CN108044999A - A kind of stone honeycombed aluminium sheet of wear-resisting durable type - Google Patents
A kind of stone honeycombed aluminium sheet of wear-resisting durable type Download PDFInfo
- Publication number
- CN108044999A CN108044999A CN201711237759.1A CN201711237759A CN108044999A CN 108044999 A CN108044999 A CN 108044999A CN 201711237759 A CN201711237759 A CN 201711237759A CN 108044999 A CN108044999 A CN 108044999A
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- parts
- honeycomb
- aluminium
- layer
- wear
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Links
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 130
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 130
- 239000004411 aluminium Substances 0.000 title claims abstract description 96
- 239000004575 stone Substances 0.000 title claims abstract description 33
- 239000010410 layer Substances 0.000 claims abstract description 66
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 65
- 229910052802 copper Inorganic materials 0.000 claims abstract description 65
- 239000010949 copper Substances 0.000 claims abstract description 65
- 239000004579 marble Substances 0.000 claims abstract description 30
- 239000000872 buffer Substances 0.000 claims abstract description 19
- 239000011229 interlayer Substances 0.000 claims abstract description 11
- 239000003822 epoxy resin Substances 0.000 claims description 35
- 229920000647 polyepoxide Polymers 0.000 claims description 35
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 30
- 239000003063 flame retardant Substances 0.000 claims description 29
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 28
- 239000000843 powder Substances 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 16
- 239000012790 adhesive layer Substances 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 15
- 235000011187 glycerol Nutrition 0.000 claims description 15
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 claims description 15
- 229920002521 macromolecule Polymers 0.000 claims description 15
- 239000004094 surface-active agent Substances 0.000 claims description 15
- 239000007983 Tris buffer Substances 0.000 claims description 14
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 14
- 239000004814 polyurethane Substances 0.000 claims description 14
- 229920002635 polyurethane Polymers 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 239000000835 fiber Substances 0.000 claims description 13
- 239000010439 graphite Substances 0.000 claims description 13
- 229910002804 graphite Inorganic materials 0.000 claims description 13
- 239000010445 mica Substances 0.000 claims description 13
- 229910052618 mica group Inorganic materials 0.000 claims description 13
- 239000006229 carbon black Substances 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 229920005906 polyester polyol Polymers 0.000 claims description 10
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 9
- FJMNNXLGOUYVHO-UHFFFAOYSA-N aluminum zinc Chemical compound [Al].[Zn] FJMNNXLGOUYVHO-UHFFFAOYSA-N 0.000 claims description 9
- 239000003963 antioxidant agent Substances 0.000 claims description 9
- 230000003078 antioxidant effect Effects 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000010426 asphalt Substances 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 238000005269 aluminizing Methods 0.000 claims 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 238000009434 installation Methods 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 description 27
- 239000003292 glue Substances 0.000 description 25
- 239000011812 mixed powder Substances 0.000 description 16
- 239000002002 slurry Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000011521 glass Substances 0.000 description 10
- 239000004568 cement Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 238000005498 polishing Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 7
- 239000004033 plastic Substances 0.000 description 7
- 239000011256 inorganic filler Substances 0.000 description 6
- 229910003475 inorganic filler Inorganic materials 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000007711 solidification Methods 0.000 description 6
- 230000008023 solidification Effects 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000000498 ball milling Methods 0.000 description 4
- 230000001413 cellular effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005553 drilling Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229920006335 epoxy glue Polymers 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000003701 mechanical milling Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- -1 Ester polyol Chemical class 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000005007 epoxy-phenolic resin Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000000979 retarding effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/043—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
- B32B3/085—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts spaced apart pieces on the surface of a layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/06—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/002—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising natural stone or artificial stone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
Landscapes
- Laminated Bodies (AREA)
Abstract
The present invention discloses a kind of stone honeycombed aluminium sheet of wear-resisting durable type, including honeycomb aluminium layer and is arranged on the soft buffer layer of honeycomb aluminium layer bottom and is arranged on the marble slab of honeycomb aluminium layer upper surface and the interlayer being arranged between honeycomb aluminium layer and marble slab；The honeycomb aluminium layer includes honeycomb aluminum and the copper coin that is arranged between honeycomb aluminum, the copper coin include copper plate bodies and be arranged on the fixed strip of copper plate bodies upper end and be arranged in copper plate bodies and the screw through copper plate bodies；The stone honeycombed aluminium sheet is provided with copper coin between honeycomb aluminum, the intensity of honeycomb aluminum can be enhanced by copper coin, and marble slab can be separated, marble slab is facilitated to paste to fix, and installation fixation conveniently can be carried out by entire stone honeycombed aluminium sheet by copper coin, in addition, with reference to glass-fiber-plate as buffer layer, it can bear stronger pressure and frictional force so that stone honeycombed aluminium sheet is more wear-resisting pressure-resistant, extends its service life.
