CN108275906A - Bituminous concrete high-modulus agent based on worn-out agricultural film - Google Patents

Bituminous concrete high-modulus agent based on worn-out agricultural film Download PDF

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Publication number
CN108275906A
CN108275906A CN201810071716.9A CN201810071716A CN108275906A CN 108275906 A CN108275906 A CN 108275906A CN 201810071716 A CN201810071716 A CN 201810071716A CN 108275906 A CN108275906 A CN 108275906A
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CN
China
Prior art keywords
parts
worn
agricultural film
out agricultural
bituminous concrete
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CN201810071716.9A
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Chinese (zh)
Inventor
彭麒桦
彭涛
白庆峰
杨传雷
何磊
张艳清
黄俭玲
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SHENZHEN TIANKUNYUAN ENVIRONMENT PROTECTION TECHNOLOGY CO LTD
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SHENZHEN TIANKUNYUAN ENVIRONMENT PROTECTION TECHNOLOGY CO LTD
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Priority to CN201810071716.9A priority Critical patent/CN108275906A/en
Publication of CN108275906A publication Critical patent/CN108275906A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The present invention provides the bituminous concrete high-modulus agent based on worn-out agricultural film, including internal polymer modification layer to wrap up in stern layer with the worn-out agricultural film being wrapped in outside polymer modification layer, wherein worn-out agricultural film wraps up in the material that stern layer includes following parts by weight:Worn-out agricultural film, 35 50 parts;Polymer modification layer includes the raw material of following parts by weight:Epoxy resin, 58 parts;Fiber, 5 10 parts;Paraffin, 35 parts;Age resister, 24 parts;Antioxidant, 0.1 0.8 parts;Stabilizer, 1.5 3 parts;Carbon black, 2.9 4.2 parts;Antistripping agent, 2 3.5 parts;Diatomite, 8.5 13 parts.The present invention makes the modulus of bituminous concrete and anti-aging property significantly be improved, and improves synthesis performance, the prolonging service life of pavement of asphalt roads, reduces road construction and maintenance cost, has high economic value and social benefit;The environmental pollution problem of China's agricultural mulching is solved simultaneously.

Description

Bituminous concrete high-modulus agent based on worn-out agricultural film
Technical field
The present invention relates to agricultural, traffic, Water Resources Domain new technology, more specifically to a kind of based on worn-out agricultural film High modulus asphalt concrete additive agent and preparation method thereof.
Background technology
Soil is the supplier of physical resources for the survival of mankind, and raw material carry during socio-economic development Donor.As a large agricultural country, the importance in soil is more prominent in China.There is no the sustainable development in soil, just without complete The sustainable development of state.But with the quickening of China's modernization, agricultural mulching is on the rise to the pollution of environment.By In the restriction of many factors, agricultural mulching pollution in China's is not administered effectively, restrict rural economy society of China into One step develops.The solution of agricultural mulching pollution problem is related to the prosperity and stability of the sustainable and healthy development and society of rural economy, How the sprawling that could effectively prevent and remedy pollution, be present society development priority project.
In the middle and later periods nineties 19th century, Europe has started worn-out agricultural film exploitation for asphalt roads base, middle face layer It builds.In China, this problem obtained the great attention of the scientific research institutions such as Ministry of Communications, Chinese Ministry of Environmental Protection since 2009, and set up the project In state key developmental research project.Therefore, if worn-out agricultural film can be converted into asphalt roads high-modulus agent for road Asphalt pavement construction and maintenance are to improving road surface comprehensive performance, reducing road construction and maintenance cost, lifting construction efficiency, protection Ecological environment, saving social resources have a very important significance.
Invention content
The bituminous concrete high-modulus agent and preparation method thereof based on worn-out agricultural film that the purpose of the present invention is to provide a kind of.
