CN108151358A - Cool and thermal power carbon sequestration alliance multipotency stream Regional Energy station based on regenerative resource driving - Google Patents

Cool and thermal power carbon sequestration alliance multipotency stream Regional Energy station based on regenerative resource driving Download PDF

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Publication number
CN108151358A
CN108151358A CN201711291423.3A CN201711291423A CN108151358A CN 108151358 A CN108151358 A CN 108151358A CN 201711291423 A CN201711291423 A CN 201711291423A CN 108151358 A CN108151358 A CN 108151358A
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China
Prior art keywords
solution pump
regenerative resource
energy station
regional energy
multipotency stream
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Granted
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CN201711291423.3A
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CN108151358B (en
Inventor
尹洪梅
王振宇
肖楚鹏
郑鑫
秦汉时
向洁
李俊
郭松
冯澎湃
赵军
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National Power Science Research Institute (wuhan) Energy Efficiency Test Co Ltd
Tianjin University
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National Power Science Research Institute (wuhan) Energy Efficiency Test Co Ltd
Tianjin University
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Publication of CN108151358A publication Critical patent/CN108151358A/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B27/00Machines, plants or systems, using particular sources of energy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D15/00Adaptations of machines or engines for special use; Combinations of engines with devices driven thereby
    • F01D15/10Adaptations for driving, or combinations with, electric generators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B15/00Sorption machines, plants or systems, operating continuously, e.g. absorption type
    • F25B15/02Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas
    • F25B15/04Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas the refrigerant being ammonia evaporated from aqueous solution
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B25/00Machines, plants or systems, using a combination of modes of operation covered by two or more of the groups F25B1/00 - F25B23/00
    • F25B25/02Compression-sorption machines, plants, or systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/08Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point using ejectors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

Abstract

The present invention discloses a kind of cool and thermal power carbon sequestration alliance multipotency stream Regional Energy station driven based on regenerative resource, including ammonia process CO2Trapping system, card Linne electricity generation system and ejector refrigeration system, the ammonia process CO2Trapping system and the card Linne electricity generation system couple a renewable heating system, and the renewable heating system photoelectricity drives the ammonia process CO2Each solution pump in trapping system and the card Linne electricity generation system, the renewable heating system further include:Thermal drivers are provided for the generator through energy distributors all the way, another way is input to heat supply end by energy distributors.The present invention can carry out the carbon sequestration of waste heat flue gas while waste heat flue gas UTILIZATION OF VESIDUAL HEAT IN is realized, while realize the trapping that heat energy utilization and carbon converge in waste heat flue gas.

