CN107974161A - A kind of coating and preparation method thereof that blocks water of carbon nanotubes - Google Patents
A kind of coating and preparation method thereof that blocks water of carbon nanotubes Download PDFInfo
- Publication number
- CN107974161A CN107974161A CN201711408876.XA CN201711408876A CN107974161A CN 107974161 A CN107974161 A CN 107974161A CN 201711408876 A CN201711408876 A CN 201711408876A CN 107974161 A CN107974161 A CN 107974161A
- Authority
- CN
- China
- Prior art keywords
- coating
- carbon nanotubes
- curing agent
- blocks water
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 54
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 54
- 238000000576 coating method Methods 0.000 title claims abstract description 51
- 239000011248 coating agent Substances 0.000 title claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 238000003756 stirring Methods 0.000 claims abstract description 50
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 26
- 239000005011 phenolic resin Substances 0.000 claims abstract description 26
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 20
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003822 epoxy resin Substances 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 9
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 16
- 229940043276 diisopropanolamine Drugs 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 239000004115 Sodium Silicate Substances 0.000 claims description 8
- 229910021538 borax Inorganic materials 0.000 claims description 8
- 239000000428 dust Substances 0.000 claims description 8
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 8
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 8
- 239000004328 sodium tetraborate Substances 0.000 claims description 8
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 238000004821 distillation Methods 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 239000008236 heating water Substances 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000002071 nanotube Substances 0.000 claims 1
- 230000007797 corrosion Effects 0.000 abstract description 8
- 238000005260 corrosion Methods 0.000 abstract description 8
- 239000011159 matrix material Substances 0.000 abstract description 5
- 230000003111 delayed effect Effects 0.000 abstract description 3
- 230000008595 infiltration Effects 0.000 abstract description 3
- 238000001764 infiltration Methods 0.000 abstract description 3
- 239000003463 adsorbent Substances 0.000 abstract description 2
- 230000000149 penetrating effect Effects 0.000 abstract description 2
- 239000013535 sea water Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 4
- 238000010422 painting Methods 0.000 description 3
- 238000011049 filling Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002048 multi walled nanotube Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A kind of coating and preparation method thereof that blocks water of carbon nanotubes disclosed by the invention, including following components：Phenolic resin, epoxy resin, dimethylbenzene, acetone, curing agent and carbon nanotubes, through mixing, stirring, heating reaction is made, the obtained coating that blocks water is compared with existing coating, due to carbon nanotubes addition in the coating, it is filled with the micropore of coating in itself, fill the passage of hydrone infiltration, significantly extend water and time used in matrix surface is penetrated into from coating surface, coating failure is delayed, add the service life of coating, if at the coating in the seawater, due to the suction-operated of carbon nanotubes, Na+ that can be effectively in adsorbent solution, Cl, it can effectively prevent Cl from penetrating into matrix surface to damage, improve corrosion resisting property；Meanwhile special curing agent of arranging in pairs or groups, the reaction rate for the coating that blocks water can be increased substantially, in use, gel time is reduced, moreover, its preparation method is simple and practicable, it is easy to implement.
Description
Technical field
The invention belongs to paint field, and in particular to a kind of coating and preparation method thereof that blocks water of carbon nanotubes.
Background technology
In natural environment, chemical action or electrochemical action can occur due to the influence of environment for material, and occur rotten
Erosion failure, loses its original mechanical property and structure function, causes potential security risk and economic loss.In big compression ring
Corrosion in border, soil environment and marine environment, and protruded the most with marine corrosion and be badly in need of research and captured.Prevent in marine corrosion
In terms of shield, coating protecting occupies very high ratio, this allows research of the coating under briny environment to become hot spot.
Synthetic resin coating of the phthalic resin coating using alkyd resin as main film forming substance, it is with weatherability, attachment
The features such as power is good, it is easy for construction, it is widely used in the applications such as bridge, machinery, vehicle, ship.