On the one hand, the embodiment of the present invention provides a kind of bituminous concrete high-modulus agent based on worn-out agricultural film, described to be based on The bituminous concrete high-modulus agent of worn-out agricultural film includes the polymer modification layer of inside and is wrapped in outside the polymer modification layer Worn-out agricultural film wrap up in stern layer, wherein the worn-out agricultural film wraps up in the material that stern layer includes following parts by weight:Worn-out agricultural film, 35-50 Part;The polymer modification layer includes the raw material of following parts by weight:
Epoxy resin, 5-8 parts;Fiber, 5-10 parts;Paraffin, 3-5 parts;Age resister, 2-4 parts;Antioxidant, 0.1-0.8 Part;Stabilizer, 1.5-3 parts;Carbon black, 2.9-4.2 parts;Antistripping agent, 2-3.5 parts;Diatomite, 8.5-13 parts.
In the bituminous concrete high-modulus agent provided by the invention based on worn-out agricultural film, the worn-out agricultural film is sheet.
In the bituminous concrete high-modulus agent provided by the invention based on worn-out agricultural film, the fiber is polyester fiber, The diatomite is modification infusorial earth.
In the bituminous concrete high-modulus agent provided by the invention based on worn-out agricultural film, the paraffin temperature is 90-110 ℃。
Correspondingly, the bituminous concrete high-modulus agent based on worn-out agricultural film as described above is prepared the present invention also provides a kind of Preparation method, include the following steps:
Step S1:Epoxy resin, fiber, paraffin, age resister, antioxidant, stabilizer, carbon black, antistripping agent are added Enter in horizontal color mixing machine, carries out uniform stirring and semi-finished product are made;
Step S2:Worn-out agricultural film and diatomite are added in horizontal color mixing machine, carried out again together with the semi-finished product equal Then even stirring produces the bituminous concrete high-modulus agent based on worn-out agricultural film with double screw extruder.
In preparation method provided by the invention, in the step S1, whipping temp is room temperature, mixing time 5-10 Minute.
In preparation method provided by the invention, in the step S2, whipping temp is room temperature, mixing time 10- 20 minutes, the production temperature of the double screw extruder was 140 DEG C -165 DEG C.
Correspondingly, the bituminous concrete high-modulus agent based on worn-out agricultural film as described above is prepared the present invention also provides a kind of Preparation method, include the following steps:
By worn-out agricultural film, epoxy resin, fiber, paraffin, age resister, antioxidant, stabilizer, carbon black, antistripping agent, Diatomite is placed in together in horizontal color mixing machine, and semi-finished product are generated after carrying out uniform stirring;
The semi-finished product are placed in double screw extruder and are stirred for, the pitch based on worn-out agricultural film is produced Concrete high-modulus agent.
In preparation method provided by the invention, the temperature stirred in the horizontal color mixing machine is room temperature, mixing time It is 15-25 minutes.
In preparation method provided by the invention, the time being stirred in the double screw extruder is 15-20 minutes, It is 140 DEG C -165 DEG C to produce temperature.
Implement the embodiment of the present invention, has the advantages that:Pitch coagulation provided by the invention based on worn-out agricultural film Native high-modulus agent directly in asphalt mixing building and can gather materials and be carried out at the same time dispensing, right under the shearing peptizaiton that high temperature gathers materials Gather materials to form website cross-linked structure;It is placed in pitch again to be mixed, pitch can equably be wrapped up in gathering materials, make pitch The modulus and anti-aging property of concrete are significantly improved, and are improved the synthesis performance of asphalt roads, are extended road surface Service life reduces road construction and maintenance cost, has high economic value and social benefit;Solve China's agriculture simultaneously With the environmental pollution problem of mulch.
Description of the drawings
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with Obtain other attached drawings according to these attached drawings.
Fig. 1 shows the perpendicular sectility for the bituminous concrete high-modulus agent based on worn-out agricultural film that one embodiment of the invention provides Face schematic diagram;
Fig. 2 shows crosscutting the cuing open for the bituminous concrete high-modulus agent based on worn-out agricultural film that one embodiment of the invention provides Face schematic diagram.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other without creative efforts Embodiment shall fall within the protection scope of the present invention.