Description

Cool and thermal power carbon sequestration alliance multipotency stream Regional Energy station based on regenerative resource driving
Technical field
The invention belongs to multi-cogeneration technology field, more particularly, it relates to which a kind of driven based on regenerative resource Cool and thermal power carbon sequestration alliance multipotency stream Regional Energy station.
Background technology
Energy-saving and emission-reduction are the important goals of current Energy restructuring, are the important measures that national economy develops in a healthy way.Such as What realizes that energy saving, emission reduction, energy cascade utilization become much-talked-about topic simultaneously.Regional Energy station based on carbon sequestration is multi-energy complementation An important measures.Chemical absorption process based on chemical absorbent, particularly using ammonia process titanium dioxide carbon-fixation-technology as representative Chemical absorption process become focus of attention.Renewable is a kind of regenerative resource being widely present, and ammonia process titanium dioxide is consolidated The absorption of carbon technique and resolving can realize the boosting of solvent gas just, and form the NH of high temperature and pressure3And CO2It is mixed Close steam.As can realizing the replacement of recoverable heat electric drive power generation cycle process working medium pump, then power generation process can be effectively reduced certainly Electricity consumption, while substitute the energy consumption during the carbon sequestration of part.Existing energy source station seldom considers the energy expenditure of pump, renewable conduct The electrically driven (operated) energy source station of heat can realize that the Regional Energy of cold electric heating carbon sequestration utilizes.
In recent years, middle low temperature double-work medium power generation cycle, the particularly development of card Linne power generation cycle are effectively improved double The generating efficiency of working medium circulation.Further, as can the complementary energy of the steam exhaust after power generation is further able to use for him, such as meet a large amount of Cooling load demand, then further improve energy source station sophistication.Therefore, the present invention is to occur and be absorbed as mistake substantially Journey, by NH3、H2O and CO2The thermophysical property of ternary working medium, organically by ammonia process CO2Trap energy source station, card Linne power generation energy Source station and spray type refrigerating energy source station, recoverable heat electric drive energy source station are coupled, and it is electrically driven (operated) to form a kind of recoverable heat Power generation, refrigeration, heat supply and carbon sequestration coupling energy source station, while power generation, refrigeration, heat supply and carbon sequestration process are realized, it effectively reduces The energy consumption of carbon sequestration process, energy source station have higher efficiency of energy utilization.
Invention content
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, propose a kind of based on the cold of regenerative resource driving Thermoelectricity carbon sequestration alliance multipotency stream Regional Energy station.
To solve technical problem mentioned above in the background art, the technical solution adopted by the present invention is:Based on renewable The cool and thermal power carbon sequestration alliance multipotency stream Regional Energy station of driven by energy, including ammonia process CO2Trapping system, card Linne electricity generation system and Ejector refrigeration system, the ammonia process CO2Trapping system shares generator, regenerator, third with the card Linne electricity generation system Solution pump, second throttle and absorber, the card Linne electricity generation system and the ejector refrigeration system share injector and Condenser, the ammonia process CO2Trapping system and the card Linne electricity generation system couple a renewable heating system, described renewable Heating system photoelectricity drives the ammonia process CO2Each solution pump in trapping system and the card Linne electricity generation system;It is described can be again Raw heating system further includes:Generator described in thermal drivers, another way are input to heat supply end all the way.
The renewable heating system photoelectricity driving is generated by regenerative resource by photovoltaic power generation equipment.
Thermal drivers generator is through heat collector and the energy using the regenerative resource to the renewable heating system all the way Distributor inputs, and the generator opposite side is provided with conveying high concentration CO2The regenerative resource outlet of flue gas is connected to institute State ammonia process CO2Trapping system.
The ammonia process CO2Trapping system includes the absorption tower being sequentially connected with pipeline, the first solution pump, generator, backheat Device, second throttle, absorber and the second solution pump, are connected with third solution pump between the regenerator and absorber;
First solution pump, the second solution pump and third solution pump pass through photovoltaic power generation equipment by regenerative resource Electrical energy drive is provided.
