CN108219338A - A kind of fire-retardant plating HIPS of electronic apparatus shell and preparation method thereof - Google Patents
A kind of fire-retardant plating HIPS of electronic apparatus shell and preparation method thereof Download PDFInfo
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- CN108219338A CN108219338A CN201810117447.5A CN201810117447A CN108219338A CN 108219338 A CN108219338 A CN 108219338A CN 201810117447 A CN201810117447 A CN 201810117447A CN 108219338 A CN108219338 A CN 108219338A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Fire-retardant plating HIPS the invention discloses a kind of electronic apparatus shell and preparation method thereof, is made of following components in parts by weight：85 parts of HIPS65,16 28 parts of makrolon, 7 15 parts of nano-titanium dioxide, 10 30 parts of fire retardant, 15 parts of filler, 0.3 0.8 parts of antioxidant, 0.1 0.3 parts of lubricant.This it is fire-retardant plating HIPS by high-speed stirred, high-temperature fusion, mold molding and etc. be made.The present invention provides fire-retardant plating HIPS of kind of electronic apparatus shell and preparation method thereof, had both met the plating requirement of HIPS, and had also met requirement of the electronic apparatus shell to flame retardant property.
Description
Technical field
The invention belongs to technical field of polymer composite materials, and in particular to a kind of fire-retardant plating of electronic apparatus shell
HIPS and preparation method thereof.
Background technology
At present, polystyrene (HIPS) is widely used in electronic apparatus shell field, have many advantages, such as it is beautiful and anti-aging,
But the HIPS for being traditionally used for electronic apparatus shell does not have flame retardant effect in itself, in use with certain fire
Hidden danger.International and national is higher and higher to the plastic material flame-retardancy requirements of electronic apparatus, and the UL standards in the U.S. have become
International standard, and in constantly improve, this just has the anti-flammability of the plastic product of electronic apparatus certain requirement.
Based on this, it is necessary to fire-retardant plating HIPS of a kind of electronic apparatus shell and preparation method thereof is proposed, to solve
Problems of the prior art.
Invention content
In view of the above-mentioned analysis to the prior art, the present invention provide kind of electronic apparatus shell fire-retardant plating HIPS and its
Preparation method had both met the plating requirement of HIPS, also met requirement of the electronic apparatus shell to flame retardant property.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of fire-retardant plating HIPS of electronic apparatus shell, is made of following components in parts by weight：
Preferably, it is made of following components in parts by weight：
Preferably, the degree of polymerization of the polycarbonate is 5000-7000.
Preferably, the grain size of the nano-titanium dioxide is 2-10nm.
Preferably, the fire retardant is magnesium hydroxide, aluminium hydroxide, the dioxygen containing DOPO phosphate flame retardant in oneself,
Any one or a few in triphenyl phosphate, antimony oxide.
Preferably, the filler is one or more of calcium carbonate, clay, silicate or talcum powder.
Preferably, the antioxidant is anti-oxidant DLTP or TNP.
Preferably, the lubricant is one in stearic acid, stearate, polyvinyl chloride wax, paraffin or oleamide
Kind is a variety of.
The present invention also provides a kind of fire-retardant plating HIPS of electronic apparatus shell, which is characterized in that including following step
Suddenly：
(1) each component is weighed by predetermined weight；
(2) HIPS, makrolon, nano-titanium dioxide, fire retardant, filler, antioxidant, lubricant are added at a high speed
In kneader, it is uniformly mixed material under the stirring action of high-speed kneading machine, in whipping process, mixed material is pinched with high speed
Conjunction machine inner wall frictional heat so that the temperature raising of mixed material when the temperature of mixture material is increased to 60-80 DEG C, is beaten
Open kneader discharging；
(3) mixture is cooled to environment temperature, then feeds the mixture into electrothermal furnace and heated, mixtures is waited to melt
After melting, open electric furnace discharge valve, material is pipelined to mold forming production line, open mold feeding valve carry out into
Type；
(6) after being molded, mold is opened, taking-up is cooled to room temperature to get the fire-retardant plating of the electronic apparatus shell
HIPS。
Compared with prior art, the present invention the present invention has following advantageous effect：
(1) the fire-retardant plating HIPS of electronic apparatus shell of the invention meets plating and electric equipment products to resistance
The requirement of combustion property.The increase of filler not only contributes to the heat resistances of HIPS materials, flame retardant property and to reduce cost etc. excellent
Gesture also causes flame-retarding HIPS material to have plating etching property.