Description
Technical field
The present invention relates to a kind of wear-resisting stone honeycombed aluminium sheets of durable type.
Background technology
Due to the excellent performances such as cellular material has anti-high wind pressure, damping, and sound insulation, heat preservation, fire-retardant and specific strength be high.It is external
The sixties use in civilian each field, and have developed rapidly, and China's cellular technology recent years is just in each of civilian industry
It applies in field.
Aluminum honeycomb panel curtain wall with its it is light, intensity is high, rigidity is big many advantages, such as, be widely used in outside skyscraper
Wall is decorated.Cellular board weight with same stiffness is only the 1/5 of aluminum veneer, the 1/10 of steel plate, the aluminium honeycomb core of interconnection
As numerous I-steel, sandwich layer distribution is fixed in entire plate face, plate is made more to stablize, resisting wind press capacity is more than significantly
Aluminium the first day of the lunar month plate and aluminum veneer, and have the characteristics that flatness is good, even if the lattice size of cellular board is very big, it can also reach high and put down
Face degree is the light material of construction industry first choice, but current honeycomb aluminum plate remains the characteristics of intensity is insufficient：1. structure is not
Enough secured, unbraced structure, the stone honeycombed aluminium sheet for causing area larger easily cracks and collapses；2. the slabstone of honeycomb aluminium surface
Installation is not neat enough, easily deviates former fixed position, finally results in slabstone and removes honeycomb aluminum；3. without buffer layer, cause stone material
Honeycomb aluminum plate is not pressure-resistant, not wear-resisting, is easily damaged.
The content of the invention
In view of this, it is an object of the present invention to provide a kind of intensity that can enhance honeycomb aluminum by copper coin, and can separate
Marble slab facilitates marble slab to paste and fixes, and conveniently can carry out installation fixation by entire stone honeycombed aluminium sheet by copper coin,
In addition, stronger pressure and frictional force can be born as buffer layer so that stone honeycombed aluminium sheet is more resistance to reference to glass-fiber-plate
It grinds pressure-resistant, extends the stone honeycombed aluminium sheet of wear-resisting durable type of its service life.
In order to solve the above-mentioned technical problem, the technical scheme is that：
A kind of stone honeycombed aluminium sheet of wear-resisting durable type, including honeycomb aluminium layer and be arranged on honeycomb aluminium layer bottom and and bee
The fixed soft buffer layer of nest aluminium layer and be arranged on honeycomb aluminium layer upper surface and fixed with honeycomb aluminium layer marble slab and set
Put the interlayer between honeycomb aluminium layer and marble slab；The honeycomb aluminium layer include honeycomb aluminum and be arranged on it is between honeycomb aluminum,
And with honeycomb aluminum is fixed, copper coin for separating marble slab, the copper coin includes copper plate bodies and is arranged on copper plate bodies
The fixed strip of upper end and be arranged in copper plate bodies and it is through copper plate bodies, for by the fixed screw of copper plate bodies.
Further, the surface of honeycomb aluminum is extended in the upper part of the copper plate bodies.
Further, the copper plate bodies are provided at both ends with jack, are provided with to accommodate spiral shell between two jack
Nail and with the fixed threaded hole of screw.
Further, the bottom of the fixed strip be provided with it is corresponding with jack and with the integrally formed inserted link of fixed strip,
The radius of the plate is consistent with the radius size of jack.
Further, the soft buffer layer include glass-fiber-plate and be arranged on glass-fiber-plate upper surface, for honeycomb aluminium layer
First adhesive-layer of fitting.
Further, the glass-fiber-plate is made of the raw material of following weight：Flame-retardant modified solid-state Halogen asphalt mixtures modified by epoxy resin
100-130 parts of fat, 100-130 parts of flame-retardant modified liquid halogen-free epoxy resin, 40-48 parts of polyester polyol, 12-18 parts of aluminium powder,
13-17 parts of macromolecule naphtha, 20-24 parts of silica, 15-21 parts of carbon black, 12-18 parts of graphite, chopped conductive fiber 15-23
Part, 20-28 parts of mica powder, 3-7 parts of dipropylenetriamine curing agent, 5-7 parts of glycerine, 4-6 parts of tris phosphite antioxidant gather
Urethane 6-10 parts of 5-9 parts of surfactant and triisobutyl Al catalysts.
