminum sulfate silicate, the first 19 48 parts of deionized water;Slow releasing composition includes the following component indicated with weight fraction:3 15 parts of melamine;25 parts of polyvinyl alcohol;Second 30 35 parts of deionized water.The characteristics of being had using water treatment agent made from above method and inhibit alga microbial growth, reducing COD contents in water.

Description

The method of water treatment agent, preparation method and water treatment agent processing fire demand water
Technical field
The present invention relates to sewage treatment fields, and in particular to a kind of water treatment agent, preparation method and water treatment agent processing The method of fire demand water.
Background technology
Fire demand water is commonly stored in fire water box, for providing water source during fire-fighting.Since fire demand water is quiet Set and be stored in fire water box, standing time relatively long after, will produce a large amount of algae, either bacterium is easy to block pipeline or water Pump, influences to use.
The method of sewage disposal at present has very much, mainly for trade effluent and sanitary sewage, pollutant in trade effluent It is numerous, it needs to carry out alignment processing according to practical pollution condition.Generally existing algae or thin in sanitary sewage and trade effluent The pollution of bacterium, generally use Physical, chemical method or biological degradation method remove the pollutant in sewage.Biological degradation method cost It is higher and more harsh to environmental requirement, be not suitable for large-scale promotion.
The applying date is on November 20th, 2014, and application No. is the Chinese patents of 201410664075.X to disclose a kind of sewage Inorganic agent, preparation method and applications, the raw material of sewage-treating agent includes mainly magnesia, zeolite, sulfate, alkali in the patent Agent, polymer coagulant when treated sewage, are needed certain density sewage-treating agent being added in sewage and be stirred, using Separation removal solid sediment.Conventional sewage processing method is similar with the above method, but for fire demand water, algae and Bacterium is major pollutants, and fire demand water stands storage, and when encountering dangerous situation, connection fire protection pipeline can be used directly, It is comparatively laborious using above method removal pollutant, be not suitable for the processing of fire demand water.
Invention content
The object of the present invention is to provide a kind of water treatment agent, have and inhibit alga microbial growth, reduces COD in water and contain The characteristics of amount.
The present invention above-mentioned technical purpose technical scheme is that:A kind of water treatment agent, including with The raw material that lower weight fraction indicates is made:30-40 parts of high temperature active aluminium oxide;45-60 parts of bactericidal composition;Slow releasing composition 40-50 parts;Bactericidal composition, slow releasing composition are coated on high temperature active aluminium oxide periphery successively, wherein bactericidal composition includes The component indicated below with weight fraction:2-5 parts of copper sulphate;3-8 parts of aluminum sulfate;5-8 parts of iron chloride;2-5 parts of polymeric aluminum sulfate silicate, First 19-48 parts of deionized water;Slow releasing composition includes the following component indicated with weight fraction:3-15 parts of melamine;It is poly- 2-5 parts of vinyl alcohol;Second 30-35 parts of deionized water.
Using above technical scheme, high temperature active aluminium oxide has degradation Measures of Algae in Water Body as main catalyst Effect, and its specific surface area is larger, and more bactericidal composition can be coated in its periphery, further increases water treatment agent Bactericidal effect, and the contact area bigger of itself and seaweed further increase the efficiency of water treatment agent degradation algae substances.This Outside, bactericidal composition periphery coats slow releasing composition, on the one hand reduces bactericidal composition and is detached from high temperature active aluminium oxide, another When aspect water treatment agent is invested in fire demand water so that bactericidal composition slow release in water body, improve persistently it is antibacterial and Inhibit the effect of seaweed growth.
Further, the grain size of high temperature active aluminium oxide is 0.3-0.5mm.
Select the high temperature active aluminium oxide of the above particle size range, the reactivity higher of water treatment agent.Water pump extracts fire-fighting When with water, water treatment agent can reach devastated under the action of water pump with water flowing, and high temperature active aluminium oxide aoxidizes to be formed Aluminium hydroxide also has preferable flame retardant effect, delays fire spreading.
