CN108218073A - A kind of device and method of integration advanced treatment of landfill leachate - Google Patents
A kind of device and method of integration advanced treatment of landfill leachate Download PDFInfo
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Abstract
一种一体化深度处理垃圾渗滤液的装置及方法,属于污水处理领域。所述的一体化深度处理垃圾渗滤液的装置由氧化装置、混凝沉淀池及滤池组成,所述的氧化装置包括进水管道、加药口、管式反应器、低压汞灯,管式反应器为一组或并列的多组,设置于混凝沉淀池外或与混凝沉淀池设为一体;所述的混凝沉淀池包括混凝药剂投加口、搅拌装置、斜板或斜管、排泥口;所述的滤池内部为可替换抽取式的滤料或滤层。本发明的有益效果是:本发明以垃圾渗滤液的生化出水为原水,以“高级氧化工艺+混凝沉淀+过滤”的方式对垃圾渗滤液的生化出水进行深度处理,可使出水水质达到《生活垃圾填埋场污染控制标准》(GB 16889‑2008)的排放标准。
An integrated advanced treatment device and method for landfill leachate, belonging to the field of sewage treatment. The integrated device for advanced treatment of landfill leachate consists of an oxidation device, a coagulation sedimentation tank and a filter tank. The oxidation device includes a water inlet pipe, a dosing port, a tubular reactor, a low-pressure mercury lamp, and a tubular reactor. The reactor is one group or multiple groups in parallel, which are arranged outside the coagulation-settling tank or integrated with the coagulation-settling tank; Pipe, mud outlet; the inside of the filter is a replaceable extractable filter material or filter layer. The beneficial effects of the present invention are: the present invention uses the biochemical effluent of landfill leachate as raw water, and performs advanced treatment on the biochemical effluent of landfill leachate in the manner of "advanced oxidation process + coagulation sedimentation + filtration", so that the quality of the effluent water can reach << Discharge standards of the Pollution Control Standards for Domestic Waste Landfill Sites (GB 16889‑2008).
Description
技术领域technical field
本发明属于污水处理领域,具体涉及一种一体化深度处理垃圾渗滤液的装置及方法。The invention belongs to the field of sewage treatment, and in particular relates to an integrated advanced treatment device and method for landfill leachate.
背景技术Background technique
垃圾渗滤液的水质和水量的变化较大、成分较复杂、处理难度大且危害性大,其出水需达到《生活垃圾填埋场污染控制标准》(GB 16889-2008),若不能够妥善处理会对自然环境和人体健康造成极大的影响,对垃圾渗滤液的处理方式一般是经预处理后进行生化处理最终进行深度处理排放。The water quality and quantity of landfill leachate vary greatly, the composition is more complex, and the treatment is difficult and harmful. It will have a great impact on the natural environment and human health. The treatment of landfill leachate is generally pretreated, followed by biochemical treatment, and finally advanced treatment and discharge.
目前经常采用的深度处理技术为膜处理技术且以反渗透技术为主,其处理效果较好,设备较为成熟,但反应后产生的浓缩液会造成二次污染,且运行成本高,不宜应用在目前的深度处理方式中。At present, the advanced treatment technology often used is membrane treatment technology and mainly reverse osmosis technology. Its treatment effect is better and the equipment is relatively mature. However, the concentrated solution produced after the reaction will cause secondary pollution, and the operating cost is high, so it is not suitable for application in In the current depth processing method.
发明内容Contents of the invention
本发明是针对现有垃圾渗滤液处理方法成本较高、易造成二次污染的问题,提出一种一体化深度处理垃圾渗滤液的装置及方法,该装置及方法投资成本低廉、处理效果好、工艺简单。The present invention aims at the problem that the existing landfill leachate treatment method has high cost and is easy to cause secondary pollution, and proposes an integrated device and method for advanced treatment of landfill leachate. The device and method have low investment cost, good treatment effect, Simple process.