Further, the interlayer include aluminum-zinc alloy thin plate and be arranged on it is on two surface of aluminum-zinc alloy thin plate, be respectively used to
Bond the second adhesive-layer and the 3rd adhesive-layer of honeycomb aluminum and marble slab.
Another technical problem to be solved by the invention is to provide a kind of preparation of the infrared energy magnetic bead for water filtration
Method comprises the following steps：
1) 12-18 parts of aluminium powder, 20-24 parts of silica, 15-21 parts of carbon black, 12-18 parts of graphite, chopped conductive fiber are taken
15-23 parts and 20-28 part of mica powder are added in ball mill, persistently carried out by ball mill 12-18 it is small when ball milling process, make
It obtains above-mentioned material to be uniformly mixed in mechanical milling process, the mixed-powder of 500 mesh is made
2) mixed-powder made from step 1) is added in agitator, while 2 times of mixed-powders is injected into agitator
The water of weight is started mixer and is stirred with the rotating speed of 30r/pm so that and mixed-powder is stirred evenly with water, and underflow is made,
It is spare；
3) flame-retardant modified 100-130 parts of solid-state halogen-free epoxy resin, flame-retardant modified liquid halogen-free epoxy resin 100-130 are taken
13-17 parts of part, 40-48 parts of polyester polyol and macromolecule naphtha are added in reaction kettle, then seal reaction kettle, and continue
When heating 1-2 is small so that temperature is increased to 600-680 DEG C so that has flame-retardant modified solid-state halogen-free epoxy resin, flame-retardant modified liquid
State halogen-free epoxy resin, polyester polyol and macromolecule naphtha are melt into glue in reaction kettle, spare；
4) slurries made from step 2) and 3-7 parts of dipropylenetriamine curing agent, 5-7 parts of glycerine, tris phosphite are taken
6-10 parts of 4-6 parts of antioxidant, 5-9 parts of polyurethane surfactant and triisobutyl Al catalysts are added to the anti-of step 3)
It answers and is mixed in kettle with glue obtained, start the mixer in reaction kettle and stirred with the rotating speed of 45r/pm so that glycerine, phosphorous
Sour three ester antioxidants, polyurethane surfactant and triisobutyl Al catalysts promote slurries and glue polymerisation compatible, increase
The plasticity ability of strong rubber liquid, and pass through the solidification effect that dipropylenetriamine curing agent improves glue after fusion slurries, mixing is made
Glue, it is spare；
5) the dumping mouth of reaction kettle is connected with the feeding mouth of forming machine, the epoxy glue in reaction kettle is defeated to forming machine
It is interior, then rubber compound be transported in molding die by forming machine, glass blanket is made, it is spare；
6) glass blanket made from step 5) is subjected to sanding and polishing by polishing machine, by puncher Drilling operation,
To obtain the final product.
The technology of the present invention effect major embodiment is in the following areas：The intensity of honeycomb aluminum can be enhanced by copper coin, and can
Separate marble slab, marble slab is facilitated to paste and is fixed, and can conveniently be installed entire stone honeycombed aluminium sheet by copper coin
It is fixed, in addition, combining flame-retardant modified solid-state halogen-free epoxy resin, flame-retardant modified liquid halogen-free asphalt mixtures modified by epoxy resin as buffer layer glass-fiber-plate
Fat and polyester polyol can improve the flame retarding function of glass-fiber-plate, then in conjunction with aluminium powder, macromolecule naphtha, silica, charcoal
Black, graphite, the slurry made from conductive fiber and mica powder and water that is chopped can improve the hardness of glass-fiber-plate and bear pressure, in addition
It may be such that glass-fiber-plate is effective against electrostatic by carbon black, graphite, chopped conductive fiber and mica powder, finally with reference to dipropylenetriamine
Curing agent, glycerine, tris phosphite antioxidant, polyurethane are enabled to surfactant and triisobutyl Al catalysts
Slurries are blended with glue, and solidification effect is more preferable in glass sheet metal forming, and glass-fiber-plate obtained is made to be used for stone honeycombed aluminium sheet
In can bear stronger pressure and frictional force so that stone honeycombed aluminium sheet is more wear-resisting pressure-resistant, and service life is longer.
Description of the drawings
Fig. 1 is a kind of stereogram of the wear-resisting stone honeycombed aluminium sheet of durable type of the present invention；
Fig. 2 is the top view of the honeycomb aluminium layer of the present invention；
Fig. 3 is the structure chart of the copper coin of the present invention；
Fig. 4 is the top view of the copper plate bodies of the present invention.
