CN108237838A - Heat insulation decorative plate of wall and preparation method thereof - Google Patents
Heat insulation decorative plate of wall and preparation method thereof Download PDFInfo
- Publication number
- CN108237838A CN108237838A CN201611229284.7A CN201611229284A CN108237838A CN 108237838 A CN108237838 A CN 108237838A CN 201611229284 A CN201611229284 A CN 201611229284A CN 108237838 A CN108237838 A CN 108237838A
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- Prior art keywords
- flame
- heat insulation
- decorative plate
- weight
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Links
- 238000009413 insulation Methods 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 42
- 230000001070 adhesive effect Effects 0.000 claims abstract description 41
- 239000003063 flame retardant Substances 0.000 claims abstract description 40
- 239000000853 adhesive Substances 0.000 claims abstract description 39
- 239000010410 layer Substances 0.000 claims abstract description 28
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 230000000712 assembly Effects 0.000 claims abstract description 25
- 238000000429 assembly Methods 0.000 claims abstract description 25
- 229920003180 amino resin Polymers 0.000 claims abstract description 23
- 230000018044 dehydration Effects 0.000 claims abstract description 22
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 18
- 239000002671 adjuvant Substances 0.000 claims abstract description 15
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 14
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 14
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 14
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 7
- 239000003292 glue Substances 0.000 claims abstract description 6
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical class OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000012790 adhesive layer Substances 0.000 claims abstract description 4
- 239000002023 wood Substances 0.000 claims description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 8
- 239000000347 magnesium hydroxide Substances 0.000 claims description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 7
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 5
- -1 cyanurotriamide modified urea Chemical class 0.000 claims description 5
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- 238000004026 adhesive bonding Methods 0.000 claims description 3
- 239000010425 asbestos Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052895 riebeckite Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 3
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 2
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 claims description 2
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 claims description 2
- 239000004640 Melamine resin Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 238000007731 hot pressing Methods 0.000 claims 1
- 210000002700 urine Anatomy 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 25
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 18
- 230000000694 effects Effects 0.000 abstract description 13
- 238000004079 fireproofing Methods 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 2
- 235000019256 formaldehyde Nutrition 0.000 abstract 1
- 238000005034 decoration Methods 0.000 description 9
- 238000010276 construction Methods 0.000 description 7
- 230000006870 function Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000011490 mineral wool Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000009970 fire resistant effect Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000009931 harmful effect Effects 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 230000000979 retarding effect Effects 0.000 description 2
- HBGPNLPABVUVKZ-POTXQNELSA-N (1r,3as,4s,5ar,5br,7r,7ar,11ar,11br,13as,13br)-4,7-dihydroxy-3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-2,3,4,5,6,7,7a,10,11,11b,12,13,13a,13b-tetradecahydro-1h-cyclopenta[a]chrysen-9-one Chemical compound C([C@@]12C)CC(=O)C(C)(C)[C@@H]1[C@H](O)C[C@]([C@]1(C)C[C@@H]3O)(C)[C@@H]2CC[C@H]1[C@@H]1[C@]3(C)CC[C@H]1C(=C)C HBGPNLPABVUVKZ-POTXQNELSA-N 0.000 description 1
- PFRGGOIBYLYVKM-UHFFFAOYSA-N 15alpha-hydroxylup-20(29)-en-3-one Natural products CC(=C)C1CCC2(C)CC(O)C3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 PFRGGOIBYLYVKM-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical group [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- 244000050510 Cunninghamia lanceolata Species 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000218652 Larix Species 0.000 description 1
- 235000005590 Larix decidua Nutrition 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 240000007263 Pinus koraiensis Species 0.000 description 1
- 235000011615 Pinus koraiensis Nutrition 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- SOKRNBGSNZXYIO-UHFFFAOYSA-N Resinone Natural products CC(=C)C1CCC2(C)C(O)CC3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 SOKRNBGSNZXYIO-UHFFFAOYSA-N 0.000 description 1