为实现上述目的,本发明采取的技术方案如下:In order to achieve the above object, the technical scheme that the present invention takes is as follows:
一种一体化深度处理垃圾渗滤液的装置,包括氧化装置、混凝沉淀池及滤池,所述的氧化装置包括进水管道、加药口、管式反应器及低压汞灯,所述的混凝沉淀池包括混凝沉淀池体、混凝药剂投加口、搅拌装置、排泥口及斜板或斜管;所述的滤池包括滤池体以及滤料或滤层;An integrated device for advanced treatment of landfill leachate, including an oxidation device, a coagulation sedimentation tank and a filter tank, the oxidation device includes a water inlet pipe, a dosing port, a tubular reactor and a low-pressure mercury lamp, and the The coagulation-sedimentation tank includes a coagulation-settling tank body, a coagulation agent dosing port, a stirring device, a mud discharge port, and an inclined plate or inclined pipe; the filter includes a filter body and a filter material or a filter layer;
所述的进水管道与管式反应器的一端连通,所述的管式反应器的另一端与混凝沉淀池体一端的进料口连接,所述的加药口设置于管式反应器的上部,所述的低压汞灯设置在管式反应器内部,所述的混凝沉淀池体的进料口下部设有混凝药剂投加口,混凝沉淀池体下部为倒圆锥形,混凝沉淀池体底部设置有排泥口,混凝沉淀池体另一端设有出料口,所述的出料口与滤池体连通,混凝沉淀池体内靠近进料口一侧设置有搅拌装置,混凝沉淀池体内靠近出料口一侧设置有斜板或斜管,所述的滤池体内设置有滤料或滤层。The water inlet pipe is communicated with one end of the tubular reactor, the other end of the tubular reactor is connected with the feeding port at one end of the coagulation sedimentation tank body, and the dosing port is set in the tubular reactor The upper part, the low-pressure mercury lamp is arranged inside the tubular reactor, the lower part of the feed port of the coagulation-settling tank body is provided with a coagulation agent dosing port, and the lower part of the coagulation-settling tank body is inverted conical, The bottom of the coagulation sedimentation tank body is provided with a mud outlet, and the other end of the coagulation sedimentation tank body is provided with a discharge port. The discharge port is connected with the filter body. Stirring device, the side of the coagulation sedimentation tank close to the discharge port is provided with a slant plate or inclined tube, and the filter material or filter layer is provided in the filter body.
一种利用上述的一体化深度处理垃圾渗滤液的装置进行垃圾渗滤液深度处理的方法,所述方法步骤如下:A method for advanced treatment of landfill leachate using the above-mentioned integrated device for advanced treatment of landfill leachate, the steps of the method are as follows:
步骤一:经过生化处理的垃圾渗滤液进入氧化装置,先经过加药口投加过硫酸盐、亚铁盐及络合剂,反应30 min,其中,过硫酸盐、亚铁盐及络合剂的质量比为25:2.5:1,三者总质量与垃圾渗滤液的COD质量比为20~30:1;Step 1: The biochemically treated landfill leachate enters the oxidation device, firstly add persulfate, ferrous salt and complexing agent through the dosing port, and react for 30 minutes. Among them, persulfate, ferrous salt and complexing agent The mass ratio of the three is 25:2.5:1, and the COD mass ratio of the total mass of the three to landfill leachate is 20~30:1;
步骤二:经氧化装置中的管道反应器处理后的垃圾渗滤液进入混凝沉淀池体内,通过混凝药剂投加口加入絮凝剂,在混凝沉淀池中混合均匀并静置沉淀;Step 2: The landfill leachate treated by the pipeline reactor in the oxidation device enters the coagulation sedimentation tank, and the flocculant is added through the coagulation agent injection port, mixed evenly in the coagulation sedimentation tank and left to settle;
步骤三:经混凝沉淀池的处理后进入滤池,通过滤料或滤层的吸附截留作用,去除污染物,最终出水水质达标排放。Step 3: After being treated in the coagulation sedimentation tank, it enters the filter tank, and the pollutants are removed through the adsorption and interception of the filter material or filter layer, and finally the effluent water quality meets the standard discharge.
