CN108164907A - It is a kind of to be used to make low temperature resistant weatherability HIPS/PE alloy materials of Plastic card and preparation method thereof - Google Patents
It is a kind of to be used to make low temperature resistant weatherability HIPS/PE alloy materials of Plastic card and preparation method thereof Download PDFInfo
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- CN108164907A CN108164907A CN201810049699.9A CN201810049699A CN108164907A CN 108164907 A CN108164907 A CN 108164907A CN 201810049699 A CN201810049699 A CN 201810049699A CN 108164907 A CN108164907 A CN 108164907A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
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- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card, raw material includes HIPS, PE, toughener, hollow glass micropearl, ultra-violet absorber, antioxidant, lubricant and color masterbatch, and each raw material weight score is as follows：HIPS52‑76；PE10‑18；Toughener 8 15；Hollow glass micropearl 5 10；Ultra-violet absorber 0.2 0.6；Antioxidant 0.1 0.2；Lubricant 0.2 2；Color masterbatch 13.The present invention is that solve conventional plastic snap-gauge with HIPS/PE alloy plastics raising weatherability and low-temperature impact-resistant with the performance of pure single plastic material, is greatly improved practicability and accomplishes the round-the-clock requirement of the more occasions in the more regions of multipurpose.
Description
Technical field
The invention belongs to plastic cement technical field of alloy material more particularly to a kind of for making the low temperature resistant resistance to of Plastic card
Time property HIPS/PE alloy materials and preparation method thereof.
Background technology
The snap-gauge industry in China is all growing at top speed year by year, since the difference foreign countries of development level have completed overall plastic or one
The turnover of secondary property snap-gauge, it is domestic or it is wooden with plastics snap-gauge and deposit and it is wooden occupy a large portion, also reason is exactly card
Plate standard is unsound and plastics snap-gauge of high cost or could not form complete industrial chain.With China's expanding economy and state
It is also the booming increasing for also having driven snap-gauge that the development import ＆ export quantity of border trade, which increases year by year in this trend subiculum operation industry,
Long demand fumigates propagation to reduce pest and disease damage since wood pallet inlet and outlet are required for thermophilic digestion or high temperature to add drug,
The developed country that foreign countries have clearly has forbidden wood pallet and this regulation also virtually increases cost and consume the time and
Plastics snap-gauge then can be directly used for importing and exporting without this requirement, therefore plastics snap-gauge had obtained significant progress and also attracted in recent years
The considerable talent begins one's study plastic clip board industry
Invention content
The present invention significantly improves the deficiency of conventional plastic snap-gauge, improves intensity and toughness, its static load is made to reach seven tons
It general requirment that dynamic load can meet industry up to two tons or more and good performance is also demonstrated by under low-temperature test uses temperature
Degree range also improves corrosion resistance at (- 30-+55) degree Celsius and round-the-clock can use.
Purpose to realize the present invention, the present invention provides following technical schemes：
A kind of low temperature resistant weatherability HIPS/PE alloy materials for being used to make Plastic card, raw material include HIPS, PE, toughening
Agent, hollow glass micropearl, ultra-violet absorber, antioxidant, lubricant and color masterbatch, each raw material weight score are as follows：
HIPS 52-76；
PE 10-18；
Toughener 8-15；
Hollow glass micropearl 5-10；
Ultra-violet absorber 0.2-0.6；
Antioxidant 0.1-0.2；
Lubricant 0.2-2；
Color masterbatch 1-3.
Preferably, the toughener include SBS, SIS, SEBS, POE, EPDM it is any one or more.
Preferably, the PE materials include LDPE and two kinds of HDPE, ratio of weight and number are：LDPE:HDPE=2-5:1.
Preferably, any one or two kinds of mixing of the high performance filled material for hollow glass micropearl and magnesium hydroxide.
Preferably, two kind mixing of the high performance filled material for hollow glass micropearl and magnesium hydroxide, ratio of weight and number
For：2-3：1.
Preferably, the antioxidant be 1010/1076/168 it is any or more.
Preferably, the lubricant is any or more of EBS, TAS-2A and calcium stearate.
Preferably, the weight ratio of the PE and hollow glass micropearl is 2：1.
A kind of preparation method for the low temperature resistant weatherability HIPS/PE alloy materials for being used to make Plastic card, including as follows
Step：
(1) above-mentioned HIPS, PE are weighed by proportioning, toughener, hollow glass micropearl, ultra-violet absorber, antioxidant, lubricant and
Color masterbatch；
(2) component is put into and 15~30min is mixed in high-speed mixer, obtain uniform mixture；
(3) mixture is subjected to melting extrusion granulation by three rank serial single-screw extruders, obtains claim 1-7
Any one of them is used to make the low temperature resistant weatherability HIPS/PE alloy material particles of Plastic card.