(2) filler that the present invention is centainly corroded by addition, forms the cavity easily adsorbed in etching process is electroplated,
The binding force between the coat of metal and plastic substrate is increased, while improves the fire-retardant and heat resistance of flame-retarding HIPS, is improved
The thermal stability of plastic products and safety.
(3) present invention uses the degree of polymerization to may be such that the flame retardant property of flame-retarding HIPS obtains for the poly- carbon resin of 5000-7000
It is further to improve.
(4) nano-titanium dioxide that uses of the present invention is while causing flame-retarding HIPS to have compared with high flame resistance, also into
One step, which increases flame-retarding HIPS, has preferable stability, makes its preferable tensile strength, bending strength.
Specific embodiment
Form by the following examples is described in further detail, but should not be by this above of present invention again
The range for being interpreted as the above-mentioned theme of the present invention is only limitted to following embodiment, all based on the technology realized belonging to the above of the present invention
It all belongs to the scope of the present invention.
Embodiment 1
A kind of fire-retardant plating HIPS of electronic apparatus shell, is made of following components in parts by weight：
Wherein, the degree of polymerization of the polycarbonate is 6000.
Wherein, the grain size of the nano-titanium dioxide is 6nm.
Wherein, the fire retardant be magnesium hydroxide, aluminium hydroxide, the dioxygen containing DOPO phosphate flame retardant, phosphoric acid in oneself
Any one or a few in triphenylmethyl methacrylate, antimony oxide.
Wherein, the filler is one or more of calcium carbonate, clay, silicate or talcum powder.
Wherein, the antioxidant is anti-oxidant DLTP or TNP.
Wherein, the lubricant be stearic acid, stearate, polyvinyl chloride wax, paraffin or one kind in oleamide or
It is a variety of.
The present invention also provides a kind of fire-retardant plating HIPS of electronic apparatus shell, which is characterized in that including following step
Suddenly：
(1) each component is weighed by predetermined weight；
(2) HIPS, makrolon, nano-titanium dioxide, fire retardant, filler, antioxidant, lubricant are added at a high speed
In kneader, it is uniformly mixed material under the stirring action of high-speed kneading machine, in whipping process, mixed material is pinched with high speed
Conjunction machine inner wall frictional heat so that the temperature raising of mixed material, when the temperature of mixture material is increased to 70 DEG C, opening is pinched
Conjunction machine discharges；
(3) mixture is cooled to environment temperature, then feeds the mixture into electrothermal furnace and heated, mixtures is waited to melt
After melting, open electric furnace discharge valve, material is pipelined to mold forming production line, open mold feeding valve carry out into
Type；
(6) after being molded, mold is opened, taking-up is cooled to room temperature to get the fire-retardant plating of the electronic apparatus shell
HIPS。
Embodiment 2
A kind of fire-retardant plating HIPS of electronic apparatus shell, is made of following components in parts by weight：
Wherein, the degree of polymerization of the polycarbonate is 5000-7000.
Wherein, the grain size of the nano-titanium dioxide is 2nm.
Wherein, the fire retardant be magnesium hydroxide, aluminium hydroxide, the dioxygen containing DOPO phosphate flame retardant, phosphoric acid in oneself
Any one or a few in triphenylmethyl methacrylate, antimony oxide.
Wherein, the filler is one or more of calcium carbonate, clay, silicate or talcum powder.
Wherein, the antioxidant is anti-oxidant DLTP or TNP.
Wherein, the lubricant be stearic acid, stearate, polyvinyl chloride wax, paraffin or one kind in oleamide or
It is a variety of.