Further, the ratio of the amount of the substance of silicon and aluminium is 1 in polymeric aluminum sulfate silicate:2-1:5.
The polymeric aluminum sulfate silicate of the above specification can accelerate algae substances flocculation, and absorption drop is carried out to algae substances to facilitate Solution improves water treatment efficiency.
Preferably, the degree of polymerization of polyvinyl alcohol is 1700-1800 in slow releasing composition.
Using above technical scheme, the polyvinyl alcohol film-formation result of the above specification is best.The above polyvinyl alcohol and melamine Amine coordinates, and in water treatment agent periphery, package film forming is more stablized, and water treatment agent is invested in fire demand water, and polyvinyl alcohol part is molten Hole is formed in Xie Yushui, facilitates the bactericidal composition slow release in water treatment agent in water body.
Another object of the present invention is to provide a kind of preparation methods of water treatment agent, with simple for process, repeatability High feature.
The above-mentioned purpose of the present invention is achieved by the following technical programs:A kind of preparation method of water treatment agent, including Following steps:
S1, bactericidal composition is prepared:Copper sulphate, aluminum sulfate, iron chloride, polymeric aluminum sulfate silicate and the first deionized water are stirred system Obtain bactericidal composition;
S2, slow releasing composition is prepared:Melamine, polyvinyl alcohol and the second deionized water are stirred obtained slow releasing composition;
S3, high temperature active are alumina modified:High temperature active aluminium oxide is immersed in room temperature immersion 2-3h in bactericidal composition, Zhi Hou Modified high temperature active aluminium oxide is made in 60-80 DEG C of heating 30-60min;
S4, water treatment agent is prepared:Modified high temperature active aluminium oxide is stirred 20-30min in slow releasing composition, is obtained after dry To water treatment agent.
Using above technical scheme, bactericidal composition and slow releasing composition are prepared respectively in advance, high temperature active aluminium oxide changes Property when, high temperature active aluminium oxide first impregnates at room temperature, then is increased to 60-80 DEG C, improves bactericidal composition in high temperature active oxygen Change the dipping effect in aluminium hole.High temperature active aluminium oxide is modified by bactericidal composition, and further in its periphery, cladding is slow Composition is released, the compactness of water treatment agent is improved, it is easy to use.
Further, mixing speed is 80-100r/min in step S2.
Using above technical scheme, melamine and polyvinyl alcohol mix under the above mixing speed, reduce obtained slow It releases composition and generates bubble.At the same time it can also retain the viscosity of slow releasing composition, facilitate film forming.
Further, mixing speed is 150-200r/min in step S3.
Using above technical scheme, when high temperature active aluminium oxide impregnates in bactericidal composition, under above-mentioned stirring condition It is mixed, the mixed effect of bactericidal composition is more preferably.
Further, mixing speed is 100-120r/min in step S4.
Using above technical scheme, in modified high temperature active aluminium oxide periphery bundled slow-releasing composition, in above-mentioned stirring It is carried out under speed, in order to avoid generating bubble, influences covered effect.
A further purpose of the present invention is to provide a kind of method for being used for above-mentioned water treatment agent to handle fire demand water, tool There is persistently to inhibit algal grown and permanent antibacterial.
The above-mentioned purpose of the present invention is achieved by the following technical programs:A kind of above-mentioned water treatment agent is for handling fire-fighting With the method for water, include the following steps:
Water treatment agent, which is added in fire demand water, is stirred 30-60min, and the addition of water treatment agent is 20-40g/L;Fire-fighting is used Filter screen is arranged in the exit of water, and the mesh number of filter screen is 40-50 mesh.
When handling fire demand water using the above water treatment agent, water process is added when fire demand water being perfused in fire water box Agent can inhibit water body in fire demand water to grow algae bio.Meanwhile filter screen being installed in the exit of fire demand water, in order to avoid Larger impurity enters pipeline in water body;Meanwhile water treatment agent can assist delaying the intensity of a fire under the action of water pump with water flowing Sprawling.