- NEHNHSYTMVZVPP-UHFFFAOYSA-N [B].O[Si](O)(O)O Chemical class [B].O[Si](O)(O)O NEHNHSYTMVZVPP-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000000191 radiation effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000009711 regulatory function Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/043—Ornamental plaques, e.g. decorative panels, decorative veneers containing wooden elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0461—Ornamental plaques, e.g. decorative panels, decorative veneers used as wall coverings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C09J161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/30—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic and acyclic or carbocyclic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Building Environments (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of heat insulation decorative plate of wall and preparation method thereof.The heat insulation decorative plate of wall includes blank assemblies and is at least attached to the flame-retarding adhesive layer formed by the adhesive containing flame-retarding adhesive along at least side surface on the blank assemblies thickness direction, the blank assemblies include at least one layer of Wooden veneer, and the flame-retarding adhesive contains water soluble amino resin, dehydration catalyst, carbon forming agent and adjuvant and with or without water；The dehydration catalyst is one or more in ammonium polyphosphate, melamine orthophosphates and melamine pyrophosphate；The degree of polymerization of the ammonium polyphosphate is more than 20.The present invention also provides a kind of fire proofings.The glue performance for the heat insulation decorative plate of wall that method using the present invention is prepared meets requirements of the national standard, and assigns base material flame retardant property；Moreover, do not interfere with the mechanical property of base material, burst size of methanal is also at E1 grades or more, safety and environmental protection；Meanwhile maintain the native texture of timber, good decorating effect.
Description
Technical field
The present invention relates to a kind of heat insulation decorative plate of wall and preparation method thereof and including the fire-retardant of the heat insulation decorative plate of wall
Material.
Background technology
It is many to the research of timber and wood materials flame retardant treatment at present but existing to wood materials progress flame retardant treatment
Method there are various defects.If CN1911613A discloses a kind of Wood fire retardant treatment process, which is by timber
It is put into the container of sealing, the container vacuum including timber is handled, then fire resistant fluid by high-pressure pump is input to and is in
In the container of vacuum state, after fire resistant fluid reaches saturation state in wood, take out timber and be dried；The fire resistant fluid contains
There are ammonium sulfate, diammonium hydrogen phosphate, boric acid and borax.This method is the method for pressure impregnating fire retardant, this to treating of wood side
Method there are it is certain the problem of：(1) fire retardant allows for being dissolved in the water, and impregnates in timber in liquid form, therefore, tree
The permeability of kind has a significant impact to its amount of impregnating and the uniformity impregnated；(2) the inorganic based flame retardant majority can not be with timber
Chemical bonding is formed, surface precipitation phenomenon is easily generated, influences subsequent secondary operation；(3) above-mentioned fire retardant is to the object of timber
Managing mechanical property, there are harmful effects, and e.g., MOR (static bending strength), MOE (elasticity modulus) are reduced, and brittleness increases；(4)
Want to reach higher fire-retardant rank, it is necessary to increase the amount of impregnating of fire retardant matter；(5) the necessary redrying of treated timber,
Timber is easily made to generate secondary cracking, deformation, loss increases.
If when carrying out flame retardant treatment to finished product glued board, the adhesive for being generally employed to produce glued board is phenolic resin
Or cyanurotriamide modified urea resin, and gluing oxidant layer has larger impact to the scattering and permeating of fire retardant.If face ply
When remaining more fire retardant, product easily generates moisture absorption and returns white phenomenon, and subsequent secondary operation can and paint poor performance, if
Only to plywood skin veneer flame retardant treatment, expected flame retardant effect is often not achieved, needs to increase aid in treatment or increase to answer
Qualifications.
In conclusion at present in the production of fire retarding wood and wood materials, it is necessary to whole to plank component units or plank
It carries out fire retardant matter impregnation and can be only achieved ideal flame retardant effect.This flame retardant treatment mode brings many unfavorable shadows
It rings, such as complex treatment process reduces the physical and mechanical property of material, there is harmful effect phenomenon to adhesive curing performance, influences
Follow-up suitability for secondary processing repeats dry and increases energy consumption etc..