一种一体化深度处理垃圾渗滤液的装置,包括氧化装置、混凝沉淀池及滤池,所述的氧化装置包括进水管道、加药口、管式反应器及低压汞灯,所述的混凝沉淀池包括混凝沉淀池体、混凝药剂投加口、搅拌装置、排泥口及斜板或斜管;所述的滤池包括滤池体以及滤料或滤层;An integrated device for advanced treatment of landfill leachate, including an oxidation device, a coagulation sedimentation tank and a filter tank, the oxidation device includes a water inlet pipe, a dosing port, a tubular reactor and a low-pressure mercury lamp, and the The coagulation-sedimentation tank includes a coagulation-settling tank body, a coagulation agent dosing port, a stirring device, a mud discharge port, and an inclined plate or inclined pipe; the filter includes a filter body and a filter material or a filter layer;
所述的管式反应器设置于混凝沉淀池体内的一端,所述的低压汞灯设置在管式反应器内部,所述的进水管道、加药口及混凝药剂投加口均与混凝沉淀池体所述的一端连通,且进水管道、加药口及混凝药剂投加口由上至下依次设置,所述的混凝沉淀池体的一端设置有搅拌装置,所述的搅拌装置的搅拌桨设置在混凝沉淀池体内,搅拌装置设置在混凝药剂投加口下部,所述的混凝沉淀池体下部为倒圆锥形,混凝沉淀池体底部设置有排泥口,混凝沉淀池体另一端设置有出料口,所述的出料口与滤池体连通,混凝沉淀池体内靠近出料口一侧设置有斜板或斜管,所述的滤池体内设置有滤料或滤层。The tubular reactor is arranged at one end of the coagulation-sedimentation tank body, the low-pressure mercury lamp is arranged inside the tubular reactor, and the water inlet pipe, the dosing port and the coagulation agent dosing port are all connected with each other. One end of the coagulation-sedimentation tank body is connected, and the water inlet pipe, the dosing port and the coagulation agent dosing port are arranged sequentially from top to bottom, and one end of the coagulation-sedimentation tank body is provided with a stirring device. The stirring paddle of the stirring device is arranged in the coagulation sedimentation tank body, the stirring device is arranged in the lower part of the coagulation agent dosing port, the lower part of the coagulation sedimentation tank body is inverted conical, and the bottom of the coagulation sedimentation tank body is provided with a mud discharge mouth, the other end of the coagulation sedimentation tank body is provided with a discharge port, the discharge port is connected with the filter body, and the side of the coagulation sedimentation tank body close to the discharge port is provided with a sloping plate or inclined tube, the filter A filter material or a filter layer is arranged in the pool body.
一种利用上述的一体化深度处理垃圾渗滤液的装置进行垃圾渗滤液深度处理的方法,所述方法步骤如下:A method for advanced treatment of landfill leachate using the above-mentioned integrated device for advanced treatment of landfill leachate, the steps of the method are as follows:
步骤一:经过生化处理的垃圾渗滤液进入氧化装置,先经过加药口投加过硫酸盐、亚铁盐及络合剂,反应30 min,其中,过硫酸盐、亚铁盐及络合剂的质量比为25:2.5:1,三者总质量与垃圾渗滤液的COD质量比为20~30:1;Step 1: The biochemically treated landfill leachate enters the oxidation device, firstly add persulfate, ferrous salt and complexing agent through the dosing port, and react for 30 minutes. Among them, persulfate, ferrous salt and complexing agent The mass ratio of the three is 25:2.5:1, and the COD mass ratio of the total mass of the three to landfill leachate is 20~30:1;
步骤二:经氧化装置中的管道反应器处理后的垃圾渗滤液进入混凝沉淀池体内,通过混凝药剂投加口加入絮凝剂,在混凝沉淀池中混合均匀并静置沉淀;Step 2: The landfill leachate treated by the pipeline reactor in the oxidation device enters the coagulation sedimentation tank, and the flocculant is added through the coagulation agent injection port, mixed evenly in the coagulation sedimentation tank and left to settle;
步骤三:经混凝沉淀池的处理后进入滤池,通过滤料或滤层的吸附截留作用,去除污染物,最终出水水质达标排放。Step 3: After being treated in the coagulation sedimentation tank, it enters the filter tank, and the pollutants are removed through the adsorption and interception of the filter material or filter layer, and finally the effluent water quality meets the standard discharge.
本发明相对于现有技术的有益效果是:本发明具有工艺简单、处理效果稳定、不存在二次污染、处理成本低廉的优点。以垃圾渗滤液的生化出水为原水,以“高级氧化工艺+混凝沉淀+过滤”的方式对垃圾渗滤液的生化出水进行深度处理,过硫酸盐高级氧化技术是一种新型高效的处理技术,该工艺处理效果较好、成本低廉,可使出水水质达到《生活垃圾填埋场污染控制标准》(GB 16889-2008)的排放标准。本发明中的内嵌式紫外灯管式反应器同时可以满足氧化反应和快速混合的要求。Compared with the prior art, the present invention has the advantages of simple process, stable treatment effect, no secondary pollution and low treatment cost. The biochemical effluent of landfill leachate is used as raw water, and the biochemical effluent of landfill leachate is subjected to advanced treatment in the way of "advanced oxidation process + coagulation sedimentation + filtration". Advanced persulfate oxidation technology is a new and efficient treatment technology. This process has good treatment effect and low cost, and can make the effluent water quality meet the discharge standard of "Pollution Control Standards for Domestic Garbage Landfill Sites" (GB 16889-2008). The embedded ultraviolet lamp tube reactor in the present invention can meet the requirements of oxidation reaction and rapid mixing at the same time.