The preferred solar energy of regenerative resource.
The side line on the absorption tower is provided with low concentration CO2Smoke outlet tube, the low concentration CO2Smoke outlet tube is through more Grade compression cooling device is delivered to carbon sequestration mothballed plant.
The card Linne electricity generation system include the generator being sequentially connected with pipeline, two-phase expanding machine, T-shaped pipe separator, Injector, condenser, absorber, third solution pump, regenerator, the two-phase expanding machine are connected with generator, the T-shaped pipe point From being provided with high-purity CO on device2Exhanst gas outlet.
The ejector refrigeration system includes the injector, condenser, first throttle valve and the evaporation that are sequentially connected with pipeline Device.
The evaporator is used to cool down.
The renewable heating system another way is input to heat supply end through heat collector, energy distributors and heat exchanger.This hair Bright advantageous effect:
1st, the renewable power generation of framework of the present invention one, heat supply driving energy source station and NH3Alliance for basic working medium Energy source station, energy source station have higher efficiency of energy utilization, effectively reduce the energy consumption problem of carbon sequestration trapping process, realize simultaneously Power generation, refrigeration, heat supply and carbon sequestration process.While waste heat flue gas UTILIZATION OF VESIDUAL HEAT IN is realized, the carbon of waste heat flue gas can be carried out It seals up for safekeeping, while realizes the trapping that heat energy utilization and carbon converge in waste heat flue gas.
2nd, the present invention suits " 13 " period energy development utilization strategy, actively and prudently Hydropower Development, comprehensive coordinate The exploitation of wind-powered electricity generation is promoted, pushes the diversification utilization of solar energy, adaptation to local conditions ground Bio-energy Development accelerates geothermal energy development profit With, while promote power generation with marine energy Demonstration Application.Try to explore carbon sequestration skill on the basis of fully rationally using regenerative resource Art, to convert and fixing the CO larger to greenhouse effects contribution function2Research lay the foundation.
Description of the drawings
Fig. 1 is the structural diagram of the present invention.
Reference numeral:1- absorption towers, 2-the first solution pumps, 3- generators, 4- two-phase expanding machines, 5- generators, 6-T type pipes Separator, 7- injectors, 8- condensers, 9- evaporators, 10- first throttle valves, 11- absorbers, the second solution pumps of 12-, 13- are returned Hot device, 14- third solution pumps, 15- second throttle, 16- energy distributors, 17- regenerative resource outlets, 18- low concentrations CO2Smoke outlet tube, 19- high-purity COs2Exhanst gas outlet, 20- heat exchangers, 21- heat supply ends, 22- multi-stage compression cooling devices, 23- Carbon sequestration mothballed plant, 24- photovoltaic power generation equipments, 25- regenerative resources, 26- heat collectors.
Specific embodiment
Below by specific embodiments and the drawings, the present invention is further illustrated.The embodiment of the present invention is in order to more Those skilled in the art is made to more fully understand the present invention well, any limitation is not made to the present invention.
Fig. 1 is flow diagram of the present invention, and the present invention is based on the cool and thermal power carbon sequestration alliance multipotency streams of regenerative resource driving Regional Energy station is absorption and resolving based on ammonia spirit, to generate electricity, freezing, heat supply and carbon sequestration trapping coupled system, Including ammonia process CO2Trapping system, card Linne electricity generation system and ejector refrigeration system and renewable heating system, it is described can be again Raw heating system photoelectricity drives the ammonia process CO2Each solution pump in trapping system and the card Linne electricity generation system, this implementation The example renewable heating system photoelectricity driving is not limited to solar energy, wind energy, waterpower, biomass energy, originally by regenerative resource 25 25 preferred solar energy of embodiment regenerative resource, produces electricl energy by photovoltaic power generation equipment 24, drives the ammonia process CO2Trapping system First solution pump 2, the second solution pump 12 and third solution pump 14 in system and the card Linne electricity generation system;It is described can Breed-in system further includes:Generator 3 described in thermal drivers, another way are input to heat supply end 21 all the way;The present embodiment thermal drivers Generator 3 is through 16 input generator 3 of heat collector 26 and energy distributors, the generator 3 using the regenerative resource 25 Opposite side is provided with conveying high concentration CO2The regenerative resource outlet 17 of flue gas is connected to the ammonia process CO2Trapping system.
The ammonia process CO2Trapping system is included the absorption tower 1 being sequentially connected with pipeline, the first solution pump 2, generator 3, returned Hot device 13, second throttle 15, absorber 11, the second solution pump 12 are connected between the regenerator 13 and absorber 11 Three solution pumps 14;