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of walls that can have fine flame retarding function
Heat insulating decorative board and the fire proofing with good flame retardant effect and mechanical property.The heat insulation decorative plate of wall and fire proofing
Fire retardant treatment process is simple, only need to the liquid mixture containing flame-retarding adhesive and curing agent be coated on blank assemblies at least
Heat insulation decorative plate of wall is can obtain along the side surface on the blank assemblies thickness direction and hot-press solidifying, by wall-insulation
The surface that decorative panel is covered on processed material (base material) can obtain flame retardant effect and the fire proofing of good mechanical performance,
And base material need not do any flame retardant treatment.This processing mode can make base material be not easy to be damaged, will not be to the performance of base material
It has an impact, and appearance looks elegant, is easy to industrialized production.
To the purpose of the present invention can be achieved through the following technical solutions：
The present invention provides a kind of heat insulation decorative plate of wall, wherein, which includes blank assemblies and at least attached
It in the fire retardant glue formed by the adhesive containing flame-retarding adhesive along the side surface on the blank assemblies thickness direction
Adhesive layer, the blank assemblies include at least one layer of Wooden veneer, and the flame-retarding adhesive contains water soluble amino resin, dehydration
Catalyst, carbon forming agent and adjuvant and with or without water；The dehydration catalyst is selected from ammonium polyphosphate, the positive phosphorus of melamine
It is one or more in hydrochlorate and melamine pyrophosphate；The degree of polymerization of the ammonium polyphosphate is more than 20.
The present invention also provides a kind of preparation method of heat insulation decorative plate of wall, wherein, this method includes to contain fire-retardant
Adhesive and curing agent liquid mixture be coated on blank assemblies at least along the side table on the blank assemblies thickness direction
Face and hot-press solidifying, the blank assemblies include at least one layer of Wooden veneer, and the flame-retarding adhesive contains water soluble amino tree
Fat, dehydration catalyst, carbon forming agent and adjuvant and the water selectively contained；The dehydration catalyst be selected from ammonium polyphosphate,
It is one or more in melamine orthophosphates and melamine pyrophosphate；The degree of polymerization of the ammonium polyphosphate is 20
More than.
In addition, the present invention also provides a kind of fire proofing, which includes base material and is attached at substrate surface
Heat insulation decorative plate of wall, the heat insulation decorative plate of wall are heat insulation decorative plate of wall provided by the invention.
Compared with prior art, the present invention has the following advantages：
1. insulation and decoration is two-in-one to integrate the high-efficiency insulated performance of mineral wool and the decoration functions of decorative panel, one block of plank
Two kinds of functions；
2. heat preservation, heat-proof quality are good
Heat insulating decorative board of the present invention is stablized using industrialization Automatic Production Line, product quality, the high density of intermediate insulating layer
Mineral wool has fabulous heat-insulating property, thermal conductivity factor λ≤0.035W/mK, the polyphenyl second generally used with the current country
Alkene (thermal conductivity factor λ≤0.042W/mK), rock wool (thermal conductivity factor λ≤0.050W/mK) are compared, and heat insulation effect carries
After high 20% -25% by keel and wall connecting, the air layer between plank and wall can play double-layer heat insulation, be separated with
Beneficial effect
The hollow pipe and accessory of uniform shapes improve acoustic decoration board standardization in itself and aesthetics；Quickly connection and
Connector system improves acoustic decoration board producing efficiency and technological level；Strong adsorption magnet arrangement and self-priming bayonet unit
Application, the installation speed of acoustic decoration board can be significantly improved, project installation expense and time is saved, dragon can be directly installed on
On bone, the application of the levelling base's plank of building interior is saved, the synthesis cost and building for significantly reducing engineering are born a heavy burden, and are expanded and are inhaled
Cavity after soundboard significantly improves the sound absorption function of abatvoix；Flatness regulatory function device and all directions translational adjustment function dress
The application put can significantly improve the flatness and aesthetics on acoustic decoration board surface, improve the decorative effect of sound-absorbing engineering；It is living
The application of dynamic plug-in card, can radical change acoustic decoration board can not it is easy to disassemble, cannot replace and can not be used repeatedly
Drawback improves the utilization ratio of product itself and resource reutilization ability；Product does not have to gypsum, without resin adhesive curing, no
With timber, make product that there is the features such as intensity height, good environmental protection, fire-proof and water-proof, non-deformability is strong.
