CN107974068A - A kind of flexible synthetic's leather and preparation method thereof - Google Patents

A kind of flexible synthetic's leather and preparation method thereof Download PDF

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Publication number
CN107974068A
CN107974068A CN201711496637.4A CN201711496637A CN107974068A CN 107974068 A CN107974068 A CN 107974068A CN 201711496637 A CN201711496637 A CN 201711496637A CN 107974068 A CN107974068 A CN 107974068A
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CN
China
Prior art keywords
parts
leather
powder
flexible synthetic
butanone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711496637.4A
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Chinese (zh)
Inventor
赵海英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Canan Sheng Xin Industry And Trade Co Ltd
Original Assignee
Qingdao Canan Sheng Xin Industry And Trade Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Canan Sheng Xin Industry And Trade Co Ltd filed Critical Qingdao Canan Sheng Xin Industry And Trade Co Ltd
Priority to CN201711496637.4A priority Critical patent/CN107974068A/en
Publication of CN107974068A publication Critical patent/CN107974068A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/324Alkali metal phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The invention discloses a kind of flexible synthetic leather and preparation method thereof, including following mass fraction formula components:36 50 parts of polyether resin, 12 19 parts of polytetrafluoroethylene (PTFE), 18 25 parts of polyester fiber, 37 parts of cell modifiers, 20 27 parts of ether, 16 22 parts of acrylic resin, 79 parts of nano microcrystalline powder, 11 18 parts of pine soot powder, 9 16 parts of silicone oil, 38 parts of butanone, 0.5 10.5 parts of tripolyphosphate, 39 55 parts of water, softness of the present invention is higher, manufacture method is simple, it is easy to implement, environmental pollution is smaller, can promote the use of on a large scale.

Description

A kind of flexible synthetic's leather and preparation method thereof
Technical field
The present invention relates to technical field of artificial leather, in particular to a kind of flexible synthetic leather and preparation method thereof.
Background technology
Artificial leather is the plastic products that a kind of appearance, feel can simultaneously replace that it is used like artificial leather.Usually using fabric the bottom of as Base, coats synthetic resin and the addition of various plastics is made.Last century the eighties, expensive fur clothing cladding common people consume not Rise, in response to the market demand, the artificial leather of counterfeit artificial leather once came into vogue, and was widely used in clothing, system bag.
Artificial leather is applied to the daily history used for having had some time such as clothing, thing to sit on, and particularly tannery goes out After now, more enable artificial leather more soft personal, more cause people to like.What is brought therewith is in artificial leather price Raise, meanwhile, artificial leather has been short of in feel and pliability, and manufacture method is more complicated.
The content of the invention
The present invention provides a kind of flexible synthetic leather and preparation method thereof.
To achieve the above object, the present invention provides following technical solution:
A kind of flexible synthetic's leather, including following mass fraction formula components:36-50 parts of polyether resin, polytetrafluoroethylene (PTFE) 12- 19 parts, 18-25 parts of polyester fiber, 3-7 parts of cell modifiers, 20-27 parts of ether, 16-22 parts of acrylic resin, nano microcrystalline powder 7-9 parts, 11-18 parts of pine soot powder, 9-16 parts of silicone oil, 3-8 parts of butanone, 0.5-10.5 parts of tripolyphosphate, 39-55 parts of water.
Further, including following mass fraction formula components:42 parts of polyether resin, 15 parts of polytetrafluoroethylene (PTFE), polyester fiber 22 parts, 5 parts of cell modifiers, 23 parts of ether, 19 parts of acrylic resin, 8 parts of nano microcrystalline powder, 15.5 parts of pine soot powder, silicone oil 13 Part, 5.5 parts of butanone, 5.6 parts of tripolyphosphate, 43 parts of water.
The present invention also provides a kind of preparation method of flexible synthetic leather, comprise the following steps:
By polyether resin, polytetrafluoroethylene (PTFE), polyester fiber, cell modifiers, ether, acrylic resin, nano microcrystalline powder, Pine soot powder, silicone oil, butanone, tripolyphosphate, water, put into the reaction kettle with stirring, maintain the temperature at constant temperature at 55-80 DEG C Reaction to reaction system viscosity is 200-300cP/25 DEG C, is molded, drying, you can.
Beneficial effects of the present invention:
Softness is higher, and manufacture method is simple, easy to implement, and environmental pollution is smaller, can promote the use of on a large scale.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical solution in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.Based in the present invention Embodiment, those of ordinary skill in the art's all other embodiments obtained without making creative work, all Belong to the scope of protection of the invention.
Embodiment one:
A kind of flexible synthetic's leather, including following mass fraction formula components:
36 parts of polyether resin, 12 parts of polytetrafluoroethylene (PTFE), 18 parts of polyester fiber, 3 parts of cell modifiers, 20 parts of ether, propylene 16 parts of acid resin, 7 parts of nano microcrystalline powder, 11 parts of pine soot powder, 9 parts of silicone oil, 3 parts of butanone, 0.5 part of tripolyphosphate, 39 parts of water.
A kind of preparation method of flexible synthetic's leather is as follows:
By polyether resin, polytetrafluoroethylene (PTFE), polyester fiber, cell modifiers, ether, acrylic resin, nano microcrystalline powder, Pine soot powder, silicone oil, butanone, tripolyphosphate, water, put into the reaction kettle with stirring, it is anti-to maintain the temperature at constant temperature at 55 DEG C It should be 200cP/25 DEG C to reaction system viscosity, be molded, drying, you can.
Embodiment two:
A kind of flexible synthetic's leather, including following mass fraction formula components:
42 parts of polyether resin, 15 parts of polytetrafluoroethylene (PTFE), 22 parts of polyester fiber, 5 parts of cell modifiers, 23 parts of ether, propylene 19 parts of acid resin, 8 parts of nano microcrystalline powder, 15.5 parts of pine soot powder, 13 parts of silicone oil, 5.5 parts of butanone, 5.6 parts of tripolyphosphate, water 43 Part.
A kind of preparation method of flexible synthetic's leather is as follows:
By polyether resin, polytetrafluoroethylene (PTFE), polyester fiber, cell modifiers, ether, acrylic resin, nano microcrystalline powder, Pine soot powder, silicone oil, butanone, tripolyphosphate, water, put into the reaction kettle with stirring, it is anti-to maintain the temperature at constant temperature at 70 DEG C It should be 250cP/25 DEG C to reaction system viscosity, be molded, drying, you can.
Embodiment three:
A kind of flexible synthetic's leather, including following mass fraction formula components:
50 parts of polyether resin, 19 parts of polytetrafluoroethylene (PTFE), 25 parts of polyester fiber, 7 parts of cell modifiers, 27 parts of ether, propylene 22 parts of acid resin, 9 parts of nano microcrystalline powder, 18 parts of pine soot powder, 16 parts of silicone oil, 8 parts of butanone, 10.5 parts of tripolyphosphate, 55 parts of water.
A kind of preparation method of flexible synthetic's leather is as follows:
By polyether resin, polytetrafluoroethylene (PTFE), polyester fiber, cell modifiers, ether, acrylic resin, nano microcrystalline powder, Pine soot powder, silicone oil, butanone, tripolyphosphate, water, put into the reaction kettle with stirring, it is anti-to maintain the temperature at constant temperature at 80 DEG C It should be 300cP/25 DEG C to reaction system viscosity, be molded, drying, you can.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.