Beneficial effects of the present invention：
1. the present invention is that solve conventional plastic snap-gauge with HIPS/PE alloy plastics raising weatherability and low-temperature impact-resistant with pure
The performance of single plastic material is greatly improved practicability and accomplishes the round-the-clock requirement of the more occasions in the more regions of multipurpose.
2. HIPS of the present invention（High impact polystyrene）It is that a kind of plastics of high rigidity high intensity are equipped with as material of main part
PE（Polyethylene）Material, due to PE have good low temperature tolerance characteristics and chemical resistance again auxiliary instrument with toughener and ultra-violet absorber
It can be made through double-screw extruding pelletizing.There is the product high fluidity can meet large and medium-sized injection molding machine forming requirements, can also meet
Conventional plastic snap-gauge mold and moulding process.
3rd, the deficiency of conventional plastic snap-gauge is significantly improved, improves intensity and toughness, its static load is made to reach seven tons
It general requirment that dynamic load can meet industry up to two tons or more and good performance is also demonstrated by under low-temperature test uses temperature
Degree range also improves corrosion resistance at (- 30-+55) degree Celsius and round-the-clock can use.
Specific embodiment
In order to which the present invention is described in more detail, following preparating examples are provided.But the scope of the invention is not limited to this.
Embodiment 1
Preparation for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card includes the following steps：
(1) it weighs by weight：52 parts of HIPS, 18 parts of PE, 15 parts of toughener, 10 parts of hollow glass micropearls, 0.5 part of ultraviolet light are inhaled
Receive agent, 0.2 part of antioxidant, 2 parts of lubricants and 2.5 parts of color masterbatch；
(2) component is put into and 15~30min is mixed in high-speed mixer, obtain uniform mixture；
(3) mixture is subjected to melting extrusion granulation by three rank serial single-screw extruders, obtains the use of embodiment 1
In the low temperature resistant weatherability HIPS/PE alloy material particles for making Plastic card.
Embodiment 2
Preparation for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card includes the following steps：
1) it weighs by weight：58 parts of HIPS, 15 parts of PE, 13 parts of toughener, 9 parts of hollow glass micropearls, 0.6 part of ultraviolet radiation absorption
Agent, 0.2 part of antioxidant, 1.5 parts of lubricants and 2.7 parts of color masterbatch；
(2) component is put into and 15~30min is mixed in high-speed mixer, obtain uniform mixture；
(3) mixture is subjected to melting extrusion granulation by three rank serial single-screw extruders, obtains the use of embodiment 2
In the low temperature resistant weatherability HIPS/PE alloy material particles for making Plastic card.
Embodiment 3
Preparation for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card includes the following steps：
1) it weighs by weight：64 parts of HIPS, 13 parts of PE, 10 parts of toughener, 8 parts of hollow glass micropearls, 0.2 part of ultraviolet radiation absorption
Agent, 0.1 part of antioxidant, 1.7 parts of lubricants and 3 parts of color masterbatch；
(2) component is put into and 15~30min is mixed in high-speed mixer, obtain uniform mixture；
(3) mixture is subjected to melting extrusion granulation by three rank serial single-screw extruders, obtains the use of embodiment 3
In the low temperature resistant weatherability HIPS/PE alloy material particles for making Plastic card.
Embodiment 4
Preparation for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card includes the following steps：
1) it weighs by weight：70 parts of HIPS, 12 parts of PE, 8 parts of toughener, 7 parts of hollow glass micropearls, 0.3 part of ultraviolet radiation absorption
Agent, 0.1 part of antioxidant, 0.5 part of lubricant and 2.1 parts of color masterbatch；
(2) component is put into and 15~30min is mixed in high-speed mixer, obtain uniform mixture；
(3) mixture is subjected to melting extrusion granulation by three rank serial single-screw extruders, obtains the use of embodiment 4
In the low temperature resistant weatherability HIPS/PE alloy material particles for making Plastic card.
Embodiment 5
Preparation for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card includes the following steps：
1) it weighs by weight：75 parts of HIPS, 10 parts of PE, 8 parts of toughener, 5 parts of hollow glass micropearls, 0.2 part of ultraviolet radiation absorption
Agent, 0.1 part of antioxidant, 0.6 part of lubricant and 1.1 parts of color masterbatch；
(2) component is put into and 15~30min is mixed in high-speed mixer, obtain uniform mixture；
(3) mixture is subjected to melting extrusion granulation by three rank serial single-screw extruders, obtains the use of embodiment 5
In the low temperature resistant weatherability HIPS/PE alloy material particles for making Plastic card.
