CN108051375A - The method that high light spectrum image-forming technology monitors marine sediment section content of material in real time - Google Patents

The method that high light spectrum image-forming technology monitors marine sediment section content of material in real time Download PDF

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Publication number
CN108051375A
CN108051375A CN201711290268.3A CN201711290268A CN108051375A CN 108051375 A CN108051375 A CN 108051375A CN 201711290268 A CN201711290268 A CN 201711290268A CN 108051375 A CN108051375 A CN 108051375A
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content
spectrum image
real time
sediment
high light
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李雪莹
范萍萍
吕美蓉
石小梅
张颖
王茜
刘岩
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Oceanographic Instrumentation Research Institute Shandong Academy of Sciences
Institute of Oceanographic Instrumentation Shandong Academy of Sciences
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Oceanographic Instrumentation Research Institute Shandong Academy of Sciences
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

The invention belongs to measure content of material technical field by spectral quality, a kind of method that high light spectrum image-forming technology monitors marine sediment section content of material in real time is disclosed, step is:1) sample cross-section high spectrum image is obtained, reads high-spectral data into computer;2) space is carried out to image and cuts out and extract effective color according to the demand of monitoring deposit different material content in a computer;3) Pretreated spectra and extraction characteristic wavelength carry out high-spectral data according to the demand of monitoring deposit different material content in a computer;4) according to the demand of monitoring deposit different material content, the spectrum substitution of each pixel of high spectrum image is had been established in model, obtains the prediction result of each content of material of the sediment sample in real time.The present invention is based on high light spectrum image-forming technology, one-shot measurement is realized, while obtain content of the different depth deposit containing different material, it is simple, convenient, quickly each content of material of different depth deposit is measured in real time.