The present invention provides the bituminous concrete high-modulus agent based on worn-out agricultural film, include the raw material of following parts by weight:
Worn-out agricultural film, 35-50 parts;Epoxy resin, 5-8 parts;Fiber, 5-10 parts;Paraffin, 3-5 parts;Age resister, 2-4 Part;Antioxidant, 0.1-0.8 parts;Stabilizer, 1.5-3 parts;Carbon black, 2.9-4.2 parts;Antistripping agent, 2-3.5 parts;Diatomite, 8.5-13 part.
Wherein, the worn-out agricultural film is sheet;
The fiber is polyester fiber;
The diatomite is modification infusorial earth;The paraffin is 90-110 DEG C.
In the present invention, first worn-out agricultural film is cleaned, is then placed in crusher and cuts into pieces, then by epoxy Resin, fiber, paraffin, age resister, antioxidant, stabilizer, carbon black, antistripping agent are added in horizontal color mixing machine, carry out equal Semi-finished product are made in even stirring;Worn-out agricultural film and diatomite will be added in horizontal color mixing machine again, together with the semi-finished product again Uniform stirring is carried out, then produces the bituminous concrete high-modulus agent based on worn-out agricultural film with double screw extruder.It obtains The bituminous concrete high-modulus agent based on worn-out agricultural film directly in asphalt mixing building and can gather materials and be carried out at the same time dispensing, mix 180-185 DEG C of temperature, duration of mixing 5-10s to form website cross-linked structure under the shearing peptizaiton that high temperature gathers materials to gathering materials; It is placed in pitch again to be mixed, mixing time 30-40s, pitch equably be wrapped up in gathering materials, thus, it is possible to make drip The modulus and anti-aging property of green concrete are significantly improved, and are improved the synthesis performance of asphalt roads, are extended road Face service life reduces road construction and maintenance cost, has high economic value and social benefit;Solve China simultaneously The environmental pollution problem of agricultural mulching.
Fig. 1 shows the perpendicular sectility for the bituminous concrete high-modulus agent based on worn-out agricultural film that one embodiment of the invention provides Face schematic diagram;Fig. 2 shows the crosscutting of the bituminous concrete high-modulus agent based on worn-out agricultural film of one embodiment of the invention offer Diagrammatic cross-section.As depicted in figs. 1 and 2, in the present invention, it is particle to be somebody's turn to do the bituminous concrete high-modulus agent based on worn-out agricultural film Shape, for example, cylinder.It should be noted that during preparation, it is possible to create the not exclusively cylinder of rule, this is not Influence the implementation of the present invention.The length that is dimensioned to of the bituminous concrete high-modulus agent based on worn-out agricultural film of the present invention is 5- 8mm, a diameter of 0.5-1.8mm so that it can quickly be melted during asphalt modification, participate in reaction.Fig. 1 is cylinder Vertically basal diameter at cutting sectional view, Fig. 2 be cylinder cross-sectional view, it can be seen that it is provided by the invention to be based on The bituminous concrete high-modulus agent of worn-out agricultural film includes the polymer modification layer 1 of inside, and is wrapped in the polymer modification Worn-out agricultural film outside layer wraps up in stern layer 2.Wherein, the worn-out agricultural film wraps up in the material that stern layer includes following parts by weight:Worn-out agricultural film, 35-50 parts;The polymer modification layer includes the raw material of following parts by weight:Epoxy resin, 5-8 parts;Fiber, 5-10 parts;Paraffin, 3-5 parts;Age resister, 2-4 parts;Antioxidant, 0.1-0.8 parts;Stabilizer, 1.5-3 parts;Carbon black, 2.9-4.2 parts;Anti-strip Agent, 2-3.5 parts;Diatomite, 8.5-13 parts.