In order to improve the water-impervious of coating itself and corrosion resistance, nano level multi-walled carbon nanotube is added herein clear
Color stuffing is served as in paint, the addition increase film forming coatings compactness of carbon nanotubes, the passage of filling hydrone infiltration, significantly extends
Water penetrates into the time used in matrix surface from coating surface, has delayed coating failure, adds the service life of coating.Will
Carbon nanotubes is applied in coating, will show more preferable water preventing ability and corrosion resistance.
The content of the invention
In order to improve the water-impervious of coating itself and corrosion resistance, the invention discloses a kind of blocking water for carbon nanotubes
Coating and preparation method thereof.
Specific technical solution is as follows：
A kind of coating and preparation method thereof that blocks water of carbon nanotubes, it is characterised in that the painting that blocks water of the carbon nanotubes
Material, by mass percentage including the following raw material：
Phenolic resin 80 ~ 85%,
Epoxy resin 1 ~ 3%,
Dimethylbenzene 0.6 ~ 0.8%,
Acetone 2 ~ 3%,
Curing agent 6 ~ 8%,
Carbon nanotubes 1 ~ 5%.
Wherein, it is preferred that the mass percent of the carbon nanotubes is 3%.
The preparation method of the coating that blocks water of the carbon nanotubes, including step in detail below：
（1）Phenolic resin, epoxy resin, dimethylbenzene and acetone are weighed by mass percentage, are added in the lump in reaction kettle；
（2）Start reaction kettle, temperature control is stirred at 25 ~ 100 DEG C, stirs 30 ~ 50min, and stir speed (S.S.) control exists
800 ~ 1200R/Min, waits to be mixed thoroughly, and obtains mixture A；
（3）Reaction kettle persistently stirs, reduce stir speed (S.S.) to 600 ~ 800R/Min, temperature control at 50 ~ 75 DEG C, stirring it is same
When, in 5 minutes, curing agent is gradually added, stirs 60 ~ 90Min, until mixture A is mixed thoroughly with curing agent, obtain
To mixture B；
（4）Prepare carbon nanotubes by mass percentage, carbon nanotubes is ground and crosses 250 mesh sieves, obtains carbon nanotube dust, by institute
The carbon nanotube dust obtained is added in reaction kettle, and heating 2 ~ 3h of reaction, reaction temperature is controlled at 50 ~ 75 DEG C, adjoint stirring, stirring
Speed control is completed in 100 ~ 120R/Min, heating reaction, to obtain the final product the coating that blocks water of the carbon nanotubes.
Wherein, the curing agent by mass percentage, including following components：
Borax 1 ~ 3%, diisopropanolamine (DIPA) 5 ~ 7%, mannich base 20 ~ 25%, phenolic resin 60 ~ 70%, sodium metasilicate 1 ~ 3%, sulfamic acid
1~3%。
The curing agent preparation method is as follows：
（a）Phenolic resin is weighed by mass percentage, is added in reaction kettle, and by way of heating water bath, by phenolic resin
30 ~ 50 DEG C are heated to, insulation；
（b）To step（a）In phenolic resin in add at borax and diisopropanolamine (DIPA), with 40 ~ 45 DEG C, keep the temperature 1 ~ 1.2h, and
With stirring, control stir speed (S.S.) is in 100R/Min；
（c）Then add sodium metasilicate and sulfamic acid, and synchronously add 35 ~ 50 DEG C of deionized water, control solution temperature 40 ~
45 DEG C, 1.5 ~ 2h is kept the temperature, and with stirring, control stir speed (S.S.) is in 600 ~ 700R/Min；
（d）By step（c）In solution, lift temperature to 80 ~ 95 DEG C, and vacuumize distillation, steamed until solvent-free, obtained described
Curing agent.
Wherein, the quality of the deionized water is 2 ~ 4 times of curing agent all components gross mass.