Thermal effect, heat-insulating property are far above the standard of national energy-saving 65%.
3. decorative effect is more
Appearance is rich and varied, imitates a variety of decorative forms such as stone material, imitative ceramic tile, imitation wood line and aluminum facade, can meet different clients
Individual demand.
4. security performance is high
Heat insulating decorative board, using dry construction, avoids aging obscission caused by traditional chemistry is pasted, in addition from heavy and light
Mineral wool is A grades of incombustible materials, eliminates security risk.
5. construction efficiency is high
Traditional exterior-wall heat insulation Finish System construction, general on-site layering are gradually constructed, and the construction time is long, complex procedures, by day
Gas factor influences big.The complete dry construction of heat insulating decorative board of the present invention is installed not by weather, seasonal effect, and mounting means is simple and direct,
Construction efficiency is 2 times of traditional method or more.
It is 6. applied widely
Building that is newly-built and repairing, public building, civil buildings can be used, and be not required to carry out building wall cumbersome
Pretreatment, especially in the reducing energy consumption to existing building, on the basis of not needing to handle original building exterior wall,
It can construct.
It is 7. durable
With preferable weatherability, service life can be with building the same service life.External surface coating is handled through special process, is not only adhered to
Performance is strong, and plate surface has excellent performance in terms of wear-resisting, acidproof, alkaline-resisting, salt spray resistance erosion.
8. comprehensive cost low
Heat preservation and decoration of outer wall system of the present invention keeps the temperature, is decoration integrated, simplifies construction procedure in installation, and reduction is constructed into
This, 20 years practical architectural appearances are still relatively new, and with the building same service life, primary input is lifelong to be benefited.
9. maintenance cost is low
(need to brush once) patch block again per 3-5 with the domestic external surface of buildings swabbing generally used now (makes
After 10 years, surface ceramic tile starts shedding off) it compares, heat insulating decorative board of the present invention does not need to the maintenance put into greatly substantially.
Self-cleaning is strong, and general dust pollution water (or common rainwater) can be clean as new after rinsing.
Specific embodiment
Heat insulation decorative plate of wall provided by the invention includes blank assemblies and is at least attached to along the blank assemblies thickness
The flame-retarding adhesive layer formed by the adhesive containing flame-retarding adhesive of a side surface on direction, the blank assemblies are at least
Including one layer of Wooden veneer, the flame-retarding adhesive contain water soluble amino resin, dehydration catalyst, carbon forming agent and adjuvant with
And with or without water；The dehydration catalyst is selected from ammonium polyphosphate, melamine orthophosphates and melamine pyrophosphate
In it is one or more；The degree of polymerization of the ammonium polyphosphate is more than 20, preferably 1000-1500.
In flame-retarding adhesive provided by the invention, the content of above-mentioned various components can change within a large range,
Under preferable case, on the basis of the total weight of flame-retarding adhesive, the content of water soluble amino resin is 30-70 weight %, is dehydrated
The content of catalyst is 8-35 weight %, and the content of carbon forming agent is 2-20 weight %, and the content of adjuvant is 2-30 weights
% is measured, the content of water is 0-40 weight %.It is water-soluble on the basis of the total weight of flame-retarding adhesive in the case of further preferably
Property amino resins content for 40-60 weight %, the content of dehydration catalyst is 10-25 weight %, and the content of carbon forming agent is
5-15 weight %, the content of adjuvant is 3-20 weight %, and the content of water is 0-30 weight %.The present inventor also sends out
Existing, when each component is in above-mentioned preferred content range, the flame retardant property of obtained flame-retarding adhesive is good, and glue performance is equal
Meet requirements of the national standard.
According to the present invention, the main function of the dehydration catalyst is the dehydration carbonization for promoting carbon forming agent, while under high temperature
The non-flammable gases generated due to resin decomposition make carbide foaming and intumescing so that form one layer uniformly in combustible surface
Expanding layer, completely cuts off external heat and oxygen internally transmits, so as to achieve the purpose that base material is protected to prevent it from burning.