附图说明Description of drawings
图1为本发明具体实施方式一的结构示意图;FIG. 1 is a schematic structural view of Embodiment 1 of the present invention;
图2为图1中管式反应器的剖面图;Fig. 2 is the sectional view of tubular reactor in Fig. 1;
图3为本发明具体实施方式四的结构示意图;Fig. 3 is a schematic structural view of Embodiment 4 of the present invention;
图4为图3中管式反应器的剖面图;Fig. 4 is the sectional view of tubular reactor among Fig. 3;
图中:1-进水管道、2-加药口、3-管式反应器、4-低压汞灯、5-混凝药剂投加口、6-搅拌装置、7-斜板或斜管、8-滤料、9-排泥口、10-滤层。In the figure: 1-water inlet pipe, 2-dosing port, 3-tubular reactor, 4-low pressure mercury lamp, 5-coagulant agent feeding port, 6-stirring device, 7-sloping plate or inclined tube, 8-filter material, 9-sludge outlet, 10-filter layer.
具体实施方式Detailed ways
下面结合附图和实施例对本发明的技术方案作进一步的说明,但并不局限于此,凡是对本发明技术方案进行修正或等同替换,而不脱离本发明技术方案的精神范围,均应涵盖在本发明的保护范围之中。The technical solution of the present invention will be further described below in conjunction with the accompanying drawings and embodiments, but it is not limited thereto. Any modification or equivalent replacement of the technical solution of the present invention without departing from the spirit of the technical solution of the present invention should be included in the scope of the present invention. Within the protection scope of the present invention.
本发明的原理是:通过亚铁盐强化紫外光活化过硫酸盐的高级氧化作用实现对垃圾渗滤液生化出水中部分污染物的直接去除,并且可以破坏难降解污染物的分子结构,提高废水的可生化性;然后在出水中加入絮凝剂,进入混凝沉淀池混匀并静置沉淀,去除废水中的有机物;最后利用滤池进一步去除污染物,确保最终出水的达标排放。The principle of the present invention is: the advanced oxidation of persulfate activated by ultraviolet light is strengthened by ferrous salt to realize the direct removal of some pollutants in the biochemical effluent of landfill leachate, and it can destroy the molecular structure of refractory pollutants and improve the efficiency of waste water. Biodegradability; then add flocculant to the effluent, enter the coagulation sedimentation tank for mixing and settling to remove the organic matter in the wastewater; finally use the filter to further remove pollutants to ensure the discharge of the final effluent.
具体实施方式一:本实施方式记载的是一种一体化深度处理垃圾渗滤液的装置,包括氧化装置、混凝沉淀池及滤池,如图1和图2所示,所述的氧化装置包括进水管道1、加药口2、管式反应器3及低压汞灯4,所述的混凝沉淀池包括混凝沉淀池体、混凝药剂投加口5、搅拌装置6、排泥口9及斜板或斜管7;所述的滤池包括滤池体以及滤料8或滤层10;Specific embodiment 1: This embodiment records an integrated device for advanced treatment of landfill leachate, including an oxidation device, a coagulation sedimentation tank and a filter tank, as shown in Figures 1 and 2, the oxidation device includes Water inlet pipe 1, dosing port 2, tubular reactor 3 and low-pressure mercury lamp 4, the coagulation sedimentation tank includes a coagulation sedimentation tank body, a coagulation agent dosing port 5, a stirring device 6, and a sludge discharge port 9 and an inclined plate or inclined pipe 7; the filter includes a filter body and a filter material 8 or a filter layer 10;
所述的进水管道1与管式反应器3的一端连通,所述的管式反应器3的另一端与混凝沉淀池体一端的进料口连接,所述的加药口2设置于管式反应器3的上部,所述的低压汞灯4设置在管式反应器3内部,所述的混凝沉淀池体的进料口下部设有混凝药剂投加口5,混凝沉淀池体下部为倒圆锥形,混凝沉淀池体底部设置有排泥口9,混凝沉淀池体另一端设有出料口,所述的出料口与滤池体连通,混凝沉淀池体内靠近进料口一侧设置有搅拌装置6,混凝沉淀池体内靠近出料口一侧设置有斜板或斜管7,所述的滤池体内设置有滤料8或滤层10。The water inlet pipe 1 is communicated with one end of the tubular reactor 3, the other end of the tubular reactor 3 is connected with the feed port at one end of the coagulation sedimentation tank body, and the dosing port 2 is arranged at The upper part of the tubular reactor 3, the low-pressure mercury lamp 4 is arranged inside the tubular reactor 3, and the lower part of the feed port of the coagulation-sedimentation tank body is provided with a coagulation agent dosing port 5, and the coagulation and sedimentation The lower part of the tank body is in an inverted conical shape, the bottom of the coagulation sedimentation tank body is provided with a mud discharge port 9, and the other end of the coagulation sedimentation tank body is provided with a discharge port, and the discharge port is connected with the filter tank body. A stirring device 6 is arranged on the side close to the feed inlet in the body, a slant plate or a slanted tube 7 is arranged on the side near the discharge outlet in the coagulation sedimentation tank body, and a filter material 8 or a filter layer 10 is arranged in the filter body.