Beneficial effects of the present invention are：
A kind of coating and preparation method thereof that blocks water of carbon nanotubes disclosed by the invention, including following components：Phenolic resin, ring
Oxygen tree fat, dimethylbenzene, acetone, curing agent and carbon nanotubes, through mix, stir, heat reaction be made, it is obtained block water coating with
Existing coating is compared, and due to carbon nanotubes addition in the coating, is filled with the micropore of coating in itself, filling hydrone infiltration is led to
Road, significantly extends water and penetrates into time used in matrix surface from coating surface, delayed coating failure, added coating
Service life, if, due to the suction-operated of carbon nanotubes, Na+, Cl- that can be effectively in adsorbent solution, at the coating in the seawater
It can effectively prevent Cl- from penetrating into matrix surface to damage, improve corrosion resisting property；Meanwhile special curing agent of arranging in pairs or groups, can be significantly
Degree improves the reaction rate for the coating that blocks water, in use, gel time is reduced, moreover, its preparation method is simple and practicable, and it is easily real
It is existing.
Embodiment
To make technical scheme become apparent from clearly, below the present invention is described further, it is any to this
The technical characteristic of inventive technique scheme carries out the scheme that equivalencing is drawn with conventional reasoning and each falls within the scope of the present invention.
Embodiment one
A kind of coating and preparation method thereof that blocks water of carbon nanotubes, it is characterised in that the painting that blocks water of the carbon nanotubes
Material, by mass percentage including the following raw material：
Phenolic resin 84%,
Epoxy resin 2%,
Dimethylbenzene 0.7%,
Acetone 3%,
Curing agent 7.3%,
Carbon nanotubes 3%.
The preparation method of the coating that blocks water of the carbon nanotubes, including step in detail below：
（1）Phenolic resin, epoxy resin, dimethylbenzene and acetone are weighed by mass percentage, are added in the lump in reaction kettle；
（2）Start reaction kettle, temperature control is stirred at 45 DEG C, stirs 45min, and stir speed (S.S.) is controlled in 1100R/
Min, waits to be mixed thoroughly, and obtains mixture A；
（3）Reaction kettle persistently stirs, and reduces stir speed (S.S.) to 700R/Min, and temperature control is at 55 DEG C, while stirring, with 5
In minute, curing agent is gradually added, stirs 85Min, until mixture A is mixed thoroughly with curing agent, obtain mixture B；
（4）Prepare carbon nanotubes by mass percentage, carbon nanotubes is ground and crosses 250 mesh sieves, obtains carbon nanotube dust, by institute
The carbon nanotube dust obtained is added in reaction kettle, and heating reaction 3h, reaction temperature is controlled at 55 DEG C, adjoint stirring, stir speed (S.S.)
Control is completed in 100R/Min, heating reaction, to obtain the final product the coating that blocks water of the carbon nanotubes.
Wherein, the curing agent by mass percentage, including following components：
Borax 2%, diisopropanolamine (DIPA) 6%, mannich base 22%, phenolic resin 65%, sodium metasilicate 2.3%, sulfamic acid 2.7%.
The curing agent preparation method is as follows：
（a）Phenolic resin is weighed by mass percentage, is added in reaction kettle, and by way of heating water bath, by phenolic resin
40 DEG C are heated to, insulation；
（b）To step（a）In phenolic resin in add at borax and diisopropanolamine (DIPA), with 45 DEG C, keep the temperature 1h, and with stirring
Mix, control stir speed (S.S.) is in 100R/Min；
（c）Sodium metasilicate and sulfamic acid are then added, and synchronously adds 45 DEG C of deionized water, controls solution temperature at 45 DEG C,
1.7h is kept the temperature, and with stirring, control stir speed (S.S.) is in 600R/Min；
（d）By step（c）In solution, lift temperature to 85 DEG C, and vacuumize distillation, steamed until solvent-free, obtain described consolidate
Agent.