Specific embodiment
Below in conjunction with attached drawing, the specific embodiment of the present invention is described in further detail, so that technical solution of the present invention is more
It should be readily appreciated that and grasp.
In embodiment, it is to be understood that term " centre ", " on ", " under ", " top ", " right side ", " left end ", " on
Side ", " back side ", " middle part ", etc. instructions orientation or position relationship be based on orientation shown in the drawings or position relationship, be only for
Convenient for the description present invention rather than instruction or imply that signified device or element there must be specific orientation, with specific
Azimuth configuration and operation, therefore be not considered as limiting the invention.
Embodiment 1
A kind of stone honeycombed aluminium sheet of wear-resisting durable type, as shown in Figure 1, including honeycomb aluminium layer 1 and being arranged on honeycomb aluminium layer 1
Soft buffer layer 2 bottom and fixed with honeycomb aluminium layer 1 and be arranged on 1 upper surface of honeycomb aluminium layer and it is solid with honeycomb aluminium layer 1
Fixed marble slab 3 and the interlayer 4 being arranged between honeycomb aluminium layer 1 and marble slab 3；The soft buffer layer 2 includes glass-fiber-plate
21 and it is arranged on 21 upper surface of glass-fiber-plate, the first adhesive-layer 211 for being bonded with honeycomb aluminium layer 1.The interlayer 4 includes
Aluminum-zinc alloy thin plate 41 and be arranged on it is on 41 liang of surfaces of aluminum-zinc alloy thin plate, be respectively used to bond honeycomb aluminum 11 and marble slab 3
Second adhesive-layer 411 and the 3rd adhesive-layer 412.As shown in Fig. 2, the honeycomb aluminium layer 1 includes honeycomb aluminum 11 and is arranged on honeycomb
It is between aluminium 11 and pass through copper coin 12 being welded and fixed, for separating marble slab 3 with honeycomb aluminum 11.As shown in Figure 3-4,
The copper coin 12 includes copper plate bodies 121 and is arranged on the fixed strip 122 of 121 upper end of copper plate bodies and is arranged on copper plate bodies
It is in 121 and through copper plate bodies 121, for by 121 fixed screw 123 of copper plate bodies.The copper plate bodies 121
Extend the surface of honeycomb aluminum 11 in upper part.The copper plate bodies 121 are provided at both ends with jack 1211, two jack 1211
Between be provided with to accommodate screw 123 and with 123 fixed threaded hole 1212 of screw.The bottom of the fixed strip 122 is set
Be equipped with it is corresponding with jack 1211 and with 122 integrally formed inserted link 1221 of fixed strip, the radius and jack of the plate 1221
1211 radius size is consistent.In the present embodiment, screw 123 is after copper plate bodies 121 and soft buffer layer 2, with wall or
Cement bottom plate is fixedly connected.
The glass-fiber-plate is made of the raw material of following weight：Flame-retardant modified 130 parts of solid-state halogen-free epoxy resin, resistance
Fire 100 parts of modified liquid halogen-free epoxy resin, 40 parts of polyester polyol, 12 parts of aluminium powder, 13 parts of macromolecule naphtha, silica
20 parts, 15 parts of carbon black, 12 parts of graphite, be chopped 15 parts of conductive fiber, 20 parts of mica powder, 3 parts of dipropylenetriamine curing agent, glycerine
5 parts, 4 parts of tris phosphite antioxidant, polyurethane 6 parts of 5 parts of surfactant and triisobutyl Al catalysts.