上述为管式反应器3设置于混凝沉淀池体外部时的方案,管式反应器3为一组或并列设置的多组,设置于混凝沉淀池体外部。The above is the scheme when the tubular reactor 3 is arranged outside the coagulation-sedimentation tank body. The tubular reactor 3 is one group or multiple groups arranged in parallel, and is arranged outside the coagulation-settling tank body.
具体实施方式二:具体实施方式一所述的一种一体化深度处理垃圾渗滤液的装置,所述的管式反应器3材质为石英玻璃,所述的低压汞灯4波长为254nm,当污水流经时可进行氧化反应,同时利用管道边壁的边界层作用可以实现快速混合,提高反应速率。Specific embodiment two: a kind of integrated deep treatment landfill leachate device described in specific embodiment one, described tubular reactor 3 material is quartz glass, described low-pressure mercury lamp 4 wavelength is 254nm, when sewage Oxidation reaction can be carried out when flowing through, and the boundary layer effect of the side wall of the pipeline can be used to realize rapid mixing and increase the reaction rate.
具体实施方式三:具体实施方式二所述的一种一体化深度处理垃圾渗滤液的装置,所述的滤料8为无烟煤滤料或石英砂滤料,所述的滤层10为活性炭纤维毡。Specific embodiment three: a kind of integrated deep treatment landfill leachate device described in specific embodiment two, described filter material 8 is anthracite filter material or quartz sand filter material, described filter layer 10 is activated carbon fiber felt .
具体实施方式四:本实施方式记载的是一种一体化深度处理垃圾渗滤液的装置,包括氧化装置、混凝沉淀池及滤池,如图3和图4所示,所述的氧化装置包括进水管道1、加药口2、管式反应器3及低压汞灯4,所述的混凝沉淀池包括混凝沉淀池体、混凝药剂投加口5、搅拌装置6、排泥口9及斜板或斜管7;所述的滤池包括滤池体以及滤料8或滤层10;Specific Embodiment 4: This embodiment records an integrated device for advanced treatment of landfill leachate, including an oxidation device, a coagulation sedimentation tank and a filter tank, as shown in Figures 3 and 4, the oxidation device includes Water inlet pipe 1, dosing port 2, tubular reactor 3 and low-pressure mercury lamp 4, the coagulation sedimentation tank includes a coagulation sedimentation tank body, a coagulation agent dosing port 5, a stirring device 6, and a sludge discharge port 9 and an inclined plate or inclined pipe 7; the filter includes a filter body and a filter material 8 or a filter layer 10;
所述的管式反应器3设置于混凝沉淀池体内的一端,所述的低压汞灯4设置在管式反应器3内部,所述的进水管道1、加药口2及混凝药剂投加口5均与混凝沉淀池体所述的一端连通,且进水管道1、加药口2及混凝药剂投加口5由上至下依次设置,所述的混凝沉淀池体的一端设置有搅拌装置6,所述的搅拌装置6的搅拌桨设置在混凝沉淀池体内,搅拌装置6设置在混凝药剂投加口5下部,所述的混凝沉淀池体下部为倒圆锥形,混凝沉淀池体底部设置有排泥口9,混凝沉淀池体另一端设置有出料口,所述的出料口与滤池体连通,混凝沉淀池体内靠近出料口一侧设置有斜板或斜管7,所述的滤池体内设置有滤料8或滤层10。The tubular reactor 3 is arranged at one end of the coagulation sedimentation tank body, the low-pressure mercury lamp 4 is arranged inside the tubular reactor 3, the water inlet pipe 1, the dosing port 2 and the coagulation agent The dosing ports 5 are all connected to one end of the coagulation-sedimentation tank body, and the water inlet pipe 1, the dosing port 2 and the coagulation agent dosing port 5 are arranged sequentially from top to bottom, and the coagulation-sedimentation tank body A stirring device 6 is provided at one end of the stirring device 6, the stirring paddle of the stirring device 6 is arranged in the coagulation sedimentation tank body, the stirring device 6 is arranged at the lower part of the coagulation agent dosing port 5, and the lower part of the coagulation sedimentation tank body is an inverted Conical, the bottom of the coagulation sedimentation tank body is provided with a mud discharge port 9, and the other end of the coagulation sedimentation tank body is provided with a discharge port, the discharge port is connected with the filter body, and the coagulation sedimentation tank body is close to the discharge port One side is provided with a slant plate or a slanted pipe 7, and the filter material 8 or filter layer 10 is provided in the filter body.