Wherein, the quality of the deionized water is 2.5 times of curing agent all components gross mass.
Embodiment two
A kind of coating and preparation method thereof that blocks water of carbon nanotubes, it is characterised in that the painting that blocks water of the carbon nanotubes
Material, by mass percentage including the following raw material：
Phenolic resin 85%,
Epoxy resin 2.5%,
Dimethylbenzene 0.8%,
Acetone 3%,
Curing agent 6%,
Carbon nanotubes 2.7%.
The preparation method of the coating that blocks water of the carbon nanotubes, including step in detail below：
（1）Phenolic resin, epoxy resin, dimethylbenzene and acetone are weighed by mass percentage, are added in the lump in reaction kettle；
（2）Starting reaction kettle, temperature control is stirred at 55 DEG C, stirs 40min, and stir speed (S.S.) is controlled in 900R/Min,
Wait to be mixed thoroughly, obtain mixture A；
（3）Reaction kettle persistently stirs, and reduces stir speed (S.S.) to 650R/Min, and temperature control is at 65 DEG C, while stirring, with 5
In minute, curing agent is gradually added, stirs 85Min, until mixture A is mixed thoroughly with curing agent, obtain mixture B；
（4）Prepare carbon nanotubes by mass percentage, carbon nanotubes is ground and crosses 250 mesh sieves, obtains carbon nanotube dust, by institute
The carbon nanotube dust obtained is added in reaction kettle, and heating reaction 2.5h, reaction temperature is controlled at 60 DEG C, adjoint stirring, stirring speed
Rate control is completed in 110R/Min, heating reaction, to obtain the final product the coating that blocks water of the carbon nanotubes.
Wherein, the curing agent by mass percentage, including following components：
Borax 3%, diisopropanolamine (DIPA) 6.5%, mannich base 22.5%, phenolic resin 64%, sodium metasilicate 2%, sulfamic acid 2%.
The curing agent preparation method is as follows：
（a）Phenolic resin is weighed by mass percentage, is added in reaction kettle, and by way of heating water bath, by phenolic resin
40 DEG C are heated to, insulation；
（b）To step（a）In phenolic resin in add at borax and diisopropanolamine (DIPA), with 40 DEG C, keep the temperature 1.2h, and with stirring
Mix, control stir speed (S.S.) is in 100R/Min；
（c）Sodium metasilicate and sulfamic acid are then added, and synchronously adds 35 DEG C of deionized water, controls solution temperature at 45 DEG C,
1.5h is kept the temperature, and with stirring, control stir speed (S.S.) is in 630R/Min；
（d）By step（c）In solution, lift temperature to 85 DEG C, and vacuumize distillation, steamed until solvent-free, obtain described consolidate
Agent.
Wherein, the quality of the deionized water is 2.5 times of curing agent all components gross mass.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, the change or replacement that can readily occur in,
It should all cover within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection domain of claims
Subject to.
Claims (4)
1. coating and preparation method thereof that blocks water of a kind of carbon nanotubes, it is characterised in that the carbon nanotubes blocks water
Coating, by mass percentage including the following raw material：
Phenolic resin 80 ~ 85%,
Epoxy resin 1 ~ 3%,
Dimethylbenzene 0.6 ~ 0.8%,
Acetone 2 ~ 3%,
Curing agent 6 ~ 8%,
Carbon nanotubes 1 ~ 5%；
The preparation method of the coating that blocks water of the carbon nanotubes, including step in detail below：
（1）Phenolic resin, epoxy resin, dimethylbenzene and acetone are weighed by mass percentage, are added in the lump in reaction kettle；
（2）Start reaction kettle, temperature control is stirred at 25 ~ 100 DEG C, stirs 30 ~ 50min, and stir speed (S.S.) control exists
800 ~ 1200R/Min, waits to be mixed thoroughly, and obtains mixture A；
（3）Reaction kettle persistently stirs, reduce stir speed (S.S.) to 600 ~ 800R/Min, temperature control at 50 ~ 75 DEG C, stirring it is same
When, in 5 minutes, curing agent is gradually added, stirs 60 ~ 90Min, until mixture A is mixed thoroughly with curing agent, obtain
To mixture B；
（4）Prepare carbon nanotubes by mass percentage, carbon nanotubes is ground and crosses 250 mesh sieves, obtains carbon nanotube dust, by institute
The carbon nanotube dust obtained is added in reaction kettle, and heating 2 ~ 3h of reaction, reaction temperature is controlled at 50 ~ 75 DEG C, adjoint stirring, stirring
Speed control is completed in 100 ~ 120R/Min, heating reaction, to obtain the final product the coating that blocks water of the carbon nanotubes.