Water treatment agent can also after be added, water treatment agent may be added in advance with algae bio in fire water box at this time After be stirred 30-60min, the algae bio in fire water box of degrading.If after water treatment agent saturation, water can also be replaced in time Inorganic agent.
In conclusion the invention has the advantages that:
1, water treatment agent uses nucleocapsid, high temperature active aluminium oxide that can both provide larger ratio as core active substance Surface area can be with the algae bio in assistant degradation water body for loading bactericidal composition;Outside high temperature active aluminium oxide according to Secondary cladding bactericidal composition and slow releasing composition further increase the bactericidal property of water treatment agent, and decompose algae bio Performance;
2, raw material used by water process all has preferable flame retardant effect, and when using fire demand water, water treatment agent can also be made For fire retardant, auxiliary fire extinguishing.
Specific implementation mode
Invention is further described in detail with reference to embodiments.
Embodiment one:A kind of water treatment agent, is made as follows:
S1, bactericidal composition is prepared:2kg copper sulphate, 3kg aluminum sulfate, 5kg iron chloride, 2kg polymeric aluminum sulfate silicates (wherein silicon and aluminium Substance amount ratio be 1:2) and the first deionized waters of 48kg are uniformly mixed obtained bactericidal composition;
S2, slow releasing composition is prepared:The second deionized water of 3kg melamines, 2kg polyvinyl alcohol (degree of polymerization 1700) and 35kg It is uniformly mixed obtained slow releasing composition, mixing speed 80r/min;
S3, high temperature active are alumina modified:30kg high temperature actives aluminium oxide (grain size 0.3-0.5mm, porosity 40%) exists 2h is impregnated in bactericidal composition made from S1 at room temperature, is being warming up to the obtained modified high temperature actives of 60 DEG C of heating 60min later Aluminium oxide, mixing speed is 150r/min during being somebody's turn to do;
S4, water treatment agent is prepared:It is stirred in modified high temperature active aluminium oxide slow releasing composition made from S2 made from S3 20min, mixing speed 100r/min obtain water treatment agent after dry.
Remaining embodiment and embodiment one difference lies in component proportion and preparation process are different, it is specific as shown in table 1.
1 each embodiment of table prepares the proportioning and process conditions of water treatment agent
Water treatment agent made from the above various embodiments is tested for the property, takes water treatment agent 20g made from each embodiment respectively It is invested in 1L sewage and stirs 30min, test removal efficiency and COD removal rates in sewage later.Comprising outstanding in raw sewage 2 ± 0.3g/L of float (gravimetric method measures), 2 ± 0.2g/L of COD total amounts (potassium dichromate method measures), at water made from each embodiment The performance test results for managing agent are as shown in table 2.
The performance test results of water treatment agent made from 2 each embodiment of table
From the above data, water treatment agent made from the present embodiment all has preferable effect in terms of removing oil removal and COD Fruit.As the Cu in bactericidal composition2+、Al3+And Fe3+Concentration increase when, the removal rate of suspended matter and COD accordingly improve.Sustained release The mass ratio of melamine and polyvinyl alcohol is at (3-5) in composition:Between 1, water treatment agent removes oil removal and the effect of COD More preferably.
Application examples:
Application examples one:For handling fire demand water, fire demand water is perfused to fire water box water treatment agent made from Example three When water treatment agent be added simultaneously be stirred 30min, the addition of water treatment agent is 20g/L.It is initially perfused in fire water box Suspended matter and COD are not detected in water, after 6 months, the water extracted in fire water box is detected, and does not also detect to hang Float and COD.
Fire drill is carried out using the water in the fire water box, the water outlet of fire water box installs filter screen, filter screen Mesh number be 40 mesh, to stop that branch etc. is compared with bigger material in fire water box.Light 20 × 20cm2Combustible, respectively use it is general Fire demand water (containing water treatment agent) fire extinguishing in water and application examples one in logical fire water box, uses the fire-fighting in application examples one Time that fire-fights by water is shorter.