Description

The method that high light spectrum image-forming technology monitors marine sediment section content of material in real time
Technical field
The present invention relates to measure content of material technical field by spectral quality, and in particular to high light spectrum image-forming technology is real-time The method for monitoring marine sediment section content of material.
Background technology
Marine sediment is that have the mineral of heterogeneity and source or the detrital material of biology by marine bottom accumulation, Marine sediment also has the coating of maximum area on the earth simultaneously, therefore marine sediment is constituted in terrestrial space covering The maximum single ecosystem, there is critical role in Global Biogeochemical Cycle.Marine sediment is by the mankind at present The influence of activity is increasing, and marine sediment is once polluted, it will causes the deterioration of the ecological environment, threatens benthon Existence, so as to cause serious marine eco-environment problem.Therefore the content of each substance of marine sediment is monitored in real time to understanding The basic condition in the marine site, the generation for preventing ecological problem, the pollution improved the ecological environment in time, reduce marine sediment play Important role.
At present, chemical method is mainly used for the measurement of each content of material of deposit, different substances will use difference Chemical measurement method, and this method needs complicated pre-treatment, and it is longer to obtain the data cycle, takes time and effort, it is impossible to prison in real time Survey the variation of each content of material of deposit.Therefore it provides it is a kind of it is simple, quick and easily measuring method is necessary.
The content of the invention
The present invention is in order to solve the above technical problems, propose that one kind is simple, quick and easily high light spectrum image-forming technology is real-time The method for monitoring marine sediment section content of material, is achieved using following technical scheme.
The method that high light spectrum image-forming technology monitors marine sediment section content of material in real time, step are as follows:
(1) its section high spectrum image is obtained to the sediment sample just gathered, high-spectral data is read, data is passed to calculating In machine.The sediment sample of acquisition is hemipelagic sediment or neritic sediment or halmeic deposit, according to sediment depth need Shoot high spectrum image.
(2) in a computer, according to the demand of monitoring deposit different material content, space is carried out to high spectrum image and is cut It cuts out, chooses the high spectrum image of the useful space, that is, the extraneous background of high spectrum image is removed, including removing effective high spectrum image Extraneous background and solve the problems, such as anamorphose.Space sanction is carried out to image using mahalanobis distance method, minimum distance method scheduling algorithm It cuts.
(3) in a computer, according to the demand of monitoring deposit different material content, have to high spectrum image RGB extractions It imitates information and carries out image segmentation, the later stage is predicted in favor of eliminating the irrelevant factors such as the grains of sand and biology in deposit high spectrum image As a result influence.Image segmentation is carried out to extracting effective color using fractional spins, mean shift segmentation algorithm scheduling algorithm.
(4) in a computer, according to the demand of monitoring deposit different material content, it is pre- that spectrum is carried out to high-spectral data Processing.Pretreated spectra is included without pretreatment, spectrum area's selection, smooth derivation, SNV, MSC, normalization scheduling algorithm.
(5) in a computer, according to the demand of monitoring deposit different material content, high-spectral data is selected different Characteristic wave bands.Characteristic wave bands selection is included using successive projection algorithm(SPA), without information variable elimination algorithm(UVE), heredity calculate Method(GA)Method scheduling algorithm.
(6) in a computer, according to the demand of monitoring deposit different material content, by each pixel of high spectrum image The spectrum substitution of point is had been established in model, if the sediment sample to be measured of acquisition and the sample that model has been established are same position, It can then be directly substituted into the model;If the sediment sample to be measured of acquisition and the sample of model has been established not in same position, It after first carrying out Model transfer to sediment sample to be measured, then substitutes into the model, obtains the sediment sample different depth in real time Each content of material prediction result.
It is by gathering several sediment samples, and to the change of its measure spectrum data and required substance that model, which has been established, Value, by 2:Sediment sample is divided into modeling collection and inspection set by 1 ratio, using Partial Least Squares to the light of modeling collection sample Modal data and chemical score establish corresponding model, and carry out forecast test to the model of foundation with inspection set, if the model modeling collection R2 is satisfied by with inspection set absolute coefficient>0.8, and meet relation analysis error RPD values>1.5, then the model can be used as it is above-mentioned There is model.
Model transfer using segmentation directly correction by sediment sample spectroscopic data to be measured by combining linear interpolation(PDS- LI), segmentation directly correction is with reference to slope/intercept revised law(PDS -S/B)Scheduling algorithm is converted, and obtains transformed data.
Prediction result shows that a kind of content for each point of the inverting deposit is shown respectively with diagram form in two forms Show the distribution of core sediments each content of material, another kind be the prediction content for each putting core sediments in table form Display.
In above step, deposit different material content includes total phosphorus, total nitrogen, copper, mercury equal size.
The technical program is based on high light spectrum image-forming technology, monitors each content of material of marine sediment section in real time.Spectrum skill Art can quickly, accurately, in real time carry out each content of material of deposit pre- while can characterize different material information It surveys.High light spectrum image-forming technology not only has the advantages that spectral technique analysis, additionally it is possible to get image, to the section of deposit into Row analysis, the content of each substance of different depth deposit can be obtained by one-shot measurement simultaneously, simpler, quick, convenient Realization each content of material of different depth deposit real-time measurement, in real time obtain the multiple points of each substance of deposit content.With The prior art is compared, and this method reduces the time of deposit content of material measurement while ensure that measurement result, saves people Power material resources.
Description of the drawings
Fig. 1:High light spectrum image-forming technology monitors the method flow diagram of marine sediment section content of material in real time;
Fig. 2:Embodiment core sediments TC(Total charcoal)Content distribution;
Fig. 3:Embodiment core sediments TN(Total nitrogen)Content distribution;
Fig. 4:Embodiment TC(Total charcoal)Content measured value and predicted value comparison diagram;
Fig. 5:Embodiment TN(Total nitrogen)Content measured value and predicted value comparison diagram.
Specific embodiment
With reference to attached drawing 1-5, technical scheme is described in further detail:
The method that high light spectrum image-forming technology monitors marine sediment section content of material in real time, to predict that a certain regional deposit is total Charcoal(TC), total nitrogen(TN)Exemplified by, step is as follows:
(1) high spectrum image is obtained
Its section high spectrum image is obtained to Qingdao somewhere sediment sample, high-spectral data is read, data is passed to computer In.
(2) graphical analysis
In a computer, according to monitoring deposit different material content demand, using mahalanobis distance method to high spectrum image into Row space is cut out, and chooses the high spectrum image of the useful space, that is, removes the extraneous background of high spectrum image, effectively high including removing The problems such as extraneous background of spectrum picture and solution anamorphose.High spectrum image RGB is extracted using fractional spins Effective information carries out image segmentation, pre- to the later stage in favor of eliminating the irrelevant factors such as the grains of sand and biology in deposit high spectrum image Surveying result influences.
(3) spectrum analysis
In a computer, according to the demand of monitoring deposit different material content, spectrum Spectral range is 226-974nm, feature Wave band chooses all band.
(4) differentiate sample to be tested whether with model sample has been established as the same area
Through differentiating, sample to be tested is with having been established model sample as the same area.
(5) substitute into and have in model, obtain prediction result
By treated, spectrum substitutes into established model(TC models, TN models)In, sample and the sample to be tested of the model exist The same area, therefore Model transfer is not required.The evaluation effect for having model see the table below:
Modeling collection R2 Inspection set R2 RPD
TC 0.938 0.933 3.477
TN 0.940 0.944 3.563
Table 1 has the effect assessment of model
Predicted value will be obtained, inversion chart is as Figure 2-3 after model has been established in the substitution of treated spectrum.
(6) inversion result is verified
Inversion prediction value and measured value compare as illustrated in figures 4-5, from Fig. 4-5, predicted value and measured value very close to, simply, Quickly, required data are easily obtained, are used manpower and material resources sparingly, solve problem of the prior art, it was demonstrated that this method takes Obtained unexpected advantageous effect.
Embodiment only illustrates technical scheme rather than carries out any restrictions to it;Although with reference to the foregoing embodiments The present invention is described in detail, it for those of ordinary skill in the art, still can be to previous embodiment institute The technical solution of record modifies or carries out equivalent substitution to which part technical characteristic;And these modifications or substitutions, and The essence of appropriate technical solution is not made to depart from the spirit and scope of claimed technical solution of the invention.