The present invention also specifically provides the preparation method of the above-mentioned bituminous concrete high-modulus agent based on worn-out agricultural film, packet It includes:
Step S1:Epoxy resin, fiber, paraffin, age resister, antioxidant, stabilizer, carbon black, antistripping agent are added Enter in horizontal color mixing machine, carries out uniform stirring and semi-finished product are made;
Step S2:Worn-out agricultural film and diatomite are added in horizontal color mixing machine, carried out again together with the semi-finished product equal Then even stirring produces the bituminous concrete high-modulus agent based on worn-out agricultural film with double screw extruder.
Specifically, in the step S1, whipping temp is room temperature, and mixing time is 5-10 minutes;In the step S2 In, whipping temp is room temperature, and mixing time is 10-20 minutes, and the production temperature of the double screw extruder is 140 DEG C -165 ℃。
In an alternative embodiment of the invention, the another of the above-mentioned bituminous concrete high-modulus agent based on worn-out agricultural film is additionally provided A kind of preparation method, includes the following steps:
By worn-out agricultural film, epoxy resin, fiber, paraffin, age resister, antioxidant, stabilizer, carbon black, antistripping agent, Diatomite is placed in together in horizontal color mixing machine, and semi-finished product are generated after carrying out uniform stirring;
The semi-finished product are placed in double screw extruder and are stirred for, the pitch based on worn-out agricultural film is produced Concrete high-modulus agent.
Specifically, the temperature stirred in the horizontal color mixing machine is room temperature, and mixing time is 15-25 minutes;Described double The time being stirred in screw extruder is 15-20 minutes, and production temperature is 140 DEG C -165 DEG C.
In preparation process, what is taken is secondary mixing for the bituminous concrete high-modulus agent based on worn-out agricultural film of the present invention Production so that various raw materials and high molecular material uniformly mix, the combination of generation physical property rapidly, thus prepare based on The bituminous concrete high-modulus agent of worn-out agricultural film not only solves the environmental pollution problem of agricultural mulching, while being changed by polymer Property, it solves the with high investment of asphalt pavement construction, high pollution, high energy consumption, integrate the skills such as pavement performance is low, service life of road surface is short Art problem reduces road construction and maintenance cost, lifting construction efficiency, preserves the ecological environment, saves social resources.
The raw material and preparation process of the material of the present invention are specifically described by the following examples, it is used below Expression " part " is by weight number.
Embodiment 1
6 parts of epoxy resin, 7 parts of fibers, 3 parts of paraffin, 3 parts of age resisters, 0.2 are added in the horizontal color mixing machine of bin device Part antioxidant, 1.6 parts of stabilizers, 3 parts of carbon blacks, 2.5 parts of antistripping agents carry out uniform stirrings and semi-finished product are made;Whipping temp is Room temperature, mixing time are 8 minutes.
40 parts of worn-out agricultural films and 10 parts of diatomite are added in horizontal color mixing machine, are carried out again together with the semi-finished product equal Then even stirring produces the bituminous concrete high-modulus agent based on worn-out agricultural film with double screw extruder.Wherein, mixing Temperature is room temperature, and the time is 15 minutes;The production temperature of double screw extruder is 145 DEG C.
Embodiment 2
By 48 parts of worn-out agricultural films, 7 parts of epoxy resin, 7 parts of fibers, 3 parts of paraffin, 2 parts of age resisters, 0.5 part of antioxidant, 1.7 parts of stabilizers, 3.5 parts of carbon blacks, 3.5 parts of antistripping agents, 9 parts of diatomite are placed in together in horizontal color mixing machine, are uniformly stirred Semi-finished product are generated after mixing;The temperature of stirring is room temperature, and mixing time is 20 minutes.
The semi-finished product are placed in double screw extruder and are stirred for, the pitch based on worn-out agricultural film is produced Concrete high-modulus agent;Wherein, the time being stirred for is 20 minutes, and production temperature is 145 DEG C.