By above example 1-5 prepare for make the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card into
Row performance test, as a result such as following table
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to restrict the invention, any to be familiar with this field
Technical staff in the technical scope disclosed by the present invention, the change or replacement that can be readily occurred in, should all cover the present invention
Within protection domain.Therefore, protection scope of the present invention should be subject to the protection scope in claims.
Claims (8)
1. a kind of for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card, raw material includes HIPS, PE, increasing
Tough dose, hollow glass micropearl, ultra-violet absorber, antioxidant, lubricant and color masterbatch, each raw material weight score are as follows：
HIPS 52-76；
PE 10-18；
Toughener 8-15；
Hollow glass micropearl 5-10；
Ultra-violet absorber 0.2-0.6；
Antioxidant 0.1-0.2；
Lubricant 0.2-2；
Color masterbatch 1-3.
2. as described in claim 1 for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card, feature exists
In：The toughener include SBS, SIS, SEBS, POE, EPDM it is any one or more.
3. as described in claim 1 for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card, feature exists
In：The PE materials include LDPE and two kinds of HDPE, ratio of weight and number are：LDPE:HDPE=2-5:1.
4. as described in claim 1 for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card, feature exists
In：Any one or two kinds of mixing of the high performance filled material for hollow glass micropearl and magnesium hydroxide.
5. as described in claim 1 for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card, feature exists
In：The antioxidant be 1010/1076/168 it is any or more.
6. as described in claim 1 for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card, feature exists
In：The lubricant is any or more for EBS, TAS-2A and calcium stearate.
7. as described in claim 1 for making the low temperature resistant weatherability HIPS/PE alloy materials of Plastic card, feature exists
In：The weight ratio of the PE and hollow glass micropearl is 2：1.
8. a kind of preparation method for the low temperature resistant weatherability HIPS/PE alloy materials for being used to make Plastic card, it is characterised in that：
Include the following steps：
(1) above-mentioned HIPS, PE are weighed by proportioning, toughener, hollow glass micropearl, ultra-violet absorber, antioxidant, lubricant and
Color masterbatch；
(2) component is put into and 15~30min is mixed in high-speed mixer, obtain uniform mixture；
(3) mixture is subjected to melting extrusion granulation by three rank serial single-screw extruders, obtains claim 1-7
Any one of them is used to make the low temperature resistant weatherability HIPS/PE alloy material particles of Plastic card.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810049699.9A CN108164907A (en) | 2018-01-18 | 2018-01-18 | It is a kind of to be used to make low temperature resistant weatherability HIPS/PE alloy materials of Plastic card and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810049699.9A CN108164907A (en) | 2018-01-18 | 2018-01-18 | It is a kind of to be used to make low temperature resistant weatherability HIPS/PE alloy materials of Plastic card and preparation method thereof |
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| CN108164907A true CN108164907A (en) | 2018-06-15 |
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| CN201810049699.9A Pending CN108164907A (en) | 2018-01-18 | 2018-01-18 | It is a kind of to be used to make low temperature resistant weatherability HIPS/PE alloy materials of Plastic card and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109957201A (en) * | 2019-03-26 | 2019-07-02 | 江西固康新材料有限公司 | A kind of nanometer of high-ductility PS composite material and preparation method |
| WO2021094524A1 (en) | 2019-11-13 | 2021-05-20 | Anheuser-Busch Inbev S.A. | Use of a polymer composition, crate manufactured in such polymer composition and method of manufacturing such crate or pallet |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6008294A (en) * | 1991-12-20 | 1999-12-28 | The Dow Chemical Company | Thermoformable, chemical resistant polymer blends |
| CN104098865A (en) * | 2014-07-03 | 2014-10-15 | 合肥杰事杰新材料股份有限公司 | Polystyrene-polyethylene resin alloy material used for refrigerator inner container and preparation method thereof |
-
2018
- 2018-01-18 CN CN201810049699.9A patent/CN108164907A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6008294A (en) * | 1991-12-20 | 1999-12-28 | The Dow Chemical Company | Thermoformable, chemical resistant polymer blends |
| CN104098865A (en) * | 2014-07-03 | 2014-10-15 | 合肥杰事杰新材料股份有限公司 | Polystyrene-polyethylene resin alloy material used for refrigerator inner container and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109957201A (en) * | 2019-03-26 | 2019-07-02 | 江西固康新材料有限公司 | A kind of nanometer of high-ductility PS composite material and preparation method |
| CN109957201B (en) * | 2019-03-26 | 2021-12-14 | 江西固康新材料有限公司 | Nano high-toughness PS composite material and preparation method thereof |
| WO2021094524A1 (en) | 2019-11-13 | 2021-05-20 | Anheuser-Busch Inbev S.A. | Use of a polymer composition, crate manufactured in such polymer composition and method of manufacturing such crate or pallet |
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Application publication date: 20180615 |