Claims (10)

1. the method that high light spectrum image-forming technology monitors marine sediment section content of material in real time, which is characterized in that including following Step:
(1) sediment sample is gathered, obtains its section high spectrum image, high-spectral data is read, data is passed to computer;
(2) carry out space to high spectrum image to cut out, choose the high spectrum image of the useful space;
(3) extract color effective information and carry out image segmentation;
(4) according to the demand of monitoring deposit different material content, spectrum analysis is carried out to high-spectral data;
(5) according to the demand of monitoring deposit different material content, the spectrum of each pixel of high spectrum image is substituted into Have in model, obtain each content of material prediction result of the sediment sample in deposit different depth in real time.
2. the method that high light spectrum image-forming technology according to claim 1 monitors marine sediment section content of material in real time, It is characterized in that, the spectrum analysis of step (4) includes the demand according to monitoring deposit different material content, to high-spectral data It carries out Pretreated spectra and/or selects different characteristic wave bands.
3. the method that high light spectrum image-forming technology according to claim 2 monitors marine sediment section content of material in real time, It is characterized in that:Pretreated spectra is using spectrum area's selection, smooth derivation, SNV, MSC or normalization algorithm.
4. marine sediment section content of material is monitored according to any high light spectrum image-forming technologies of claim 1-3 in real time Method, it is characterised in that:Spatial reference is carried out to image using mahalanobis distance method or minimum distance method in step (2).
5. marine sediment section content of material is monitored according to any high light spectrum image-forming technologies of claim 1-3 in real time Method, it is characterised in that:The effective color of fractional spins or mean shift segmentation algorithm to extraction is used in step (3) Carry out image segmentation.
6. marine sediment section content of material is monitored according to any high light spectrum image-forming technologies of claim 2-3 in real time Method, it is characterised in that:In the step (4), characteristic wave bands selection is using successive projection algorithm(SPA), disappear without information variable Except algorithm(UVE)Or genetic algorithm(GA)Method.
7. marine sediment section content of material is monitored according to any high light spectrum image-forming technologies of claim 1-3 in real time Method, it is characterised in that:In the step (5), existing model is built by several sediment samples in same Spectral range It is vertical, if sediment sample and existing model sample in same geographical location, are directly substituted into the model;If sediment sample With existing model sample not in same geographical location, then Model transfer first is carried out to sediment sample, then substituted into the model.
8. marine sediment section content of material is monitored according to any high light spectrum image-forming technologies of claim 1-3 in real time Method, it is characterised in that:In the step (5), prediction result is shown in two forms, and one kind is each point of the inverting deposit Content, show that each content of material of core sediments is distributed respectively with diagram form;Another kind is by each point of core sediments Prediction content show in table form.
9. marine sediment section content of material is monitored according to any high light spectrum image-forming technologies of claim 1-3 in real time Method, it is characterised in that:In step (1), the sediment sample of acquisition is hemipelagic sediment, neritic sediment or absmal deposit Object, the high spectrum image shot according to sediment depth needs.
10. marine sediment section content of material is monitored according to any high light spectrum image-forming technologies of claim 1-3 in real time Method, it is characterised in that:Deposit substance is total phosphorus, total nitrogen, total charcoal, copper or mercury.
CN201711290268.3A 2017-12-08 2017-12-08 The method that high light spectrum image-forming technology monitors marine sediment section content of material in real time Pending CN108051375A (en)

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Application publication date: 20180518