According to the present invention, the adjuvant can known in those skilled in the art various improve the fire retardant glue
The flame retardant property of stick, smoke suppressing and the substance for reducing free formaldehyde, under preferable case, the adjuvant is aluminium hydroxide
And/or magnesium hydroxide or for selected from alumina silicate fibre, glass fibre, asbestos fibre, hollow glass microbead, modified silicic acid
Boron, expansible graphite, have layer silicate, silica, alundum (Al2O3) and urea in one or more and hydrogen
The mixture of aluminium oxide and/or magnesium hydroxide.
Wherein, the aluminium hydroxide and magnesium hydroxide decompose caloric receptivity greatly, and the H2O generated after pyrolytic can play suction
Heat effect, the oxide isolation heat and the translocation of oxygen internally of molten condition, and the oxide after decomposition is resistance to
High temperature substance, the progress of burning can further be prevented again by being attached to combustible surface.Aluminium hydroxide and magnesium hydroxide are entire
It is not only generated during fire-retardant without any harmful substance, and the product decomposed also is able to play elimination cigarette fire-retardant while
Mist and the effect for absorbing heat.
According to the present invention, the water soluble amino resin can be selected from the various water soluble amino resins of this field routine,
Under preferable case, the water soluble amino resin in melamine resin and cyanurotriamide modified urea resin one
Kind is a variety of.The various methods that cyanurotriamide modified urea resin used in the present invention is known in the art obtain, the trimerization
Cyanamide modified urea-formaldehyde resin can be by commercially available or be prepared, for example, can be according to method disclosed in CN100572445C
Cyanurotriamide modified urea resin is prepared.The water soluble amino resin using have good glue performance and water resistance as
It is main, while one of composition for also doubling as fire retardant matter, heat, which can decompose, releases the non-flammable compressive gases such as ammonia, vapor, reduces
The heat of combustible surface dilutes the concentration of combustible surface fuel gas, therefore water soluble amino resin is this item hair
One of bright crucial component.The water soluble amino resin can be commercially available, can also be according to known in this field
Various preparation methods obtain, for example, can be according to CN1527853A, CN 1105694A, CN 1834186A, CN
101134835A and document [J Wood Sci (2001) 47：451-457] etc. disclosed in method be prepared.
According to the present invention, the carbon forming agent can be selected from the various carbon forming agents of this field routine, under preferable case, it is described into
One or more of charcoal agent in sucrose, sorbose, starch, pentaerythrite, dipentaerythritol and tripentaerythritol.With water solubility
The non-flammable compressive gases such as ammonia, vapor that amino resins heat releases are air source, and the carbon forming agent is in the effect of dehydration catalyst
Lower dehydration carbonization forms the expanded charred layer of foam-like in combustible surface, has been coated in the expanded charred layer of the foam-like big
The non-flammable compressive gas of amount has not only effectively obstructed radiation effects of the external heat source to internal timber, but also has separated oxygen and inside
The contact of timber, so as to reach fire-retardant, fire prevention purpose.
The preparation method of the flame-retarding adhesive is not particularly limited in the present invention, for example, by water soluble amino resin, taking off
Water catalyst, carbon forming agent and fire-retardant adjuvant and the water selectively contained are uniformly mixed；The dehydration catalyst is selected from
It is one or more in ammonium polyphosphate, melamine orthophosphates and melamine pyrophosphate；The ammonium polyphosphate
The degree of polymerization is more than 20, preferably 1000-1500.
Wherein, the dosage of each substance is preferably so that on the basis of the total weight of flame-retarding adhesive, water soluble amino resin
Content is 30-70 weight %, and the content of dehydration catalyst is 8-35 weight %, and the content of carbon forming agent is 2-20 weight %, auxiliary
The content of auxiliary agent is 2-30 weight %, and the content of water is 0-40 weight %.In the case of further preferably, the dosage of each substance makes
It is able on the basis of the total weight of flame-retarding adhesive, the content of water soluble amino resin is 40-60 weight %, dehydration catalyst
Content is 10-25 weight %, and the content of carbon forming agent is 5-15 weight %, and the content of adjuvant is 3-20 weight %, and water contains
It measures as 0-30 weight %.