The present invention also provides a kind of fire-retardant plating HIPS of electronic apparatus shell, which is characterized in that including following step
Suddenly：
(1) each component is weighed by predetermined weight；
(2) HIPS, makrolon, nano-titanium dioxide, fire retardant, filler, antioxidant, lubricant are added at a high speed
In kneader, it is uniformly mixed material under the stirring action of high-speed kneading machine, in whipping process, mixed material is pinched with high speed
Conjunction machine inner wall frictional heat so that the temperature raising of mixed material, when the temperature of mixture material is increased to 60 DEG C, opening is pinched
Conjunction machine discharges；
(3) mixture is cooled to environment temperature, then feeds the mixture into electrothermal furnace and heated, mixtures is waited to melt
After melting, open electric furnace discharge valve, material is pipelined to mold forming production line, open mold feeding valve carry out into
Type；
(6) after being molded, mold is opened, taking-up is cooled to room temperature to get the fire-retardant plating of the electronic apparatus shell
HIPS。
Embodiment 3
A kind of fire-retardant plating HIPS of electronic apparatus shell, is made of following components in parts by weight：
Wherein, the degree of polymerization of the polycarbonate is 7000.
Wherein, the grain size of the nano-titanium dioxide is 10nm.
Wherein, the fire retardant be magnesium hydroxide, aluminium hydroxide, the dioxygen containing DOPO phosphate flame retardant, phosphoric acid in oneself
Any one or a few in triphenylmethyl methacrylate, antimony oxide.
Wherein, the filler is one or more of calcium carbonate, clay, silicate or talcum powder.
Wherein, the antioxidant is anti-oxidant DLTP or TNP.
Wherein, the lubricant be stearic acid, stearate, polyvinyl chloride wax, paraffin or one kind in oleamide or
It is a variety of.
The present invention also provides a kind of fire-retardant plating HIPS of electronic apparatus shell, which is characterized in that including following step
Suddenly：
(1) each component is weighed by predetermined weight；
(2) HIPS, makrolon, nano-titanium dioxide, fire retardant, filler, antioxidant, lubricant are added at a high speed
In kneader, it is uniformly mixed material under the stirring action of high-speed kneading machine, in whipping process, mixed material is pinched with high speed
Conjunction machine inner wall frictional heat so that the temperature raising of mixed material, when the temperature of mixture material is increased to 80 DEG C, opening is pinched
Conjunction machine discharges；
(3) mixture is cooled to environment temperature, then feeds the mixture into electrothermal furnace and heated, mixtures is waited to melt
After melting, open electric furnace discharge valve, material is pipelined to mold forming production line, open mold feeding valve carry out into
Type；
(6) after being molded, mold is opened, taking-up is cooled to room temperature to get the fire-retardant plating of the electronic apparatus shell
HIPS。
Comparative example 1
A kind of fire-retardant plating HIPS of electronic apparatus shell, as different from Example 1, which eliminates filling
Object is made of following components in parts by weight：
Wherein, the degree of polymerization of the polycarbonate is 6000.
Wherein, the grain size of the nano-titanium dioxide is 6nm.
Wherein, the fire retardant be magnesium hydroxide, aluminium hydroxide, the dioxygen containing DOPO phosphate flame retardant, phosphoric acid in oneself
Any one or a few in triphenylmethyl methacrylate, antimony oxide.
Wherein, the filler is one or more of calcium carbonate, clay, silicate or talcum powder.
Wherein, the antioxidant is anti-oxidant DLTP or TNP.
Wherein, the lubricant be stearic acid, stearate, polyvinyl chloride wax, paraffin or one kind in oleamide or
It is a variety of.
The present invention also provides a kind of fire-retardant plating HIPS of electronic apparatus shell, which is characterized in that including following step
Suddenly：
(1) each component is weighed by predetermined weight；
(2) HIPS, makrolon, nano-titanium dioxide, fire retardant, filler, antioxidant, lubricant are added at a high speed
In kneader, it is uniformly mixed material under the stirring action of high-speed kneading machine, in whipping process, mixed material is pinched with high speed
Conjunction machine inner wall frictional heat so that the temperature raising of mixed material, when the temperature of mixture material is increased to 70 DEG C, opening is pinched
Conjunction machine discharges；
(3) mixture is cooled to environment temperature, then feeds the mixture into electrothermal furnace and heated, mixtures is waited to melt
After melting, open electric furnace discharge valve, material is pipelined to mold forming production line, open mold feeding valve carry out into
Type；
(6) after being molded, mold is opened, taking-up is cooled to room temperature to get the fire-retardant plating of the electronic apparatus shell
HIPS。
Comparative example 2
A kind of fire-retardant plating HIPS of electronic apparatus shell, as different from Example 1, which eliminates poly- carbon
Acid esters is made of following components in parts by weight：
Wherein, the degree of polymerization of the polycarbonate is 6000.