上述为管式反应器3与混凝沉淀池体设为一体时的方案,管式反应器3为一组或并列设置的多组,并与混凝沉淀池体设为一体。The above is the scheme when the tubular reactor 3 and the coagulation-sedimentation tank body are integrated. The tubular reactor 3 is one group or multiple groups arranged in parallel, and is integrated with the coagulation-settling tank body.
具体实施方式五:具体实施方式四所述的一种一体化深度处理垃圾渗滤液的装置,所述的管式反应器3材质为石英玻璃,所述的低压汞灯4波长为254nm,当污水流经时可进行氧化反应,同时利用管道边壁的边界层作用可以实现快速混合,提高反应速率。Embodiment 5: A device for integrated advanced treatment of landfill leachate described in Embodiment 4, the material of the tubular reactor 3 is quartz glass, and the wavelength of the low-pressure mercury lamp 4 is 254nm. Oxidation reaction can be carried out when flowing through, and the boundary layer effect of the side wall of the pipeline can be used to realize rapid mixing and increase the reaction rate.
具体实施方式六:具体实施方式五所述的一种一体化深度处理垃圾渗滤液的装置,所述的滤料8为无烟煤滤料或石英砂滤料,所述的滤层10为活性炭纤维毡。Specific embodiment six: a kind of integrated deep treatment landfill leachate device described in specific embodiment five, described filter material 8 is anthracite filter material or quartz sand filter material, described filter layer 10 is activated carbon fiber felt .
具体实施方式七:一种利用具体实施方式一至三任一具体实施方式所述的一体化深度处理垃圾渗滤液的装置进行垃圾渗滤液深度处理的方法,所述方法步骤如下:Embodiment 7: A method for advanced treatment of landfill leachate using the device for advanced treatment of landfill leachate described in any one of Embodiments 1 to 3. The steps of the method are as follows:
步骤一:经过生化处理的垃圾渗滤液进入氧化装置,先经过加药口2投加过硫酸盐、亚铁盐及络合剂,反应30 min,络合物可强化紫外光活化过硫酸盐,产生硫酸根自由基,其氧化作用去除部分污染物,并提高废水的可生化性;其中,过硫酸盐、亚铁盐及络合剂的质量比为25:2.5:1,三者总质量与垃圾渗滤液的COD质量比为20~30:1;Step 1: The biochemically treated landfill leachate enters the oxidation device, firstly add persulfate, ferrous salt and complexing agent through the dosing port 2, and react for 30 minutes. The complex can strengthen the ultraviolet light activation of persulfate, Sulfate radicals are produced, and their oxidation removes some pollutants and improves the biodegradability of wastewater; among them, the mass ratio of persulfate, ferrous salt and complexing agent is 25:2.5:1, and the total mass of the three is the same as The COD mass ratio of landfill leachate is 20~30:1;
步骤二:经氧化装置中的管道反应器3处理后的垃圾渗滤液进入混凝沉淀池体内,通过混凝药剂投加口5加入絮凝剂,在混凝沉淀池中混合均匀并静置沉淀;Step 2: The landfill leachate treated by the pipeline reactor 3 in the oxidation device enters the coagulation sedimentation tank, and the flocculant is added through the coagulation agent dosing port 5, mixed evenly in the coagulation sedimentation tank and left to settle;
步骤三:经混凝沉淀池的处理后进入滤池,通过滤料8或滤层10的吸附截留作用,去除污染物,最终出水水质达标排放。Step 3: After being treated in the coagulation sedimentation tank, it enters the filter tank, and the pollutants are removed through the adsorption and interception of the filter material 8 or the filter layer 10, and finally the effluent water quality reaches the standard and is discharged.