A kind of preparation method of glass-fiber-plate, comprises the following steps：
1) 12 parts of aluminium powder, 20 parts of silica, 15 parts of carbon black, 12 parts of graphite, 15 parts of chopped conductive fiber and mica powder are taken
20 parts are added in ball mill, persistently carried out by ball mill 12 it is small when ball milling processing so that above-mentioned material is in mechanical milling process
In be uniformly mixed, be made 500 mesh mixed-powder
2) mixed-powder made from step 1) is added in agitator, while 2 times of mixed-powders is injected into agitator
The water of weight is started mixer and is stirred with the rotating speed of 30r/pm so that and mixed-powder is stirred evenly with water, and underflow is made,
It is spare；
3) flame-retardant modified 130 parts of solid-state halogen-free epoxy resin, 100 parts of flame-retardant modified liquid halogen-free epoxy resin, polyester are taken
13 parts of 40 parts of polyalcohol and macromolecule naphtha are added in reaction kettle, then seal reaction kettle, and when continuous heating 1 is small, make
It obtains temperature and is increased to 600 DEG C so that have flame-retardant modified solid-state halogen-free epoxy resin, flame-retardant modified liquid halogen-free epoxy resin, gather
Ester polyol and macromolecule naphtha are melt into glue in reaction kettle, spare；
4) slurries made from step 2) and 3 parts of dipropylenetriamine curing agent, 5 parts of glycerine, tris phosphite antioxygen are taken
With making in 6 parts of 4 parts of agent, 5 parts of polyurethane surfactant and triisobutyl Al catalysts reaction kettles for being added to step 3)
The glue mixing obtained, is started the mixer in reaction kettle and is stirred with the rotating speed of 45r/pm so that glycerine, tris phosphite antioxygen
Agent, polyurethane surfactant and triisobutyl Al catalysts promote slurries and glue polymerisation compatible, enhance the modeling of glue
Sexuality, and pass through the solidification effect that dipropylenetriamine curing agent improves glue after fusion slurries, mixed glue solution is made, it is spare；
5) the dumping mouth of reaction kettle is connected with the feeding mouth of forming machine, the epoxy glue in reaction kettle is defeated to forming machine
It is interior, then rubber compound be transported in molding die by forming machine, glass blanket is made, it is spare；
6) glass blanket made from step 5) is subjected to sanding and polishing by polishing machine, by puncher Drilling operation,
To obtain the final product.
Embodiment 2
A kind of stone honeycombed aluminium sheet of wear-resisting durable type, as shown in Figure 1, including honeycomb aluminium layer 1 and being arranged on honeycomb aluminium layer 1
Soft buffer layer 2 bottom and fixed with honeycomb aluminium layer 1 and be arranged on 1 upper surface of honeycomb aluminium layer and it is solid with honeycomb aluminium layer 1
Fixed marble slab 3 and the interlayer 4 being arranged between honeycomb aluminium layer 1 and marble slab 3；The soft buffer layer 2 includes glass-fiber-plate
21 and it is arranged on 21 upper surface of glass-fiber-plate, the first adhesive-layer 211 for being bonded with honeycomb aluminium layer 1.The interlayer 4 includes
Aluminum-zinc alloy thin plate 41 and be arranged on it is on 41 liang of surfaces of aluminum-zinc alloy thin plate, be respectively used to bond honeycomb aluminum 11 and marble slab 3
Second adhesive-layer 411 and the 3rd adhesive-layer 412.As shown in Fig. 2, the honeycomb aluminium layer 1 includes honeycomb aluminum 11 and is arranged on honeycomb
It is between aluminium 11 and pass through copper coin 12 being welded and fixed, for separating marble slab 3 with honeycomb aluminum 11.As shown in Figure 3-4,
The copper coin 12 includes copper plate bodies 121 and is arranged on the fixed strip 122 of 121 upper end of copper plate bodies and is arranged on copper plate bodies
It is in 121 and through copper plate bodies 121, for by 121 fixed screw 123 of copper plate bodies.The copper plate bodies 121
Extend the surface of honeycomb aluminum 11 in upper part.The copper plate bodies 121 are provided at both ends with jack 1211, two jack 1211
Between be provided with to accommodate screw 123 and with 123 fixed threaded hole 1212 of screw.The bottom of the fixed strip 122 is set
Be equipped with it is corresponding with jack 1211 and with 122 integrally formed inserted link 1221 of fixed strip, the radius and jack of the plate 1221
1211 radius size is consistent.In the present embodiment, screw 123 is after copper plate bodies 121 and soft buffer layer 2, with wall or
Cement bottom plate is fixedly connected.
The glass-fiber-plate is made of the raw material of following weight：Flame-retardant modified solid-state halogen-free epoxy resin 100-130
Part, 100 parts of flame-retardant modified liquid halogen-free epoxy resin, 48 parts of polyester polyol, 18 parts of aluminium powder, 17 parts of macromolecule naphtha, two
24 parts of silica, 21 parts of carbon black, 18 parts of graphite, be chopped 23 parts of conductive fiber, 28 parts of mica powder, 7 parts of dipropylenetriamine curing agent,
7 parts of glycerine, 6 parts of tris phosphite antioxidant, polyurethane 10 parts of 9 parts of surfactant and triisobutyl Al catalysts.