First solution pump 2, the second solution pump 12 and third solution pump 14 pass through photovoltaic by regenerative resource 25 Generating equipment 24 provides electrical energy drive.
The side line on the absorption tower 1 is provided with low concentration CO2Smoke outlet tube 18, the low concentration CO2Smoke outlet tube 18 Carbon sequestration mothballed plant 23 is delivered to through multi-stage compression cooling device 22;
The card Linne electricity generation system includes the generator 3, two-phase expanding machine 4, the T-shaped pipe separator that are sequentially connected with pipeline 6th, injector 7, condenser 8, absorber 11, third solution pump 14, regenerator 13, the two-phase expanding machine 4 are connected with generator 5, high-purity CO is provided on the T-shaped pipe separator 62Exhanst gas outlet 19;
As it can be seen that ammonia process CO2Trapping system and card Linne electricity generation system realize generator 3, regenerator 13, third solution pump 14th, second throttle 15, absorber 11 share.
The ejector refrigeration system is included the injector 7 being sequentially connected with pipeline, condenser 8, first throttle valve 10, steamed Device 9 is sent out, the evaporator 9 is used to cool down;
As it can be seen that card Linne electricity generation system and ejector refrigeration system realize injector 7, condenser 8 share.
It is molten that the renewable heating system includes regenerative resource 25, photovoltaic power generation equipment 24, the first solution pump 2, second Liquid pump 12, third solution pump 14, heat collector 26, energy distributors 16, heat exchanger 20, heat supply end 21;
It can be seen that renewable heating system and ammonia process CO2Trapping system realize the first solution pump pump the 2, second solution pump 12, Third solution pump 14 shares.
The course of work of the present invention is as follows:
Regenerative resource 25, by photovoltaic power generation equipment 24, the first solution pump 2 of supply, the second solution pump 12 pass through thermal-arrest Device 26 is divided into two-way by energy distributors 16, all the way into generator 3 and after driving generator 3, cools down as lower temperature High concentration CO2Flue gas is introduced the side on absorption tower 1 by regenerative resource outlet 17, is absorbed by ammonia spirit in absorption tower 1 high Concentration C O2CO in flue gas2Afterwards, become low concentration CO2Flue gas from the low concentration CO of absorption tower 1_218 row of smoke outlet tube Go out;Another way heat source exports heat source supply heat supply end 21 by heat exchanger 20;Absorb CO2Ammonia spirit through the first solution pump 2 Generator 3 is transported to, generator 3 absorbs parsing after regenerative resource 25 is exported to the heat of heat collector 26 and goes out high temperature and pressure NH3And CO2Mixed vapour, NH3And CO2Entering expansion work in two-phase expanding machine 4 after mixed vapour drives generator 5 to export electricity Energy;Lack of gas after acting enter T-shaped pipe separator 6, and mixed vapour is after separation, CO therein2Through high-purity CO2Exhanst gas outlet 19 discharges form the CO of elevated pressures2Pure matter gas.At this point, complete the carbon sequestration trapping of flue gas and cogeneration cycle.
The higher NH of residual compression3Lack of gas enter in injector 7, the decompressing speed-increasing in 7 nozzle of injector, by evaporator 9 In the gas injection of sender property outlet to injector 7, the two mixing chamber mixing diffusion to refrigeration cycle condensing pressure, with laggard Enter in condenser 8 and condense to liquid;The liquid refrigerant part come out from condenser 8 enters the decompression of first throttle valve 10 and returns to steaming It sends out in device 9, so as to fulfill refrigeration cycle, another part then enters in absorber 11, continues carbon sequestration trapping and power generation cycle;
Wherein, it is laggard to be sent into regenerator 13 after the boosting of third solution pump 14 for the ammonium hydroxide concentrated solution part in absorber 11 Enter generator 3, another part enters the CO absorbed in absorption tower 1 in flue gas after the boosting of the second solution pump 122It is molten by first Liquid pump 2 is boosted in generator 3, in generator 3, a part of dense dense CO of ammonia2The heat that solution absorbs regenerative resource 25 adds Heat is extremely boiled, the high temperature and pressure NH of generation3With CO2Mixed vapour enters two-phase expanding machine 4, a part of dense dense CO of ammonia2Solution warp can Renewable sources of energy outlet 17 enters absorption tower 1, by low concentration CO2Smoke outlet tube 18 enters CO2The multi-stage compression cooling of gas Device 22 is compressed into liquid, into carbon sequestration mothballed plant 23;Ammonium hydroxide weak solution in the generator 3 enters in regenerator 13, With from the absorber 11 ammonium hydroxide concentrated solution carry out heat exchange, after after second throttle 15 enter absorber 11.
It should be understood that embodiment and example discussed herein simply to illustrate that, to those skilled in the art For, it can be improved or converted, and all these modifications and variations should all belong to the protection of appended claims of the present invention Range.