According to the present invention, the selection of the type of above-mentioned each component has been described above, and repeats no more herein.
The application method of flame-retarding adhesive of the present invention is to be mixed to get aqueous flame-retarding adhesive with curing agent
The mixture is coated on the surface of the material of pending flame retardant treatment by mixture, then will be coated with the flame-retarding adhesive
Wood materials assembly and hot-press solidifying.The painting of the mixture of aqueous flame-retarding adhesive and curing agent containing the present invention
Cloth amount can be depending on the fire-retardant demand to various different materials, and there is no particular limitation.It in other words, can when unused
Directly flame-retarding adhesive provided by the invention will be can obtain after the mixing of each solid component.
According to the present invention, the mixing of various components can be carried out at the same time and can also carry out step by step, and the sequence of mixing can't
The performance of flame-retarding adhesive to obtaining has an impact, for example, can water and water soluble amino resin first be mixed to get liquid
Water soluble amino resin, then remaining component is uniformly mixed with the water soluble amino resin of the liquid again or
A certain amount of water can also be filled into as needed to meet the needs of coating；After can also each component directly be mixed with water
It arrives；When in use, the content of water is preferably the 20-30 weight % of the total weight of aqueous flame-retarding adhesive.
Time of the present invention to the temperature of mixing and mixing, there is no particular limitation, as long as various components is made to be uniformly mixed i.e.
Can, under preferable case, the temperature of mixing can be 10-40 DEG C, and the time of mixing can be 10-60 minutes.
Flame-retarding adhesive provided by the invention can carry out flame retardant treatment to a variety of materials, especially suitable for wooden material
Material, is more applicable for being coated directly onto the surface of single-board materials to carry out flame retardant treatment.
According to the present invention, the blank assemblies include at least one layer of Wooden veneer, and in other words, the blank assemblies can be
One layer of Wooden veneer, or multilayer laminated, gluing mutually multilayered wood veneer.
Wherein, the number of plies of the multilayered wood veneer can reach according to the thickness and actual needs of individual layer Wooden veneer
Flame retardant effect depending on.The thickness of the individual layer Wooden veneer is by depending on the wood quality that selects, under normal circumstances, the individual layer
The thickness of Wooden veneer can be 0.1-5mm, further preferably preferably 0.1-1.5mm, 0.15-1mm.Multilayered wood veneer
The number of plies usually can be by 1-30 layers, the preferably 2-20 layers of individual layer Wooden veneer is laminated, is bonded to obtain including delta wood
The blank assemblies of matter veneer.The Wooden veneer of required thickness can be used that well known to a person skilled in the art various methods to obtain, example
Such as, the method for rotary-cut or slicing.The material of the Wooden veneer can be various wood materials, described wooden under preferable case
Veneer is coniferous wood or broad-leaved wood, the coniferous wood or broad-leaved wood can and preferably poplar, Eucalyptus, Korean pine, China fir
Wood, birch, paulownia, larch.
It is above disclosed to be merely a preferred embodiment of the present invention, the right of the present invention cannot be limited with this certainly
Range, therefore the equivalent variations made according to scope of the present invention patent, are still within the scope of the present invention.
Claims (7)
1. a kind of heat insulation decorative plate of wall, which is characterized in that the heat insulation decorative plate of wall includes blank assemblies and is at least attached to
Along the fire retardant glue formed by the adhesive containing flame-retarding adhesive of at least side surface on the blank assemblies thickness direction
Adhesive layer, the blank assemblies include at least one layer of Wooden veneer, and the flame-retarding adhesive is water soluble amino resin, dehydration is urged
Agent, carbon forming agent and adjuvant and with or without water；The dehydration catalyst is selected from ammonium polyphosphate, melamine orthophosphoric acid
It is one or more in salt and melamine pyrophosphate；The degree of polymerization of the ammonium polyphosphate is 1000-1500；It is described auxiliary
Auxiliary agent is aluminium hydroxide and/or magnesium hydroxide or is selected from alumina silicate fibre, glass fibre, asbestos fibre, hollow glass
In microballon, modified borosilicate, expansible graphite, the silicate with layer structure, silica, alundum (Al2O3) and urea
The mixture of one or more and aluminium hydroxide and/or magnesium hydroxide.