A kind of preparation method of glass-fiber-plate, comprises the following steps：
1) 18 parts of aluminium powder, 24 parts of silica, 21 parts of carbon black, 18 parts of graphite, 23 parts of chopped conductive fiber and mica powder are taken
28 parts are added in ball mill, persistently carried out by ball mill 18 it is small when ball milling processing so that above-mentioned material is in mechanical milling process
In be uniformly mixed, be made 500 mesh mixed-powder
2) mixed-powder made from step 1) is added in agitator, while 2 times of mixed-powders is injected into agitator
The water of weight is started mixer and is stirred with the rotating speed of 30r/pm so that and mixed-powder is stirred evenly with water, and underflow is made,
It is spare；
3) flame-retardant modified 100 parts of solid-state halogen-free epoxy resin, 130 parts of flame-retardant modified liquid halogen-free epoxy resin, polyester are taken
17 parts of 48 parts of polyalcohol and macromolecule naphtha are added in reaction kettle, then seal reaction kettle, and when continuous heating 2 is small, make
It obtains temperature and is increased to 680 DEG C so that have flame-retardant modified solid-state halogen-free epoxy resin, flame-retardant modified liquid halogen-free epoxy resin, gather
Ester polyol and macromolecule naphtha are melt into glue in reaction kettle, spare；
4) slurries made from step 2) and 7 parts of dipropylenetriamine curing agent, 7 parts of glycerine, tris phosphite antioxygen are taken
With making in 10 parts of 6 parts of agent, 9 parts of polyurethane surfactant and triisobutyl Al catalysts reaction kettles for being added to step 3)
The glue mixing obtained, is started the mixer in reaction kettle and is stirred with the rotating speed of 45r/pm so that glycerine, tris phosphite antioxygen
Agent, polyurethane surfactant and triisobutyl Al catalysts promote slurries and glue polymerisation compatible, enhance the modeling of glue
Sexuality, and pass through the solidification effect that dipropylenetriamine curing agent improves glue after fusion slurries, mixed glue solution is made, it is spare；
5) the dumping mouth of reaction kettle is connected with the feeding mouth of forming machine, the epoxy glue in reaction kettle is defeated to forming machine
It is interior, then rubber compound be transported in molding die by forming machine, glass blanket is made, it is spare；
6) glass blanket made from step 5) is subjected to sanding and polishing by polishing machine, by puncher Drilling operation,
To obtain the final product.
Embodiment 3
A kind of stone honeycombed aluminium sheet of wear-resisting durable type, as shown in Figure 1, including honeycomb aluminium layer 1 and being arranged on honeycomb aluminium layer 1
Soft buffer layer 2 bottom and fixed with honeycomb aluminium layer 1 and be arranged on 1 upper surface of honeycomb aluminium layer and it is solid with honeycomb aluminium layer 1
Fixed marble slab 3 and the interlayer 4 being arranged between honeycomb aluminium layer 1 and marble slab 3；The soft buffer layer 2 includes glass-fiber-plate
21 and it is arranged on 21 upper surface of glass-fiber-plate, the first adhesive-layer 211 for being bonded with honeycomb aluminium layer 1.The interlayer 4 includes
Aluminum-zinc alloy thin plate 41 and be arranged on it is on 41 liang of surfaces of aluminum-zinc alloy thin plate, be respectively used to bond honeycomb aluminum 11 and marble slab 3
Second adhesive-layer 411 and the 3rd adhesive-layer 412.As shown in Fig. 2, the honeycomb aluminium layer 1 includes honeycomb aluminum 11 and is arranged on honeycomb
It is between aluminium 11 and pass through copper coin 12 being welded and fixed, for separating marble slab 3 with honeycomb aluminum 11.As shown in Figure 3-4,
The copper coin 12 includes copper plate bodies 121 and is arranged on the fixed strip 122 of 121 upper end of copper plate bodies and is arranged on copper plate bodies
It is in 121 and through copper plate bodies 121, for by 121 fixed screw 123 of copper plate bodies.The copper plate bodies 121
Extend the surface of honeycomb aluminum 11 in upper part.The copper plate bodies 121 are provided at both ends with jack 1211, two jack 1211
Between be provided with to accommodate screw 123 and with 123 fixed threaded hole 1212 of screw.The bottom of the fixed strip 122 is set
Be equipped with it is corresponding with jack 1211 and with 122 integrally formed inserted link 1221 of fixed strip, the radius and jack of the plate 1221
1211 radius size is consistent.In the present embodiment, screw 123 is after copper plate bodies 121 and soft buffer layer 2, with wall or
Cement bottom plate is fixedly connected.
The glass-fiber-plate is made of the raw material of following weight：Flame-retardant modified 115 parts of solid-state halogen-free epoxy resin, resistance
Fire 115 parts of modified liquid halogen-free epoxy resin, 44 parts of polyester polyol, 15 parts of aluminium powder, 15 parts of macromolecule naphtha, silica
22 parts, 18 parts of carbon black, 15 parts of graphite, be chopped 19 parts of conductive fiber, 24 parts of mica powder, 5 parts of dipropylenetriamine curing agent, glycerine
6 parts, 5 parts of tris phosphite antioxidant, polyurethane 8 parts of 7 parts of surfactant and triisobutyl Al catalysts.