A kind of 2. coating and preparation method thereof that blocks water of carbon nanotubes as claimed in claim 1, it is characterised in that the carbon
The mass percent of nanotube is 3%.
3. coating and preparation method thereof that blocks water of a kind of carbon nanotubes as claimed in claim 1, it is characterised in that described
Curing agent by mass percentage, including following components：
Borax 1 ~ 3%, diisopropanolamine (DIPA) 5 ~ 7%, mannich base 20 ~ 25%, phenolic resin 60 ~ 70%, sodium metasilicate 1 ~ 3%, sulfamic acid
1~3%；
The curing agent preparation method is as follows：
（a）Phenolic resin is weighed by mass percentage, is added in reaction kettle, and by way of heating water bath, by phenolic resin
30 ~ 50 DEG C are heated to, insulation；
（b）To step（a）In phenolic resin in add at borax and diisopropanolamine (DIPA), with 40 ~ 45 DEG C, keep the temperature 1 ~ 1.2h, and
With stirring, control stir speed (S.S.) is in 100R/Min；
（c）Then add sodium metasilicate and sulfamic acid, and synchronously add 35 ~ 50 DEG C of deionized water, control solution temperature 40 ~
45 DEG C, 1.5 ~ 2h is kept the temperature, and with stirring, control stir speed (S.S.) is in 600 ~ 700R/Min；
（d）By step（c）In solution, lift temperature to 80 ~ 95 DEG C, and vacuumize distillation, steamed until solvent-free, obtained described
Curing agent.
4. coating and preparation method thereof that blocks water of a kind of carbon nanotubes as claimed in claim 3, it is characterised in that described to go
The quality of ionized water is 2 ~ 4 times of curing agent all components gross mass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711408876.XA CN107974161A (en) | 2017-12-22 | 2017-12-22 | A kind of coating and preparation method thereof that blocks water of carbon nanotubes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711408876.XA CN107974161A (en) | 2017-12-22 | 2017-12-22 | A kind of coating and preparation method thereof that blocks water of carbon nanotubes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107974161A true CN107974161A (en) | 2018-05-01 |
Family
ID=62007335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711408876.XA Pending CN107974161A (en) | 2017-12-22 | 2017-12-22 | A kind of coating and preparation method thereof that blocks water of carbon nanotubes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107974161A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112300657A (en) * | 2020-07-02 | 2021-02-02 | 上海兴赛尔表面材料有限公司 | Water-based corrosion-resistant composition suitable for color coating production line and manufacturing and using methods thereof |
| CN112574606A (en) * | 2020-12-31 | 2021-03-30 | 江苏科辉环境科技有限公司 | Carbon nano tube anticorrosive paint |
| CN115821585A (en) * | 2022-12-10 | 2023-03-21 | 江苏金呢工程织物股份有限公司 | Textile auxiliary for high-wear-resistance forming net and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1651524A (en) * | 2005-01-14 | 2005-08-10 | 清华大学 | Carbon nano-pipe composite coating layer type wave absorption material and its preparation method |
| CN103881304A (en) * | 2014-03-04 | 2014-06-25 | 天津虹炎科技有限公司 | Epoxy resin composition with low organic matter volatility |
| CN105062300A (en) * | 2015-07-17 | 2015-11-18 | 金湖县杰达机械制造有限公司 | Anti-corrosion and wear-resisting coating for throwing disc of pneumatic type feeder and preparation method of coating |
-
2017
- 2017-12-22 CN CN201711408876.XA patent/CN107974161A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1651524A (en) * | 2005-01-14 | 2005-08-10 | 清华大学 | Carbon nano-pipe composite coating layer type wave absorption material and its preparation method |