2. the heat insulation decorative plate of wall according to claim 1, wherein, it is water-soluble on the basis of the total weight of flame-retarding adhesive
Property amino resins content be 30-70 weight %；The content of dehydration catalyst is 8-35 weight %；The content of carbon forming agent is 2-
20 weight %；The content of adjuvant is 2-30 weight %；The content of water is 0-40 weight %.
3. the heat insulation decorative plate of wall according to claim 2, wherein, it is water-soluble on the basis of the total weight of flame-retarding adhesive
Property amino resins content be 40-60 weight %；The content of dehydration catalyst is 10-25 weight %；The content of carbon forming agent
For 5-15 weight %；The content of adjuvant is 3-20 weight %；The content of water is 0-30 weight %.
4. according to the heat insulation decorative plate of wall described in any one in claim 1-3, wherein, the water soluble amino resin
It is one or more in melamine resin and cyanurotriamide modified urea resin.
5. according to the heat insulation decorative plate of wall described in any one in claim 1-3, wherein, the carbon forming agent be selected from sucrose,
It is one or more in sorbose, starch, pentaerythrite, dipentaerythritol and tripentaerythritol.
6. the heat insulation decorative plate of wall according to claim 1, wherein, the blank assemblies include multilayer laminated, mutual
Glued Wooden veneer, further include between two layers adjacent of Wooden veneer formed by the adhesive containing flame-retarding adhesive it is fire-retardant
Gluing oxidant layer；The dosage of the flame-retarding adhesive is 50-500g/m2；The thickness of the Wooden veneer be 0.1-5mm, the wood
Matter veneer is coniferous wood or broad-leaved wood.
7. a kind of preparation method of heat insulation decorative plate of wall, which is characterized in that this method includes that flame-retarding adhesive will be contained and consolidates
Agent liquid mixing after be coated on blank assemblies at least along at least side surface on the blank assemblies thickness direction simultaneously
Hot-press solidifying, the blank assemblies include at least one layer of Wooden veneer, and the flame-retarding adhesive is water soluble amino resin, dehydration
Catalyst, carbon forming agent and adjuvant and the water selectively contained；The dehydration catalyst is selected from ammonium polyphosphate, melamine
It is one or more in orthophosphates and melamine pyrophosphate；The degree of polymerization of the ammonium polyphosphate is 1000-1500；
The adjuvant be aluminium hydroxide and/or magnesium hydroxide or for selected from alumina silicate fibre, glass fibre, asbestos fibre, in
Empty glass microballoon, modified borosilicate, expansible graphite, silicate, silica, alundum (Al2O3) and the urine with layer structure
The mixture of one or more and aluminium hydroxide and/or magnesium hydroxide in element；The blank assemblies include it is multilayer laminated,
The Wooden veneer mutually to fit, this method are additionally included between two layers adjacent of Wooden veneer coating and contain flame-retarding adhesive and solid
The liquid mixture of agent and hot pressing, curing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611229284.7A CN108237838A (en) | 2016-12-27 | 2016-12-27 | Heat insulation decorative plate of wall and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611229284.7A CN108237838A (en) | 2016-12-27 | 2016-12-27 | Heat insulation decorative plate of wall and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108237838A true CN108237838A (en) | 2018-07-03 |
Family
ID=62702896
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611229284.7A Withdrawn CN108237838A (en) | 2016-12-27 | 2016-12-27 | Heat insulation decorative plate of wall and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108237838A (en) |
-
2016
- 2016-12-27 CN CN201611229284.7A patent/CN108237838A/en not_active Withdrawn
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Application publication date: 20180703 |