具体实施方式八:具体实施方式七所述的一种一体化深度处理垃圾渗滤液的方法,步骤一中,所述的管式反应器内的pH控制在2~7之间;所述的过硫酸盐为过硫酸钾、过硫酸钠、过硫酸钾中的一种或几种;所述的亚铁盐为氯化亚铁,可以强化紫外光活化过硫酸盐,所述的络合剂为柠檬酸、EDTA或酒石酸,所述的络合剂与亚铁盐形成络合物,反应后的铁盐可减少后续混凝反应絮凝剂的用量,络合剂与亚铁盐的质量比为1:3~5;所述的絮凝剂为聚合氯化铝、聚合氯化铁或氯化铁,絮凝剂与待处理垃圾渗滤液的COD质量比为1:1~2。Embodiment 8: A method for integrated advanced treatment of landfill leachate described in Embodiment 7, in step 1, the pH in the tubular reactor is controlled between 2 and 7; Sulphate is one or more in potassium persulfate, sodium persulfate, potassium persulfate; described ferrous salt is ferrous chloride, which can strengthen ultraviolet light to activate persulfate, and described complexing agent is Citric acid, EDTA or tartaric acid, the complexing agent and ferrous salt form a complex, the reacted ferrous salt can reduce the amount of flocculant for subsequent coagulation reaction, and the mass ratio of complexing agent to ferrous salt is 1 : 3~5; the flocculant is polyaluminum chloride, polyferric chloride or ferric chloride, and the COD mass ratio of the flocculant to the landfill leachate to be treated is 1:1~2.
具体实施方式九:一种利用具体实施方式四至六任一具体实施方式所述的一体化深度处理垃圾渗滤液的装置进行垃圾渗滤液深度处理的方法,所述方法步骤如下:Embodiment 9: A method for advanced treatment of landfill leachate using the device for advanced treatment of landfill leachate described in any of Embodiments 4 to 6. The steps of the method are as follows:
步骤一:经过生化处理的垃圾渗滤液进入氧化装置,先经过加药口2投加过硫酸盐、亚铁盐及络合剂,反应30 min,络合物可强化紫外光活化过硫酸盐,产生硫酸根自由基,其氧化作用去除部分污染物,并提高废水的可生化性;其中,过硫酸盐、亚铁盐及络合剂的质量比为25:2.5:1,三者总质量与垃圾渗滤液的COD质量比为20~30:1;Step 1: The biochemically treated landfill leachate enters the oxidation device, firstly add persulfate, ferrous salt and complexing agent through the dosing port 2, and react for 30 minutes. The complex can strengthen the ultraviolet light activation of persulfate, Sulfate radicals are produced, and their oxidation removes some pollutants and improves the biodegradability of wastewater; among them, the mass ratio of persulfate, ferrous salt and complexing agent is 25:2.5:1, and the total mass of the three is the same as The COD mass ratio of landfill leachate is 20~30:1;
步骤二:经氧化装置中的管道反应器3处理后的垃圾渗滤液进入混凝沉淀池体内,通过混凝药剂投加口5加入絮凝剂,在混凝沉淀池中混合均匀并静置沉淀;Step 2: The landfill leachate treated by the pipeline reactor 3 in the oxidation device enters the coagulation sedimentation tank, and the flocculant is added through the coagulation agent dosing port 5, mixed evenly in the coagulation sedimentation tank and left to settle;
步骤三:经混凝沉淀池的处理后进入滤池,通过滤料8或滤层10的吸附截留作用,去除污染物,最终出水水质达标排放。Step 3: After being treated in the coagulation sedimentation tank, it enters the filter tank, and the pollutants are removed through the adsorption and interception of the filter material 8 or the filter layer 10, and finally the effluent water quality reaches the standard and is discharged.