Wherein, the grain size of the nano-titanium dioxide is 6nm.
Wherein, the fire retardant be magnesium hydroxide, aluminium hydroxide, the dioxygen containing DOPO phosphate flame retardant, phosphoric acid in oneself
Any one or a few in triphenylmethyl methacrylate, antimony oxide.
Wherein, the filler is one or more of calcium carbonate, clay, silicate or talcum powder.
Wherein, the antioxidant is anti-oxidant DLTP or TNP.
Wherein, the lubricant be stearic acid, stearate, polyvinyl chloride wax, paraffin or one kind in oleamide or
It is a variety of.
The present invention also provides a kind of fire-retardant plating HIPS of electronic apparatus shell, which is characterized in that including following step
Suddenly：
(1) each component is weighed by predetermined weight；
(2) HIPS, makrolon, nano-titanium dioxide, fire retardant, filler, antioxidant, lubricant are added at a high speed
In kneader, it is uniformly mixed material under the stirring action of high-speed kneading machine, in whipping process, mixed material is pinched with high speed
Conjunction machine inner wall frictional heat so that the temperature raising of mixed material, when the temperature of mixture material is increased to 70 DEG C, opening is pinched
Conjunction machine discharges；
(3) mixture is cooled to environment temperature, then feeds the mixture into electrothermal furnace and heated, mixtures is waited to melt
After melting, open electric furnace discharge valve, material is pipelined to mold forming production line, open mold feeding valve carry out into
Type；
(6) after being molded, mold is opened, taking-up is cooled to room temperature to get the fire-retardant plating of the electronic apparatus shell
HIPS。
Experimental example
Take fire-retardant plating HIPS and comparative example 1 made from embodiment 1-3, fire-retardant plating HIPS made from comparative example 2 into
Test in terms of row tensile strength, bending strength, anti-flammability and coating combination grade, specific test result are shown in Table 1：
1 the performance test results of table
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
| Tensile strength (MPa) | 48 | 45 | 50 | 41 | 38 |
| Bending strength (MPa) | 76 | 73 | 78 | 67 | 69 |
| Anti-flammability | 1 grade | 1 grade | 1 grade | 2 grades | 2 grades |
| Coating combination grade | 1 grade | 1 grade | 1 grade | 2 grades | 2 grades |
As shown in Table 1, tensile strength of the invention, bending strength, anti-flammability and coating combination grade are superior to comparative example,
Illustrate that the fire-retardant plating HIPS of the electronic apparatus shell of the present invention has more flame-retarding.
It is merely a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned implementation described in upper
The present invention is described in detail in example, for those skilled in the art, still can be to foregoing embodiments
Recorded technical solution modifies or carries out equivalent replacement to which part technical characteristic.All spirit in the present invention
Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Claims (9)
1. the fire-retardant plating HIPS of a kind of electronic apparatus shell, which is characterized in that be made of following components in parts by weight：
65-85 parts of HIPS
16-28 parts of makrolon
7-15 parts of nano-titanium dioxide
10-30 parts of fire retardant
1-5 parts of filler
0.3-0.8 parts of antioxidant
0.1-0.3 parts of lubricant.
2. the fire-retardant plating HIPS of a kind of electronic apparatus shell, which is characterized in that be made of following components in parts by weight：
70 parts of HIPS
22 parts of makrolon
11 parts of nano-titanium dioxide
20 parts of fire retardant
3 parts of filler
0.5 part of antioxidant
0.2 part of lubricant.
3. the fire-retardant plating HIPS of electronic apparatus shell according to claim 1, which is characterized in that the polycarbonate
The degree of polymerization be 5000-7000.
4. the fire-retardant plating HIPS of electronic apparatus shell according to claim 1, which is characterized in that the nano-silica
The grain size for changing titanium is 2-10nm.
5. the fire-retardant plating HIPS of electronic apparatus shell according to claim 1, which is characterized in that the fire retardant is
It is arbitrary in magnesium hydroxide, aluminium hydroxide, the dioxygen containing DOPO oneself interior phosphate flame retardant, triphenyl phosphate, antimony oxide
It is one or more of.