Application examples two:Water treatment agent made from Example three is for handling fire demand water, the fire-fighting in the fire water box It is pre-placed 6 months with water, it is 3.5 ± 0.2g/L (gravimetric method measures), COD contents to detect the suspended matter in initial fire demand water For 3 ± 0.2g/L (potassium dichromate method measures).The dosage that water treatment agent is added in the fire demand water is 40g/L, water treatment agent 60min is stirred after being added in fire demand water, the removal rate that suspended matter in fire demand water is measured after standing is going for 85.4%, COD Except rate is 78.6%.
From the above data, water treatment agent produced by the present invention not only has good inhibiting effect to suspended matter and COD, Can also degrade suspended matter and COD, and application range is wider.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, people in the art Member can as needed make the present embodiment the modification of not creative contribution after reading this specification, but as long as at this It is all protected by Patent Law in the right of invention.

Claims (9)

1. a kind of water treatment agent, it is characterised in that:The raw material indicated including following weight fraction is made:High temperature active aluminium oxide 30-40 parts;45-60 parts of bactericidal composition;40-50 parts of slow releasing composition;Bactericidal composition, slow releasing composition are coated on height successively Warm activated alumina periphery, wherein bactericidal composition includes the following component indicated with weight fraction:2-5 parts of copper sulphate;Sulfuric acid 3-8 parts of aluminium;5-8 parts of iron chloride;2-5 parts of polymeric aluminum sulfate silicate, the first 19-48 parts of deionized water;Slow releasing composition include below with The component that weight fraction indicates:3-15 parts of melamine;2-5 parts of polyvinyl alcohol;Second 30-35 parts of deionized water.
2. water treatment agent according to claim 1, it is characterised in that:The grain size of high temperature active aluminium oxide is 0.3-0.5mm.
3. water treatment agent according to claim 1, it is characterised in that:The ratio of the amount of the substance of silicon and aluminium in polymeric aluminum sulfate silicate It is 1:2-1:5.
4. water treatment agent according to claim 1, it is characterised in that:The degree of polymerization of polyvinyl alcohol is in slow releasing composition 1700-1800。
5. a kind of preparation method of claim 1-4 any one of them water treatment agents, it is characterised in that:Include the following steps:
S1, bactericidal composition is prepared:Copper sulphate, aluminum sulfate, iron chloride, polymeric aluminum sulfate silicate and the first deionized water are stirred system Obtain bactericidal composition;
S2, slow releasing composition is prepared:Melamine, polyvinyl alcohol and the second deionized water are stirred obtained slow releasing composition;
S3, high temperature active are alumina modified:High temperature active aluminium oxide is immersed in room temperature immersion 2-3h in bactericidal composition, Zhi Hou Modified high temperature active aluminium oxide is made in 60-80 DEG C of heating 30-60min;
S4, water treatment agent is prepared:Modified high temperature active aluminium oxide is stirred 20-30min in slow releasing composition, is obtained after dry To water treatment agent.
6. the preparation method of water treatment agent according to claim 5, it is characterised in that:Mixing speed is 80- in step S2 100r/min。
7. the preparation method of water treatment agent according to claim 5, it is characterised in that:Mixing speed is 150- in step S3 200r/min。
8. the preparation method of water treatment agent according to claim 5, it is characterised in that:Mixing speed is 100- in step S4 120r/min。
9. a kind of method that claim 1-4 any one of them water treatment agents are used to handle fire demand water, it is characterised in that:Packet Include following steps:
Water treatment agent, which is added in fire demand water, is stirred 30-60min, and the addition of water treatment agent is 20-40g/L;
Filter screen is arranged in the exit of fire demand water, and the mesh number of filter screen is 40-50 mesh.
CN201810176059.4A 2018-03-02 2018-03-02 Water treatment agent, preparation method and method for treating fire-fighting water by using water treatment agent Active CN108341440B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109896601A (en) * 2019-03-06 2019-06-18 上海盛安消防工程有限公司 A kind of fire demand water inorganic agent and its preparation process

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Publication number Priority date Publication date Assignee Title
CN109896601A (en) * 2019-03-06 2019-06-18 上海盛安消防工程有限公司 A kind of fire demand water inorganic agent and its preparation process

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