Claims (10)

1. based on the cool and thermal power carbon sequestration alliance multipotency stream Regional Energy station of regenerative resource driving, including ammonia process CO2Trapping system, Card Linne electricity generation system and ejector refrigeration system, the ammonia process CO2Trapping system shares hair with the card Linne electricity generation system Raw device (3), regenerator (13), third solution pump (14), second throttle (15) and absorber (11), the card Linne power generation system System shares injector (7) and condenser (8) with the ejector refrigeration system, which is characterized in that the ammonia process CO2Trapping system A renewable heating system is coupled with the card Linne electricity generation system, the renewable heating system photoelectricity drives the ammonia process CO2Each solution pump in trapping system and the card Linne electricity generation system;The renewable heating system further includes:Heat is driven all the way The generator (3) is moved, another way is input to heat supply end (21).
2. multipotency stream Regional Energy station according to claim 1, it is characterised in that:The renewable heating system photoelectricity drives It is dynamic to be generated by regenerative resource (25) by photovoltaic power generation equipment (24).
3. multipotency stream Regional Energy station according to claim 1, it is characterised in that:The renewable heating system is hot all the way Driving generator (3) is to be inputted using the regenerative resource (25) through heat collector (26) and energy distributors (16), the hair Raw device (3) opposite side is provided with conveying high concentration CO2The regenerative resource outlet (17) of flue gas is connected to the ammonia process CO2It catches Collecting system.
4. multipotency stream Regional Energy station according to claim 1, it is characterised in that:The ammonia process CO2Trapping system include with Absorption tower (1) that pipeline is sequentially connected, generator (3), regenerator (13), second throttle (15), is inhaled at the first solution pump (2) Device (11) and the second solution pump (12) are received, third solution pump is connected between the regenerator (13) and absorber (11) (14);
First solution pump (2), the second solution pump (12) and third solution pump (14) are passed through by regenerative resource (25) Photovoltaic power generation equipment (24) provides electrical energy drive.
5. the multipotency stream Regional Energy station according to claim 2,3 or 4, it is characterised in that:The regenerative resource (25) It is preferred that solar energy.
6. multipotency stream Regional Energy station according to claim 4, it is characterised in that:The side line setting of the absorption tower (1) There is low concentration CO2Smoke outlet tube (18), the low concentration CO2Smoke outlet tube (18) is defeated through multi-stage compression cooling device (22) It send to carbon sequestration mothballed plant (23).
7. multipotency stream Regional Energy station according to claim 1, it is characterised in that:The card Linne electricity generation system include with Generator (3) that pipeline is sequentially connected, T-shaped pipe separator (6), injector (7), condenser (8), absorbs two-phase expanding machine (4) Device (11), third solution pump (14), regenerator (13), the two-phase expanding machine (4) are connected with generator (5), the T-shaped pipe point From being provided with high-purity CO on device (6)2Exhanst gas outlet (19).
8. multipotency stream Regional Energy station according to claim 1, it is characterised in that:The ejector refrigeration system include with Injector (7), condenser (8), first throttle valve (10) and the evaporator (9) that pipeline is sequentially connected.
9. multipotency stream Regional Energy station according to claim 8, it is characterised in that:The evaporator (9) is for cooling down.
10. multipotency stream Regional Energy station according to claim 1, it is characterised in that:The renewable heating system is another Road is input to heat supply end (21) through heat collector (26), energy distributors (16) and heat exchanger (20).
CN201711291423.3A 2017-12-08 2017-12-08 Renewable energy source drive-based combined cooling, heating, power and solid carbon supply multi-energy flow area energy station Active CN108151358B (en)

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CN113701380A (en) * 2021-07-05 2021-11-26 中国科学院理化技术研究所 CO2 multi-energy complementary distributed energy station based on supersonic speed rotational flow two-phase expansion system

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