6. the fire-retardant plating HIPS of electronic apparatus shell according to claim 1, which is characterized in that the filler is
One or more of calcium carbonate, clay, silicate or talcum powder.
7. the fire-retardant plating HIPS of electronic apparatus shell according to claim 1, which is characterized in that the antioxidant is
Anti-oxidant DLTP or TNP.
8. the fire-retardant plating HIPS of electronic apparatus shell according to claim 1, which is characterized in that the lubricant is
It is one or more in stearic acid, stearate, polyvinyl chloride wax, paraffin or oleamide.
9. a kind of fire-retardant plating HIPS of electronic apparatus shell according to claim 1-8, which is characterized in that including with
Lower step：
（1）Each component is weighed by predetermined weight；
（2）HIPS, makrolon, nano-titanium dioxide, fire retardant, filler, antioxidant, lubricant are added to high-speed kneading
In machine, it is uniformly mixed material under the stirring action of high-speed kneading machine, in whipping process, mixed material and high-speed kneading machine
Inner wall frictional heat so that the temperature raising of mixed material, when the temperature of mixture material is increased to 60-80 DEG C, opening is pinched
Conjunction machine discharges；
（3）Mixture is cooled to environment temperature, then feeds the mixture into electrothermal furnace and is heated, mixtures is waited to melt
Afterwards, open electric furnace discharge valve, material is pipelined to mold forming production line, open mold feeding valve carry out into
Type；
(6) after being molded, mold is opened, takes out the fire-retardant plating HIPS being cooled to room temperature to get the electronic apparatus shell.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810117447.5A CN108219338A (en) | 2018-02-06 | 2018-02-06 | A kind of fire-retardant plating HIPS of electronic apparatus shell and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810117447.5A CN108219338A (en) | 2018-02-06 | 2018-02-06 | A kind of fire-retardant plating HIPS of electronic apparatus shell and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108219338A true CN108219338A (en) | 2018-06-29 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810117447.5A Withdrawn CN108219338A (en) | 2018-02-06 | 2018-02-06 | A kind of fire-retardant plating HIPS of electronic apparatus shell and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110421936A (en) * | 2019-07-25 | 2019-11-08 | 浙江路联装饰材料有限公司 | A kind of soft PVC flame retardant type foaming decoration leather and its processing method |
| CN113429771A (en) * | 2021-06-23 | 2021-09-24 | 安徽缤飞塑胶科技有限公司 | Strong acid corrosion resistant color master batch and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277410A (en) * | 2013-07-03 | 2015-01-14 | 合肥杰事杰新材料股份有限公司 | Preparation method of flame-retardant electroplating ABS for shell of electronic apparatus |
| CN106280291A (en) * | 2015-05-20 | 2017-01-04 | 深圳市联创科技集团有限公司 | Substitute PBS composite of electric appliance casing PP and preparation method thereof |
| CN107501834A (en) * | 2017-08-22 | 2017-12-22 | 合肥会通新材料有限公司 | A kind of electric appliance casing flame-retarding HIPS material of low smell, high glaze and high fluidity and preparation method thereof |
-
2018
- 2018-02-06 CN CN201810117447.5A patent/CN108219338A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277410A (en) * | 2013-07-03 | 2015-01-14 | 合肥杰事杰新材料股份有限公司 | Preparation method of flame-retardant electroplating ABS for shell of electronic apparatus |
| CN106280291A (en) * | 2015-05-20 | 2017-01-04 | 深圳市联创科技集团有限公司 | Substitute PBS composite of electric appliance casing PP and preparation method thereof |
| CN107501834A (en) * | 2017-08-22 | 2017-12-22 | 合肥会通新材料有限公司 | A kind of electric appliance casing flame-retarding HIPS material of low smell, high glaze and high fluidity and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110421936A (en) * | 2019-07-25 | 2019-11-08 | 浙江路联装饰材料有限公司 | A kind of soft PVC flame retardant type foaming decoration leather and its processing method |
| CN113429771A (en) * | 2021-06-23 | 2021-09-24 | 安徽缤飞塑胶科技有限公司 | Strong acid corrosion resistant color master batch and preparation method thereof |
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Application publication date: 20180629 |