Claims (3)

  1. A kind of 1. flexible synthetic's leather, it is characterised in that:Including following mass fraction formula components:
    36-50 parts of polyether resin, 12-19 parts of polytetrafluoroethylene (PTFE), 18-25 parts of polyester fiber, 3-7 parts of cell modifiers, ether 20- 27 parts, 16-22 parts of acrylic resin, 7-9 parts of nano microcrystalline powder, 11-18 parts of pine soot powder, 9-16 parts of silicone oil, 3-8 parts of butanone, three Polyphosphoric acid receives 0.5-10.5 parts, 39-55 parts of water.
  2. A kind of 2. flexible synthetic's leather according to claim 1, it is characterised in that:Including following mass fraction formula components:
    42 parts of polyether resin, 15 parts of polytetrafluoroethylene (PTFE), 22 parts of polyester fiber, 5 parts of cell modifiers, 23 parts of ether, acrylic acid tree 19 parts of fat, 8 parts of nano microcrystalline powder, 15.5 parts of pine soot powder, 13 parts of silicone oil, 5.5 parts of butanone, 5.6 parts of tripolyphosphate, 43 parts of water.
  3. A kind of 3. preparation method of the flexible synthetic's leather prepared as described in claim 1-2 any one, it is characterised in that:Including Following steps:
    By polyether resin, polytetrafluoroethylene (PTFE), polyester fiber, cell modifiers, ether, acrylic resin, nano microcrystalline powder, pine soot Powder, silicone oil, butanone, tripolyphosphate, water, put into the reaction kettle with stirring, maintain the temperature at isothermal reaction at 55-80 DEG C It is 200-300cP/25 DEG C to reaction system viscosity, is molded, drying, you can.
CN201711496637.4A 2017-12-31 2017-12-31 A kind of flexible synthetic's leather and preparation method thereof Withdrawn CN107974068A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711496637.4A CN107974068A (en) 2017-12-31 2017-12-31 A kind of flexible synthetic's leather and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711496637.4A CN107974068A (en) 2017-12-31 2017-12-31 A kind of flexible synthetic's leather and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107974068A true CN107974068A (en) 2018-05-01

Family

ID=62005589

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711496637.4A Withdrawn CN107974068A (en) 2017-12-31 2017-12-31 A kind of flexible synthetic's leather and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107974068A (en)

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Application publication date: 20180501