A kind of preparation method of glass-fiber-plate, comprises the following steps：
1) 15 parts of aluminium powder, 22 parts of silica, 18 parts of carbon black, 15 parts of graphite, 19 parts of chopped conductive fiber and mica powder are taken
24 parts are added in ball mill, persistently carried out by ball mill 15 it is small when ball milling processing so that above-mentioned material is in mechanical milling process
In be uniformly mixed, be made 500 mesh mixed-powder
2) mixed-powder made from step 1) is added in agitator, while 2 times of mixed-powders is injected into agitator
The water of weight is started mixer and is stirred with the rotating speed of 30r/pm so that and mixed-powder is stirred evenly with water, and underflow is made,
It is spare；
3) flame-retardant modified 115 parts of solid-state halogen-free epoxy resin, 115 parts of flame-retardant modified liquid halogen-free epoxy resin, polyester are taken
15 parts of 44 parts of polyalcohol and macromolecule naphtha are added in reaction kettle, then seal reaction kettle, and when continuous heating 1.5 is small,
So that temperature is increased to 640 DEG C so that have flame-retardant modified solid-state halogen-free epoxy resin, flame-retardant modified liquid halogen-free epoxy resin,
Polyester polyol and macromolecule naphtha are melt into glue in reaction kettle, spare；
4) slurries made from step 2) and 5 parts of dipropylenetriamine curing agent, 6 parts of glycerine, tris phosphite antioxygen are taken
With making in 8 parts of 5 parts of agent, 7 parts of polyurethane surfactant and triisobutyl Al catalysts reaction kettles for being added to step 3)
The glue mixing obtained, is started the mixer in reaction kettle and is stirred with the rotating speed of 45r/pm so that glycerine, tris phosphite antioxygen
Agent, polyurethane surfactant and triisobutyl Al catalysts promote slurries and glue polymerisation compatible, enhance the modeling of glue
Sexuality, and pass through the solidification effect that dipropylenetriamine curing agent improves glue after fusion slurries, mixed glue solution is made, it is spare；
5) the dumping mouth of reaction kettle is connected with the feeding mouth of forming machine, the epoxy glue in reaction kettle is defeated to forming machine
It is interior, then rubber compound be transported in molding die by forming machine, glass blanket is made, it is spare；
6) glass blanket made from step 5) is subjected to sanding and polishing by polishing machine, by puncher Drilling operation,
To obtain the final product.
Experimental example
Following table is for the plastic plate normal conditions after the 25mm of stone honeycombed aluminium sheet
Experimental subjects：Using plastic cement plate body made of epoxy resin mixing inorganic filler as a control group one, using epoxy
Plastic cement plate body made of resin and phenolic resin mixing inorganic filler as a control group two and the application glass-fiber-plate as real
Group is tested, and is compared.
Requirement of experiment：The test area of above-mentioned three groups of experiment products, test consistency of thickness.
Experimental method：By to plastic cement plate body, epoxy resin and phenolic resin made of epoxy resin mixing inorganic filler
Plastic cement plate body made of mixing inorganic filler and with the glass-fiber-plate of the application by dry sanding paper carry out polishing test, burn test,
Shot shock-testing and gravity compressing test, compare the situation of three groups of experiment products, in this experimental example, the quality of shot is respectively
1KG, gravity compressing test use the bucket of 50KG.
Concrete outcome is as shown in the table：
With reference to upper table, plastic cement plate body, epoxy resin and phenolic resin made of comparison epoxy resin mixing inorganic filler mix
Close plastic cement plate body made of inorganic filler and the data with the glass-fiber-plate of the application gained under identical experimental method, the present invention
The test data of glass-fiber-plate be superior to control group one and control two, therefore, it is high to embody the glass-fiber-plate intensity of the present invention, resistance to
Mill, nonflammable advantage.
Therefore, in the glass-fiber-plate with reference to made from above-mentioned preparation method and preparation formula so that glass-fiber-plate is applied to stone material bee
Wear-resisting, pressure-resistant effect can be further improved in nest aluminium sheet, the service life of stone honeycombed aluminium sheet can be extended.