It is above disclosed to be only a preferred embodiment of the present invention, the power of the present invention cannot be limited with this certainly Sharp range, those skilled in the art can understand all or part of the processes for realizing the above embodiment, and is weighed according to the present invention Equivalent variations made by profit requirement, still belong to the scope covered by the invention.

Claims (10)

1. a kind of bituminous concrete high-modulus agent based on worn-out agricultural film, which is characterized in that the pitch based on worn-out agricultural film Concrete high-modulus agent includes that internal polymer modification layer and the worn-out agricultural film being wrapped in outside the polymer modification layer wrap up in abdomen Layer, wherein the worn-out agricultural film wraps up in the material that stern layer includes following parts by weight:Worn-out agricultural film, 35-50 parts;The polymer changes Property layer includes the raw material of following parts by weight:
Epoxy resin, 5-8 parts;Fiber, 5-10 parts;Paraffin, 3-5 parts;Age resister, 2-4 parts;Antioxidant, 0.1-0.8 parts; Stabilizer, 1.5-3 parts;Carbon black, 2.9-4.2 parts;Antistripping agent, 2-3.5 parts;Diatomite, 8.5-13 parts.
2. the bituminous concrete high-modulus agent according to claim 1 based on worn-out agricultural film, which is characterized in that described waste and old Agricultural film is sheet.
3. the bituminous concrete high-modulus agent according to claim 1 based on worn-out agricultural film, which is characterized in that the fiber For polyester fiber, the diatomite is modification infusorial earth.
4. the bituminous concrete high-modulus agent according to claim 1 based on worn-out agricultural film, the paraffin temperature is 90- 110℃。
5. a kind of preparation method preparing the bituminous concrete high-modulus agent based on worn-out agricultural film as described in claim 1, It is characterized in that, includes the following steps:
Step S1:Epoxy resin, fiber, paraffin, age resister, antioxidant, stabilizer, carbon black, antistripping agent are added sleeping In formula color mixing machine, carries out uniform stirring and semi-finished product are made;
Step S2:Worn-out agricultural film and diatomite are added in horizontal color mixing machine, uniformly stirred again together with the semi-finished product It mixes, then produces the bituminous concrete high-modulus agent based on worn-out agricultural film with double screw extruder.
6. preparation method according to claim 5, which is characterized in that in the step S1, whipping temp is room temperature, is stirred It is 5-10 minutes to mix the time.
7. preparation method according to claim 5, which is characterized in that in the step S2, whipping temp is room temperature, is stirred It is 10-20 minutes to mix the time, and the production temperature of the double screw extruder is 140 DEG C -165 DEG C.
8. a kind of preparation method preparing the bituminous concrete high-modulus agent based on worn-out agricultural film as described in claim 1, It is characterized in that, includes the following steps:
By worn-out agricultural film, epoxy resin, fiber, paraffin, age resister, antioxidant, stabilizer, carbon black, antistripping agent, diatom Soil is placed in together in horizontal color mixing machine, and semi-finished product are generated after carrying out uniform stirring;
The semi-finished product are placed in double screw extruder and are stirred for, the pitch coagulation based on worn-out agricultural film is produced Native high-modulus agent.
9. preparation method according to claim 8, which is characterized in that the temperature stirred in the horizontal color mixing machine is room Temperature, mixing time are 15-25 minutes.
10. preparation method according to claim 8, which is characterized in that be stirred in the double screw extruder when Between be 15-20 minute, production temperature be 140 DEG C -165 DEG C.
CN201810071716.9A 2018-01-24 2018-01-24 Bituminous concrete high-modulus agent based on worn-out agricultural film Pending CN108275906A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109486234A (en) * 2018-11-16 2019-03-19 深圳市天坤元环保科技有限公司 A kind of waste plastic regeneration direct putting type asphalt mixed material modifier and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN109486234A (en) * 2018-11-16 2019-03-19 深圳市天坤元环保科技有限公司 A kind of waste plastic regeneration direct putting type asphalt mixed material modifier and preparation method thereof

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