| CN103881304A (en) * | 2014-03-04 | 2014-06-25 | 天津虹炎科技有限公司 | Epoxy resin composition with low organic matter volatility |
| CN105062300A (en) * | 2015-07-17 | 2015-11-18 | 金湖县杰达机械制造有限公司 | Anti-corrosion and wear-resisting coating for throwing disc of pneumatic type feeder and preparation method of coating |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112300657A (en) * | 2020-07-02 | 2021-02-02 | 上海兴赛尔表面材料有限公司 | Water-based corrosion-resistant composition suitable for color coating production line and manufacturing and using methods thereof |
| CN112574606A (en) * | 2020-12-31 | 2021-03-30 | 江苏科辉环境科技有限公司 | Carbon nano tube anticorrosive paint |
| CN115821585A (en) * | 2022-12-10 | 2023-03-21 | 江苏金呢工程织物股份有限公司 | Textile auxiliary for high-wear-resistance forming net and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107974161A (en) | A kind of coating and preparation method thereof that blocks water of carbon nanotubes | |
| CN102050608B (en) | Polymer cement waterproof paint and method for preparing waterproof coating layer | |
| CN106189719A (en) | A kind of Graphene anticorrosive paint and preparation method thereof | |
| CN109517481A (en) | A kind of preparation method of the water corrosion-resistant epoxy paint of containing graphene | |
| CN102875085B (en) | External wall water-fast putty powder | |
| CN104497633A (en) | Nano calcium carbonate surface treatment method | |
| CN104844090A (en) | Raw soil plastering binding material suitable for raw soil building blocks and preparation method of binding material | |
| CN103819144A (en) | Preparation method of epoxy mortar for filling ocean oil and gas pipeline | |
| CN107445509B (en) | Composite modified cement concrete internal curing material and preparation method thereof | |
| CN104610666A (en) | High-performance composite cable jacket material for cables | |
| CN101289619B (en) | Organic-inorganic composite material for strengthening earth site and method for preparing same | |
| CN101914229A (en) | Method for preparing kieselguhr/natural rubber composite material | |
| CN104650714A (en) | Flame-retardant waterproof coating for interior wall of building and preparation method thereof | |
| WO2019128420A1 (en) | Long-effect desert expansion inhibitor and long-effect desert expansion inhibiting method | |
| CN114409327A (en) | Environment-friendly solidified soil | |
| CN106519834A (en) | Modified polymer coating and preparation method thereof | |
| CN105419363A (en) | Preparation technology of high activity superfine alumina/epoxy resin composite modified asphalt | |
| CN108409229A (en) | A kind of graphene is modified resistance-lowering material and preparation method thereof | |
| CN101811887B (en) | Concrete curing agent and preparation method thereof | |
| CN104650715A (en) | Waterproof coating with excellent anti-aging wear-resisting property and preparation method of waterproof coating | |
| CN105585683A (en) | Method for preparing melamine formaldehyde resin flocculating agent | |
| CN104629200A (en) | Modified composite cable sheath material and preparation method thereof | |
| CN115626790B (en) | Biological material for rapidly repairing concrete microcracks and preparation method thereof | |
| CN107227057A (en) | A kind of building roof waterproofing slurry and preparation method | |
| CN106892598A (en) | A kind of geopolymer modified JS waterproofing paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180501 |