The technology of the present invention effect major embodiment is in the following areas：The intensity of honeycomb aluminum can be enhanced by copper coin, and can
Separate marble slab, marble slab is facilitated to paste and is fixed, and can conveniently be installed entire stone honeycombed aluminium sheet by copper coin
It is fixed, in addition, combining flame-retardant modified solid-state halogen-free epoxy resin, flame-retardant modified liquid halogen-free asphalt mixtures modified by epoxy resin as buffer layer glass-fiber-plate
Fat and polyester polyol can improve the flame retarding function of glass-fiber-plate, then in conjunction with aluminium powder, macromolecule naphtha, silica, charcoal
Black, graphite, the slurry made from conductive fiber and mica powder and water that is chopped can improve the hardness of glass-fiber-plate and bear pressure, in addition
It may be such that glass-fiber-plate is effective against electrostatic by carbon black, graphite, chopped conductive fiber and mica powder, finally with reference to dipropylenetriamine
Curing agent, glycerine, tris phosphite antioxidant, polyurethane are enabled to surfactant and triisobutyl Al catalysts
Slurries are blended with glue, and solidification effect is more preferable in glass sheet metal forming, and glass-fiber-plate obtained is made to be used for stone honeycombed aluminium sheet
In can bear stronger pressure and frictional force so that stone honeycombed aluminium sheet is more wear-resisting pressure-resistant, and service life is longer.
Certainly, representative instance simply of the invention more than, in addition, the present invention can also have other a variety of specific implementations
Mode, all technical solutions formed using equivalent substitution or equivalent transformation, is all fallen within the scope of protection of present invention.
Claims (7)
1. a kind of stone honeycombed aluminium sheet of wear-resisting durable type, including honeycomb aluminium layer and be arranged on honeycomb aluminium layer bottom and and honeycomb
The fixed soft buffer layer of aluminium layer and be arranged on honeycomb aluminium layer upper surface and fixed with honeycomb aluminium layer marble slab and set
Interlayer between honeycomb aluminium layer and marble slab；It is characterized in that：The honeycomb aluminium layer includes honeycomb aluminum and is arranged on honeycomb
It is between aluminium and with honeycomb aluminum is fixed, copper coin for separating marble slab, the copper coin includes copper plate bodies and sets
Copper plate bodies upper end fixed strip and be arranged in copper plate bodies and it is through copper plate bodies, for copper plate bodies to be consolidated
Fixed screw.
2. a kind of wear-resisting stone honeycombed aluminium sheet of durable type as described in claim 1, it is characterised in that：The copper plate bodies it is upper
Extend the surface of honeycomb aluminum in part.
3. a kind of wear-resisting stone honeycombed aluminium sheet of durable type as claimed in claim 2, it is characterised in that：The two of the copper plate bodies
End is provided with jack, be provided with to accommodate between two jack screw and with the fixed threaded hole of screw.
4. a kind of wear-resisting stone honeycombed aluminium sheet of durable type as claimed in claim 3, it is characterised in that：The bottom of the fixed strip
Be provided with it is corresponding with jack and with the integrally formed inserted link of fixed strip, the radius of the plate and the radius size one of jack
It causes.
5. a kind of wear-resisting stone honeycombed aluminium sheet of durable type as claimed in claim 4, it is characterised in that：The soft buffer layer includes
Glass-fiber-plate and it is arranged on glass-fiber-plate upper surface, the first adhesive-layer for being bonded with honeycomb aluminium layer.
6. a kind of wear-resisting stone honeycombed aluminium sheet of durable type as claimed in claim 5, it is characterised in that：The glass-fiber-plate is by following
The raw material of weight is made：Flame-retardant modified 100-130 parts of solid-state halogen-free epoxy resin, flame-retardant modified liquid halogen-free asphalt mixtures modified by epoxy resin
100-130 parts of fat, 40-48 parts of polyester polyol, 12-18 parts of aluminium powder, 13-17 parts of macromolecule naphtha, silica 20-24
Part, 15-21 parts of carbon black, 12-18 parts of graphite, be chopped 15-23 parts of conductive fiber, 20-28 parts of mica powder, dipropylenetriamine curing agent
3-7 parts, 5-7 parts of glycerine, 4-6 parts of tris phosphite antioxidant, polyurethane 5-9 parts of surfactant and triisobutyl aluminium
6-10 parts of catalyst.
7. a kind of wear-resisting stone honeycombed aluminium sheet of durable type as described in claim 1, it is characterised in that：The interlayer includes aluminizing
Zinc thin plate and it is arranged on the second adhesive-layer on two surface of aluminum-zinc alloy thin plate, being respectively used to bond honeycomb aluminum and marble slab
With the 3rd adhesive-layer.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109680579A (en) * | 2018-12-14 | 2019-04-26 | 华北水利水电大学 | A kind of high strength fibre skeleton FRP is without magnetic metal composite road deck and preparation method thereof |
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