具体实施方式十:具体实施方式九所述的一种一体化深度处理垃圾渗滤液的方法,步骤一中,所述的管式反应器内的pH控制在2~7之间;所述的过硫酸盐为过硫酸钾、过硫酸钠、过硫酸钾中的一种或几种;所述的亚铁盐为氯化亚铁,可以强化紫外光活化过硫酸盐,所述的络合剂为柠檬酸、EDTA或酒石酸,所述的络合剂与亚铁盐形成络合物,反应后的铁盐可减少后续混凝反应絮凝剂的用量,络合剂与亚铁盐的质量比为1:3~5;所述的絮凝剂为聚合氯化铝、聚合氯化铁或氯化铁,絮凝剂与待处理垃圾渗滤液的COD质量比为1:1~2。Embodiment 10: In Embodiment 9, a method for integrated advanced treatment of landfill leachate, in step 1, the pH in the tubular reactor is controlled between 2 and 7; Sulphate is one or more in potassium persulfate, sodium persulfate, potassium persulfate; described ferrous salt is ferrous chloride, which can strengthen ultraviolet light to activate persulfate, and described complexing agent is Citric acid, EDTA or tartaric acid, the complexing agent and ferrous salt form a complex, the reacted ferrous salt can reduce the amount of flocculant for subsequent coagulation reaction, and the mass ratio of complexing agent to ferrous salt is 1 : 3~5; the flocculant is polyaluminum chloride, polyferric chloride or ferric chloride, and the COD mass ratio of the flocculant to the landfill leachate to be treated is 1:1~2.
实施例1:Example 1:
经过生化反应的垃圾渗滤液出水COD值约为800mg/L,依次进行亚铁盐强化紫外光活化过硫酸盐的高级氧化处理、混凝沉淀处理、过滤处理,具体步骤如下:After the biochemical reaction, the COD value of the landfill leachate effluent is about 800mg/L, and the advanced oxidation treatment of ferrous salt-enhanced ultraviolet light-activated persulfate, coagulation and sedimentation treatment, and filtration treatment are carried out in sequence. The specific steps are as follows:
(1)亚铁酸盐强化紫外光活化过硫酸盐的高级氧化处理(1) Advanced oxidation treatment of ferrous acid-enhanced UV-activated persulfate
调节生化处理后的出水pH值在4左右,加入氧化剂过硫酸钾5~10g/L,氯化亚铁为5mmol/L,柠檬酸为1mmol/L,通过管式反应器5~10min,使其与废水混合均匀后,在高级氧化的主反应区,通过在波长为254nm的低压汞灯照射下,过硫酸盐产生硫酸根自由基,破坏难降解有机物的分子结构,提高废水的可生化性。Adjust the pH value of the effluent after biochemical treatment to about 4, add oxidant potassium persulfate 5~10g/L, ferrous chloride 5mmol/L, citric acid 1mmol/L, and pass through the tubular reactor for 5~10min to make it After being evenly mixed with wastewater, in the main reaction zone of advanced oxidation, under the irradiation of a low-pressure mercury lamp with a wavelength of 254nm, persulfate generates sulfate radicals, destroys the molecular structure of refractory organic matter, and improves the biodegradability of wastewater.
(2)混凝沉淀处理(2) Coagulation and sedimentation treatment
将经过高级氧化处理后的废水加入到混凝沉淀池,按照聚合氯化铁与待处理垃圾渗滤液的COD质量比为1:1向混凝池内投加,并加入助凝剂PAM,每吨水加入0.01kg,并通过搅拌装置,搅拌时间为5~8min,使其混合均匀,然后静置沉淀,沉淀设为斜板装置,混凝沉淀时间为2h。The wastewater after advanced oxidation treatment is added to the coagulation sedimentation tank, and the COD mass ratio of polyferric chloride to the landfill leachate to be treated is 1:1, and the coagulation aid PAM is added to the coagulation tank, per ton Add 0.01kg of water and pass it through the stirring device for 5-8 minutes to make it evenly mixed, then let it stand for sedimentation, and set the inclined plate device for sedimentation, and the coagulation and sedimentation time is 2 hours.
(3)过滤处理(3) Filtration treatment
经混凝沉淀后的出水加入到滤池中,滤池为可替换抽取滤料或滤层的滤池,该装置上层为无烟煤滤料、中层为石英砂滤料、底层为活性炭纤维毡,通过滤料的吸附和截留作用去除污染物,各部分由有机玻璃支撑。The effluent after coagulation and sedimentation is added to the filter tank. The filter tank is a filter tank that can replace the filter material or filter layer. The upper layer of the device is anthracite filter material, the middle layer is quartz sand filter material, and the bottom layer is activated carbon fiber felt. The adsorption and interception of the filter material removes pollutants, and each part is supported by plexiglass.
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